Elvacite® 4111 - Lucite International
Elvacite® 4111 Acrylic Resin Elvacite® 4111 is a low molecular weight methyl methacrylate / n-butyl methacrylate copolymer. Elvacite® 4111 is useful in clear, translucent or pigmented metal lacquers. It is a fast dissolving, low viscosity resin for coatings, inks, and adhesives.
Performance Features and Key Benefits
Low VOC applications Clear, translucen or pigmented metal coatings Heat seal lacquers Traffic marking paints Inks
Typical Properties & Manufacturers Release Specifications Typical Propertiesa of Elvacite® 4111 Appearance
Spherical beads
Specific Gravity, 25° C
1.13
Glass Transition Temp, onset
54°C
Molecular Weight (Mw)
32,000
Acid Number
3.5
a)
Typical physical properties listed are approximate values and should not be considered manufacturers release specifications. Manufacturers release specifications are subject to change without notice, please contact your Lucite International Representative for the latest product specification details.
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 1
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Elvacite® 4111 Manufacturers Release Specificationsb Inherent Viscosityc
0.150 – 0.165
% Moisture (max)
0.5
% Methacrylic Acid
0.6 – 0.8
Particle Size (Microtrac® D50)
100 – 300 microns
b) c)
Manufacturers release specifications are subject to change without notice. Please contact Lucite International, Inc. for the latest information. Inherent viscosity of a solution containing 0.25 g polymer in 50 ml of methylene chloride measured at 20°C using a No. 50 Cannon-Fenske viscometer
Preparing Solutions Elvacite® resins dissolve at room temperature but require constant agitation to prevent solvent-swollen granules of polymer from forming agglomerates and sticking to the walls of the vessel. Important: The polymer beads should be sifted directly into the vortex of the stirred solvent to speed wetting-out and dispersion. Continuous lowshear agitation for periods of 1-12 hours, depending on the grade and concentration of resin, is recommended. After the solution appears clear in the tank, a sample should be spread out on a Leneta card or glass. After the solvent evaporates and a film forms on the card or glass, there should not be any resin seeds. If there are any seeds, the tank should be agitated further to fully dissolve the resin. Tank agitation should not be stopped (except for sampling) until the film test indicates there are no resin seeds. Any cloudiness or residue may indicate that some polymer remains undissolved. The presence of water in the system can also cause cloudiness. Solution time can be reduced by heating; most common solvents can be heated to approximately 49°C (120°F) without the need for reflux equipment. High-shear agitation also cuts dissolving time, but requires care to avoid overheating and excessive solvent loss.
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 2
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Solvent Solubility Table I depicts the solubility of Elvacite® 4111 at 30% solids in various solvents. (S=Soluble, C=Cloudy solution, I=Insoluble) Alcohols Methyl Alcohol Ethyl Alcohol n-propyl alcohol Isopropyl alcohol Isoamyl alcohol Cyclohexanol Ethylene glycol Glycerol
I I I I I I I I
Amides Formamide I Dimethyl formamide (DMF) S Chlorohydrocarbons Methylene Chloride S Ethylene dichloride Perchloroethylene 1,1,1-Trichloroethane S Esters Methyl Formate Ethyl acetate
S S
Technical Data Sheet
Isopropyl acetate n-Butyl acetate n-Amyl acetate Butyl lactate Propylene glycol monoethyl ether acetate Methyl amyl acetate Ethers Diethyl Ether Diisopropyl ether Tetrahydrofuran (THF) “Cellosolve” Solvent Hydrocarbons Toluene Xylene n-Hexane Cyclohexane VM & P Naphtha Mineral Spirits Turpentine
S S S S S S S S S S S I I I I I
Ketones Acetone Methyl Ethyl Ketone Methyl Isobutyl Ketone Diisobutyl ketone Cyclohexanone Isophorone Diacetone Alcohol Methyl amyl ketone
S S S S S S S
Nitrile Acetonitrile
-
Nitroparaffins Nitromethane Nitroethane
S -
Vegetable Oils Castor oil Linseed oil (alkali-refined)
Elvacite® 4111 v20130624
I I
Page: 3
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Resin Compatibility Elvacite® 4111 is compatible with the following Elvacite® Resin Grades: 2013, 2014, 2016, 2028, 2042, and 2043. It is also compatible with the other types of resins, as illustrated in the following table: Blending Resin Alkyd Aroplaz 1271 Aroplaz 1351 Chempol 13-1410 Paraplex RG-2 Plaskon 3105 Cellulosic Cellulose acetate 39-5-5B
Description
Long linseed drying oil Long castor nondrying oil Safflower drying oil, acrylate mod. Nondrying oil, sebacic
30% in MEK
Elvacite / Blending Resin* (by solids weight) 75/25 50/50 25/75 Spencer Kellogg C H H Spencer Kellogg C C C Freeman C C C Chemical Rohm & Haas I I I Co. Cargill, Inc. --H H Supplier
30% in Acetone or Hercules Inc. MEK 30% in MEK Eastman Chemical 30% in MEK Hercules Inc. MEK/alcohol soln. Hercules Inc.
100% Resin
Epon 1001
Neoprene AC-Soft
30% in MEK 30% in MEK 50% in Xylene
Short coconut nondrying oil 60% in Xylene
Cellulose Acetate Butyrate, ½ - sec. Ethyl Cellulose N-7 Nitrocellulose “RS”, ½-sec Isopropyl Epoxy Epon 828
Elastomers EMD-504 Hypalon 30
Form of Blended Resin Tested
30% in MEK
Polyisobutylene Clorosulfonated polyethylene Polychloroprene
30% in Toluene 15% in Toluene 15% in Toluene
I
I
I
C
C
C
I C
I C
I C
Shell Chemical Co. Shell Chemical Co.
C
---
C
C
C
C
Exxon Chemical Dupont Polymers Dupont Polymers
I I
I I
----
I
I
---
Rosin Derivatives Ester Gum 8L Pentalyn 255 Pentalyn 830
Pentaerythritol ester Pentaerythritol ester
30% in MEK 30% in MEK 30% in MEK
Hercules Inc. Hercules Inc. Hercules Inc.
-H H
H H H
H H H
Vinyl Chloride Resins Bakelite VAGH Bakelite VMCH Bakelite VYHH
Copolymer Copolymer Copolymer
30% in MEK 30% in MEK 30% in MEK
Union Carbide Union Carbide Union Carbide
C C C
C C C
C C C
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 4
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Bakelite VYNS Exon 450
Copolymer Copolymer
15% in MEK 15% in MEK
Union Carbide Firestone Plastics
C C
C C
C --
Exon 9290
Homopolymer
15% in THF
C
C
C
Geon 103 EP Other Types Arochem 650 Aroset 4110 Dammar DC-840
Homopolymer
15% in THF
Firestone Plastics B.F. Goodrich
C
C
C
Maleic-modified hard resin Acrylic resin
30% in MEK 30% in MEK 30% in Toluene 60% in Toluene
Spencer Kellogg Spencer Kellogg
C C I C
C C I C
C C H C
Parlon S 10 Piccoumaron Santolite MHP Shellac Super-Bechacite 2000
Chlorinated rubber 30% in MEK Coumarone-indene resin 30% in MEK Sulfonamide-formaldehyde 30% in MEK 30% in Methanol Permanently fusible 30% in MEK phenolic Triazine-formaldehyde resin 30% in MEK
C C C H C
C C C I C
C C C I C
C
H
I
Uformite MX-61
Silicone resin
Dow Corning Corp. Hercules Inc. Hercules Inc. Monsanto Co. Reichold Chemicals Rohm & Haas Co.
* 4111 was not tested, but is expected to be similar to 2013.
(C=Clear solution, H=Hazy solution, I=Insoluble)
Plasticizer Compatibility Elvacite® 4111 is compatible at a 50/50 resin/plasticizer ratio with the following plasticizers: Santicizer 8 (N-ethyl toluene sulfonamides) Santicizer 160 (butyl benzyl phthalate) Tricresyl phosphate Hercoflex 600 (pentaerythritol ester)
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 5
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Lucite International Inc. The Lucite Center 7275 Goodlett Farms Parkway Cordova, TN 38016 USA T: +1 (901) 381 2000 www.luciteinternational.com/resins Lucite International Specialty Polymers and Resins Ltd Horndale Avenue Newton Aycliffe DL5 6YE United Kingdom T: +44 (0) 1325 300990 F: +44 (0) 1325 314925 www.luciteinternational.com/resins
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 6
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Performance Features and Key Benefits
Low VOC applications Clear, translucen or pigmented metal coatings Heat seal lacquers Traffic marking paints Inks
Typical Properties & Manufacturers Release Specifications Typical Propertiesa of Elvacite® 4111 Appearance
Spherical beads
Specific Gravity, 25° C
1.13
Glass Transition Temp, onset
54°C
Molecular Weight (Mw)
32,000
Acid Number
3.5
a)
Typical physical properties listed are approximate values and should not be considered manufacturers release specifications. Manufacturers release specifications are subject to change without notice, please contact your Lucite International Representative for the latest product specification details.
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 1
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Elvacite® 4111 Manufacturers Release Specificationsb Inherent Viscosityc
0.150 – 0.165
% Moisture (max)
0.5
% Methacrylic Acid
0.6 – 0.8
Particle Size (Microtrac® D50)
100 – 300 microns
b) c)
Manufacturers release specifications are subject to change without notice. Please contact Lucite International, Inc. for the latest information. Inherent viscosity of a solution containing 0.25 g polymer in 50 ml of methylene chloride measured at 20°C using a No. 50 Cannon-Fenske viscometer
Preparing Solutions Elvacite® resins dissolve at room temperature but require constant agitation to prevent solvent-swollen granules of polymer from forming agglomerates and sticking to the walls of the vessel. Important: The polymer beads should be sifted directly into the vortex of the stirred solvent to speed wetting-out and dispersion. Continuous lowshear agitation for periods of 1-12 hours, depending on the grade and concentration of resin, is recommended. After the solution appears clear in the tank, a sample should be spread out on a Leneta card or glass. After the solvent evaporates and a film forms on the card or glass, there should not be any resin seeds. If there are any seeds, the tank should be agitated further to fully dissolve the resin. Tank agitation should not be stopped (except for sampling) until the film test indicates there are no resin seeds. Any cloudiness or residue may indicate that some polymer remains undissolved. The presence of water in the system can also cause cloudiness. Solution time can be reduced by heating; most common solvents can be heated to approximately 49°C (120°F) without the need for reflux equipment. High-shear agitation also cuts dissolving time, but requires care to avoid overheating and excessive solvent loss.
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 2
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Solvent Solubility Table I depicts the solubility of Elvacite® 4111 at 30% solids in various solvents. (S=Soluble, C=Cloudy solution, I=Insoluble) Alcohols Methyl Alcohol Ethyl Alcohol n-propyl alcohol Isopropyl alcohol Isoamyl alcohol Cyclohexanol Ethylene glycol Glycerol
I I I I I I I I
Amides Formamide I Dimethyl formamide (DMF) S Chlorohydrocarbons Methylene Chloride S Ethylene dichloride Perchloroethylene 1,1,1-Trichloroethane S Esters Methyl Formate Ethyl acetate
S S
Technical Data Sheet
Isopropyl acetate n-Butyl acetate n-Amyl acetate Butyl lactate Propylene glycol monoethyl ether acetate Methyl amyl acetate Ethers Diethyl Ether Diisopropyl ether Tetrahydrofuran (THF) “Cellosolve” Solvent Hydrocarbons Toluene Xylene n-Hexane Cyclohexane VM & P Naphtha Mineral Spirits Turpentine
S S S S S S S S S S S I I I I I
Ketones Acetone Methyl Ethyl Ketone Methyl Isobutyl Ketone Diisobutyl ketone Cyclohexanone Isophorone Diacetone Alcohol Methyl amyl ketone
S S S S S S S
Nitrile Acetonitrile
-
Nitroparaffins Nitromethane Nitroethane
S -
Vegetable Oils Castor oil Linseed oil (alkali-refined)
Elvacite® 4111 v20130624
I I
Page: 3
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Resin Compatibility Elvacite® 4111 is compatible with the following Elvacite® Resin Grades: 2013, 2014, 2016, 2028, 2042, and 2043. It is also compatible with the other types of resins, as illustrated in the following table: Blending Resin Alkyd Aroplaz 1271 Aroplaz 1351 Chempol 13-1410 Paraplex RG-2 Plaskon 3105 Cellulosic Cellulose acetate 39-5-5B
Description
Long linseed drying oil Long castor nondrying oil Safflower drying oil, acrylate mod. Nondrying oil, sebacic
30% in MEK
Elvacite / Blending Resin* (by solids weight) 75/25 50/50 25/75 Spencer Kellogg C H H Spencer Kellogg C C C Freeman C C C Chemical Rohm & Haas I I I Co. Cargill, Inc. --H H Supplier
30% in Acetone or Hercules Inc. MEK 30% in MEK Eastman Chemical 30% in MEK Hercules Inc. MEK/alcohol soln. Hercules Inc.
100% Resin
Epon 1001
Neoprene AC-Soft
30% in MEK 30% in MEK 50% in Xylene
Short coconut nondrying oil 60% in Xylene
Cellulose Acetate Butyrate, ½ - sec. Ethyl Cellulose N-7 Nitrocellulose “RS”, ½-sec Isopropyl Epoxy Epon 828
Elastomers EMD-504 Hypalon 30
Form of Blended Resin Tested
30% in MEK
Polyisobutylene Clorosulfonated polyethylene Polychloroprene
30% in Toluene 15% in Toluene 15% in Toluene
I
I
I
C
C
C
I C
I C
I C
Shell Chemical Co. Shell Chemical Co.
C
---
C
C
C
C
Exxon Chemical Dupont Polymers Dupont Polymers
I I
I I
----
I
I
---
Rosin Derivatives Ester Gum 8L Pentalyn 255 Pentalyn 830
Pentaerythritol ester Pentaerythritol ester
30% in MEK 30% in MEK 30% in MEK
Hercules Inc. Hercules Inc. Hercules Inc.
-H H
H H H
H H H
Vinyl Chloride Resins Bakelite VAGH Bakelite VMCH Bakelite VYHH
Copolymer Copolymer Copolymer
30% in MEK 30% in MEK 30% in MEK
Union Carbide Union Carbide Union Carbide
C C C
C C C
C C C
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 4
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Bakelite VYNS Exon 450
Copolymer Copolymer
15% in MEK 15% in MEK
Union Carbide Firestone Plastics
C C
C C
C --
Exon 9290
Homopolymer
15% in THF
C
C
C
Geon 103 EP Other Types Arochem 650 Aroset 4110 Dammar DC-840
Homopolymer
15% in THF
Firestone Plastics B.F. Goodrich
C
C
C
Maleic-modified hard resin Acrylic resin
30% in MEK 30% in MEK 30% in Toluene 60% in Toluene
Spencer Kellogg Spencer Kellogg
C C I C
C C I C
C C H C
Parlon S 10 Piccoumaron Santolite MHP Shellac Super-Bechacite 2000
Chlorinated rubber 30% in MEK Coumarone-indene resin 30% in MEK Sulfonamide-formaldehyde 30% in MEK 30% in Methanol Permanently fusible 30% in MEK phenolic Triazine-formaldehyde resin 30% in MEK
C C C H C
C C C I C
C C C I C
C
H
I
Uformite MX-61
Silicone resin
Dow Corning Corp. Hercules Inc. Hercules Inc. Monsanto Co. Reichold Chemicals Rohm & Haas Co.
* 4111 was not tested, but is expected to be similar to 2013.
(C=Clear solution, H=Hazy solution, I=Insoluble)
Plasticizer Compatibility Elvacite® 4111 is compatible at a 50/50 resin/plasticizer ratio with the following plasticizers: Santicizer 8 (N-ethyl toluene sulfonamides) Santicizer 160 (butyl benzyl phthalate) Tricresyl phosphate Hercoflex 600 (pentaerythritol ester)
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 5
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Lucite International Inc. The Lucite Center 7275 Goodlett Farms Parkway Cordova, TN 38016 USA T: +1 (901) 381 2000 www.luciteinternational.com/resins Lucite International Specialty Polymers and Resins Ltd Horndale Avenue Newton Aycliffe DL5 6YE United Kingdom T: +44 (0) 1325 300990 F: +44 (0) 1325 314925 www.luciteinternational.com/resins
Technical Data Sheet
Elvacite® 4111 v20130624
Page: 6
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
