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Investor Presentation March 2016

Safe Harbor Statement Statements contained in this presentation that state the company’s or management’s expectations or predictions of the future are forward–looking statements intended to be covered by the safe harbor provisions of the Securities Act of 1933 and the Securities Exchange Act of 1934. The words

“believe,” “expect,” “should,” “estimates,” “intend,” and other similar expressions identify forward–looking statements. It is important to note that actual results could differ materially from those projected in such forward– looking statements. For more information concerning factors that could cause actual results to differ from those expressed or forecasted, see Valero’s annual reports on Form 10-K and quarterly reports on Form 10-Q, filed with the Securities and Exchange Commission, and available on Valero’s website

at www.valero.com.

2

Who We Are

World’s Largest Independent Refiner

Operator of Liquids-Focused Logistics Assets

• 15 refineries, 3 million barrels per day (BPD) of highcomplexity throughput capacity

• General partner and majority owner of Valero Energy Partners LP (NYSE: VLP), a fee-based master limited partnership (MLP)

• Volumes distributed through branded and unbranded channels

• Significant inventory of logistics assets within Valero

• Brands include Valero, Ultramar, Texaco, Shamrock, Diamond Shamrock and Beacon

• Greater than 70% of refining capacity located in U.S. Gulf Coast and Mid-Continent • Approximately 10,000 employees

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Wholesale Fuels Marketer

• Approximately 7,500 marketing sites in the U.S., Canada, United Kingdom and Ireland

One of North America’s Largest Renewable Fuels Producers • 11 corn ethanol plants, 1.4 billion gallons per year (85,000 BPD) production capacity • Operator and 50% owner of Diamond Green Diesel joint venture – 10,800 BPD renewable diesel production capacity

Strong U.S. Gulf Coast and Mid-Continent Presence

Refineries and ethanol plants are in advantaged locations See slide 20 for capacities

4

Current Macro Environment

SUPPLY 1

DEMAND 3

Abundant global supply of crude oil and natural gas

Forecasted world GDP growth 4

2 North American logistics build out adds efficiency and removes mid-continent bottlenecks

5

Demand response to lower product prices Structural product shortage in Latin America, Europe, Africa and Eastern Canada

See slide 19 in Appendix for notes regarding this slide and slides 25 – 28 for supply and demand details.

Expect ample supply to keep prices low, which should continue driving increased petroleum demand. 5

Safety and Reliability are Imperative for Profitability

Industry

Contractors

0.70

Process Safety Event Rate

Employees

Tier 1 Process Safety

0.41 0.38

1.60 0.97 0.75

Total Recordable Incident Rate (TRIR)

Personnel Safety 0.19

0.08

VLO’s Performance Versus Industry Benchmarks 1st Quartile

2008

2nd Quartile

2010 2012

3rd Quartile

2014 4th Quartile

Mechanical Availability

Personnel Index

Maintenance Index

Non-Energy Cash Opex

See slide 19 in Appendix for notes regarding this slide.

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Operate Safely and Reliably

Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

Energy Intensity Index

Advantaged Location in U.S. Gulf Coast Over 55% of our throughput capacity is located in U.S. Gulf Coast – Access to low cost natural gas, North American and foreign crudes, deep skilled labor pool

U.S Gulf Coast CDU Capacity (MBPD) 1,354

1,084

– Pipeline takeaway capacity additions have increased crude competition – Proximity to growing product export markets in Mexico and Latin America

743

– Competitive refined products supplier to Eastern Canada and Northwest Europe – 13.4 weighted average regional Nelson Complexity Index – Flexibility to process wide range of crudes and feedstocks

VLO

MPC

See slide 19 in Appendix for notes regarding this slide. Capacities as of January 1, 2016.

7

Operate Safely and Reliably

Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

PSX

0

0

TSO

HFC

High Complexity Refineries and Lowest Cost Operator Feedstock Ranges in U.S. Gulf Coast

2015 Refining Cash Operating Expenses Per Barrel of Throughput

(2010 – 2015)

(Excludes Turnaround and D&A)

$7

37% 34%

Peer Range

34%

VLO

Median $6.30

23% 24%

$5.40 17%

10% 12%

12%

4% $3.70 $3 Refining Peers See slide 19 in Appendix for notes regarding this slide.

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Operate Safely and Reliably

Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

Our Portfolio Facilitates Optimization of Product Exports VLO’s U.S. Product Exports (MBPD)

Gasoline

Diesel

472 412

237 164

255

Distillate 105

69 Gasoline

2011

308

2012

2013

2014

2015

Current Potential Capacity Future Capacity

Actual export volumes for 2011 – 2015. See slide 19 in Appendix for notes regarding this slide.

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Operate Safely and Reliably

Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

Capital Allocation 1

Maintain Strong Balance Sheet • Maintain investment grade credit rating and strong balance sheet

3

Sustaining Capex • Approximately $1.5 billion annually • Key to safe and reliable operations

Discretionary

2

Non-Discretionary

• Target 20% to 30% debt-to-cap ratio(1)

Dividend • Strategy is to maintain a sustainable dividend

Growth Capex

Acquisitions

Cash Returns

• Prioritize highervalue, highergrowth, quicker payback opportunities

• Evaluate versus alternative uses of cash

• Stock buybacks afford flexibility to return cash and manage capital employed • Targeting 75% payout ratio(2) for 2016

• Dividend increases compete for cash flow versus reinvestments

(1)Debt-to-cap (2) Payout

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ratio based on total debt reduced by $2 billion of cash. ratio is the sum of dividends plus stock buybacks divided by net income from continuing operations excluding special items.

Operate Safely and Reliably

Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

Capital Investments Focused on Maintaining Asset Base, Enhancing Margins, and Growing Logistics 2016 Capital Budget ($MM)

• Targeting $2.6 billion in 2016 – Includes some 2015 carry forward

• 2016 growth investments allocated approximately 50/50 for logistics and asset optimization

Asset Optimization $480

– Logistics

Logistics $460 Sustaining $1,640

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Operate Safely and Reliably

Commercial and Operational Flexibility



Approximately 95% MLP-eligible



Expect cash proceeds to VLO via drop downs to VLP

– Asset optimization •

Advantaged feedstocks and upgrading



Focused on shorter payback cycle projects



Hurdle rate of 25% IRR

Disciplined Capital Mgmt to Unlock Value

Investing in Asset Optimization

Light Crude

Products & Other

• 160 MBPD total new CDU capacity at Corpus Christi (commissioned Dec 2015) and Houston (expected 2Q16) to process up to 50 API sweet crude

• Hydrocracker expansions at Port Arthur (completed Oct 2015) and St. Charles (expected in 1H16) estimated to increase distillate yield by approximately 23 MBPD

• Replaces approximately 55 MBPD of purchased low sulfur resid for FCCs with indigenous production

• New 13 MPBD Houston alkylation unit expected to startup in 1H19 • Projects under development:

• Expect net throughput capacity increase of about 105 MBPD and annual EBITDA contribution of approximately $430 MM using 2015 prices

12

Operate Safely and Reliably

 Octane enhancement  Feedstock flexibility  FCC feed desalting  Cogeneration Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

Investing to Improve Access to North American Crude

Diamond Pipeline • • •

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440 miles of 20-inch pipe (200 MBPD capacity) connecting Memphis to Cushing, expected to startup in 3Q17 Provides supply flexibility and ability to improve crude blend quality Approximately $930 MM total project cost 

Exercised option in Dec 2015 to acquire 50% interest; approximately $140 MM spent in 2015 and $170 MM budgeted in 2016



Expect to receive cash proceeds if 50% interest is dropped to VLP and 12% pre-tax IRR for VLP

Operate Safely and Reliably

Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

Our Sponsored MLP Valero Energy Partners (NYSE:VLP) Summary

Accomplishments since IPO

• VLO owns entire 2% GP interest, all incentive distribution rights, and a 67.1% of outstanding LP interests • High-quality assets integrated with VLO’s system • Fee-based, liquids-focused revenue generation with no direct commodity price exposure

• 51% increase in quarterly cash distribution over MQD (23% CAGR as of 4Q15 distribution) • $1.3 billion of drop down transactions completed • VLO’s GP interest in VLP reached 50% split for 4Q15 distribution, paid on Feb 3

Distribution per LP Unit

4Q13* 1Q14 2Q14 3Q14 4Q14 1Q15 2Q15 3Q15 4Q15

4Q13 1Q14 2Q14 3Q14 4Q14 1Q15 2Q15 3Q15 4Q15

* This is the minimum quarterly distribution (MQD). The actual distribution was smaller as it was prorated for the period of December 16 – 31.

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Operate Safely and Reliably

Commercial and Operational Flexibility

$52.9

$2.6

$0.2125

$0.3200

Distributable Cash Flow (millions)

Disciplined Capital Mgmt to Unlock Value

More Than $1 Billion of Estimated MLP Eligible EBITDA Inventory

Pipelines(1) • Over 1,200 miles of active pipelines • 440-mile Diamond Pipeline from Cushing to Memphis expected to be commissioned in 3Q17

(1)Includes

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Racks, Terminals, and Storage(1)

Marine(1)

Rail

• Over 80 million barrels of active shell capacity for crude and products

• Three crude unloading facilities with estimated total capacity of 150 MBPD

• 139 truck rack bays

• 5,320 purchased railcars, expected to serve long-term needs in ethanol and asphalt

• 51 docks • Two Panamax class vessels

assets that have other joint venture or minority interests.

Operate Safely and Reliably

Commercial and Operational Flexibility

Disciplined Capital Mgmt to Unlock Value

Wholesale Fuels Marketing • Approximately 800 MBPD fuels distribution volume

Renewables Business

Ethanol plant in Linden, Indiana

Renewables Operations

Renewables Outlook

• 11 ethanol plants with 1.4 billion gallons total annual production capacity

• Low crude and gasoline prices expected to challenge ethanol margins

– Low capital investment with scale and location in corn belt – Operational best practices transferred from refining

• Expect ethanol demand to be strong globally, driven by increasing usage mandates, low absolute finished gasoline prices, and increased vehicle miles traveled

• Diamond Green Diesel plant – 50-50 JV with approximately 11 MBPD of renewable diesel production capacity

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Operate Safely and Reliably

Commercial and Operational Flexibility

• Expect renewable diesel margins to be supported by increased usage mandates and carbon pricing

Disciplined Capital Mgmt to Unlock Value

We Believe Valero is an Excellent Investment 2015 Total Stockholder Return

2016E Return on Capital Employed(1)

55%

Peer Range

47%

47%

VLO

2016E Price to Earnings Ratio 11x

Average

24%

9.9x 22%

21%

18% 7.0x

16% 6.4x

5.2x 11%

-8% -15%

9%

4x

We Believe VLO is Undervalued • Disciplined management team

• Delivering industry-leading returns

• Strong financial position

– Disciplined investing to drive earnings growth

• Favorable macro environment

– Unlocking value through growth in MLP-eligible assets and drop-downs to VLP

• Proven operations excellence – Reliability drives profitability

– Demonstrated commitment to capital allocation to stockholders

Chart data sources: Bloomberg and Credit Suisse as of Feb 12, 2016. See slide 19 in Appendix for notes regarding this slide. (1) Return on capital employed adjusted to add back cumulative depreciation.

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Appendix Contents Topic Notes

19

Refining Operating Statistics

20 – 21

Natural Gas Cost Sensitivity

22

Crude Oil Transportation

23 – 24

Fundamentals

25 – 28

Valero Energy Partners LP

29 – 31

Investor Relations Contacts

18

Pages

32

Notes Slide 5 Macro environment themes represent industry consultant views.

Slide 6 Contractor total recordable incident rate from U.S. Bureau of Labor Statistics. Tier 1 process safety event defined within API Recommended Practice 754. Industry benchmarking and VLO performance statistics from Solomon Associates and Valero.

Slide 7 Crude distillation capacities from company reports by geographic location.

Slide 8 Valero’s U.S. Gulf Coast feedstock ranges are based upon quarterly processing rates between 2010 and 2015. Refining cash operating expenses per barrel of throughput, excluding D&A, from company reports for MPC, TSO, and HFC. PSX operating expense data from Scotia Howard Weil.

Slide 9 Valero’s potential future gasoline and distillate export capacities are based upon potential expansion opportunities at the St. Charles and Port Arthur refineries.

Slide 17 Peer groups in total stockholder return (TSR) and 2016E price to earnings ratios (P/E) consist of PSX, MPC, TSO, HFC, PBF, WNR, and DK. Peer group in 2016E return on capital employed (ROCE) includes PSX, MPC, TSO, and PBF. Credit Suisse’s ROCE is calculated as earnings before interest and taxes, divided by the sum of stockholders’ equity and debt adjusted to add back cumulative depreciation.

19

Our Refining Capacity and Nelson Complexity Capacities (MBPD)(1) Throughput

Crude

Nelson Complexity Index

Corpus Christi(2) Houston Meraux Port Arthur St. Charles Texas City Three Rivers U.S. Gulf Coast Ardmore McKee Memphis U.S. Mid-Continent Pembroke Quebec City North Atlantic Benicia Wilmington U.S. West Coast

370 175 135 375 305 260 100 1,720 90 200 195 485 270 235 505 170 135 305

275 90 125 335 215 225 89 1,354 86 195 180 461 210 230 440 145 85 230

15.1 15.4 9.7 12.7 16.1 11.1 13.2 13.4 12.1 8.3 7.9 8.9 10.1 7.7 8.8 16.1 15.8 16.0

Total

3,015

2,485

12.0*

Refinery

(1)Capacities

and Nelson complexity indices as of Jan 1, 2016. the combined capacities of two refineries—Corpus Christi East and Corpus Christi West. 45MBPD increase in throughput compared to 2014 is related to the 70MBPD Crude Unit commissioned in December of 2015, net of 25MBPD of displaced low sulfur atmospheric resid purchases. *Weighted average. (2)Represents

20

Reliability Initiatives Have Improved Refinery Availability and Enabled Higher Utilization Valero Refinery Availability and Utilization Rates

Solomon availability

95% 92% 88%

86% 82%

21

87%

96%

95%

U.S. Natural Gas Provides Opex and Feedstock Cost Advantages • Our refining operations consume approximately 896,000 mmBtu/day of natural gas, of which 56% is operating expense and balance is cost of goods sold • Significant annual pre-tax cost savings compared to refiners in Europe or Asia • Prices expected to remain low and disconnected from global oil and gas markets

Natural Gas Cost Sensitivity for Valero’s Refineries

$1.7 billion higher pre-tax annual costs

$2.20/mmBtu U.S. $0.70/bbl

$0.75 billion higher pre-tax annual costs

$9.60/mmBtu Asian LNG $3.20/bbl

$4.40/mmBtu Europe $1.50/bbl

Natural gas prices month to date as of Oct 31, 2015 for Asia and year to date as of Feb 16, 2016 for U.S. and Europe. Estimated per barrel cost of 896,000 mmBtu/day of natural gas consumption at 93% refinery throughput capacity utilization, or 2.8 MMBPD.

22

Estimated Crude Oil Transportation Costs to Eastern Canada Rail $9 to $10/bbl

Alberta

Rail $9/bbl

Alberta to Bakken $1 to $2/bbl

Bakken U.S. Ship $4 to $5/bbl to West Coast Rail $11 to $13/bbl

to Cushing Pipe $5 to $6/bbl

to USEC Rail $10 to $11/bbl

USGC to Canada Foreign Ship $2/bbl

Brent to USEC $2/bbl

to Cushing Rail $7/bbl to St. James Rail $9/bbl Cushing

Midland

to Houston Pipe $2 to $4/bbl

to Houston Pipe $3/bbl Corpus Christi to Houston $1 to $2/bbl 23

Houston to St. James $1 to $2 /bbl

USGC to USEC U.S. Ship $4/bbl

USGC to Europe Foreign Ship $2-3/bbl

Pipeline Takeaway Capacity Additions Have Increased Crude Competition in the U.S. Gulf Coast Alberta

Bakken

Niobrara

Cushing Permian

• Discounts for inland crudes versus WTI and Brent expected to narrow

KEY Completed 2014 – 15 2016 or Later Startup

Eagle Ford

Capacities in MBPD. Pipeline completion and startup dates are subject to change.

24

• Pipeline takeaway capacity additions expected to increase market liquidity and crude competition in U.S. Gulf Coast

• Eagle Ford and Houston WTI likely to price at quality adjusted differentials to LLS

Production Growth Provides Resource Advantage to North American Refiners U.S. Crude Oil Production and Imports

U.S. Natural Gas Production

(MBPD)

(Bcf/day)

Imports

Production 74

9,447 9,212

7,312 58 5,475

Source: DOE, 2015 data through November

25

Global Petroleum Demand Growth Expected to Outpace Refinery Capacity Expansion MMBPD

2.0 1.6 1.2 0.8 0.4

0.0 -0.4 -0.8 2012 Europe

China

2013 Middle East

Other

2014 Net CDU Capacity Additions

2015E

World Petroleum Demand Growth

Source: Consultant and Valero estimates. Net Global Refinery CDU Additions = New Capacity + Restarts – Announced Closures.

26

2016E

U.S. Gasoline Exports 800

12 Month Moving Average Other

700 600 500

(MBPD)

Europe Other Latin America Mexico Canada

400 300

Latest 4 Wk avg estimate (Finished only)

200 100 0 2005

2006

2007

2008

2009

2010

2011

2012

2013

2014

2015

Gasoline represents all finished gasoline plus all blendstocks (including ethanol, MTBE, and other oxygenates) Source: DOE Petroleum Supply Monthly data through November 2015. 4 Week Average estimate from Weekly Petroleum Statistics Report and Valero estimates.

27

U.S. Diesel Exports 1400

12 Month Moving Average (MBPD)

1200 1000

Other Europe Other Latin America

800

Mexico Canada

600

Latest 4 Wk avg estimate 400 200 0 2005

2006

2007

2008

2009

2010

2011

2012

2013

2014

Source: DOE Petroleum Supply Monthly data through November 2015. 4 Week Average estimate from Weekly Petroleum Statistics Report.

28

2015

VLP’s Competitive Strengths Strong Sponsor

Quality Assets

Stable Revenues

• Strategic relationship with investment grade sponsor VLO

• High quality, well maintained assets integrated with VLO’s refineries and located in advantaged regions

• Stable and predictable cash flows from long term, fee-based contracts with no direct exposure to commodity price risks

• High level of minimum volume commitments from VLO

Long Runway for Growth • Drop downs from sponsor to primarily fuel growth • Opportunities to diversify business and develop third party volumes as VLP matures

29

Strong Balance Sheet • Minimal debt and ample liquidity provides opportunities for accretive acquisitions • Targeting investment grade credit ratings

Top Tier Distribution Growth • 23% CAGR for distributions since IPO • Targeting distributions to grow at about 25% for next couple of years

VLP Assets Located in U.S. Gulf Coast and Mid-Continent IPO assets Drop downs

Texas Crude Systems McKee, Three Rivers, Wynnewood July 1, 2014 - $154 mm(1) Houston and St. Charles Terminals March 1, 2015 - $671 mm(1)

Corpus Christi Terminals October 1, 2015 - $465 mm(1) (1)Total

consideration value.

VLP’s assets are integrated with Valero’s refining system 30

VLP Unit Price Outperformed Peers since 2014 VLP

TLLP

MPLX

PSXP

$85

-14%

-8% -32%

-65%

$15

Prices through Feb 25 close.

31

Investor Relations Contacts

For more information, please contact: John Locke

32

Karen Ngo

Vice President, Investor Relations

Manager, Investor Relations

210.345.3077

210.345.4574

[email protected]

[email protected]

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