WRITING CHEMICAL FORMULAE 1 Chemical formulae are very useful to chemists as they show the numbers and types of atoms that make up chemical compounds. Many people know that the chemical formula for water is H2O, but how many know that this tells us that a water particle is made up of two hydrogen atoms and one oxygen atom, which are chemically combined. Some compounds are very simple and are made up of just two atoms. Others, like the proteins that are found in all living organisms can be made up of tens of thousands of atoms. By following some simple rules we can write the formulae of most of the chemical compounds that we are likely to encounter in this course of study. Chemical names. A chemical compound will always have two, or more, parts to its name. The name of a chemical compound tells us about the numbers and types of atoms that have combined to form it. The name can also be used to help us write the chemical formula of the compound. Sometimes one of the parts of the compound’s name will have a prefix, which indicates how many atoms of that element are present in the formula. The following prefixes are often encountered. Prefix. Mon(o)DiTriTetr(a)Pent(a)Hex(a)Hept(a)Oct(a)Non(a)Dec(a)-
Number of atoms. One Two Three Four Five Six Seven Eight Nine Ten
Formula CO CO2 SO3 CCl4 P 2O 5 UF6 IF7 C8H18 C9H20 C10H22
I. In the first example, carbon monoxide is made up of one atom of carbon and one atom of oxygen, chemically combined. (When writing chemical formulae we do not write the number 1. This is because the presence of a chemical symbol in the formula tells us that there is at least one atom of that element present in the compound.) In the final example, decane is composed of ten carbon atoms and twenty- two hydrogen atoms chemically combined; a total of thirty-two atoms. Name endings also tell us about the chemical make-up of a compound. Compounds whose name ends in IDE are composed of two elements only. Compounds whose name ends in ATE contain the element oxygen. Compounds whose name contains the prefix PER contain extra atoms of one of the elements. eg Hydrogen oxide H2O, hydrogen peroxide H2O2.
Name: ______________________ Valency Number. Each element is assigned a valency number. A valency number is assigned to each group in the periodic table. All the elements in a particular group have that assigned number. An element’s valency number is used to calculate the ratios in which it combines with other elements. Group 1 2 3 4 5 6 7 8
Name: ______________________ Writing formulae for two element compounds which contain a variable valency element. If an element can have more than one valency number, then the number is written after the name of the element in the compound. The valency number is written in Roman numerals and is in brackets. eg Iron (II) oxide
FeO
Iron (III) oxide
Fe2O3
The method of writing the formulae for these compounds is exactly the same as shown in the previous section. eg Write the formula of lead (IV) oxide. Write the symbols. PbO Write in the valency numbers. Pb4O2 Swap the valency numbers. Pb2O4 Cancel down. In this case using a common denominator of 2. Pb1O2 Formula = PbO2 Use the valency swapping method to determine the formulae of the following two - element compounds.