Appendix D Air Quality

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APPENDIX D AIR QUALITY STANDARDS AND CALCULATIONS

Ambient Air Quality Standards Pollutant

Averaging Time

California Standards 1 Concentration

3

1 Hour

0.09 ppm (180 µg/m3)

8 Hour

3

Method

Fine Particulate Matter (PM2.5)8 Carbon Monoxide (CO)

Nitrogen 9 Dioxide (NO2)

Sulfur Dioxide (SO2)10

Lead11,12

4

Ultraviolet Photometry

Ozone (O3)

24 Hour Respirable Particulate Annual 8 Matter (PM10) Arithmetic Mean

National Standards 2

0.070 ppm (137 µg/m )

Primary

3,5

Secondary

— 3

3,6

Same as Primary Standard

Ultraviolet Photometry

Same as Primary Standard

Inertial Separation and Gravimetric Analysis

150 µg/m3 Gravimetric or Beta Attenuation



24 Hour





35 µg/m3

Same as Primary Standard

Annual Arithmetic Mean

12 µg/m3

Gravimetric or Beta Attenuation

12.0 µg/m3

15 µg/m3

1 Hour

20 ppm (23 mg/m3)

35 ppm (40 mg/m3)



9 ppm (10 mg/m3)







100 ppb (188 µg/m3)



8 Hour

9.0 ppm (10 mg/m3)

8 Hour (Lake Tahoe)

6 ppm (7 mg/m3)

1 Hour

0.18 ppm (339 µg/m3)

Non-Dispersive Infrared Photometry (NDIR)

Gas Phase Chemiluminescence

Annual Arithmetic Mean

0.030 ppm (57 µg/m )

0.053 ppm (100 µg/m )

Same as Primary Standard

1 Hour

0.25 ppm (655 µg/m3)

75 ppb (196 µg/m3)



3 Hour





0.5 ppm (1300 µg/m3)

24 Hour

0.04 ppm (105 µg/m3)

0.14 ppm (for certain areas)10



Annual Arithmetic Mean



0.030 ppm (for certain areas)10



30 Day Average

1.5 µg/m3





Calendar Quarter



3

7

0.075 ppm (147 µg/m )

50 µg/m3 20 µg/m3

Method

Ultraviolet Fluorescence

Atomic Absorption

Rolling 3-Month Average



Visibility Reducing Particles13

8 Hour

See footnote 13

Beta Attenuation and Transmittance through Filter Tape

Sulfates

24 Hour

25 µg/m3

Ion Chromatography

Hydrogen Sulfide

1 Hour

0.03 ppm (42 µg/m3)

Ultraviolet Fluorescence

Vinyl Chloride11

24 Hour

0.01 ppm (26 µg/m3)

Gas Chromatography

3

1.5 µg/m3 (for certain areas)12

Same as Primary Standard

Inertial Separation and Gravimetric Analysis

Non-Dispersive Infrared Photometry (NDIR)

Gas Phase Chemiluminescence

Ultraviolet Flourescence; Spectrophotometry (Pararosaniline Method)

High Volume Sampler and Atomic Absorption

0.15 µg/m3

No National

Standards

See footnotes on next page … For more information please call ARB-PIO at (916) 322-2990

California Air Resources Board (6/4/13)

1.

California standards for ozone, carbon monoxide (except 8-hour Lake Tahoe), sulfur dioxide (1 and 24 hour), nitrogen dioxide, and particulate matter (PM10, PM2.5, and visibility reducing particles), are values that are not to be exceeded. All others are not to be equaled or exceeded. California ambient air quality standards are listed in the Table of Standards in Section 70200 of Title 17 of the California Code of Regulations.

2.

National standards (other than ozone, particulate matter, and those based on annual arithmetic mean) are not to be exceeded more than once a year. The ozone standard is attained when the fourth highest 8-hour concentration measured at each site in a year, averaged over three years, is equal to or less than the standard. For PM10, the 24 hour standard is attained when the expected number of days per 3 calendar year with a 24-hour average concentration above 150 µg/m is equal to or less than one. For PM2.5, the 24 hour standard is attained when 98 percent of the daily concentrations, averaged over three years, are equal to or less than the standard. Contact the U.S. EPA for further clarification and current national policies.

3.

Concentration expressed first in units in which it was promulgated. Equivalent units given in parentheses are based upon a reference temperature of 25°C and a reference pressure of 760 torr. Most measurements of air quality are to be corrected to a reference temperature of 25°C and a reference pressure of 760 torr; ppm in this table refers to ppm by volume, or micromoles of pollutant per mole of gas.

4.

Any equivalent measurement method which can be shown to the satisfaction of the ARB to give equivalent results at or near the level of the air quality standard may be used.

5.

National Primary Standards: The levels of air quality necessary, with an adequate margin of safety to protect the public health.

6.

National Secondary Standards: The levels of air quality necessary to protect the public welfare from any known or anticipated adverse effects of a pollutant.

7.

Reference method as described by the U.S. EPA. An “equivalent method” of measurement may be used but must have a “consistent relationship to the reference method” and must be approved by the U.S. EPA.

8.

On December 14, 2012, the national annual PM2.5 primary standard was lowered from 15 µg/m3 to 12.0 µg/m3. The existing national 24hour PM2.5 standards (primary and secondary) were retained at 35 µg/m3, as was the annual secondary standard of 15 µg/m3. The existing 24-hour PM10 standards (primary and secondary) of 150 µg/m3 also were retained. The form of the annual primary and secondary standards is the annual mean, averaged over 3 years.

9.

To attain the 1-hour national standard, the 3-year average of the annual 98th percentile of the 1-hour daily maximum concentrations at each site must not exceed 100 ppb. Note that the national 1-hour standard is in units of parts per billion (ppb). California standards are in units of parts per million (ppm). To directly compare the national 1-hour standard to the California standards the units can be converted from ppb to ppm. In this case, the national standard of 100 ppb is identical to 0.100 ppm.

10.

On June 2, 2010, a new 1-hour SO2 standard was established and the existing 24-hour and annual primary standards were revoked. To attain the 1-hour national standard, the 3-year average of the annual 99th percentile of the 1-hour daily maximum concentrations at each site must not exceed 75 ppb. The 1971 SO2 national standards (24-hour and annual) remain in effect until one year after an area is designated for the 2010 standard, except that in areas designated nonattainment for the 1971 standards, the 1971 standards remain in effect until implementation plans to attain or maintain the 2010 standards are approved. Note that the 1-hour national standard is in units of parts per billion (ppb). California standards are in units of parts per million (ppm). To directly compare the 1-hour national standard to the California standard the units can be converted to ppm. In this case, the national standard of 75 ppb is identical to 0.075 ppm.

11.

The ARB has identified lead and vinyl chloride as 'toxic air contaminants' with no threshold level of exposure for adverse health effects determined. These actions allow for the implementation of control measures at levels below the ambient concentrations specified for these pollutants.

12.

The national standard for lead was revised on October 15, 2008 to a rolling 3-month average. The 1978 lead standard (1.5 µg/m3 as a quarterly average) remains in effect until one year after an area is designated for the 2008 standard, except that in areas designated nonattainment for the 1978 standard, the 1978 standard remains in effect until implementation plans to attain or maintain the 2008 standard are approved.

13.

In 1989, the ARB converted both the general statewide 10-mile visibility standard and the Lake Tahoe 30-mile visibility standard to instrumental equivalents, which are "extinction of 0.23 per kilometer" and "extinction of 0.07 per kilometer" for the statewide and Lake Tahoe Air Basin standards, respectively. For more information please call ARB-PIO at (916) 322-2990

California Air Resources Board (6/4/13)

November 18, 2011 AMEC Project Number 7551005103

Montecito Fire Station Emergency Generator Emissions

Emission Factors CO (g/kW-hr) 0.90000 Rating (KW) 80

Rating (hp) 107.3

Operating Hours/yr 500

NOx (g/kW-hr) 3.610

SOx (lb/hp-hr) 0.00205

PM10 (g/kW-hr) 0.1600

1

PM2.5 (g/kW-hr) 0.1600

VOC (g/kW-hr) 0.19000

CO2 (lb/hp-hr) 1.15

Total HAPs (lb/MMBTU) 0.00632

0.034

92.00

0.0047

0.80

2208.00

0.114

0.008

23

0.00119

Emissions (lb/hr) 0.16

0.64

0.22

0.028

3.81

15.28

5.28

0.68

0.04

0.16

0.05498

0.0071

0.028

Emissions (lbs/day) (based on 24 hr operation) 0.68

Emissions (tons/yr) 0.0071

1. Emission in g/kW-hr taken from manufacturer's spec sheet and factors in lb/hp-hr taken from AP-42, Table 3.3-1 and 3.3-2 for Diesel Fired Engines (full load conditions) Emission (lb/hr) = EF (lb/hp-hr) * 107.3 (hp)

or EF (g/kW-hr) * 80 kW / 453.59 (g/lb)

Emission (lb/hr) = EF (lb/MMBTU) * 0.007 (MMBTU / hp-hr) * 107.3 (hp) Based on ARB Diesel Engine Screening Risk Assessment Tables at 50% load there is no cancer risk beyond 200 meters http://www.arb.ca.gov/ab2588/diesel/instructions.htm

Montecito Fire Station Emissions of CO2 from Electricity Usage

Emission Factor Energy Use 2 Building Size

1

681 lbs CO2/MWh 54,160 BTU/sqft 7100 sqft

Energy Usage

3.85E+08 BTU

BTU to KWh

2.93E-04 (KWh/BTU)

Energy Usage

1.13E+05 KWh

CO2 emissions CO2 emission

April 29, 2011 AMEC Project Number 7551005103

76728 lbs

(Energy Use x Building Size)

(Energy Usage x BTU to KWh) (Emission Factor x Energy Use/1000)

38.4 tons

1. USEPA OAS at http://oaspub.epa.gov/powpro/ept_pack.charts 2. DOE Buildings Energy Data Book at http://buildingsdatabook.eren.doe.gov

Buildings Energy Data Book

1 of 1

http://buildingsdatabook.eren.doe.gov/CBECS.aspx

The criteria you have selected returns a small sample set (under 25). This may make the data unreliable. For more information on reliability, please visit EIA’s website.

Results Sample Size: 4 Represents (# of buildings): 4,264 Total Square Feet: 33,159,350

Thousand Expenditures/ Expenditures Btu/ Square Foot ( $) Square ($) Foot

Fuels

Thousand Btu

Electricity

1,795,982,059

36,780,519

37,234,565

465,767

1.12

0.01

0

0

0.00

0.00

1,833,216,624

37,246,286

55.29

1.12

Natural Gas Fuel Oil All Major Fuels

End-Use

54.16

1.11

Thousand Btu/ Square Foot

Thousand Total Btu

Heating

457,832,980

Cooling

129,494,637

3.91

82,657,710

2.49

Water Heating

159,836,858

4.82

Lighting

492,807,589

14.86

Ventilation

Cooking

13.81

0

0.00

158,711,065

4.79

Office Equipment

26,462,726

0.80

Computer Use

52,987,290

1.60

Miscellaneous

272,427,874

8.22

Refrigeration

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Last Updated: March 2011

4/29/2011 10:41 AM

How clean is the electricity I use? - Power Profiler | Clean Energy | US EPA

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http://oaspub.epa.gov/powpro/ept_pack.charts http://oaspub.epa.gov/powpro/ept_pack.charts Last updated on Friday, April 29, 2011

Clean Energy You are here: EPA Home use? - Power Profiler

Climate Change

Clean Energy

Energy and You

How clean is the electricity I

The table below contains two charts: The first chart compares the fuel mix used to generate electricity in your region of the power grid to the national fuel mix. The second chart compares the average air emissions rates in your region of the power grid to the national average emissions rates. eGRID Subregion: WECC California (which includes the ZIP code: 93108)

FUEL MIX COMPARISON

What Is My Fuel Mix?

52.5

This chart compares fuel mix (%) of sources used to generate

9.6

2.5

12.1

5.8

Non-Hydro Hydro Renewables

48.5 21.7

16.2 19.4

7.6

1.0 1.6 Nuclear

Oil

Gas

%

Coal

electricity in your region to the fuel mix (%) for the entire United States.

EMISSIONS RATE COMPARISON

What Are the Emissions in My Area? This chart compares the average

1300

emissions rates (lbs/MWh) in your geographical

4.75 0.62

1.79

681

0.42

region to the

4/29/2011 10:47 AM

How clean is the electricity I use? - Power Profiler | Clean Energy | US EPA

http://oaspub.epa.gov/powpro/ept_pack.charts

national average emissions rates (lbs/MWh) for nitgrogen oxide, sulfur dioxide,

Nitrogen Oxide

Sulfur Dioxide

Carbon Dioxide

and carbon dioxide.

MAKE A DIFFERENCE

What Can I Do to Make a Difference?

Find out about the actual emissions attributable to the electricity you use in your home or business.

Choose one of the buttons on the right to find out what you can do to make a

Find out how you can make your home or business more energy efficient.

difference.

Learn how you can buy green power (power generated from renewable energy sources) for your home or business.

Note: The information reported above is derived from EPA's eGRID database for calendar year 2007.

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