Light-Emitting Diodes (LEDs) for Illumination Applications

Report 8 Downloads 174 Views
Light-Emitting Diodes (LEDs) for Illumination Applications Mike Krames, CTO

LIGHTING IS… …fundamental to life

…consuming 20% of world’s electricity …a ~ 100B USD market

Dec 3, 2012 • Stanford University

2

1 LED Fundamentals

LIGHT-EMITTING DIODE (LED) • • • • •

Monocrystalline atomic arrangement determines bandgap & optical properties Impurity doping provides p- and n-type regions At forward bias, injected electrons and holes recombine Energy may be released radiatively (light) or non-radiatively (heat) Fundamentally non-destructive

Dec 3, 2012 • Stanford University

4

LUMINOSITY • Human eye is not equally sensitive to all wavelengths of light

• Eye sensitivity is represented by the Luminosity Function, V(λ) (CIE) Luminosity Function UV

1 Watt at 555 nm = 683 lumens • Lumens decrease in the blue and red spectral regions

2/8/12

Lumens per Watt

• Definition:

Visible Spectrum

Infrared

V(λ)

5

LEDs: FUNDAMENTALLY BETTER UV

INFRA-RED VISIBLE

• 2900K White, Equal-Lumen Spectra

Incandescents 95% heat



Fluorescents

Spectral Irradiance, W m-2 nm-1

Max. efficiency ~ 50%



LEDs “ultimate lamp”*

Tri-phosphor Fluorescent Lamp (FL)

Incandescent Tungsten LED ~ 5 eV

Hg

200

LED FL

1000

Wavelength, nm

Stokes’ loss

10000 *N. Holonyak, Jr., et al., Am. J. Phys. 68, 864 (2000)

Dec 3, 2012 • Stanford University

6

III-V MATERIALS SYSTEMS FOR LEDs

Dec 3, 2012 • Stanford University

7

WHITE LIGHT GENERATION WITH LEDs • RYGB White Mixing Optics

Multi-Primary Color Mixing – Color tunability option – Requires color control – Requires color mixing optics

RYGB LEDs

• Down-Conversion Materials – Typically inorganic phosphors – Disadvantage: Stoke’s shift – Advantage: integrated color mixing after Mueller-Mach et al., phys. stat. sol. (a) 202, 1727 (2005)

Dec 3, 2012 • Stanford University

8

EVOLUTION OF LED PERFORMANCE

1000

Luminous Efficacy (lm/W)

white theoretical limit InGaN-based PC White

100

Shaped/Textured AlGaInP AlGaInP/GaP AlGaInP/GaAs

10

HID FL

High-Intensity Discharge

W-H W

Tungsten-Halogen

Fluorescent

Tungsten

AlGaAs/AlGaAs InGaN

1

AlGaAs/GaAs GaAsP:N GaP:Zn,O

InGaN

GaAsP

0.1 1960

1970

1980

1990

2000

Dec 3, 2012 • Stanford University

2010

2020

9

LED APPLICATIONS (12.5B USD in 2011)

Dec 3, 2012 • Stanford University

10

2 LEDs for Lighting Applications

ENERGY SAVINGS POTENTIAL By 2030, LEDs can save (U.S. only):

Forecasted U.S. Lighting Energy Consumption and Savings

300 TeraWatt hours of energy p. a. (50 1-GigaWatt power plants) $30 Billion 200M metric tonnes carbon emission

Worldwide savings ~ 4x higher Source: Energy Savings Potential of Solid-State Lighting in General Illumination Applications. Prepared by Navigant Consulting, Inc., for the U.S. Department of Energy, Washington, D.C., January 2012.

Dec 3, 2012 • Stanford University

12

LED FABRICATION FLOW

SUBSTRATE Sapphire Silicon Carbide (Silicon)

EPITAXY GaN MOCVD (MBE)

WAFER FAB Lithograpy Metallization Etching

DIE FAB Singulation

PACKAGING Die-attach Interconnect Phosphor

LUMINAIRE Driver Optics Heatsink Assy.

MOCVD = metal-organic chemical vapor deposition MBE = molecular beam epitaxy

Dec 3, 2012 • Stanford University

13

CONVENTIONAL InGaN-GaN LED Typically Lz ~ 2-3 nm InGaN multiple quantum wells (MQWs) Spontaneous and Piezoelectric Polarization Fields complicate bandstructure AlGaN “electron blocker” layer for electron confinement Symmetric carrier injection not a given (mhh >> me) p-electrode Current spreading (e.g., ITO)

p-GaN p-AlxGa1-xN n-electrode n-GaN

p-AlGaN

• • • •

nucleation layer

sapphire www.str-soft.com

Dec 3, 2012 • Stanford University

14

INTERNAL QUANTUM EFFICIENCY Internal Quantum Efficiency is the fraction of electrical current converted to photon emission Product of injection efficiency (fraction of injected carriers that recombine in active region) radiative efficiency (fraction of electron-hole pairs that recombine to emit photons)

ηint = ηinj ⋅η rad Jtot e-

J rec ηinj = J tot Jleak Ec P-GaN

p-AlGaN

InGaN

n-GaN

Jrec

Dec 3, 2012 • Stanford University

15

A-B-C RECOMBINATION MODEL η rad

Rrad Bn 2 = = Rtotal An + Bn 2 + Cn 3

2np = An n+ p

A = Shockley-Read-Hall (crystal defects)

GSRH = A

B = Spontaneous emission

GRad = Bn 2

C = Auger scattering

G Auger = Cn 3

Dec 3, 2012 • Stanford University

trap

16

LIGHT EXTRACTION EFFICIENCY • Light extraction efficiency is the fraction of light that escapes semiconductor chip • Exacerbated by high optical refractive indices n(GaN) ~ 2.4, n(AlGaInP) ~ 3.5

• Product of ηint and Cext is external quantum effciency, ηext

ηext = ηint ⋅ Cext

Dec 3, 2012 • Stanford University

17

LIGHT EXTRACTION EFFICIENCY Dramatic improvement last twenty years Light extraction efficiencies reached ~80%+ (InGaN) and 60%+ (AlGaInP) 100 Light Extraction (%) Light extractionEfficiency, efficiency, C Cext ext (%)

• •

90 TFFC

80

CC(PS/ITO) low power

VTF

70 Shaped TS

60

CC (PS) Thick RS

50

CC (PS/ITO) high power

FC (Al)

40

Improved TS

30

CC TS

20 10

FC (Ag)

Thick AS + DBR Thick AS Thin AS

into silicone or epoxy (n ~ 1.5)

0 1990

1995

2000

2005

2010

Year after Krames et al., JOURNAL OF DISPLAY TECHNOLOGY, VOL. 3, NO. 2, JUNE 2007 Dec 3, 2012 • Stanford University

18

LIGHT EXTRACTION TECHNIQUES Vertical Thin Film (VTF)1

Thin Film Flip Chip (TFFC)3 1) 2) 3) 4)

Patterned Substrate (PS)2

Shaped Transparent Substrate (TS)4

B. Hahn et al., Proc SPIE 6910:691004 (2008) Y. Narukawa et al., J. Phys. D: Appl. Phys. 43: 354002 (2010) O. Shchekin et al., Appl Phys Lett 89:2365–2367 (2006) M. Krames et al., Appl Phys Lett 75(16):071109 (1999)

Dec 3, 2012 • Stanford University

19

EXTERNAL QUANTUM EFFICIENCY InGaN 1

2

AlGaInP V(λ)

1) M. Cich et al., Appl. Phys. Lett. 101, 223509 (2012); doi: 10.1063/1.4769228 2) Y. Narukawa et al., J. Phys. D: Appl. Phys. 43 (2010) 354002 3) R. Mueller-Mach et al., Phys. Status Solidi RRL, 1–3 (2009) / DOI 10.1002/pssr.200903188 Other: Janglin Chen, Wayne Cranton, Mark Fihn (eds.), Handbook of Visual Display Technology, DOI 10.1007/978-3-540-79567-4_6.4.1, # Springer-Verlag Berlin Heidelberg 2012

Dec 3, 2012 • Stanford University

20

PHOSPHOR-CONVERTED WHITE LEDs blackbody

3000K

350

450

550

650

750

Wavlength (nm)

Janglin Chen, Wayne Cranton, Mark Fihn (eds.), Handbook of Visual Display Technology, DOI 10.1007/978-3-540-79567-4_6.4.1, # Springer-Verlag Berlin Heidelberg 2012

Dec 3, 2012 • Stanford University

21

LIGHTING MARKET

• 30+Billion world wide installed sockets • 90 Tera-lumen capacity for these sockets • Socket penetration by LED lighting is 1 kA.cm-2 • Low Dislocation Densities required • Quasi-Bulk GaN substrates based on Hydride Vapor Phase Epitaxy (HVPE)

GaN HVPE Substrate

S. Tomiya et al., IEEE Sel. Top. Quantum Elect. 10, 1277 (2004).

Dec 3, 2012 • Stanford University

28

GaN on GaN: NATIVE SUBSTR. ADVANTAGE •

Growth plane option



Ultra-low dislocations (to < 104 cm-2)



Reliability at high current density



High thermal conductivity



Breakthrough in lumens density



Reduced droop



Simplified chip architecture & mfg

Dec 3, 2012 • Stanford University

29

LED FABRICATION FLOW SUBSTRATE Sapphire, Silicon Carbide, (Silicon)

EPITAXY GaN MOCVD, (MBE)

WAFER FAB Lithograpy Metallization Etching

DIE FAB Singulation

PACKAGING Die-attach Interconnect Phosphor

Gallium Nitride (GaN)

AP MOCVD (GaN)

Simple Flow

Proprietary Dicing

Proprietary Unique Design Si-wafer based packaging

Dec 3, 2012 • Stanford University

LUMINAIRE Driver Optics Heatsink Assy.

30

GaN on GaN™: LED FABRICATION • No substrate removal

Light Extraction • Single optical refractive index • Volumetric emitter: Surface/Junction area >> 1

*Simulation

Light Extraction Efficiency

Simple fabrication process

Volumetric chip

Thin-film chip

• Tri-lateral (“Tri-LED”) configuration

Chip Height (µm)

• Approaching 90%*

Photon escape

Dec 3, 2012 • Stanford University

SEM image of a Tri-LED chip

31

GaN on GaN™: LED PERFORMANCE Peak external quantum efficiency of 73%

~ 850 mW at 500 mA

External Quantum Efficiency

Extremely low droop

Pulsed, 300K, λ ~ 410 nm Y. Narukawa et al., J. Phys. D: Appl. Phys. 43 (2010) 354002

Output Power (W)

Commercially available package with silicone encapsulation

InGaN-GaN Heterostructure Tri-LED on Native GaN Substrate

15-25x smaller than conventional power LED chips Forward Current Density (kA cm-2)

Dec 3, 2012 • Stanford University

32

GaN on GaN™: POWER DENSITY Conventional LED • Unprecedented power density uniformity • No current crowding • Quiescent point optimization D. Kuo et al., Materials Science in Semiconductor Processing, Volume 15, Issue 1, February 2012, Pages 52–55

1.4

Intensity (arb. units)

1.2 1 0.8 0.6 0.4 0.2

0.5 kA.cm-2

0

-150 -100

-50

0

50

100

150

x (µm) Dec 3, 2012 • Stanford University

33

GaN on GaN™ LED RELIABILITY Stable violet flux at 160 Acm-2 and Tj = 140°C operation 5000 hours white-emitter reliability under same drive conditions Single-exponential fit made following TM-21 convention for long-term life predictions

95% Lumen Maintenance at 100khrs

Dec 3, 2012 • Stanford University

34

GaN on GaN™ LIGHTCHIP™ Proprietary Si-based wafer level packaging Multi-die array Red, Green, and Blue phosphor mix Ultra-small (bright) form factor

Dec 3, 2012 • Stanford University

35

GaN on GaN™ LED MR16 LAMPS • Technology differentiation leveraged into most difficult lamp, with unique design • High lumen density • High center beam candle power • Single, high quality beam • Uniform, high quality color • 50W halogen MR16 level (2400 cd, 24°)

SORAA

Other

• Three beam angles (10,25,36) • No mechanical fan! • Up to 80% energy savings (Less than one year payback) Dec 3, 2012 • Stanford University

36

FULL vs. TRUNCATED SPECTRUM Violet- vs. Blue-pumped Photon Energy Loss: 10%

3.0 electron volts

2.7 electron volts

Intensity Dec 3, 2012 • Stanford University

37

Blue

Infrared

• Better match to blackbody curve → Natural colors

Violet

• World’s only Full Spectrum MR16 Product

Ultraviolet

COLOR QUALITY

• Reduced blue overshoot → Circadian Rhythm friendly • Violet → Improved Whiteness

Color Rendering Indices (CRI) Dec 3, 2012 • Stanford University

38

LIGHTING DESIGN “Despite a number of product attempts… none (LED MR16) until recently have posed a reasonable challenge to the performance of the halogen lamps they might replace … … The MR16 lamp that has been introduced based on GaN-on-GaN technology represents a significant leap in LED technology for the huge worldwide MR marketplace, with performance that… rivals common halogen MR16.” James R. Benya, PE, FIES, FIALD. A Critical Advance in MR16 LED Lamps

LED HISTORY: 50 YEARS First GaN GaN on sapphire (polycrystalline) (monocrystalline) P. Maruska I. Akasaki

1962 First LED (red) N. Holonyak, Jr.

1969

1986

Watt-class White LEDs

1993

1999

First Blue LEDs / LDs S. Nakamura

Dec 3, 2012 • Stanford University

Soraa Founded

2006 Bulk-GaN based LEDs / LDs UCSB

2008

2012 First GaN-on-GaN™ Lighting Product

40