Concentrated Solar Power on Demand-CSPond - MIT

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Concentrated Solar Power on Demand CSPond: Solar Harvesting and Storage Charles Forsberg Department of Nuclear Science and Engineering (NSE) Massachusetts Institute of Technology 77 Massachusetts Ave; Bld. 42-207a; Cambridge, MA 02139 Tel: (617) 324-4010; Email: [email protected] November, 2011

CSPond Faculty: Alexander Slocum (ME), Jacopo Buongiorno (NSE), Charles Forsberg (NSE), Thomas McKrell (NSE), Alexander Mitsos (ME), Jean-Christophe Nave (ME) CSPond Students: Daniel Codd (ME), Amin Ghobeity (ME), Corey J. Noone (ME), Stefano Passerini (NSE), Jennifer Rees (ME), Folkers Rojas (ME)

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Joint Mechanical and Nuclear Science and Engineering Project Solar beam

Shared Liquid-Salt Technology Base Aperture (closes at night or in bad weather) Ground

L D

Fluoride-Salt HighTemperature Reactor (FHR)

Z

Graphite

Molten Salt Pond

Insulation

Salt to/from salt in loop at steam generator

Concentrated Solar Power on Demand (CSPonD)

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Outline Existing solar systems CSPond Base Case Design Experimental Validation Alternative Design Options Path Forward A. Slocum, J. Buongiorno, C. W. Forsberg, T. McKrell, A. Mitsos, J. Nave, D. Codd, A. Ghobeity, C. J. Noone, S. Passerini, F. Rojas, “Concentrated Solar Power on Demand,” J. Solar Energy

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Existing Solar Power Towers Mirrors reflect sunlight to boiler Boiler tubes on top of tall tower absorb light Heat water and convert to steam Steam turbine produces electricity Poor economics  

High capital cost Low thermal efficiency PS-10, 11MWe peak, image courtesy of N. Hanumara

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The Challenge is Cost Low efficiency system  

In theory: high efficiency In practice 

Low steam temperatures to avoid boiler-tube thermal fatigue from variable light 



Wind and sunlight always changing energy fluxes

High heat loses from exposed boiler tubes

High costs 

Mirrors  



Largest cost component Incentives for efficient light to electricity system

Tall tower

PS-10, Spain, 11MWe peak, image courtesy of N. Hanumara

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CSPond Base-Case Design

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CSPond Characteristics Combining Many Technologies in a New Way Concentrated solar thermal power system Built-in thermal storage Heliostat field similar to solar power tower Radically different light receiver to:  

Boost light-to-electricity efficiency Provide thermal heat storage

Unique features:  

Light volumetrically absorbed in liquid salt bath Salt bath could operate to 1000°C

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CSPond Description Figure Next Page

 

Mirrors shine sunlight to receiver Receiver is a high-temperature liquid salt bath inside insulated structure with open window for focused light   



Small window minimizes heat losses but very high power density of sunlight through open window  



Light volumetrically absorbed through several meters of liquid salt Building minimizes heat losses by receiver Enables salt temperatures to 900 C

Power density would destroy conventional boiler-tube collector Light absorbed volumetrically in several meters in salt

Requires high-temperature (semi-transparent) salt— Similar salt requirements as for FHR heat transfer loop

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Two Component System Non-Imaging Refractor Lid

Lid Heat Extraction Hot Salt to HX

Cold Salt from HX Light Reflected From Hillside Heliostat rows to CSPonD System

(Not to scale!)

Light Collected Inside Insulated Building With Open Window

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Advantages of Hillside Heliostat Field 



 

Eliminate tower-based receiver—heavy equipment on ground Avoid remote storage and high pressure pumps Downward focused light Potentially lower land costs

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CSPond Light Receiver 

Efficient light-to-heat collection  





Non-Imaging Refractor Lid

Hot Salt to HX

Concentrate light Focus light through small open window Minimize heat losses

Challenge  Light energy per unit area very high  Will vaporize solid collectors

Lid Heat Extraction

Cold Salt from HX

Light Volumetrically Absorbed in Liquid Salt Bath

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Light Focused On “Transparent” Salt Light volumetrically absorbed through several meters of salt Molten salt experience  Metal heat treating baths (right bottom)  Molten salt nuclear reactor Advantages  No light-flux limit  No thermal fatigue  Can go to extreme temperatures Molten Chloride Salt Bath (1100°C)

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Salt Vapor Condenses On Ceiling Cooled ceiling: Lid Heat Extraction Salt buildup until “liquid” salt layer with flow back to salt bath Self-protecting, self-healing ceiling Highly reflective

Non-Imaging Refractor Lid

Lid Heat Extraction Hot Salt to HX

Cold Salt from HX

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Capture Efficiency: Energy Balance

Heat to lid:

Qin

Qrad, pond-lid

Qconv, pond-lid Qvaporization Qreflected

System Losses: Qrad, lid-aperture Qconv, lid-aperture Qrad, pond-aperture

Qsalt

Qtank

ηcapture =

Qsystem Qin

=

Qin – Qlosses Qin

=

Qin – (Qrad, l-a + Qconv, l-a + Qrad, p-a + Qtank) Qin

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Two Classes Of Molten Salts 

Near-term: Nitrates 

 



Appearance of molten NaCl-KCl salt at 850°C

Used in some concentrated thermal energy solar systems Off the shelf Temperature limit of ~550°C (Degradation)

Longer-term: Chlorides and Carbonates  

Thermodynamically stable Peak temperatures > 1000°C

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System Design Enables Efficient Light Collection and High Temperatures 1.0

fraction of incident energy at aperture

0.9

NREL Solar II: salt 565C

0.8 0.7 0.6

Chloride Salt: 950C lid temp 660C

NREL Solar I: steam 500C

0.5

Compares favorably with measured values for CSP Power Tower Systems

Nitrate Salt: 550C lid temp 240C

Peak & average values

0.4 0.3

Aperture to Illuminated Pond Area ratio

0.2

system output (MWe):

4

nominal pond size

0.1

diameter (m):

0.0 0

500

1000

1500

2000

2500

Peak Concentration (kW/m^2, 'suns')

3000

3500

depth (m):

avg beam down angle (deg): Nitrate Salt, Lid peak temp (C): Chloride Salt, Lid peak temp (C): NREL (2003)

25.0 5.0 21.4 550/240 950/660 16/29

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CSPond Integral Heat Storage 



Divider plate (moves down)

Salt tank has insulated separator plate Plate functions  



Daytime

Separates hot and cold salt Bottom light absorber

Storage role 



If excess heat input, plate sinks to provide hot salt storage volume If power demand high, plate raised with cold salt storage under plate

Nighttime

Divider plate (moves up)

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Virtual Two-Tank Concept 4 MWe System Sizing: 2500 m3 salt 40 hours storage

Hot salt

Divider plate (moves down)

5m ∅28m

Daytime = charging

24/7 “hot salt” as the average temperature of the tank decreases when the sun is not shining

Nighttime

Cold salt Divider plate (moves up)

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System Performance Uses for lid heat:

Chloride (950/660)

Overall System Useful Energy

Nitrate (550/240) Salt Useful Energy

Low temp (Nitrate) •Power cycle pre/reheat •RO feedwater heat •MED feedwater heat High temp (Chloride) •Power cycle primary heat system output (MWe):

4

nominal pond size Lid Useful Energy

diameter (m):

25.0

depth (m):

5.0

avg beam down angle (deg):

21.4

Nitrate Salt, Lid peak temp (C):

550/240

Chloride Salt, Lid peak temp (C):

950/660

Lid αvis /εir

0.44

Low-temp heat rejection (C):

25

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CSPond Experimental Testing and Analysis

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Molten Salt Optical Characterization Solar Irradiance Attenuation of NaClKCl (50-50wt%) salt at 850°C NaNO3-KNO 3 (60-40wt%)

NaCl-KCl (50-50wt%)

(l) Variable optical path length transmission apparatus (r) Appearance of molten NaCl-KCl salt at 850°C

Experimental Range

Stefano Passerini, Dr. Tom McKrell, Prof. Jacopo Buongiorno, MIT

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60-Sun Solar Simulator 7x 1500 W metal halide lights MIT CSP Simulator

Spectral Intensity (arbitrary units)



Terrestrial solar spectrum

300



60 kW/m2 peak



∅38 cm aperture



Adjustable:

400

500

700

800

900

1000



height (0-1 m)

ε n = α solar = 0.11

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Calculated Optical Power (kW/m 2)

600

wavelength (nm)

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MIT CSP Solar Simulator

Commercial Xenon Solar Simulator

60



50

angle (0-90° tilt)

ε n = 0.05 α solar = 0.11

ε n = 0.06 α solar = 0.14

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30

x

20

10

0

10.5 kWe

0

2

4

6

X = radial offset from aperture center (cm)

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10

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Volumetric Light Absorption 1

0.9

2.8 h

t=0 0.8

8.3 h

Height (x/L)

0.7

0.6

Increasing Increasing time time

0.5

0.4

0 h salt 0 h tank

0.3

2.8 h salt 0.2

2.8 h tank 8.3 h salt

0.1

8.3 h tank 0 200

220

240

260

280

300

320

340

Temperature (°C)

Temperature distribution of NaNO3KNO3 (60-40wt%) heated optically

360

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Virtual Two-Tank System Testing Salt tank @ 300°C with nitrate salt

Ceramic (high temp) insulation

Fiberglass insulation

Inside Solar Simulator

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Divided Thermocline Storage UP

DOWN

Temperature distribution of NaNO3-KNO3 (60-40wt%) heated optically Enables 24/7 power

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Tank Wall Design  



Flexible alloy liner Reduces thermal shock in refractory lining “Internal” firebrick insulation allows for mild steel tank shell

Flexible protective liner made of AISI 321H stainless steel

from Kolb (1993) and Gabbrielli (2009)

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Solar Flux Distribution Modeling Incident Beam-down angle =

ϕ

Reflected θi

θr

θt

Transmitted

θ i = 90° − φ θr = θi n salt sin θ t = n air sin θ i

 sin(θ t − θ i )  Rs =    sin(θ t + θ i ) 

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 tan(θ t − θ i )  Rp =    tan(θ t + θ i )  R = (Rs + R p ) / 2

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CSPonD beam-down systems are in this range

1 Reflected intensity

0 0

45 Beam-down angle

90

Flux distribution in receiver from a single central heliostat

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CSPond Alternative Design Options

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Heliostat Field Placement Options Mirrors to Hilltop Collector

Tower Reflects Light Downward

Hillside Mirrors to Collector

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Multiple Power Cycle Options Salt Temperature: 500°C, 700°C, and 700+°C

Steam power cycles--Today Supercritical carbon dioxide power cycle   

High efficiency Very compact and potentially low cost Advanced technology

Air Brayton power cycle   

Existing technology No cooling water options Requires 700 C salt temperatures

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Carbon Dioxide Properties Result in Very Small Equipment Main compressor wheel: 85kW

Manufactured by Barber & Nichols for SNL

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50-MWe Power Conversion Unit

Small Units Shop Fabricated

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Air-Brayton Power Cycles Air Brayton power cycles have low cooling requirements relative to other power cycles Viable at salt peak temperatures of ~700 C 

Significant efficiency penalties at lower temperatures

Several different options

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Open-Air Recuperated Brayton Liquid-Salt Power Conversion Cycle

Stack

Air Inlet Recuperator

Heater

Reheater

salt

salt

Liquid Salt Air

Generator Compressor

Turbines

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Open-Air Brayton Liquid-Salt Combined Cycle Power Cycle

Stack

Heat Recovery Steam Generator

Air Inlet

High Temperature Salt Air Water or Steam

Heater

Reheater

Reheater

salt

salt

salt

Generator Compressor

Turbines

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Comparison of Brayton Power Cycles 700 C1 Salt; 100 MW(t) Plant Cycle

Air Brayton

Combined Cycle

Efficiency

40%

44%

Condenser Heat Rejection*

None (No water requirement)

28 MW(t)

1Efficiency

drops rapidly with peak temperature 2Traditional closed power cycles (Steam, Carbon Dioxide, Helium) with 50% efficiency reject 50 MW(t) to Condenser

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CSPond Status Patents Pending

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Two Parallel or Sequential Paths Forward Small 100 kw systems integration test using nitrate salts Uses proven existing solar salt  Rapid testing possible 

Develop higher-temperature chloride or carbonate CSPond Higher efficiency with potentially lower costs  Robust against salt degradation  Follow-on integration test with different salts 

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Next Step: 100 kWt Research System salt loop to/from HX

Overall receiver size: ~ 4m dia x 3m (w/o lid)

Lid geometry T.B.D. for 1-bounce down

Hot salt

Salt Tank: •2m dia x 2m depth •6.2 m3 salt capacity (11.2 metric tons) •Nitrate salt (550C/275C) •15 h storage (1.5 MWh) •2.4 MWh daily solar input required for continuous operation

Cold salt

Not shown: aperture cover, concentration “booster”, lid heat rejection system and divider plate actuator

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Next Step: Alternative Salts Insufficient Data for Non-Nitrate Systems NaNO Solar Irradiance Attenuation of NaCl3-KNO3 (60-40wt%) KCl (50-50wt%) salt at 850°C

NaCl-KCl (50-50wt%) Higher temperature salts more robust (no possibility of thermal decomposition) Higher efficiency with open air Brayton power cycles and no water requirements

Experimental Range

Stefano Passerini, Dr. Tom McKrell, Prof. Jacopo Buongiorno, MIT

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Conclusions Analysis and experiments indicate significantly better economics than existing concentrated solar power-tower systems (Higher efficiency) Significant uncertainties (Path forward)   

No small pilot plant under realistic conditions Limited review (Wider review underway now that patent filings complete) Large incentives for higher-temperature salt than nitrate (more robust system and dry cooling) but limited experimental data

Large incentives to determine commercial viability of CSPond

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Questions

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Biography: Charles Forsberg Dr. Charles Forsberg is the Executive Director of the Massachusetts Institute of Technology Nuclear Fuel Cycle Study, Director and principle investigator of the HighTemperature Salt-Cooled Reactor Project, and University Lead for Idaho National Laboratory Institute for Nuclear Energy and Science (INEST) Nuclear Hybrid Energy Systems program. Before joining MIT, he was a Corporate Fellow at Oak Ridge National Laboratory. He is a Fellow of the American Nuclear Society, a Fellow of the American Association for the Advancement of Science, and recipient of the 2005 Robert E. Wilson Award from the American Institute of Chemical Engineers for outstanding chemical engineering contributions to nuclear energy, including his work in hydrogen production and nuclear-renewable energy futures. He received the American Nuclear Society special award for innovative nuclear reactor design on salt-cooled reactors. Dr. Forsberg earned his bachelor's degree in chemical engineering from the University of Minnesota and his doctorate in Nuclear Engineering from MIT. He has been awarded 11 patents and has published over 200 papers.