Liquid Boot

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Using Vapor Intrusion Subslab Barriers Rob Carvahlo and Amanda Petrocelli EAI, Inc.

LINING TECHNOLOGIES

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REMEDIATION TECHNOLOGIES

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DRILLING SYSTEMS

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BUILDING ENVELOPE

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CONTRACTING SERVICES

GAS VAPOR MITIGATION SYSTEMS FOR PROTECTION AGAINST VAPOR INTRUSION Amanda Petrocelli [email protected]

Robert Carvalho [email protected] 201.395.0010 October 11, 2011

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GAS VAPOR MITIGATION SYSTEMS

Agenda Gas Vapor Mitigation Options Chemical/Physical Properties Diffusion Testing

CETCO Offerings Gas Vapor Barrier Systems Gas Venting Systems

Quality Control Case Studies by EAI

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GAS VAPOR MITIGATION SYSTEMS

The Risk: Vapor Intrusion Vapor intrusion is the migration of subsurface chemical vapors into overlying structures. Vapors may include: Volatile organic compounds (VOCs) Semi-volatile organic compounds Inorganics (i.e.. mercury, hydrogen sulfide, etc.) Methane Radon Naturally-occurring / man-made contaminants

Vapor intrusion and indoor air risk occurs when you have: A source An inhabited building A pathway from the source to the inhabitants

Vapor intrusion has become a significant environmental issue for regulators, industry leaders, and concerned residents nationwide.

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GAS VAPOR MITIGATION SYSTEMS

The Risk: Vapor Intrusion “Current lack of knowledge about indoor air issues and evaluation techniques may oversimplify the problem and may cause air quality investigations and subsequent risk assessments to understate or overstate the problem. Indoor air quality is overlooked in many environmental site investigation and soil or groundwater plume contamination scenarios. Lack of knowledge regarding indoor air quality issues and cost considerations tend to contribute to the omission of indoor air sampling and evaluation.” – ITRC

CETCO offers:     

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Solutions for various site conditions, backed by extensive track record/case history Experienced technical managers with knowledge on current industry trends Technical and design assistance for gas vapor membrane and venting systems World-class Research & Development facility Design-build capabilities

GAS VAPOR MITIGATION SYSTEMS

GAS VAPOR MITIGATION OPTIONS

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GAS VAPOR MITIGATION SYSTEMS

Two Types of Gas Vapor Barriers (per ITRC Guidance) Gas vapor barrier options include:

Sheet-applied, batten and welded 60 mil - HDPE

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GAS VAPOR MITIGATION SYSTEMS

Spray-Applied Membranes 60 mil - Liquid Boot®

Physical Properties of Liquid Boot® (spray-applied) Physical Property

*

* * *

Test Method

Result

ASTM D6392

Passed

ASTM D4068-88

Passed

City of Los Angeles

Passed

ASTM D1693-78

Passed

Soil Burial

ASTM E154-88

Passed

Elongation

ASTM D412

1,332% - Ø reinforcement, 90% recovery

Tensile Strength

ASTM D412

58 p.s.i. without reinforcement

Tensile Bond Strength to Concrete

ASTM D413

2,707 lbs/ft2 uplift force

Water Vapor Permeability

ASTM E96

0.24 perms

Water Vapor Transmission

ASTM E96

0.10 grains/h-ft2

Bonded Seam Strength Tests

Heat Aging- average tensile strength change, average tensile stress change, average elongation change, bonded seams

Dead Load Seam Strength

Environmental Stress-Cracking

* City of Los Angeles approval for 60-mil Liquid Boot® Gas Vapor Barrier

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GAS VAPOR MITIGATION SYSTEMS

Chemical Properties of Liquid Boot® (spray-applied)

* * *

Chemical Property

Test Method

Result

Acid Exposure (10% H2SO4 for 90 days)

ASTM D543

Less than 1% weight change

Diesel (1000 mg/l), Ethylbenzene (1000 mg/l), Naphthalene (5000 mg/l) and Acetone (500 mg/l) Exposure for 7 days

ASTM D543

Less than 1% weight change, Less than 1% tensile strength change

Radon Permeability

Tested by US Dept. of Energy

Zero permeability to Radon (222Rn)

Micro Organism Resistance (Soil Burial)

ASTM D4068-88

Passed*

Methane Permeability

ASTM 1434-82

Passed*

Oil Resistance Test- average weight change, average tensile strength change, average tensile stress change, average elongation change, bonded seams, methane permeability

ASTM D543-87

Passed*

PCE Diffusion Coefficient

Tested at 6,000 mg/m3

2.74 x 10-14 m2/sec

TCE Diffusion Coefficient

mg/m3

8.04 x 10-14 m2/sec

Tested at 43,000 mg/m3

2.90 x 10-11 m2/sec

Benzene Diffusion Coefficient

Tested at 20,000

* City of Los Angeles approval for 60-mil Liquid Boot® Gas Vapor Barrier

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GAS VAPOR MITIGATION SYSTEMS

Membrane Diffusion Test – Modified ASTM E96 The diagram illustrates how the diffusion coefficients on the Liquid Boot membrane for PCE, TCE and Benzene were determined CETCO R&D facility is capable of performing these tests

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GAS VAPOR MITIGATION SYSTEMS

Fick’s Law Applying diffusion test data into the Fick’s Law equation results in the diffusion coefficient:

E= A(Csource - Cg0)Dczeff / Lcz where

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E

=

Rate of mass transfer, g/s

A

=

Cross-sectional area through which vapors pass, cm2

Csource

=

Vapor concentration within the capillary zone, g/cm3-v

Cg0

=

A known vapor concentration at the top of the capillary zone, g/cm3-v (Cg0 is assumed to be zero as diffusion proceeds upward)

Dczeff

=

Effective diffusion coefficient across the capillary zone, cm2/s

Lcz

=

Thickness of capillary zone, cm

GAS VAPOR MITIGATION SYSTEMS

Diffusion Test Results Summary

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Test Conditions

Average Solvent Diffusion Rate

Membrane Area

Membrane Thickness

Calculated Diffusion Coefficient

PCE Solvent @ 6,000 mg/m3

0.12 mg/day

1.45 x 10-2 m2

1.68 x 10-3 m

2.74 x 10-14 m2/sec

TCE Solvent @ 20,000 mg/m3

1.22 mg/day

1.48 x 10-2 m2

1.57 x 10-3 m

8.04 x 10-14 m2/sec

Benzene @ 13,000 mg/m3

1.4 mg/day

1.48 x 10-2 m2

1.57 x 10-3 m

1.4 x 10-14 m2/sec

Benzene @ 136,000 mg/m3

19 mg/day

1.48 x 10-2 m2

1.57 x 10-3 m

1.9 x 10-13 m2/sec

GAS VAPOR MITIGATION SYSTEMS

Venting Systems (Used In Conjunction with a Gas Vapor Barrier per ITRC Guidance) Passive Venting

Rely on nature pressure differentials to vent the subsurface gas Can be designed to be converted to active, if needed, to reduce vapor concentrations Should be properly designed to allow adequate flow of vapors Evaluation of air flow should be conducted

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GAS VAPOR MITIGATION SYSTEMS

Active Venting Use of mechanical means to alter and maintain pressure gradients & redirect subsurface gas flow Major system components generally include gas extraction wells and piping, vacuum blowers, and gas/vapor treatment or reuse systems

CETCO SYSTEM OFFERINGS

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GAS VAPOR MITIGATION SYSTEMS

CETCO System Offerings

Liquid Boot® Gas Vapor Barrier System

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Liquid Boot® Plus

Coreflex®

High-Performance Gas Vapor Barrier System

Methane Barrier & Waterproofing System

GAS VAPOR MITIGATION SYSTEMS

GeoVent® Gas Venting System

LIQUID BOOT® GAS VAPOR BARRIER SYSTEM

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® System Description: Liquid Boot® is a cold, spray-applied membrane that acts as a gas vapor barrier and damp-proof membrane.

Typical Uses: Applied under slab and on below grade vertical walls as a gas vapor barrier to minimize vapor and nuisance water (non-hydrostatic conditions) migration into buildings Ideal for methane migration control Concrete water tank and reservoirs liner to prevent water seepage into concrete Applied as a liner to concrete canals for rehabilitation

Agency Approvals: City of Los Angeles Research Report # 24860 Approved for Liquid Boot®

Membrane for Gas Barrier

County of Los Angeles Department of Public Works Approved for “Liquid Boot® Application

as a Methane Gas Barrier”

NSF International-NSF/61

Approved for “Potable Water Tank Liner” for tanks >300,000 gallons

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® System Components and Features: GeoVentTM Gas Venting System Low profile; no trenching required

Liquid Boot® BaseFabric T-40/T-60 (fabric selection depends on site conditions) Heat bonded non-woven geotextile

Liquid Boot® Two component spray applied membrane (60 mils typical) Water based - No VOCs, odorless Bonds to most surfaces – eases detailing Seamless - eliminating membrane failures Rapid curing - reducing construction time High strength and elongation – durable

Liquid Boot® UltraShield Series Protection Course G Series - Needle-punched, nonwoven geotextile P Series - HDPE Polyethylene geomembrane Adheres to the underslab providing superior tensile strength

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® PILE CAPS AND FOOTINGS

PENETRATIONS

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® VERTICAL SURFACE ATTACHMENTS

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® TYPICAL SYSTEM INSTALLATION

1. Liquid Boot® applied to BaseFabric

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GAS VAPOR MITIGATION SYSTEMS

2. Penetrations Detailed

3. UltraShield Protection Fabric

LIQUID BOOT® PLUS HIGH-PERFORMANCE GAS VAPOR BARRIER SYSTEM

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® Plus System Description: The Liquid Boot® Plus Gas Vapor Barrier system is a multi-layer and high-performance, cold spray-applied membrane that acts as a gas vapor barrier and damp-proof membrane.

Typical Uses: Installed under slab and on below grade vertical walls as a gas vapor barrier to minimize vapor and nuisance water (non-hydrostatic conditions) migration into buildings Ideal for applications with chlorinated solvents, BTEX and other PAHs

Agency Approvals: City of Los Angeles Research Report # 24860

Approved for Liquid Boot® Membrane for Gas Barrier County of Los Angeles Department of Public Works

Approved for “Liquid Boot® Application as a Methane Gas Barrier”

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® Plus System Components and Features: GeoVent® Gas Venting System

Low profile; no trenching required Liquid Boot® VI-20 Geomembrane

EVOH composite geomembrane - 20x lower VOC diffusion than 80 mil HDPE Liquid Boot® VI-20 Detailing Fabric Liquid Boot®

Two component spray applied membrane (60 mils typical) Water based - No VOCs, odorless Bonds to most surfaces – eases detailing Seamless - eliminating membrane failures Rapid curing - reducing construction time High strength and elongation - durable Liquid Boot® UltraShield Series Protection Course

G Series - Needle-punched, nonwoven geotextile P Series - HDPE Polyethylene geomembrane Adheres to the underslab providing superior tensile strength

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GAS VAPOR MITIGATION SYSTEMS

Liquid Boot® VI-20 Geomembrane Tested by Dr. Kerry Rowe, Queens University, Ontario

Author of the POLLUTE model Well-known in geosynthetics industry Determined upper bound partition and diffusion coefficients Aqueous phase diffusion coefficient of co-extruded geomembrane

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Liquid Boot® VI-20

80-mil HDPE

Contaminant

Diffusion Coefficient (m2/s)

Diffusion Coefficient (m2/s)

Benzene

9.0 x 10-15

3.5 x 10-13

Ethyl Benzene

8.0 x 10-15

1.8 x 10-13

Toluene

8.5 x 10-15

3.0 x 10-13

O-Xylene

7.5 x 10-15

1.5 x 10-13

GAS VAPOR MITIGATION SYSTEMS

EVOH Geomembrane Technology Liquid Boot® VI-20 geomembrane is a layer of EVOH between two layers of polyethylene. EVOH is a copolymer of:

Polyethylene (extrudes easily and improves bonding) Polyvinyl Alcohol and Ethylene Vinyl Alcohol (provides gas barrier)

Major applications for EVOH is in automotive fuel systems to control emissions of hydrocarbons The use of EVOH in a co-extrusion blow-molded tank with molecular weight HDPE originated in the US in response to mandates of VOC emissions reductions by the US EPA and the CA Air Resources Board (CARB) and is has been in widespread use globally for more than 15 years.

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GAS VAPOR MITIGATION SYSTEMS

EVOH Geomembrane Technology Development started in 1989 in response to EPA and CARB mandates Emissions regulations have progressively become tighter each decade EVOH became barrier of choice due to VOC barrier properties Emissions through tank shell are