AKS784 SODIUM THIOPHENOXIDE, tech 95 GHS EU English
AKS784 - SODIUM THIOPHENOXIDE, tech-95
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet AKS784 Date of issue: 23/02/2015
Revision date: 01/09/2015
Version: 2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Substance
Physical state
: Solid
Substance name
: SODIUM THIOPHENOXIDE, tech-95
Product code
: AKS784
Formula
: C6H5NaS
Synonyms
: BENZENETHIOL, SODIUM ; SODIUM BENZENETHIOLATE
Chemical family
: ORGANIC SALT
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Use of the substance/mixture
1.2.2.
: Chemical intermediate For research and industrial use only
Uses advised against
No additional information available 1.3.
Details of the supplier of the safety data sheet
GELEST, INC. 11 East Steel Road Morrisville, PA 19067 USA T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST [email protected] - www.gelest.com GELEST INC. Stroofstrasse 27 Geb.2901 65933 Frankfurt am Main Germany T +49-(0)-69-3800-2150 - F +49-(0)-69-3800-2300 - (M-F): 8:00 AM - 5:30 PM [email protected] - www.gelestde.com 1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 1B
H314
Serious eye damage/eye irritation, Category H318 1 Specific target organ toxicity — Single H335 exposure, Category 3, Respiratory tract irritation Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects No additional information available
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
:
GHS05
Print date: 29/01/2018
EN (English)
GHS07
SDS ID: AKS784
1/8
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet Signal word (CLP)
: Danger
Hazard statements (CLP)
: H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation
Precautionary statements (CLP)
: P280 - Wear protective gloves/protective clothing/eye protection/face protection P260 - Do not breathe dust P264 - Wash hands thoroughly after handling P403+P233 - Store in a well-ventilated place. Keep container tightly closed P271 - Use only outdoors or in a well-ventilated area P310 - Immediately call a POISON CENTER or doctor/physician
2.3.
Other hazards
No additional information available
SECTION 3: Composition/information on ingredients 3.1.
Substances
Substance type
: Mono-constituent
Name
: SODIUM THIOPHENOXIDE, tech-95
CAS-No.
: 930-69-8
EC-No.
: 213-224-0
Name
Product identifier
%
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Benzenethiol thiophenoxide
(CAS-No.) 930-69-8 (EC-No.) 213-224-0
95 - 100
Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335
Full text of H-statements: see section 16 3.2.
Mixtures
Not applicable
SECTION 4: First aid measures 4.1.
Description of first aid measures
First-aid measures general
: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label.
First-aid measures after inhalation
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice.
First-aid measures after skin contact
: Wash with plenty of soap and water. Get medical advice/attention.
First-aid measures after eye contact
: Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion
: Never give anything by mouth to an unconscious person. Get medical advice/attention.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/effects
: Causes severe skin burns and eye damage.
Symptoms/effects after inhalation
: May cause respiratory irritation. Inhalation will cause sneezing, irritation and burns.
Symptoms/effects after skin contact
: Causes (severe) skin burns.
Symptoms/effects after eye contact
: Causes serious eye damage.
Symptoms/effects after ingestion
: May be harmful if swallowed.
4.3.
Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures 5.1.
Extinguishing media
Suitable extinguishing media 5.2.
Special hazards arising from the substance or mixture
Fire hazard 5.3.
: Dry chemical. Dry soda ash. Dry sodium chloride.
: Irritating fumes and caustic vapors may develop when material is exposed to elevated temperatures or open flame.
Advice for firefighters
Firefighting instructions
Print date: 29/01/2018
: Exercise caution when fighting any chemical fire.
EN (English)
SDS ID: AKS784
2/8
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection. Avoid contact with skin and eyes. Do not breathe dust. Wear pressure demand self-contained breathing apparatus with full facepiece and full protective clothing.
SECTION 6: Accidental release measures 6.1.
Personal precautions, protective equipment and emergency procedures
6.1.1.
For non-emergency personnel
Emergency procedures 6.1.2.
For emergency responders
Protective equipment 6.2.
: Evacuate unnecessary personnel.
: Equip cleanup crew with proper protection.
Environmental precautions
Notify authorities if product enters sewers or public waters. 6.3.
Methods and material for containment and cleaning up
Methods for cleaning up 6.4.
: Sweep or shovel spills into appropriate container for disposal.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage 7.1.
Precautions for safe handling
Precautions for safe handling
: Avoid contact with skin and eyes. Do not breathe dust. Provide local exhaust or general room ventilation to minimize exposure to dust.
Hygiene measures
: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
7.2.
Conditions for safe storage, including any incompatibilities
Storage conditions
: Keep container tightly closed. Store under dry nitrogen or argon in sealed containers.
Incompatible materials
: Air. Water :
Storage area
: Store in a well-ventilated place. Store away from heat.
7.3.
Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection 8.1.
Control parameters
Benzenethiol thiophenoxide (930-69-8) USA OSHA OSHA PEL (TWA) (ppm) 8.2.
0.5 ppm Thiophenol
Exposure controls
Appropriate engineering controls: Handle in an enclosing hood with exhaust ventilation. Personal protective equipment: Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Hand protection: Neoprene or nitrile rubber gloves Eye protection: Chemical goggles. Contact lenses should not be worn Skin and body protection: Wear suitable protective clothing Respiratory protection: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified dust and mist (orange cartridge) respirator.
SECTION 9: Physical and chemical properties 9.1.
Information on basic physical and chemical properties
Physical state
: Solid
Appearance
: Powder.
Print date: 29/01/2018
EN (English)
SDS ID: AKS784
3/8
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet Molecular mass
: 132.17 g/mol
Colour
: Off-white. Brown.
Odour
: Disagreeable sulfur odor.
Odour threshold
: No data available
Refractive index
: No additional information available
pH
: No data available
Relative evaporation rate (butylacetate=1)
: No data available
Melting point
: > 300 °C decomposes
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapour pressure
: No data available
Relative vapour density at 20 °C
: No data available
Relative density
: >1
% Volatiles
:
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet AKS784 Date of issue: 23/02/2015
Revision date: 01/09/2015
Version: 2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Substance
Physical state
: Solid
Substance name
: SODIUM THIOPHENOXIDE, tech-95
Product code
: AKS784
Formula
: C6H5NaS
Synonyms
: BENZENETHIOL, SODIUM ; SODIUM BENZENETHIOLATE
Chemical family
: ORGANIC SALT
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Use of the substance/mixture
1.2.2.
: Chemical intermediate For research and industrial use only
Uses advised against
No additional information available 1.3.
Details of the supplier of the safety data sheet
GELEST, INC. 11 East Steel Road Morrisville, PA 19067 USA T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST [email protected] - www.gelest.com GELEST INC. Stroofstrasse 27 Geb.2901 65933 Frankfurt am Main Germany T +49-(0)-69-3800-2150 - F +49-(0)-69-3800-2300 - (M-F): 8:00 AM - 5:30 PM [email protected] - www.gelestde.com 1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 1B
H314
Serious eye damage/eye irritation, Category H318 1 Specific target organ toxicity — Single H335 exposure, Category 3, Respiratory tract irritation Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects No additional information available
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
:
GHS05
Print date: 29/01/2018
EN (English)
GHS07
SDS ID: AKS784
1/8
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet Signal word (CLP)
: Danger
Hazard statements (CLP)
: H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation
Precautionary statements (CLP)
: P280 - Wear protective gloves/protective clothing/eye protection/face protection P260 - Do not breathe dust P264 - Wash hands thoroughly after handling P403+P233 - Store in a well-ventilated place. Keep container tightly closed P271 - Use only outdoors or in a well-ventilated area P310 - Immediately call a POISON CENTER or doctor/physician
2.3.
Other hazards
No additional information available
SECTION 3: Composition/information on ingredients 3.1.
Substances
Substance type
: Mono-constituent
Name
: SODIUM THIOPHENOXIDE, tech-95
CAS-No.
: 930-69-8
EC-No.
: 213-224-0
Name
Product identifier
%
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Benzenethiol thiophenoxide
(CAS-No.) 930-69-8 (EC-No.) 213-224-0
95 - 100
Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335
Full text of H-statements: see section 16 3.2.
Mixtures
Not applicable
SECTION 4: First aid measures 4.1.
Description of first aid measures
First-aid measures general
: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label.
First-aid measures after inhalation
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice.
First-aid measures after skin contact
: Wash with plenty of soap and water. Get medical advice/attention.
First-aid measures after eye contact
: Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion
: Never give anything by mouth to an unconscious person. Get medical advice/attention.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/effects
: Causes severe skin burns and eye damage.
Symptoms/effects after inhalation
: May cause respiratory irritation. Inhalation will cause sneezing, irritation and burns.
Symptoms/effects after skin contact
: Causes (severe) skin burns.
Symptoms/effects after eye contact
: Causes serious eye damage.
Symptoms/effects after ingestion
: May be harmful if swallowed.
4.3.
Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures 5.1.
Extinguishing media
Suitable extinguishing media 5.2.
Special hazards arising from the substance or mixture
Fire hazard 5.3.
: Dry chemical. Dry soda ash. Dry sodium chloride.
: Irritating fumes and caustic vapors may develop when material is exposed to elevated temperatures or open flame.
Advice for firefighters
Firefighting instructions
Print date: 29/01/2018
: Exercise caution when fighting any chemical fire.
EN (English)
SDS ID: AKS784
2/8
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection. Avoid contact with skin and eyes. Do not breathe dust. Wear pressure demand self-contained breathing apparatus with full facepiece and full protective clothing.
SECTION 6: Accidental release measures 6.1.
Personal precautions, protective equipment and emergency procedures
6.1.1.
For non-emergency personnel
Emergency procedures 6.1.2.
For emergency responders
Protective equipment 6.2.
: Evacuate unnecessary personnel.
: Equip cleanup crew with proper protection.
Environmental precautions
Notify authorities if product enters sewers or public waters. 6.3.
Methods and material for containment and cleaning up
Methods for cleaning up 6.4.
: Sweep or shovel spills into appropriate container for disposal.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage 7.1.
Precautions for safe handling
Precautions for safe handling
: Avoid contact with skin and eyes. Do not breathe dust. Provide local exhaust or general room ventilation to minimize exposure to dust.
Hygiene measures
: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
7.2.
Conditions for safe storage, including any incompatibilities
Storage conditions
: Keep container tightly closed. Store under dry nitrogen or argon in sealed containers.
Incompatible materials
: Air. Water :
Storage area
: Store in a well-ventilated place. Store away from heat.
7.3.
Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection 8.1.
Control parameters
Benzenethiol thiophenoxide (930-69-8) USA OSHA OSHA PEL (TWA) (ppm) 8.2.
0.5 ppm Thiophenol
Exposure controls
Appropriate engineering controls: Handle in an enclosing hood with exhaust ventilation. Personal protective equipment: Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Hand protection: Neoprene or nitrile rubber gloves Eye protection: Chemical goggles. Contact lenses should not be worn Skin and body protection: Wear suitable protective clothing Respiratory protection: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified dust and mist (orange cartridge) respirator.
SECTION 9: Physical and chemical properties 9.1.
Information on basic physical and chemical properties
Physical state
: Solid
Appearance
: Powder.
Print date: 29/01/2018
EN (English)
SDS ID: AKS784
3/8
SODIUM THIOPHENOXIDE, tech-95 Safety Data Sheet Molecular mass
: 132.17 g/mol
Colour
: Off-white. Brown.
Odour
: Disagreeable sulfur odor.
Odour threshold
: No data available
Refractive index
: No additional information available
pH
: No data available
Relative evaporation rate (butylacetate=1)
: No data available
Melting point
: > 300 °C decomposes
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapour pressure
: No data available
Relative vapour density at 20 °C
: No data available
Relative density
: >1
% Volatiles
:
