AKZ934 ZINC METHOXYETHOXIDE, 95% GHS EU English

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AKZ934 - ZINC METHOXYETHOXIDE, 95%

ZINC METHOXYETHOXIDE, 95% Safety Data Sheet AKZ934 Date of issue: 13/03/2015

Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.

Product identifier

Product form

: Substance

Physical state

: Solid

Substance name

: ZINC METHOXYETHOXIDE, 95%

Product code

: AKZ934

Formula

: C6H14O4Zn

Synonyms

: ZINC METHOXYETHYLATE

Chemical family

: METAL COMPOUND

1.2.

Relevant identified uses of the substance or mixture and uses advised against

1.2.1.

Relevant identified uses

Use of the substance/mixture

1.2.2.

: Chemical intermediate For research use only

Uses advised against

No additional information available 1.3.

Details of the supplier of the safety data sheet

GELEST, INC. 11 East Steel Road Morrisville, PA 19067 USA T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST [email protected] - www.gelest.com GELEST INC. Stroofstrasse 27 Geb.2901 65933 Frankfurt am Main Germany T +49-(0)-69-3800-2150 - F +49-(0)-69-3800-2300 - (M-F): 8:00 AM - 5:30 PM [email protected] - www.gelestde.com 1.4.

Emergency telephone number

Emergency number

: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)

SECTION 2: Hazards identification 2.1.

Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation, Category H319 2 Reproductive toxicity, Category 1B H360 Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects No additional information available

2.2.

Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)

:

Signal word (CLP)

: Danger

Hazard statements (CLP)

: H319 - Causes serious eye irritation

GHS07

Print date: 29/01/2018

EN (English)

GHS08

SDS ID: AKZ934

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ZINC METHOXYETHOXIDE, 95% Safety Data Sheet H360 - May damage fertility or the unborn child Precautionary statements (CLP)

2.3.

: P202 - Do not handle until all safety precautions have been read and understood P280 - Wear protective gloves/protective clothing/eye protection/face protection P264 - Wash hands thoroughly after handling P337+P313 - If eye irritation persists: Get medical advice/attention P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - IF exposed or concerned: Get medical advice/attention

Other hazards

No additional information available

SECTION 3: Composition/information on ingredients 3.1.

Substances

Substance type

: Multi-constituent

Name

: ZINC METHOXYETHOXIDE, 95%

CAS-No.

: 129918-15-6

Name

Product identifier

%

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Zinc methoxyethoxide

(CAS-No.) 129918-15-6

> 95

Eye Irrit. 2, H319

2-Methoxyethanol

(CAS-No.) 109-86-4 (EC-No.) 203-713-7 (EC Index-No.) 603-011-00-4

130 °C decomposes

Freezing point

: No data available

Boiling point

: No data available

Flash point

: No data available

Auto-ignition temperature

: No data available

Decomposition temperature

: No data available

Flammability (solid, gas)

: No data available

Vapour pressure

: No data available

Relative vapour density at 20 °C

: No data available

Relative density

: >1

Solubility

: No data available

Log Pow

: No data available

Log Kow

: No data available

Viscosity, kinematic

: No data available

Viscosity, dynamic

: No data available

Explosive properties

: No data available

Oxidising properties

: No data available

Explosive limits

: No data available

9.2.

Other information

No additional information available

SECTION 10: Stability and reactivity 10.1.

Reactivity

No additional information available 10.2.

Chemical stability

Stable. 10.3.

Possibility of hazardous reactions

Material decomposes slowly in contact with water. 10.4.

Conditions to avoid

Heat. Open flame. Sparks. 10.5.

Incompatible materials

Water : 10.6.

Hazardous decomposition products

Organic acid vapors. Zinc oxide fumes.

SECTION 11: Toxicological information 11.1.

Information on toxicological effects

Acute toxicity

: Not classified

2-Methoxyethanol (109-86-4) LD50 oral rat LD50 dermal rabbit Print date: 29/01/2018

2370 mg/kg 2460 mg/kg 1280 mg/kg EN (English)

SDS ID: AKZ934

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ZINC METHOXYETHOXIDE, 95% Safety Data Sheet 2-Methoxyethanol (109-86-4) LC50 inhalation rat (ppm) ATE CLP (oral) ATE CLP (dermal) ATE CLP (vapours)

1478 ppm (Exposure time: 7 h) 500 mg/kg bodyweight 1280 mg/kg bodyweight 11 mg/l/4h

Skin corrosion/irritation

: Not classified

Serious eye damage/irritation

: Causes serious eye irritation.

Respiratory or skin sensitisation

: Not classified

Germ cell mutagenicity

: Not classified

Carcinogenicity

: Not classified

Reproductive toxicity

: May damage fertility or the unborn child.

STOT-single exposure

: Not classified

STOT-repeated exposure

: Not classified

Aspiration hazard

: Not classified

Potential adverse human health effects and symptoms

: Health hazards of this material are expected to be associated with the hydrolysis products: methoxyethanol and zinc oxide.

Symptoms/effects after inhalation

: May cause irritation to the respiratory tract.

Symptoms/effects after skin contact

: May cause skin irritation.

Symptoms/effects after eye contact

: Causes serious eye irritation.

Symptoms/effects after ingestion

: May be harmful if swallowed.

Reason for classification

: Expert judgment

SECTION 12: Ecological information 12.1.

Toxicity

Acute aquatic toxicity

: Not classified

Chronic aquatic toxicity

: Not classified

2-Methoxyethanol (109-86-4) LC50 fish 1 LC50 fish 2 12.2.

10000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) 9650 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])

Persistence and degradability

No additional information available 12.3.

Bioaccumulative potential

2-Methoxyethanol (109-86-4) Log Pow 12.4.

-0.85

Mobility in soil

No additional information available 12.5.

Results of PBT and vPvB assessment

Component 2-Methoxyethanol (109-86-4) 12.6.

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

Other adverse effects

No additional information available

SECTION 13: Disposal considerations 13.1.

Waste treatment methods

Product/Packaging disposal recommendations

: Dispose of solid materials or residues at a licensed site. Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials

: Avoid release to the environment.

SECTION 14: Transport information 14.1.

UN number

Not regulated for transport. 14.2.

UN proper shipping name

Not applicable 14.3.

Transport hazard class(es)

Not applicable Print date: 29/01/2018

EN (English)

SDS ID: AKZ934

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ZINC METHOXYETHOXIDE, 95% Safety Data Sheet 14.4.

Packing group

Not applicable 14.5.

Environmental hazards

Other information 14.6.

Special precautions for user

14.6.1.

Overland transport

: No supplementary information available.

No additional information available 14.6.2.

Transport by sea

No additional information available 14.6.3.

Air transport

No additional information available 14.7.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

SECTION 15: Regulatory information 15.1.

Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1.

EU-Regulations

No REACH Annex XVII restrictions ZINC METHOXYETHOXIDE, 95% is not on the REACH Candidate List Contains a substance on the REACH candidate list in concentration ≥ 0.1% or with a lower specific limit: 2-Methoxyethanol (EC 203-713-7, CAS 109-86-4) ZINC METHOXYETHOXIDE, 95% is not on the REACH Annex XIV List 15.1.2.

National regulations

Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV

: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)

Netherlands SZW-lijst van kankerverwekkende stoffen

: The substance is not listed

SZW-lijst van mutagene stoffen

: The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding

: The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid

: The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling

: The substance is not listed

Denmark Recommendations Danish Regulation

: Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal

ZINC METHOXYETHOXIDE, 95% (129918-15-6) TSCA Exemption/Exclusion CAUTION: This material is supplied for research and development purposes subject to the R&D exemption under TSCA, 40 CFR 720.36, and must meet the requirements of the exemption, including supervision by a "technically qualified individual" as defined by 40 CFR 720.3(ee). The use of this material for "commercial purposes" as defined by 40 CFR 720.3(r) is not permitted in the United States. Zinc methoxyethoxide (129918-15-6) Not listed on the United States TSCA (Toxic Substances Control Act) inventory

Print date: 29/01/2018

EN (English)

SDS ID: AKZ934

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ZINC METHOXYETHOXIDE, 95% Safety Data Sheet 2-Methoxyethanol (109-86-4) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Substances List) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Japanese Pollutant Release and Transfer Register Law (PRTR Law) Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican National Inventory of Chemical Substances) Listed on Turkish inventory of chemical 15.2.

Chemical safety assessment

No additional information available

SECTION 16: Other information Abbreviations and acronyms

: Abbreviations: ND: Not Determined, No Data; NA: Not Applicable; LD: Lethal Dose; LC: Lethal Concentration; ATE: Acute Toxicity Estimates; H: hour; °: °C unless otherwise stated; mm: millimeters Hg, torr; PEL: permissible exposure level; TWA: time weighted average; TLV: threshold limit value; TG: Test Guideline; NIOSH: National Institute for Occupational Safety and Health; IARC: International Agency for Research on Cancer; NTP: National Toxicology Program; HMIS: Hazardous Material Information System; CAS No.: Chemcial Abstract Service Registration Number; EC No.: European Commission Registration Number; EC Index No.: European Commission Index Number; OECD: The Organisation for Economic Co-operation and Development; GHS: The Globally Harmonized System of Classification and Labelling; APF: Assigned Protection Factor.

Full text of H- and EUH-statements: Acute Tox. 4 (Dermal) Acute Tox. 4 (Inhalation) Acute Tox. 4 (Oral) Eye Irrit. 2 Flam. Liq. 3 Repr. 1B Repr. 1B H226 H302 H312 H319 H332 H360 H360FD

Acute toxicity (dermal), Category 4 Acute toxicity (inhal.), Category 4 Acute toxicity (oral), Category 4 Serious eye damage/eye irritation, Category 2 Flammable liquids, Category 3 Reproductive toxicity, Category 1B Reproductive toxicity, Category 1B Flammable liquid and vapour Harmful if swallowed Harmful in contact with skin Causes serious eye irritation Harmful if inhaled May damage fertility or the unborn child May damage fertility. May damage the unborn child

Prepared by safety and environmental affairs.

SDS EU (REACH Annex II) - Custom according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 The information contained in this document has been gathered from reference materials and/or Gelest, Inc. test data and is to the best knowledge and belief of Gelest, Inc. accurate and reliable. Such information is offered solely for your consideration, investigation and verification. It is not suggested or guaranteed that the hazard precautions or procedures described are the only ones which exist. Gelest, Inc. makes no warranties, express or implied, with respect to the use of such information and assumes no responsibility therefore. Information on this safety data sheet is not intended to constitute a basis for product specifications. © 2018 Gelest Inc. Morrisville, PA 19067

Print date: 29/01/2018

EN (English)

SDS ID: AKZ934

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