BORON ALLYLOXIDE
AKB154 - BORON ALLYLOXIDE
BORON ALLYLOXIDE Safety Data Sheet AKB154 Date of issue: 17/08/2015
Revision date: 01/09/2015
Version: 2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Substance
Physical state
: Liquid
Substance name
: BORON ALLYLOXIDE
Product code
: AKB154
Formula
: C9H15BO3
Synonyms
: TRIALLYL BORATE, TRIALLYLOXYBORANE, BORIC ACID-TRIALLYL ESTER; BORIC ACID (H3BO3), TRI-2-PROPEN-1-YL ESTER
Chemical family
: ESTER
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Use of the substance/mixture
1.2.2.
: Chemical intermediate For research and industrial use only
Uses advised against
No additional information available 1.3.
Details of the supplier of the safety data sheet
GELEST, INC. 11 East Steel Road Morrisville, PA 19067 USA T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST [email protected] - www.gelest.com GELEST INC. Stroofstrasse 27 Geb.2901 65933 Frankfurt am Main Germany T +49-(0)-69-3800-2150 - F +49-(0)-69-3800-2300 - (M-F): 8:00 AM - 5:30 PM [email protected] - www.gelestde.com 1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 3 H226 Skin Irrit. 2
H315
Eye Irrit. 2
H319
STOT SE 3 H335 Full text of classification categories and H statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xi; R36/37/38 R10 Full text of R-phrases: see section 16
01/09/2015
EN (English)
SDS ID: AKB154
1/11
BORON ALLYLOXIDE Safety Data Sheet 2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
:
Signal word (CLP)
: Warning
Hazard statements (CLP)
: H226 - Flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation
Precautionary statements (CLP)
: P280 - Wear protective gloves/protective clothing/eye protection/face protection P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground/bond container and receiving equipment P261 - Avoid breathing vapours P264 - Wash hands thoroughly after handling P312 - Call a doctor if you feel unwell
GHS02
GHS07
No labelling applicable 2.3.
Other hazards
No additional information available
SECTION 3: Composition/information on ingredients 3.1.
Substance
Substance type
: Multi-constituent
Name
: BORON ALLYLOXIDE
CAS No
: 1693-71-6
EC no
: 216-897-9
Name
Product identifier
%
Classification according to Directive 67/548/EEC
Triallyl borate
(CAS No) 1693-71-6 (EC no) 216-897-9
95 - 100
Xi; R36/37/38 R10
Allyl alcohol
(CAS No) 107-18-6 (EC no) 203-470-7 (EC index no) 603-015-00-6
1-2
R10 T; R23/24/25 Xi; R36/37/38 N; R50
Name
Product identifier
%
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Triallyl borate
(CAS No) 1693-71-6 (EC no) 216-897-9
95 - 100
Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335
Allyl alcohol
(CAS No) 107-18-6 (EC no) 203-470-7 (EC index no) 603-015-00-6
1-2
Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 Aquatic Acute 1, H400
Full text of R- and H-phrases: see section 16 3.2.
Mixture
Not applicable 4.1.
Description of first aid measures
First-aid measures general
: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. IF exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice.
First-aid measures after skin contact
: Wash with plenty of soap and water. Get medical advice/attention.
01/09/2015
EN (English)
SDS ID: AKB154
2/11
BORON ALLYLOXIDE Safety Data Sheet First-aid measures after eye contact
: Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion
: Never give anything by mouth to an unconscious person. Get medical advice/attention.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
: May cause respiratory irritation. Allyl alcohol is considered a poison by inhalation and a systemic irritant.
Symptoms/injuries after skin contact
: Causes skin irritation.
Symptoms/injuries after eye contact
: Causes serious eye irritation.
Symptoms/injuries after ingestion
: May be harmful if swallowed.
4.3.
Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures 5.1.
Extinguishing media
Suitable extinguishing media
: Alcohol-resistant foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media
: Avoid water spray as toxic allyl alcohol will be generated.
5.2.
Special hazards arising from the substance or mixture
Fire hazard 5.3.
: Flammable liquid and vapour. Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame.
Advice for firefighters
Firefighting instructions
: Exercise caution when fighting any chemical fire.
Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection. Avoid all eye and skin contact and do not breathe vapour and mist.
SECTION 6: Accidental release measures 6.1.
Personal precautions, protective equipment and emergency procedures
General measures 6.1.1.
: Remove ignition sources. Use special care to avoid static electric charges.
For non-emergency personnel
Protective equipment
: Wear protective equipment as described in Section 8.
Emergency procedures
: Evacuate unnecessary personnel.
6.1.2.
For emergency responders
Protective equipment
6.2.
: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3.
Methods and material for containment and cleaning up
For containment
: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for cleaning up
: Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal. Use only non-sparking tools.
6.4.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage 7.1.
Precautions for safe handling
Precautions for safe handling
: Avoid all eye and skin contact and do not breathe vapour and mist. Provide good ventilation in process area to prevent formation of vapour. Take precautionary measures against static discharge. Containers and transfer lines require grounding during use. Use only non-sparking tools.
Hygiene measures
: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: Ground/bond container and receiving equipment.
Storage conditions
: Keep container tightly closed.
Incompatible materials
: Carbon tetrachloride. Mineral acids. Oxidizing agent. Water.
Storage area
: Store in a well-ventilated place. Store away from heat.
7.3.
Specific end use(s)
No additional information available 01/09/2015
EN (English)
SDS ID: AKB154
3/11
BORON ALLYLOXIDE Safety Data Sheet SECTION 8: Exposure controls/personal protection 8.1.
Control parameters
Triallyl borate (1693-71-6) Italy - Portugal - USA ACGIH
ACGIH TWA (ppm)
100 ppm
Allyl alcohol (107-18-6) EU EU EU EU Austria Austria Austria Austria Belgium Belgium Belgium Belgium Bulgaria Bulgaria Bulgaria Bulgaria Cyprus Cyprus Cyprus Cyprus France France France France Germany Germany Gibraltar Gibraltar Gibraltar Gibraltar Greece Greece Greece Greece Italy - Portugal - USA ACGIH Italy
IOELV TWA (mg/m³) IOELV TWA (ppm) IOELV STEL (mg/m³) IOELV STEL (ppm) MAK (mg/m³) MAK (ppm) MAK Short time value (mg/m³) MAK Short time value (ppm) Limit value (mg/m³) Limit value (ppm) Short time value (mg/m³) Short time value (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) VLE (mg/m³) VLE (ppm) VME (mg/m³) VME (ppm) TRGS 900 Occupational exposure limit value (mg/m³) TRGS 900 Occupational exposure limit value (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) ACGIH TWA (ppm) OEL TWA (mg/m³)
4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³ 2 ppm 12 mg/m³ 5 ppm 4.8 mg/m³ 2 ppm 9.6 mg/m³ 4 ppm 4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³ (indicative limit) 2 ppm (indicative limit) 0.48 mg/m³ (indicative limit) 0.2 ppm (indicative limit) 4.8 mg/m³ 2 ppm 4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 5 mg/m³ 2 ppm 10 mg/m³ 4 ppm 0.5 ppm 4.8 mg/m³
Italy
OEL TWA (ppm)
2 ppm
Italy
OEL STEL (mg/m³)
12.1 mg/m³
Italy
OEL STEL (ppm)
5 ppm
Latvia
OEL TWA (mg/m³)
4.8 mg/m³
Latvia
OEL TWA (ppm)
2 ppm
USA IDLH
US IDLH (ppm)
20 ppm
USA NIOSH
NIOSH REL (TWA) (mg/m³)
5 mg/m³
USA NIOSH
NIOSH REL (TWA) (ppm)
2 ppm
USA NIOSH
NIOSH REL (STEL) (mg/m³)
10 mg/m³
USA NIOSH
NIOSH REL (STEL) (ppm)
4 ppm
USA OSHA
OSHA PEL (TWA) (mg/m³)
5 mg/m³
USA OSHA
OSHA PEL (TWA) (ppm)
2 ppm
Spain Spain Spain
VLA-ED (mg/m³) VLA-ED (ppm) VLA-EC (mg/m³)
5 mg/m³ (indicative limit value) 2 ppm (indicative limit value) 12 mg/m³
01/09/2015
EN (English)
SDS ID: AKB154
4/11
BORON ALLYLOXIDE Safety Data Sheet Allyl alcohol (107-18-6) Spain Switzerland Switzerland Switzerland Switzerland Netherlands Netherlands United Kingdom United Kingdom United Kingdom United Kingdom Czech Republic
VLA-EC (ppm) VLE (mg/m³) VLE (ppm) VME (mg/m³) VME (ppm) Grenswaarde TGG 8H (mg/m³) Grenswaarde TGG 15MIN (mg/m³) WEL TWA (mg/m³) WEL TWA (ppm) WEL STEL (mg/m³) WEL STEL (ppm) Expoziční limity (PEL) (mg/m³)
5 ppm 10 mg/m³ 4 ppm 5 mg/m³ 2 ppm 4.8 mg/m³ 12.1 mg/m³ 4.8 mg/m³ 2 ppm 9.7 mg/m³ 4 ppm 4 mg/m³
Denmark
Grænseværdie (langvarig) (mg/m³)
4.8 mg/m³
Denmark
Grænseværdie (langvarig) (ppm)
2 ppm
Finland
HTP-arvo (8h) (mg/m³)
1.2 mg/m³
Finland
HTP-arvo (8h) (ppm)
0.5 ppm
Finland
HTP-arvo (15 min)
4.8 mg/m³
Finland
HTP-arvo (15 min) (ppm)
2 ppm
Hungary
AK-érték
4.8 mg/m³
Hungary
CK-érték
12.1 mg/m³
Ireland
OEL (8 hours ref) (mg/m³)
4.8 mg/m³
Ireland
OEL (8 hours ref) (ppm)
2 ppm
Ireland
OEL (15 min ref) (mg/m3)
12.1 mg/m³
Ireland
OEL (15 min ref) (ppm)
5 ppm
Lithuania
IPRV (mg/m³)
4.8 mg/m³
Lithuania
IPRV (ppm)
2 ppm
Lithuania
TPRV (mg/m³)
12.1 mg/m³
Lithuania
TPRV (ppm)
5 ppm
Malta Malta Malta Malta Norway
OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) Gjennomsnittsverdier (AN) (mg/m³)
4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 5 mg/m³
Norway
Gjennomsnittsverdier (AN) (ppm)
2 ppm
Norway
Gjennomsnittsverdier (Korttidsverdi) (mg/m3)
5 mg/m³
Norway
Gjennomsnittsverdier (Korttidsverdi) (ppm)
2 ppm
Poland
NDS (mg/m³)
2 mg/m³
Poland
NDSCh (mg/m³)
10 mg/m³
Romania Romania Romania Romania Slovakia
OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) NPHV (priemerná) (mg/m³)
4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³
Slovakia
NPHV (priemerná) (ppm)
2 ppm
Slovakia
NPHV (Hraničná) (mg/m³)
12.1 mg/m³
Sweden
nivågränsvärde (NVG) (mg/m³)
5 mg/m³
Sweden
nivågränsvärde (NVG) (ppm)
2 ppm
Sweden
kortidsvärde (KTV) (mg/m³)
14 mg/m³
Sweden
kortidsvärde (KTV) (ppm)
6 ppm
Canada (Quebec) Canada (Quebec)
VECD (mg/m³) VECD (ppm)
9.5 mg/m³ 4 ppm
01/09/2015
EN (English)
SDS ID: AKB154
5/11
BORON ALLYLOXIDE Safety Data Sheet Allyl alcohol (107-18-6) Canada (Quebec) Canada (Quebec) Australia Australia Australia Australia Portugal Portugal Portugal Portugal Portugal
8.2.
VEMP (mg/m³) VEMP (ppm) TWA (mg/m³) TWA (ppm) STEL (mg/m³) STEL (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) OEL chemical category (PT)
4.8 mg/m³ 2 ppm 4.8 mg/m³ 2 ppm 9.5 mg/m³ 4 ppm 4.8 mg/m³ (indicative limit value) 2 ppm (indicative limit value) 21.1 mg/m³ (indicative limit value) 5 ppm (indicative limit value) A4 - Not Classifiable as a Human Carcinogen,skin potential for cutaneous exposure indicative limit value
Exposure controls
Appropriate engineering controls
: Handle in an enclosing hood with exhaust ventilation.
Personal protective equipment
: Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
Hand protection
: Neoprene or nitrile rubber gloves.
Eye protection
: Chemical goggles. Contact lenses should not be worn.
Skin and body protection
: Wear suitable protective clothing.
Respiratory protection
: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended.
SECTION 9: Physical and chemical properties 9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Appearance
: Liquid.
Molecular mass
: 182.03 g/mol
Colour
: Water white.
Odour
: Slight. Pungent.
Odour threshold
: No data available
Refractive index
: 1.427
pH
: No data available
Relative evaporation rate (butylacetate=1)
: No data available
Melting point
: No data available
Freezing point
: < 0 °C
Boiling point
: 72 °C @ 12
Flash point
: 31 °C
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: Flammable liquid and vapour
Vapour pressure
: No data available
Relative vapour density at 20 °C
: >1
Relative density
: 0.919
Solubility
: Reacts with water.
Log Pow
: No data available
Log Kow
: No data available
Viscosity, kinematic
: 0.9 cSt @ 23˚C
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidising properties
: No data available
Explosive limits
: No data available
9.2.
Other information
No additional information available
01/09/2015
EN (English)
SDS ID: AKB154
6/11
BORON ALLYLOXIDE Safety Data Sheet SECTION 10: Stability and reactivity 10.1.
Reactivity
No additional information available 10.2.
Chemical stability
Stable. 10.3.
Possibility of hazardous reactions
Material decomposes slowly in contact with air by reaction with moisture, liberating allyl alcohol and boric acid. Avoid contact with water. Violent and potentially explosive reactions may occur on contact with oxidizers, mineral acids and carbon tetrachloride. 10.4.
Conditions to avoid
Heat. Open flame. Sparks. 10.5.
Incompatible materials
Carbon tetrachloride. Mineral acids. Oxidizing agent. Water. 10.6.
Hazardous decomposition products
Boron oxide fumes. Organic acid vapors.
SECTION 11: Toxicological information 11.1.
Information on toxicological effects
Acute toxicity
: Not classified
Allyl alcohol (107-18-6) LD50 oral rat LD50 oral mouse LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE CLP (oral) ATE CLP (dermal) ATE CLP (vapours) ATE CLP (dust,mist)
64 mg/kg 96 mg/kg 89 mg/kg 0.391 mg/l/4h 64.000 mg/kg bodyweight 45.000 mg/kg bodyweight 1.760 mg/l/4h 1.760 mg/l/4h
Skin corrosion/irritation
: Causes skin irritation.
Serious eye damage/irritation
: Causes serious eye irritation.
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
: Not classified
Aspiration hazard
: Not classified
Potential adverse human health effects and symptoms
: Boron allyloxide hydrolyzes in contact with moisture in air to form allyl alcohol and boron oxide. Allyl alcohol is considered a highly toxic byproduct.
Symptoms/injuries after inhalation
: May cause respiratory irritation. Allyl alcohol is considered a poison by inhalation and a systemic irritant.
Symptoms/injuries after skin contact
: Causes skin irritation.
Symptoms/injuries after eye contact
: Causes serious eye irritation.
Symptoms/injuries after ingestion
: May be harmful if swallowed.
Reason for classification
: Expert judgment
SECTION 12: Ecological information 12.1.
Toxicity
Ecology - general Allyl alcohol (107-18-6) LC50 fish 1 LC50 fish 2 12.2.
: Harmful to aquatic life.
0.28 - 0.37 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) 0.32 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Persistence and degradability
No additional information available 12.3. 01/09/2015
Bioaccumulative potential EN (English)
SDS ID: AKB154
7/11
BORON ALLYLOXIDE Safety Data Sheet Allyl alcohol (107-18-6) BCF fish 1 Log Pow 12.4.
(no bioaccumulation expected) 0.17
Mobility in soil
No additional information available 12.5.
Results of PBT and vPvB assessment
No additional information available 12.6.
Other adverse effects
Other adverse effects
: This substance may be hazardous to the environment.
SECTION 13: Disposal considerations 13.1.
Waste treatment methods
Sewage disposal recommendations
: Do not dispose of waste into sewer.
Waste disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to licensed waste disposal facility.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information 14.1.
UN number
UN-No. (ADR)
: 1992
UN-No.(IATA)
: 1992
UN-No. (IMDG)
: 1992
14.2.
UN proper shipping name
Proper Shipping Name (ADR)
: FLAMMABLE LIQUID, TOXIC, N.O.S.
Proper Shipping Name (IATA)
: Flammable liquid, toxic, n.o.s.
Proper Shipping Name (IMDG)
: FLAMMABLE LIQUID, TOXIC, N.O.S.
Transport document description (ADR)
: UN 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. (BORON ALLYLOXIDE), 3 (6.1), III, (D/E)
14.3.
Transport hazard class(es)
Class (ADR)
: 3
Class (IATA)
: 3
Class (IMDG)
: 3
Subsidiary risk (ADR)
: 6.1
Subsidiary risk (IMDG)
: 6.1
Danger labels (ADR)
: 3, 6.1
Hazard labels (IATA)
: 3, 6.1
Danger labels (IMDG)
: 3, 6.1
14.4.
Packing group
Packing group (ADR) Packing group (IATA) Packing group (IMDG) 14.5.
Environmental hazards
Other information
01/09/2015
: III : III : III : No supplementary information available.
EN (English)
SDS ID: AKB154
8/11
BORON ALLYLOXIDE Safety Data Sheet 14.6.
Special precautions for user
14.6.1.
Overland transport
Hazard identification number (Kemler No.)
: 36
Classification code (ADR)
: FT1
Orange plates
:
Special provisions (ADR)
: 274
Transport category (ADR)
: 3
Tunnel restriction code (ADR)
: D/E
Limited quantities (ADR)
: 5l
Excepted quantities (ADR)
: E1
EAC code
: •3WE
APP code
: A(fl)
14.6.2.
Transport by sea
Special provisions (IMDG)
: 223, 274
Limited quantities (IMDG)
: 5L
Excepted quantities (IMDG)
: E1
Packing instructions (IMDG)
: P001
IBC packing instructions (IMDG)
: IBC03
Tank instructions (IMDG)
: T7
Tank special provisions (IMDG)
: TP1, TP28
EmS-No. (Fire)
: F-E
EmS-No. (Spillage)
: S-D
Stowage category (IMDG)
: A
14.6.3.
Air transport
CAO packing instructions (IATA)
: 366
CAO max net quantity (IATA)
: 220L
PCA packing instructions (IATA)
: 355
PCA Limited quantities (IATA)
: Y343
PCA limited quantity max net quantity (IATA)
: 2L
PCA max net quantity (IATA)
: 60L
PCA Excepted quantities (IATA)
: E1
Special provisions (IATA)
: A3
ERG code (IATA)
: 3P
14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information 15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
No REACH Annex XVII restrictions BORON ALLYLOXIDE is not on the REACH Candidate List Contains no substance on the REACH candidate list BORON ALLYLOXIDE is not on the REACH Annex XIV List Contains no REACH Annex XIV substances
15.1.2.
01/09/2015
National regulations
EN (English)
SDS ID: AKB154
9/11
BORON ALLYLOXIDE Safety Data Sheet Triallyl borate (1693-71-6) Listed on the Canadian NDSL (Non-Domestic Substances List) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican national Inventory of Chemical Substances) Allyl alcohol (107-18-6) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Sustances List) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Japanese Poisonous and Deleterious Substances Control Law Japanese Pollutant Release and Transfer Register Law (PRTR Law) Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican national Inventory of Chemical Substances) 15.2.
Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information Abbreviations and acronyms
Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute Tox. 3 (Inhalation) Acute Tox. 3 (Oral) Aquatic Acute 1 Eye Irrit. 2 Flam. Liq. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 H225 H226 H301 H311 H315 H319 H331 H335 H400 R10 R23/24/25 R36/37/38 R50 N T Xi
: Abbreviations: ND: Not Determined, No Data; NA: Not Applicable; LD: Lethal Dose; LC: Lethal Concentration; ATE: Acute Toxicity Estimates; H: hour; °: °C unless otherwise stated; mm: millimeters Hg, torr; PEL: permissible exposure level; TWA: time weighted average; TLV: threshold limit value; TG: Test Guideline; NIOSH: National Institute for Occupational Safety and Health; IARC: International Agency for Research on Cancer; NTP: National Toxicology Program; HMIS: Hazardous Material Information System; CAS No.: Chemcial Abstract Service Registration Number; EC No.: European Commission Registration Number; EC Index No.: European Commission Index Number; OECD: The Organisation for Economic Co-operation and Development. Acute toxicity (dermal), Category 3 Acute toxicity (inhal.), Category 3 Acute toxicity (oral), Category 3 Hazardous to the aquatic environment — Acute Hazard, Category 1 Serious eye damage/eye irritation, Category 2 Flammable liquids, Category 2 Flammable liquids, Category 3 Skin corrosion/irritation, Category 2 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation Highly flammable liquid and vapour Flammable liquid and vapour Toxic if swallowed Toxic in contact with skin Causes skin irritation Causes serious eye irritation Toxic if inhaled May cause respiratory irritation Very toxic to aquatic life Flammable Toxic by inhalation, in contact with skin and if swallowed Irritating to eyes, respiratory system and skin Very toxic to aquatic organisms Dangerous for the environment Toxic Irritant
Prepared by safety and environmental affairs. 01/09/2015
EN (English)
SDS ID: AKB154
10/11
BORON ALLYLOXIDE Safety Data Sheet
SDS EU (REACH Annex II) - Custom according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010 The information contained in this document has been gathered from reference materials and/or Gelest, Inc. test data and is to the best knowledge and belief of Gelest, Inc. accurate and reliable. Such information is offered solely for your consideration, investigation and verification. It is not suggested or guaranteed that the hazard precautions or procedures described are the only ones which exist. Gelest, Inc. makes no warranties, express or implied, with respect to the use of such information and assumes no responsibility therefore. Information on this safety data sheet is not intended to constitute a basis for product specifications.
© 2015 Gelest Inc. Morrisville, PA 19067
01/09/2015
EN (English)
SDS ID: AKB154
11/11
BORON ALLYLOXIDE Safety Data Sheet AKB154 Date of issue: 17/08/2015
Revision date: 01/09/2015
Version: 2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Substance
Physical state
: Liquid
Substance name
: BORON ALLYLOXIDE
Product code
: AKB154
Formula
: C9H15BO3
Synonyms
: TRIALLYL BORATE, TRIALLYLOXYBORANE, BORIC ACID-TRIALLYL ESTER; BORIC ACID (H3BO3), TRI-2-PROPEN-1-YL ESTER
Chemical family
: ESTER
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Use of the substance/mixture
1.2.2.
: Chemical intermediate For research and industrial use only
Uses advised against
No additional information available 1.3.
Details of the supplier of the safety data sheet
GELEST, INC. 11 East Steel Road Morrisville, PA 19067 USA T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST [email protected] - www.gelest.com GELEST INC. Stroofstrasse 27 Geb.2901 65933 Frankfurt am Main Germany T +49-(0)-69-3800-2150 - F +49-(0)-69-3800-2300 - (M-F): 8:00 AM - 5:30 PM [email protected] - www.gelestde.com 1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 3 H226 Skin Irrit. 2
H315
Eye Irrit. 2
H319
STOT SE 3 H335 Full text of classification categories and H statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xi; R36/37/38 R10 Full text of R-phrases: see section 16
01/09/2015
EN (English)
SDS ID: AKB154
1/11
BORON ALLYLOXIDE Safety Data Sheet 2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
:
Signal word (CLP)
: Warning
Hazard statements (CLP)
: H226 - Flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation
Precautionary statements (CLP)
: P280 - Wear protective gloves/protective clothing/eye protection/face protection P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground/bond container and receiving equipment P261 - Avoid breathing vapours P264 - Wash hands thoroughly after handling P312 - Call a doctor if you feel unwell
GHS02
GHS07
No labelling applicable 2.3.
Other hazards
No additional information available
SECTION 3: Composition/information on ingredients 3.1.
Substance
Substance type
: Multi-constituent
Name
: BORON ALLYLOXIDE
CAS No
: 1693-71-6
EC no
: 216-897-9
Name
Product identifier
%
Classification according to Directive 67/548/EEC
Triallyl borate
(CAS No) 1693-71-6 (EC no) 216-897-9
95 - 100
Xi; R36/37/38 R10
Allyl alcohol
(CAS No) 107-18-6 (EC no) 203-470-7 (EC index no) 603-015-00-6
1-2
R10 T; R23/24/25 Xi; R36/37/38 N; R50
Name
Product identifier
%
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Triallyl borate
(CAS No) 1693-71-6 (EC no) 216-897-9
95 - 100
Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335
Allyl alcohol
(CAS No) 107-18-6 (EC no) 203-470-7 (EC index no) 603-015-00-6
1-2
Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 Aquatic Acute 1, H400
Full text of R- and H-phrases: see section 16 3.2.
Mixture
Not applicable 4.1.
Description of first aid measures
First-aid measures general
: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. IF exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice.
First-aid measures after skin contact
: Wash with plenty of soap and water. Get medical advice/attention.
01/09/2015
EN (English)
SDS ID: AKB154
2/11
BORON ALLYLOXIDE Safety Data Sheet First-aid measures after eye contact
: Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion
: Never give anything by mouth to an unconscious person. Get medical advice/attention.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
: May cause respiratory irritation. Allyl alcohol is considered a poison by inhalation and a systemic irritant.
Symptoms/injuries after skin contact
: Causes skin irritation.
Symptoms/injuries after eye contact
: Causes serious eye irritation.
Symptoms/injuries after ingestion
: May be harmful if swallowed.
4.3.
Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures 5.1.
Extinguishing media
Suitable extinguishing media
: Alcohol-resistant foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media
: Avoid water spray as toxic allyl alcohol will be generated.
5.2.
Special hazards arising from the substance or mixture
Fire hazard 5.3.
: Flammable liquid and vapour. Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame.
Advice for firefighters
Firefighting instructions
: Exercise caution when fighting any chemical fire.
Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection. Avoid all eye and skin contact and do not breathe vapour and mist.
SECTION 6: Accidental release measures 6.1.
Personal precautions, protective equipment and emergency procedures
General measures 6.1.1.
: Remove ignition sources. Use special care to avoid static electric charges.
For non-emergency personnel
Protective equipment
: Wear protective equipment as described in Section 8.
Emergency procedures
: Evacuate unnecessary personnel.
6.1.2.
For emergency responders
Protective equipment
6.2.
: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3.
Methods and material for containment and cleaning up
For containment
: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for cleaning up
: Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal. Use only non-sparking tools.
6.4.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage 7.1.
Precautions for safe handling
Precautions for safe handling
: Avoid all eye and skin contact and do not breathe vapour and mist. Provide good ventilation in process area to prevent formation of vapour. Take precautionary measures against static discharge. Containers and transfer lines require grounding during use. Use only non-sparking tools.
Hygiene measures
: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: Ground/bond container and receiving equipment.
Storage conditions
: Keep container tightly closed.
Incompatible materials
: Carbon tetrachloride. Mineral acids. Oxidizing agent. Water.
Storage area
: Store in a well-ventilated place. Store away from heat.
7.3.
Specific end use(s)
No additional information available 01/09/2015
EN (English)
SDS ID: AKB154
3/11
BORON ALLYLOXIDE Safety Data Sheet SECTION 8: Exposure controls/personal protection 8.1.
Control parameters
Triallyl borate (1693-71-6) Italy - Portugal - USA ACGIH
ACGIH TWA (ppm)
100 ppm
Allyl alcohol (107-18-6) EU EU EU EU Austria Austria Austria Austria Belgium Belgium Belgium Belgium Bulgaria Bulgaria Bulgaria Bulgaria Cyprus Cyprus Cyprus Cyprus France France France France Germany Germany Gibraltar Gibraltar Gibraltar Gibraltar Greece Greece Greece Greece Italy - Portugal - USA ACGIH Italy
IOELV TWA (mg/m³) IOELV TWA (ppm) IOELV STEL (mg/m³) IOELV STEL (ppm) MAK (mg/m³) MAK (ppm) MAK Short time value (mg/m³) MAK Short time value (ppm) Limit value (mg/m³) Limit value (ppm) Short time value (mg/m³) Short time value (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) VLE (mg/m³) VLE (ppm) VME (mg/m³) VME (ppm) TRGS 900 Occupational exposure limit value (mg/m³) TRGS 900 Occupational exposure limit value (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) ACGIH TWA (ppm) OEL TWA (mg/m³)
4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³ 2 ppm 12 mg/m³ 5 ppm 4.8 mg/m³ 2 ppm 9.6 mg/m³ 4 ppm 4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³ (indicative limit) 2 ppm (indicative limit) 0.48 mg/m³ (indicative limit) 0.2 ppm (indicative limit) 4.8 mg/m³ 2 ppm 4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 5 mg/m³ 2 ppm 10 mg/m³ 4 ppm 0.5 ppm 4.8 mg/m³
Italy
OEL TWA (ppm)
2 ppm
Italy
OEL STEL (mg/m³)
12.1 mg/m³
Italy
OEL STEL (ppm)
5 ppm
Latvia
OEL TWA (mg/m³)
4.8 mg/m³
Latvia
OEL TWA (ppm)
2 ppm
USA IDLH
US IDLH (ppm)
20 ppm
USA NIOSH
NIOSH REL (TWA) (mg/m³)
5 mg/m³
USA NIOSH
NIOSH REL (TWA) (ppm)
2 ppm
USA NIOSH
NIOSH REL (STEL) (mg/m³)
10 mg/m³
USA NIOSH
NIOSH REL (STEL) (ppm)
4 ppm
USA OSHA
OSHA PEL (TWA) (mg/m³)
5 mg/m³
USA OSHA
OSHA PEL (TWA) (ppm)
2 ppm
Spain Spain Spain
VLA-ED (mg/m³) VLA-ED (ppm) VLA-EC (mg/m³)
5 mg/m³ (indicative limit value) 2 ppm (indicative limit value) 12 mg/m³
01/09/2015
EN (English)
SDS ID: AKB154
4/11
BORON ALLYLOXIDE Safety Data Sheet Allyl alcohol (107-18-6) Spain Switzerland Switzerland Switzerland Switzerland Netherlands Netherlands United Kingdom United Kingdom United Kingdom United Kingdom Czech Republic
VLA-EC (ppm) VLE (mg/m³) VLE (ppm) VME (mg/m³) VME (ppm) Grenswaarde TGG 8H (mg/m³) Grenswaarde TGG 15MIN (mg/m³) WEL TWA (mg/m³) WEL TWA (ppm) WEL STEL (mg/m³) WEL STEL (ppm) Expoziční limity (PEL) (mg/m³)
5 ppm 10 mg/m³ 4 ppm 5 mg/m³ 2 ppm 4.8 mg/m³ 12.1 mg/m³ 4.8 mg/m³ 2 ppm 9.7 mg/m³ 4 ppm 4 mg/m³
Denmark
Grænseværdie (langvarig) (mg/m³)
4.8 mg/m³
Denmark
Grænseværdie (langvarig) (ppm)
2 ppm
Finland
HTP-arvo (8h) (mg/m³)
1.2 mg/m³
Finland
HTP-arvo (8h) (ppm)
0.5 ppm
Finland
HTP-arvo (15 min)
4.8 mg/m³
Finland
HTP-arvo (15 min) (ppm)
2 ppm
Hungary
AK-érték
4.8 mg/m³
Hungary
CK-érték
12.1 mg/m³
Ireland
OEL (8 hours ref) (mg/m³)
4.8 mg/m³
Ireland
OEL (8 hours ref) (ppm)
2 ppm
Ireland
OEL (15 min ref) (mg/m3)
12.1 mg/m³
Ireland
OEL (15 min ref) (ppm)
5 ppm
Lithuania
IPRV (mg/m³)
4.8 mg/m³
Lithuania
IPRV (ppm)
2 ppm
Lithuania
TPRV (mg/m³)
12.1 mg/m³
Lithuania
TPRV (ppm)
5 ppm
Malta Malta Malta Malta Norway
OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) Gjennomsnittsverdier (AN) (mg/m³)
4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 5 mg/m³
Norway
Gjennomsnittsverdier (AN) (ppm)
2 ppm
Norway
Gjennomsnittsverdier (Korttidsverdi) (mg/m3)
5 mg/m³
Norway
Gjennomsnittsverdier (Korttidsverdi) (ppm)
2 ppm
Poland
NDS (mg/m³)
2 mg/m³
Poland
NDSCh (mg/m³)
10 mg/m³
Romania Romania Romania Romania Slovakia
OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) NPHV (priemerná) (mg/m³)
4.8 mg/m³ 2 ppm 12.1 mg/m³ 5 ppm 4.8 mg/m³
Slovakia
NPHV (priemerná) (ppm)
2 ppm
Slovakia
NPHV (Hraničná) (mg/m³)
12.1 mg/m³
Sweden
nivågränsvärde (NVG) (mg/m³)
5 mg/m³
Sweden
nivågränsvärde (NVG) (ppm)
2 ppm
Sweden
kortidsvärde (KTV) (mg/m³)
14 mg/m³
Sweden
kortidsvärde (KTV) (ppm)
6 ppm
Canada (Quebec) Canada (Quebec)
VECD (mg/m³) VECD (ppm)
9.5 mg/m³ 4 ppm
01/09/2015
EN (English)
SDS ID: AKB154
5/11
BORON ALLYLOXIDE Safety Data Sheet Allyl alcohol (107-18-6) Canada (Quebec) Canada (Quebec) Australia Australia Australia Australia Portugal Portugal Portugal Portugal Portugal
8.2.
VEMP (mg/m³) VEMP (ppm) TWA (mg/m³) TWA (ppm) STEL (mg/m³) STEL (ppm) OEL TWA (mg/m³) OEL TWA (ppm) OEL STEL (mg/m³) OEL STEL (ppm) OEL chemical category (PT)
4.8 mg/m³ 2 ppm 4.8 mg/m³ 2 ppm 9.5 mg/m³ 4 ppm 4.8 mg/m³ (indicative limit value) 2 ppm (indicative limit value) 21.1 mg/m³ (indicative limit value) 5 ppm (indicative limit value) A4 - Not Classifiable as a Human Carcinogen,skin potential for cutaneous exposure indicative limit value
Exposure controls
Appropriate engineering controls
: Handle in an enclosing hood with exhaust ventilation.
Personal protective equipment
: Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
Hand protection
: Neoprene or nitrile rubber gloves.
Eye protection
: Chemical goggles. Contact lenses should not be worn.
Skin and body protection
: Wear suitable protective clothing.
Respiratory protection
: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended.
SECTION 9: Physical and chemical properties 9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Appearance
: Liquid.
Molecular mass
: 182.03 g/mol
Colour
: Water white.
Odour
: Slight. Pungent.
Odour threshold
: No data available
Refractive index
: 1.427
pH
: No data available
Relative evaporation rate (butylacetate=1)
: No data available
Melting point
: No data available
Freezing point
: < 0 °C
Boiling point
: 72 °C @ 12
Flash point
: 31 °C
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: Flammable liquid and vapour
Vapour pressure
: No data available
Relative vapour density at 20 °C
: >1
Relative density
: 0.919
Solubility
: Reacts with water.
Log Pow
: No data available
Log Kow
: No data available
Viscosity, kinematic
: 0.9 cSt @ 23˚C
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidising properties
: No data available
Explosive limits
: No data available
9.2.
Other information
No additional information available
01/09/2015
EN (English)
SDS ID: AKB154
6/11
BORON ALLYLOXIDE Safety Data Sheet SECTION 10: Stability and reactivity 10.1.
Reactivity
No additional information available 10.2.
Chemical stability
Stable. 10.3.
Possibility of hazardous reactions
Material decomposes slowly in contact with air by reaction with moisture, liberating allyl alcohol and boric acid. Avoid contact with water. Violent and potentially explosive reactions may occur on contact with oxidizers, mineral acids and carbon tetrachloride. 10.4.
Conditions to avoid
Heat. Open flame. Sparks. 10.5.
Incompatible materials
Carbon tetrachloride. Mineral acids. Oxidizing agent. Water. 10.6.
Hazardous decomposition products
Boron oxide fumes. Organic acid vapors.
SECTION 11: Toxicological information 11.1.
Information on toxicological effects
Acute toxicity
: Not classified
Allyl alcohol (107-18-6) LD50 oral rat LD50 oral mouse LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE CLP (oral) ATE CLP (dermal) ATE CLP (vapours) ATE CLP (dust,mist)
64 mg/kg 96 mg/kg 89 mg/kg 0.391 mg/l/4h 64.000 mg/kg bodyweight 45.000 mg/kg bodyweight 1.760 mg/l/4h 1.760 mg/l/4h
Skin corrosion/irritation
: Causes skin irritation.
Serious eye damage/irritation
: Causes serious eye irritation.
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
: Not classified
Aspiration hazard
: Not classified
Potential adverse human health effects and symptoms
: Boron allyloxide hydrolyzes in contact with moisture in air to form allyl alcohol and boron oxide. Allyl alcohol is considered a highly toxic byproduct.
Symptoms/injuries after inhalation
: May cause respiratory irritation. Allyl alcohol is considered a poison by inhalation and a systemic irritant.
Symptoms/injuries after skin contact
: Causes skin irritation.
Symptoms/injuries after eye contact
: Causes serious eye irritation.
Symptoms/injuries after ingestion
: May be harmful if swallowed.
Reason for classification
: Expert judgment
SECTION 12: Ecological information 12.1.
Toxicity
Ecology - general Allyl alcohol (107-18-6) LC50 fish 1 LC50 fish 2 12.2.
: Harmful to aquatic life.
0.28 - 0.37 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) 0.32 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Persistence and degradability
No additional information available 12.3. 01/09/2015
Bioaccumulative potential EN (English)
SDS ID: AKB154
7/11
BORON ALLYLOXIDE Safety Data Sheet Allyl alcohol (107-18-6) BCF fish 1 Log Pow 12.4.
(no bioaccumulation expected) 0.17
Mobility in soil
No additional information available 12.5.
Results of PBT and vPvB assessment
No additional information available 12.6.
Other adverse effects
Other adverse effects
: This substance may be hazardous to the environment.
SECTION 13: Disposal considerations 13.1.
Waste treatment methods
Sewage disposal recommendations
: Do not dispose of waste into sewer.
Waste disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to licensed waste disposal facility.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information 14.1.
UN number
UN-No. (ADR)
: 1992
UN-No.(IATA)
: 1992
UN-No. (IMDG)
: 1992
14.2.
UN proper shipping name
Proper Shipping Name (ADR)
: FLAMMABLE LIQUID, TOXIC, N.O.S.
Proper Shipping Name (IATA)
: Flammable liquid, toxic, n.o.s.
Proper Shipping Name (IMDG)
: FLAMMABLE LIQUID, TOXIC, N.O.S.
Transport document description (ADR)
: UN 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. (BORON ALLYLOXIDE), 3 (6.1), III, (D/E)
14.3.
Transport hazard class(es)
Class (ADR)
: 3
Class (IATA)
: 3
Class (IMDG)
: 3
Subsidiary risk (ADR)
: 6.1
Subsidiary risk (IMDG)
: 6.1
Danger labels (ADR)
: 3, 6.1
Hazard labels (IATA)
: 3, 6.1
Danger labels (IMDG)
: 3, 6.1
14.4.
Packing group
Packing group (ADR) Packing group (IATA) Packing group (IMDG) 14.5.
Environmental hazards
Other information
01/09/2015
: III : III : III : No supplementary information available.
EN (English)
SDS ID: AKB154
8/11
BORON ALLYLOXIDE Safety Data Sheet 14.6.
Special precautions for user
14.6.1.
Overland transport
Hazard identification number (Kemler No.)
: 36
Classification code (ADR)
: FT1
Orange plates
:
Special provisions (ADR)
: 274
Transport category (ADR)
: 3
Tunnel restriction code (ADR)
: D/E
Limited quantities (ADR)
: 5l
Excepted quantities (ADR)
: E1
EAC code
: •3WE
APP code
: A(fl)
14.6.2.
Transport by sea
Special provisions (IMDG)
: 223, 274
Limited quantities (IMDG)
: 5L
Excepted quantities (IMDG)
: E1
Packing instructions (IMDG)
: P001
IBC packing instructions (IMDG)
: IBC03
Tank instructions (IMDG)
: T7
Tank special provisions (IMDG)
: TP1, TP28
EmS-No. (Fire)
: F-E
EmS-No. (Spillage)
: S-D
Stowage category (IMDG)
: A
14.6.3.
Air transport
CAO packing instructions (IATA)
: 366
CAO max net quantity (IATA)
: 220L
PCA packing instructions (IATA)
: 355
PCA Limited quantities (IATA)
: Y343
PCA limited quantity max net quantity (IATA)
: 2L
PCA max net quantity (IATA)
: 60L
PCA Excepted quantities (IATA)
: E1
Special provisions (IATA)
: A3
ERG code (IATA)
: 3P
14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information 15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
No REACH Annex XVII restrictions BORON ALLYLOXIDE is not on the REACH Candidate List Contains no substance on the REACH candidate list BORON ALLYLOXIDE is not on the REACH Annex XIV List Contains no REACH Annex XIV substances
15.1.2.
01/09/2015
National regulations
EN (English)
SDS ID: AKB154
9/11
BORON ALLYLOXIDE Safety Data Sheet Triallyl borate (1693-71-6) Listed on the Canadian NDSL (Non-Domestic Substances List) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican national Inventory of Chemical Substances) Allyl alcohol (107-18-6) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Sustances List) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Japanese Poisonous and Deleterious Substances Control Law Japanese Pollutant Release and Transfer Register Law (PRTR Law) Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican national Inventory of Chemical Substances) 15.2.
Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information Abbreviations and acronyms
Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute Tox. 3 (Inhalation) Acute Tox. 3 (Oral) Aquatic Acute 1 Eye Irrit. 2 Flam. Liq. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 H225 H226 H301 H311 H315 H319 H331 H335 H400 R10 R23/24/25 R36/37/38 R50 N T Xi
: Abbreviations: ND: Not Determined, No Data; NA: Not Applicable; LD: Lethal Dose; LC: Lethal Concentration; ATE: Acute Toxicity Estimates; H: hour; °: °C unless otherwise stated; mm: millimeters Hg, torr; PEL: permissible exposure level; TWA: time weighted average; TLV: threshold limit value; TG: Test Guideline; NIOSH: National Institute for Occupational Safety and Health; IARC: International Agency for Research on Cancer; NTP: National Toxicology Program; HMIS: Hazardous Material Information System; CAS No.: Chemcial Abstract Service Registration Number; EC No.: European Commission Registration Number; EC Index No.: European Commission Index Number; OECD: The Organisation for Economic Co-operation and Development. Acute toxicity (dermal), Category 3 Acute toxicity (inhal.), Category 3 Acute toxicity (oral), Category 3 Hazardous to the aquatic environment — Acute Hazard, Category 1 Serious eye damage/eye irritation, Category 2 Flammable liquids, Category 2 Flammable liquids, Category 3 Skin corrosion/irritation, Category 2 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation Highly flammable liquid and vapour Flammable liquid and vapour Toxic if swallowed Toxic in contact with skin Causes skin irritation Causes serious eye irritation Toxic if inhaled May cause respiratory irritation Very toxic to aquatic life Flammable Toxic by inhalation, in contact with skin and if swallowed Irritating to eyes, respiratory system and skin Very toxic to aquatic organisms Dangerous for the environment Toxic Irritant
Prepared by safety and environmental affairs. 01/09/2015
EN (English)
SDS ID: AKB154
10/11
BORON ALLYLOXIDE Safety Data Sheet
SDS EU (REACH Annex II) - Custom according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010 The information contained in this document has been gathered from reference materials and/or Gelest, Inc. test data and is to the best knowledge and belief of Gelest, Inc. accurate and reliable. Such information is offered solely for your consideration, investigation and verification. It is not suggested or guaranteed that the hazard precautions or procedures described are the only ones which exist. Gelest, Inc. makes no warranties, express or implied, with respect to the use of such information and assumes no responsibility therefore. Information on this safety data sheet is not intended to constitute a basis for product specifications.
© 2015 Gelest Inc. Morrisville, PA 19067
01/09/2015
EN (English)
SDS ID: AKB154
11/11
