Client Name. - ThomasNet
Client Name. Contact Name
Released by: Mark Jordi, Ph.D. President Job Number: J8679 Case Study
Page 1 of 24
Dear Client, Please find enclosed the test results for your samples described as: 1234-
Milk Jug PE Rope Unstabilized Resin Clear PE Bag
The following tests were performed: 1. Differential Scanning Calorimetry-Oxidative Induction Time (DSC-OIT)
Objective The goal of the analysis was to determine the relative abundance of thermal stabilizers in each sample using DSC-OIT. The unstabilized resin is known to contain no stabilizer, while the stabilizer content of each other resin is unknown.
Summary of Results Milk Jug was analyzed at temperatures between 190 °C and 230 °C to determine an optimal temperature that provides an optimal balance of run time and resolution. The results of optimization can be found in Table 1. 195 °C was found to be an appropriate temperature, and all samples were analyzed at 195 °C. It was found that Milk jug showed the longest oxidative induction time. This indicates that Milk Jug possessed the most effective thermal stabilizer relative to the other samples. The effectiveness of the stabilizer in PE Rope and Clear PE Bag was compared relative to Milk Jug. Unstabilized resin was used as a baseline for minimum oxidation time of polyethylene as it did not possess stabilizer and was used to correct for the oxidation time of PE. Oxidation times of the samples can be found in Table 2.
Background Differential Scanning Calorimetry-Oxidative Induction Time (DSC-OIT) is a thermal analysis method performed typically on stabilized polyolefins to determine the relative amount of antioxidant remaining in a material. DSC-OIT is therefore commonly used in two capacities: To investigate the current state of the thermal stabilizer as a quality control measure or to ensure
Page 2 of 24
sufficient thermal stabilizer is present in a polymer formulation for a particular application. Both common applications are accomplished through comparison of the sample with a standard known to possess either sufficient or deficient amounts of thermal stabilizer relative to the unknown sample.
Individual Test Results A summary of the individual test results is provided below. All accompanying data, including spectra, has been included in the data section of this report.
DSC-OIT The samples were analyzed to determine their oxidation induction time. In this analysis, the sample is initially heated to a predefined temperature under nitrogen and then the atmosphere is switched to oxygen. The time for the onset of oxidation is then measured. A longer time for onset of oxidation generally indicates a higher level of stabilization is present in the polymer. Results Milk Jug was analyzed at temperatures between 190, 195, 200, 210, 220, and 230 °C to determine an optimal temperature that provides an optimal balance of run time and resolution. The results of optimization can be found in Table 1. Furthermore, an overlay of the thermograms acquired at each temperature can be found in Figure 1. It was also found that the reduction of oxidation time as a function of temperature exhibits an exponential decay curve with an R2 value of 0.9906 as can be seen in Figure 2. Based on the exponential decay curve seen in Figure 2, 195 °C was selected as a temperature to analyze the remaining samples. Table 1 DSC-OIT Oxidation Times of Plastic Milk Jug at Various Temperatures Oxidation Average Oxidation Temperature (°C) Run Time Time 230 220 210 200 195 190
1 2 1 2 1 2 1 2 1 2 1 2
1.56 1.60 2.83 3.48 7.09 7.49 13.56 14.15 28.34 27.01 N/A N/A
Page 3 of 24
1.58 3.16 7.29 13.86 27.68 N/A
Figure 1: Overlay of thermograms of Milk Jug at various oxidation temperature of Milk Jug
Oxidation time of stabilized Polyethylene with respect to Oxidation Temperature 30
Oxidation Time (Min)
25 20 15 y = 1E+08e-0.079x R² = 0.9906
10 5 0 190
195
200
205
210
215
220
225
230
Oxidation Temperature (°C)
Figure 2: Graph of Oxidation Time as a Function of Oxidation Temperature of Milk Jug
Page 4 of 24
235
An overlay of the thermograms for each sample can be found in Figure 1. It was found that Milk jug showed the longest oxidative induction time. This indicates that Milk Jug possessed the highest thermal stability relative to the other samples. The thermal stability of the PE Rope and Clear PE Bag relative to Milk Jug was determined. Unstabilized resin was used as a baseline for the minimum oxidation time of polyethylene. Oxidation times of the samples and their relative thermal stability can be found in Table 2. Table 2 DSC-OIT Oxidation Times of Samples at 195 °C Temperature (°C) Milk Jug PE Rope Clear PE Bag Unstabilized Resin
Run
Oxidation Time
1 2 1 2 1 2 1 2
28.34 27.01 20.29 19.92 17.24 17.93 0.22 0.24
Average Oxidation Time
Thermal Stability Compared to Milk Jug (%)
27.68
100
20.11
72.42
17.59
63.24
0.23
0
Figure 3: Overlay of thermograms of Milk Jug at various oxidation temperature of Milk Jug
Page 5 of 24
Analysis Conditions This section of a Jordi report provides information on the methods used including instrument type, temperatures, solvents, sample preparation, etc. The specific conditions have been removed for this case study.
Closing Comments Deformulation of an unknown material is intended to provide a best estimate of the chemical nature of the sample. All chemical structures are supported by the evidence presented but are subject to revision upon receipt of additional evidence. Additional factors such as material processing conditions may also affect final material properties. Jordi Labs’ reports are issued solely for the use of the clients to whom they are addressed. No quotations from reports or use of the Jordi name is permitted except as authorized in writing. The liability of Jordi Labs with respect to the services rendered shall be limited to the amount of consideration paid for such services and do not include any consequential damages. Jordi Labs specializes in polymer testing and has 30 years experience doing complete polymer deformulations. We are one of the few labs in the country specialized in this type of testing. We will work closely with you to help explain your test results and solve your problem. We appreciate your business and are looking forward to speaking with you concerning these results. Sincerely,
David York
Mark Jordi
David York, M.S. Senior Chemist Jordi Labs LLC
Mark Jordi, Ph. D. President Jordi Labs LLC
Page 6 of 24
Sample: Milk Jug 190C Size: 5.2460 mg Method: Oxygen induction time
File: R:...\Milk Jug 190C.002
DSC
Run Date: 15-Aug-2014 14:04 Instrument: DSC Q2000 V24.11 Build 124
Heat Flow (W/g)
1
-1 0 Exo Up
10
20
Page 7 of 24
Time (min)
30
40
50 Universal V4.5A TA Instruments
Sample: Milk Jug 190C Size: 5.0580 mg Method: Oxygen induction time
File: R:...\Milk Jug 190C.001
DSC
Run Date: 06-Aug-2014 11:32 Instrument: DSC Q2000 V24.11 Build 124
Heat Flow (W/g)
1
-1 0 Exo Up
10
20
Page 8 of 24
Time (min)
30
40
50 Universal V4.5A TA Instruments
Sample: Milk Jug 195C Size: 5.2100 mg Method: Oxygen induction time
File: R:...\Milk Jug 195C.002
DSC
Run Date: 12-Aug-2014 13:02 Instrument: DSC Q2000 V24.11 Build 124
1.2
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0 0.69min194.99°C
28.34min
-0.2 10 Exo Up
20
30
Page 9 of 24
Time (min)
40
50
60 Universal V4.5A TA Instruments
Sample: Milk Jug 195C Size: 5.2620 mg Method: Oxygen induction time
File: R:...\Milk Jug 195C.005
DSC
Run Date: 14-Aug-2014 09:06 Instrument: DSC Q2000 V24.11 Build 124
1.5
Heat Flow (W/g)
1.0
0.5
0.0 0.57min194.99°C
27.01min
-0.5 10 Exo Up
20
30
Page 10 of 24
Time (min)
40
50
60 Universal V4.5A TA Instruments
Sample: Milk Jug 200C Size: 5.1580 mg Method: Oxygen induction time
File: R:...\Milk Jug 200C.001
DSC
Run Date: 06-Aug-2014 09:54 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
13.56min
0.0
-0.5 10 Exo Up
15
20
25
Page 11 of 24
Time (min)
30
35
40 Universal V4.5A TA Instruments
Sample: Milk Jug 200C Size: 5.3060 mg Method: Oxygen induction time
File: R:...\Milk Jug 200C.003
DSC
Run Date: 08-Aug-2014 14:19 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.0
14.15min
-0.5 10 Exo Up
15
20
25
Page 12 of 24
Time (min)
30
35
40 Universal V4.5A TA Instruments
Sample: Milk Jug 210C Size: 5.3100 mg Method: Oxygen induction time
File: R:...\Milk Jug 210C.001
DSC
Run Date: 05-Aug-2014 13:17 Instrument: DSC Q2000 V24.11 Build 124
3
Heat Flow (W/g)
2
1
7.09min
0
-1 12 Exo Up
14
16
18
20
Page 13 of 24
22
Time (min)
24
26
28
30
Universal V4.5A TA Instruments
Sample: Milk Jug 210C Size: 5.1540 mg Method: Oxygen induction time
File: R:...\Milk Jug 210C.002
DSC
Run Date: 07-Aug-2014 14:41 Instrument: DSC Q2000 V24.11 Build 124
2.5
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.0
7.49min
-0.5 12 Exo Up
14
16
18
Page 14 of 24
Time (min)
20
22
24
26 Universal V4.5A TA Instruments
Sample: Milk Jug 220C Size: 5.2040 mg Method: Oxygen induction time
File: R:...\Milk Jug 220C.002
DSC
Run Date: 05-Aug-2014 08:59 Instrument: DSC Q2000 V24.11 Build 124
4
Heat Flow (W/g)
3
2
1
2.83min
0
-1 13 Exo Up
14
15
16
Page 15 of 24
Time (min)
17
18
19
20 Universal V4.5A TA Instruments
Sample: Milk Jug 220C Size: 5.1220 mg Method: Oxygen induction time
File: R:...\Milk Jug 220C.001
DSC
Run Date: 07-Aug-2014 13:28 Instrument: DSC Q2000 V24.11 Build 124
4
Heat Flow (W/g)
3
2
1
3.48min
0
-1 13 Exo Up
14
15
16
Page 16 of 24
Time (min)
17
18
19
20 Universal V4.5A TA Instruments
Sample: Milk Jug 230C Size: 5.1160 mg Method: Oxygen induction time
File: R:...\Milk Jug 230C.003
DSC
Run Date: 05-Aug-2014 10:07 Instrument: DSC Q2000 V24.11 Build 124
8
Heat Flow (W/g)
6
4
2
1.56min
0
-2 14 Exo Up
15
16
17
Page 17 of 24
Time (min)
18
19
20
21 Universal V4.5A TA Instruments
Sample: Milk Jug 230C Size: 5.1180 mg Method: Oxygen induction time
File: R:...\Milk Jug 230C.001
DSC
Run Date: 07-Aug-2014 11:56 Instrument: DSC Q2000 V24.11 Build 124
10
8
Heat Flow (W/g)
6
4
2
1.60min
0
-2 14 Exo Up
15
16
17
Page 18 of 24
Time (min)
18
19
20
21 Universal V4.5A TA Instruments
Sample: Rope 195C Size: 5.1880 mg Method: Oxygen induction time
File: R:...\Rope 195C.001
DSC
Run Date: 20-Aug-2014 13:42 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.0
17.24min
-0.5 10 Exo Up
15
20
25
Page 19 of 24
Time (min)
30
35
40
45 Universal V4.5A TA Instruments
Sample: Rope 195C Size: 5.0160 mg Method: Oxygen induction time
File: R:...\Rope 195C.002
DSC
Run Date: 21-Aug-2014 09:41 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.83min 195.03°C
0.0
17.93min
-0.5 10 Exo Up
15
20
25
Page 20 of 24
Time (min)
30
35
40
45 Universal V4.5A TA Instruments
Sample: Clear Plastic Bag 195C Size: 4.9580 mg Method: Oxygen induction time
File: R:...\Clear Plastic Bag 195C.001
DSC
Run Date: 19-Aug-2014 11:23 Instrument: DSC Q2000 V24.11 Build 124
1.2
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0
20.29min
-0.2 10 Exo Up
15
20
25
30
Page 21 of 24
Time (min)
35
40
45
50
Universal V4.5A TA Instruments
Sample: Clear Plastic Bag 195C Size: 5.0940 mg Method: Oxygen induction time
File: R:...\Clear Plastic Bag 195C.003
DSC
Run Date: 20-Aug-2014 09:56 Instrument: DSC Q2000 V24.11 Build 124
1.2
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0
19.92min
-0.2 10 Exo Up
15
20
25
30
Page 22 of 24
Time (min)
35
40
45
50
Universal V4.5A TA Instruments
Sample: Kodak Size: 5.1640 mg Method: Oxygen induction time
File: R:...\Kodak 195C.001
DSC
Run Date: 15-Aug-2014 15:39 Instrument: DSC Q2000 V24.11 Build 124
1.2
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0 0.22min
-0.2 12 Exo Up
14
16
18
20
Page 23 of 24
22
Time (min)
24
26
28
30
Universal V4.5A TA Instruments
Sample: Kodak Size: 5.4060 mg Method: Oxygen induction time
File: R:...\Kodak 195C.002
DSC
Run Date: 15-Aug-2014 16:52 Instrument: DSC Q2000 V24.11 Build 124
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0 0.24min
-0.2 12 Exo Up
14
16
Page 24 of 24
Time (min)
18
20
22 Universal V4.5A TA Instruments
Released by: Mark Jordi, Ph.D. President Job Number: J8679 Case Study
Page 1 of 24
Dear Client, Please find enclosed the test results for your samples described as: 1234-
Milk Jug PE Rope Unstabilized Resin Clear PE Bag
The following tests were performed: 1. Differential Scanning Calorimetry-Oxidative Induction Time (DSC-OIT)
Objective The goal of the analysis was to determine the relative abundance of thermal stabilizers in each sample using DSC-OIT. The unstabilized resin is known to contain no stabilizer, while the stabilizer content of each other resin is unknown.
Summary of Results Milk Jug was analyzed at temperatures between 190 °C and 230 °C to determine an optimal temperature that provides an optimal balance of run time and resolution. The results of optimization can be found in Table 1. 195 °C was found to be an appropriate temperature, and all samples were analyzed at 195 °C. It was found that Milk jug showed the longest oxidative induction time. This indicates that Milk Jug possessed the most effective thermal stabilizer relative to the other samples. The effectiveness of the stabilizer in PE Rope and Clear PE Bag was compared relative to Milk Jug. Unstabilized resin was used as a baseline for minimum oxidation time of polyethylene as it did not possess stabilizer and was used to correct for the oxidation time of PE. Oxidation times of the samples can be found in Table 2.
Background Differential Scanning Calorimetry-Oxidative Induction Time (DSC-OIT) is a thermal analysis method performed typically on stabilized polyolefins to determine the relative amount of antioxidant remaining in a material. DSC-OIT is therefore commonly used in two capacities: To investigate the current state of the thermal stabilizer as a quality control measure or to ensure
Page 2 of 24
sufficient thermal stabilizer is present in a polymer formulation for a particular application. Both common applications are accomplished through comparison of the sample with a standard known to possess either sufficient or deficient amounts of thermal stabilizer relative to the unknown sample.
Individual Test Results A summary of the individual test results is provided below. All accompanying data, including spectra, has been included in the data section of this report.
DSC-OIT The samples were analyzed to determine their oxidation induction time. In this analysis, the sample is initially heated to a predefined temperature under nitrogen and then the atmosphere is switched to oxygen. The time for the onset of oxidation is then measured. A longer time for onset of oxidation generally indicates a higher level of stabilization is present in the polymer. Results Milk Jug was analyzed at temperatures between 190, 195, 200, 210, 220, and 230 °C to determine an optimal temperature that provides an optimal balance of run time and resolution. The results of optimization can be found in Table 1. Furthermore, an overlay of the thermograms acquired at each temperature can be found in Figure 1. It was also found that the reduction of oxidation time as a function of temperature exhibits an exponential decay curve with an R2 value of 0.9906 as can be seen in Figure 2. Based on the exponential decay curve seen in Figure 2, 195 °C was selected as a temperature to analyze the remaining samples. Table 1 DSC-OIT Oxidation Times of Plastic Milk Jug at Various Temperatures Oxidation Average Oxidation Temperature (°C) Run Time Time 230 220 210 200 195 190
1 2 1 2 1 2 1 2 1 2 1 2
1.56 1.60 2.83 3.48 7.09 7.49 13.56 14.15 28.34 27.01 N/A N/A
Page 3 of 24
1.58 3.16 7.29 13.86 27.68 N/A
Figure 1: Overlay of thermograms of Milk Jug at various oxidation temperature of Milk Jug
Oxidation time of stabilized Polyethylene with respect to Oxidation Temperature 30
Oxidation Time (Min)
25 20 15 y = 1E+08e-0.079x R² = 0.9906
10 5 0 190
195
200
205
210
215
220
225
230
Oxidation Temperature (°C)
Figure 2: Graph of Oxidation Time as a Function of Oxidation Temperature of Milk Jug
Page 4 of 24
235
An overlay of the thermograms for each sample can be found in Figure 1. It was found that Milk jug showed the longest oxidative induction time. This indicates that Milk Jug possessed the highest thermal stability relative to the other samples. The thermal stability of the PE Rope and Clear PE Bag relative to Milk Jug was determined. Unstabilized resin was used as a baseline for the minimum oxidation time of polyethylene. Oxidation times of the samples and their relative thermal stability can be found in Table 2. Table 2 DSC-OIT Oxidation Times of Samples at 195 °C Temperature (°C) Milk Jug PE Rope Clear PE Bag Unstabilized Resin
Run
Oxidation Time
1 2 1 2 1 2 1 2
28.34 27.01 20.29 19.92 17.24 17.93 0.22 0.24
Average Oxidation Time
Thermal Stability Compared to Milk Jug (%)
27.68
100
20.11
72.42
17.59
63.24
0.23
0
Figure 3: Overlay of thermograms of Milk Jug at various oxidation temperature of Milk Jug
Page 5 of 24
Analysis Conditions This section of a Jordi report provides information on the methods used including instrument type, temperatures, solvents, sample preparation, etc. The specific conditions have been removed for this case study.
Closing Comments Deformulation of an unknown material is intended to provide a best estimate of the chemical nature of the sample. All chemical structures are supported by the evidence presented but are subject to revision upon receipt of additional evidence. Additional factors such as material processing conditions may also affect final material properties. Jordi Labs’ reports are issued solely for the use of the clients to whom they are addressed. No quotations from reports or use of the Jordi name is permitted except as authorized in writing. The liability of Jordi Labs with respect to the services rendered shall be limited to the amount of consideration paid for such services and do not include any consequential damages. Jordi Labs specializes in polymer testing and has 30 years experience doing complete polymer deformulations. We are one of the few labs in the country specialized in this type of testing. We will work closely with you to help explain your test results and solve your problem. We appreciate your business and are looking forward to speaking with you concerning these results. Sincerely,
David York
Mark Jordi
David York, M.S. Senior Chemist Jordi Labs LLC
Mark Jordi, Ph. D. President Jordi Labs LLC
Page 6 of 24
Sample: Milk Jug 190C Size: 5.2460 mg Method: Oxygen induction time
File: R:...\Milk Jug 190C.002
DSC
Run Date: 15-Aug-2014 14:04 Instrument: DSC Q2000 V24.11 Build 124
Heat Flow (W/g)
1
-1 0 Exo Up
10
20
Page 7 of 24
Time (min)
30
40
50 Universal V4.5A TA Instruments
Sample: Milk Jug 190C Size: 5.0580 mg Method: Oxygen induction time
File: R:...\Milk Jug 190C.001
DSC
Run Date: 06-Aug-2014 11:32 Instrument: DSC Q2000 V24.11 Build 124
Heat Flow (W/g)
1
-1 0 Exo Up
10
20
Page 8 of 24
Time (min)
30
40
50 Universal V4.5A TA Instruments
Sample: Milk Jug 195C Size: 5.2100 mg Method: Oxygen induction time
File: R:...\Milk Jug 195C.002
DSC
Run Date: 12-Aug-2014 13:02 Instrument: DSC Q2000 V24.11 Build 124
1.2
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0 0.69min194.99°C
28.34min
-0.2 10 Exo Up
20
30
Page 9 of 24
Time (min)
40
50
60 Universal V4.5A TA Instruments
Sample: Milk Jug 195C Size: 5.2620 mg Method: Oxygen induction time
File: R:...\Milk Jug 195C.005
DSC
Run Date: 14-Aug-2014 09:06 Instrument: DSC Q2000 V24.11 Build 124
1.5
Heat Flow (W/g)
1.0
0.5
0.0 0.57min194.99°C
27.01min
-0.5 10 Exo Up
20
30
Page 10 of 24
Time (min)
40
50
60 Universal V4.5A TA Instruments
Sample: Milk Jug 200C Size: 5.1580 mg Method: Oxygen induction time
File: R:...\Milk Jug 200C.001
DSC
Run Date: 06-Aug-2014 09:54 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
13.56min
0.0
-0.5 10 Exo Up
15
20
25
Page 11 of 24
Time (min)
30
35
40 Universal V4.5A TA Instruments
Sample: Milk Jug 200C Size: 5.3060 mg Method: Oxygen induction time
File: R:...\Milk Jug 200C.003
DSC
Run Date: 08-Aug-2014 14:19 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.0
14.15min
-0.5 10 Exo Up
15
20
25
Page 12 of 24
Time (min)
30
35
40 Universal V4.5A TA Instruments
Sample: Milk Jug 210C Size: 5.3100 mg Method: Oxygen induction time
File: R:...\Milk Jug 210C.001
DSC
Run Date: 05-Aug-2014 13:17 Instrument: DSC Q2000 V24.11 Build 124
3
Heat Flow (W/g)
2
1
7.09min
0
-1 12 Exo Up
14
16
18
20
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22
Time (min)
24
26
28
30
Universal V4.5A TA Instruments
Sample: Milk Jug 210C Size: 5.1540 mg Method: Oxygen induction time
File: R:...\Milk Jug 210C.002
DSC
Run Date: 07-Aug-2014 14:41 Instrument: DSC Q2000 V24.11 Build 124
2.5
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.0
7.49min
-0.5 12 Exo Up
14
16
18
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Time (min)
20
22
24
26 Universal V4.5A TA Instruments
Sample: Milk Jug 220C Size: 5.2040 mg Method: Oxygen induction time
File: R:...\Milk Jug 220C.002
DSC
Run Date: 05-Aug-2014 08:59 Instrument: DSC Q2000 V24.11 Build 124
4
Heat Flow (W/g)
3
2
1
2.83min
0
-1 13 Exo Up
14
15
16
Page 15 of 24
Time (min)
17
18
19
20 Universal V4.5A TA Instruments
Sample: Milk Jug 220C Size: 5.1220 mg Method: Oxygen induction time
File: R:...\Milk Jug 220C.001
DSC
Run Date: 07-Aug-2014 13:28 Instrument: DSC Q2000 V24.11 Build 124
4
Heat Flow (W/g)
3
2
1
3.48min
0
-1 13 Exo Up
14
15
16
Page 16 of 24
Time (min)
17
18
19
20 Universal V4.5A TA Instruments
Sample: Milk Jug 230C Size: 5.1160 mg Method: Oxygen induction time
File: R:...\Milk Jug 230C.003
DSC
Run Date: 05-Aug-2014 10:07 Instrument: DSC Q2000 V24.11 Build 124
8
Heat Flow (W/g)
6
4
2
1.56min
0
-2 14 Exo Up
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Time (min)
18
19
20
21 Universal V4.5A TA Instruments
Sample: Milk Jug 230C Size: 5.1180 mg Method: Oxygen induction time
File: R:...\Milk Jug 230C.001
DSC
Run Date: 07-Aug-2014 11:56 Instrument: DSC Q2000 V24.11 Build 124
10
8
Heat Flow (W/g)
6
4
2
1.60min
0
-2 14 Exo Up
15
16
17
Page 18 of 24
Time (min)
18
19
20
21 Universal V4.5A TA Instruments
Sample: Rope 195C Size: 5.1880 mg Method: Oxygen induction time
File: R:...\Rope 195C.001
DSC
Run Date: 20-Aug-2014 13:42 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.0
17.24min
-0.5 10 Exo Up
15
20
25
Page 19 of 24
Time (min)
30
35
40
45 Universal V4.5A TA Instruments
Sample: Rope 195C Size: 5.0160 mg Method: Oxygen induction time
File: R:...\Rope 195C.002
DSC
Run Date: 21-Aug-2014 09:41 Instrument: DSC Q2000 V24.11 Build 124
2.0
Heat Flow (W/g)
1.5
1.0
0.5
0.83min 195.03°C
0.0
17.93min
-0.5 10 Exo Up
15
20
25
Page 20 of 24
Time (min)
30
35
40
45 Universal V4.5A TA Instruments
Sample: Clear Plastic Bag 195C Size: 4.9580 mg Method: Oxygen induction time
File: R:...\Clear Plastic Bag 195C.001
DSC
Run Date: 19-Aug-2014 11:23 Instrument: DSC Q2000 V24.11 Build 124
1.2
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0
20.29min
-0.2 10 Exo Up
15
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25
30
Page 21 of 24
Time (min)
35
40
45
50
Universal V4.5A TA Instruments
Sample: Clear Plastic Bag 195C Size: 5.0940 mg Method: Oxygen induction time
File: R:...\Clear Plastic Bag 195C.003
DSC
Run Date: 20-Aug-2014 09:56 Instrument: DSC Q2000 V24.11 Build 124
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Heat Flow (W/g)
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0.0
19.92min
-0.2 10 Exo Up
15
20
25
30
Page 22 of 24
Time (min)
35
40
45
50
Universal V4.5A TA Instruments
Sample: Kodak Size: 5.1640 mg Method: Oxygen induction time
File: R:...\Kodak 195C.001
DSC
Run Date: 15-Aug-2014 15:39 Instrument: DSC Q2000 V24.11 Build 124
1.2
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0 0.22min
-0.2 12 Exo Up
14
16
18
20
Page 23 of 24
22
Time (min)
24
26
28
30
Universal V4.5A TA Instruments
Sample: Kodak Size: 5.4060 mg Method: Oxygen induction time
File: R:...\Kodak 195C.002
DSC
Run Date: 15-Aug-2014 16:52 Instrument: DSC Q2000 V24.11 Build 124
1.0
Heat Flow (W/g)
0.8
0.6
0.4
0.2
0.0 0.24min
-0.2 12 Exo Up
14
16
Page 24 of 24
Time (min)
18
20
22 Universal V4.5A TA Instruments
