CXCE040 CERIUM(lll) 2 ETHYLHEXANOATE GHS EU English
CXCE040 - CERIUM(lll) 2-ETHYLHEXANOATE
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet CXCE040 Date of issue: 27/07/2015
Version: 1.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Substance
Physical state
: Solid
Substance name
: CERIUM(lll) 2-ETHYLHEXANOATE
Product code
: CXCE040
Formula
: C24H45CeO6
Synonyms
: CEROUS OCTOATE; CERIUM TRIS(2-ETHYLHEXANOATE)
Chemical family
: RARE EARTH COMPOUND
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Use of the substance/mixture
1.2.2.
: Chemical intermediate For research and industrial use only
Uses advised against
No additional information available 1.3.
Details of the supplier of the safety data sheet
GELEST, INC. 11 East Steel Road Morrisville, PA 19067 USA T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST [email protected] - www.gelest.com GELEST INC. Stroofstrasse 27 Geb.2901 65933 Frankfurt am Main Germany T +49-(0)-69-3800-2150 - F +49-(0)-69-3800-2300 - (M-F): 8:00 AM - 5:30 PM [email protected] - www.gelestde.com 1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation, Category H319 2 Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects No additional information available
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
:
Signal word (CLP)
: Warning
Hazard statements (CLP)
: H319 - Causes serious eye irritation
Precautionary statements (CLP)
: P280 - Wear protective gloves/protective clothing/eye protection/face protection
GHS07
Print date: 29/01/2018
EN (English)
SDS ID: CXCE040
1/7
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet P264 - Wash hands thoroughly after handling P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention
2.3.
Other hazards
No additional information available
SECTION 3: Composition/information on ingredients 3.1.
Substances
Substance type
: Multi-constituent
Name
: CERIUM(lll) 2-ETHYLHEXANOATE
CAS-No.
: 56797-01-4
EC-No.
: 260-386-3
Name
Product identifier
%
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Cerium 2-ethylhexoate
(CAS-No.) 56797-01-4 (EC-No.) 260-386-3
> 95
Eye Irrit. 2, H319
2-Ethylhexanoic acid
(CAS-No.) 149-57-5 (EC-No.) 205-743-6 (EC Index-No.) 607-230-00-6
275 °C decomposes
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapour pressure
: No data available
Relative vapour density at 20 °C
: No data available
Relative density
: >1
% Volatiles
: 2000 mg/kg
2-Ethylhexanoic acid (149-57-5) LD50 oral rat LD50 dermal rabbit
1600 mg/kg 1140 mg/kg
Print date: 29/01/2018
EN (English)
SDS ID: CXCE040
4/7
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet 2-Ethylhexanoic acid (149-57-5) ATE CLP (oral)
3000 mg/kg bodyweight
Skin corrosion/irritation
: Not classified
Serious eye damage/irritation
: Causes serious eye irritation.
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
STOT-single exposure
: Not classified
STOT-repeated exposure
: Not classified
Aspiration hazard
: Not classified
Potential adverse human health effects and symptoms
: Compounds of cerium are generally of low toxicity. Workers exposed to cerium compounds have experienced sensitivity to heat, itching and skin lesions. Large doses to experimental animals have caused writhing, ataxia, labored respiration, sedation, hypotension and death by cardiovascular collapse. The toxicity of cerium oxalate, nonahydrate has not been studied.
Symptoms/effects after inhalation
: May cause irritation to the respiratory tract.
Symptoms/effects after skin contact
: May cause skin irritation.
Symptoms/effects after eye contact
: Causes serious eye irritation.
Symptoms/effects after ingestion
: May be harmful if swallowed.
Reason for classification
: Expert judgment
SECTION 12: Ecological information 12.1.
Toxicity
Acute aquatic toxicity
: Not classified
Chronic aquatic toxicity
: Not classified
2-Ethylhexanoic acid (149-57-5) LC50 fish 1 EC50 Daphnia 1 12.2.
70 mg/l (Exposure time: 96 h - Species: Pimephales promelas) 85.4 mg/l (Exposure time: 48 h - Species: Daphnia magna)
Persistence and degradability
No additional information available 12.3.
Bioaccumulative potential
2-Ethylhexanoic acid (149-57-5) Log Pow 12.4.
2.7
Mobility in soil
No additional information available 12.5.
Results of PBT and vPvB assessment
No additional information available 12.6.
Other adverse effects
No additional information available
SECTION 13: Disposal considerations 13.1.
Waste treatment methods
Product/Packaging disposal recommendations
: Dispose of solid materials or residues at a licensed site. Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information 14.1.
UN number
Not regulated for transport. 14.2.
UN proper shipping name
Not applicable 14.3.
Transport hazard class(es)
Not applicable 14.4.
Packing group
Not applicable Print date: 29/01/2018
EN (English)
SDS ID: CXCE040
5/7
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet 14.5.
Environmental hazards
Other information 14.6.
Special precautions for user
14.6.1.
Overland transport
: No supplementary information available.
No additional information available 14.6.2.
Transport by sea
No additional information available 14.6.3.
Air transport
No additional information available 14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information 15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
No REACH Annex XVII restrictions CERIUM(lll) 2-ETHYLHEXANOATE is not on the REACH Candidate List CERIUM(lll) 2-ETHYLHEXANOATE is not on the REACH Annex XIV List % Volatiles 15.1.2.
:
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet CXCE040 Date of issue: 27/07/2015
Version: 1.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Substance
Physical state
: Solid
Substance name
: CERIUM(lll) 2-ETHYLHEXANOATE
Product code
: CXCE040
Formula
: C24H45CeO6
Synonyms
: CEROUS OCTOATE; CERIUM TRIS(2-ETHYLHEXANOATE)
Chemical family
: RARE EARTH COMPOUND
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Use of the substance/mixture
1.2.2.
: Chemical intermediate For research and industrial use only
Uses advised against
No additional information available 1.3.
Details of the supplier of the safety data sheet
GELEST, INC. 11 East Steel Road Morrisville, PA 19067 USA T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST [email protected] - www.gelest.com GELEST INC. Stroofstrasse 27 Geb.2901 65933 Frankfurt am Main Germany T +49-(0)-69-3800-2150 - F +49-(0)-69-3800-2300 - (M-F): 8:00 AM - 5:30 PM [email protected] - www.gelestde.com 1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation, Category H319 2 Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects No additional information available
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
:
Signal word (CLP)
: Warning
Hazard statements (CLP)
: H319 - Causes serious eye irritation
Precautionary statements (CLP)
: P280 - Wear protective gloves/protective clothing/eye protection/face protection
GHS07
Print date: 29/01/2018
EN (English)
SDS ID: CXCE040
1/7
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet P264 - Wash hands thoroughly after handling P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention
2.3.
Other hazards
No additional information available
SECTION 3: Composition/information on ingredients 3.1.
Substances
Substance type
: Multi-constituent
Name
: CERIUM(lll) 2-ETHYLHEXANOATE
CAS-No.
: 56797-01-4
EC-No.
: 260-386-3
Name
Product identifier
%
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Cerium 2-ethylhexoate
(CAS-No.) 56797-01-4 (EC-No.) 260-386-3
> 95
Eye Irrit. 2, H319
2-Ethylhexanoic acid
(CAS-No.) 149-57-5 (EC-No.) 205-743-6 (EC Index-No.) 607-230-00-6
275 °C decomposes
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapour pressure
: No data available
Relative vapour density at 20 °C
: No data available
Relative density
: >1
% Volatiles
: 2000 mg/kg
2-Ethylhexanoic acid (149-57-5) LD50 oral rat LD50 dermal rabbit
1600 mg/kg 1140 mg/kg
Print date: 29/01/2018
EN (English)
SDS ID: CXCE040
4/7
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet 2-Ethylhexanoic acid (149-57-5) ATE CLP (oral)
3000 mg/kg bodyweight
Skin corrosion/irritation
: Not classified
Serious eye damage/irritation
: Causes serious eye irritation.
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
STOT-single exposure
: Not classified
STOT-repeated exposure
: Not classified
Aspiration hazard
: Not classified
Potential adverse human health effects and symptoms
: Compounds of cerium are generally of low toxicity. Workers exposed to cerium compounds have experienced sensitivity to heat, itching and skin lesions. Large doses to experimental animals have caused writhing, ataxia, labored respiration, sedation, hypotension and death by cardiovascular collapse. The toxicity of cerium oxalate, nonahydrate has not been studied.
Symptoms/effects after inhalation
: May cause irritation to the respiratory tract.
Symptoms/effects after skin contact
: May cause skin irritation.
Symptoms/effects after eye contact
: Causes serious eye irritation.
Symptoms/effects after ingestion
: May be harmful if swallowed.
Reason for classification
: Expert judgment
SECTION 12: Ecological information 12.1.
Toxicity
Acute aquatic toxicity
: Not classified
Chronic aquatic toxicity
: Not classified
2-Ethylhexanoic acid (149-57-5) LC50 fish 1 EC50 Daphnia 1 12.2.
70 mg/l (Exposure time: 96 h - Species: Pimephales promelas) 85.4 mg/l (Exposure time: 48 h - Species: Daphnia magna)
Persistence and degradability
No additional information available 12.3.
Bioaccumulative potential
2-Ethylhexanoic acid (149-57-5) Log Pow 12.4.
2.7
Mobility in soil
No additional information available 12.5.
Results of PBT and vPvB assessment
No additional information available 12.6.
Other adverse effects
No additional information available
SECTION 13: Disposal considerations 13.1.
Waste treatment methods
Product/Packaging disposal recommendations
: Dispose of solid materials or residues at a licensed site. Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information 14.1.
UN number
Not regulated for transport. 14.2.
UN proper shipping name
Not applicable 14.3.
Transport hazard class(es)
Not applicable 14.4.
Packing group
Not applicable Print date: 29/01/2018
EN (English)
SDS ID: CXCE040
5/7
CERIUM(lll) 2-ETHYLHEXANOATE Safety Data Sheet 14.5.
Environmental hazards
Other information 14.6.
Special precautions for user
14.6.1.
Overland transport
: No supplementary information available.
No additional information available 14.6.2.
Transport by sea
No additional information available 14.6.3.
Air transport
No additional information available 14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information 15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
No REACH Annex XVII restrictions CERIUM(lll) 2-ETHYLHEXANOATE is not on the REACH Candidate List CERIUM(lll) 2-ETHYLHEXANOATE is not on the REACH Annex XIV List % Volatiles 15.1.2.
:
