Rapid Chemical Analysis for Control Measurements.
Rapid Chemical Analysis for Control Measurements. Presented by Ken Schmidt, Wilson Analytical
You collect the samples in the field…
But where do you analyze them?
Inherent Problems with the Status Quo: Central Laboratory Analysis • Sampling and chain of custody errors
• Degradation of sample quality with time • High cost of third-party analyses or maintaining in-house lab infrastructure
• Poor statistics, as the number of samples taken and transported is usually minimized
• Delays in problem diagnosis and hence remedial action www.wilsonanalytical.com
The Solution: Rugged, Portable Analytical Equipment Excellence Required in:
• • • • •
Chemical Analysis
Mechanical Design and Fabrication Optical and Electronic Design Miniaturization of equipment Field Robustness and Ease of Use
Final Integration into a complete analytical solution www.wilsonanalytical.com
Optical Spectroscopy : Rapid Chemical Analysis of Liquids UV/Visible Absorbance: Colorimetric Analysis
• Must have coloured samples or colour-change reagents
•
Moderate sensitivity and prone to interference
www.wilsonanalytical.com
UV/Visible Absorbance: Colorimetric Analysis
www.wilsonanalytical.com
Oilfield Absorbance-Based Measurements
• • • •
Chloroform Extraction-Dye Coupling (Corrosion Inhibitors) pH and titrations Sample digestion followed by purple phosphate-molybdate complex formation (Scale Inhibitors) Other reagent-based analyses (Hach Tests)
www.wilsonanalytical.com
Optical Spectroscopy : Rapid Chemical Analysis of Liquids Fluorescence Emission Analysis
• Must have fluorescent samples or fluorescent reagents
•
Excellent sensitivity and fairly immune to interference
www.wilsonanalytical.com
Fluorescence Emission Analysis
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
• Tracing with Fluorescent Dyes (Water Flows and Solvents) • Intrinsically Fluorescent Materials (Corrosion Inhibitors) • Fluorescently-tagged Analytes (Scale Inhibitors) • Nanochemistry-based fluorescent reagents (In Progress)
www.wilsonanalytical.com
Absorbance and Fluorescence Measurements Out of the Lab
How www.wilsonanalytical.com
Wilson Analytical’s rugged technology brings the accuracy of laboratory instruments directly to the field or to a process lab location
www.wilsonanalytical.com
Wilson Instruments use Dependable LED Technology for Light Sources No flash lamps or other delicate light sources Monochromatic Inherently Robust Versatile
In combination with a USB-driven micro-spectrometer for Detection Small No moving parts Full spectrum detection
Lab on a Tailgate
www.wilsonanalytical.com
Wilson Analytical’s unique QuatBox technology brings the accuracy of laboratory fluorescence methods directly to the field in one easy-to-use, ruggedized package
www.wilsonanalytical.com
The Wilson LabBox • Lab model, no field-use
• • •
• • •
features Same high performance as the QuatBox Same internal ruggedness Fluorescence or Absorbance measurements Attractively priced Well suited to “rough” labs Perfect for process control measurements
The Wilson X-Probebox • Highly stabilized, high• •
• •
www.wilsonanalytical.com
output LED Light Source Integrated Spectrometer Works with fiber optic probes Dipping, reflection, fluorescence or other For external samples or inline process analysis systems
The New Wilson Open Platform System • Easily interchangeable
•
•
www.wilsonanalytical.com
highly stabilized, highoutput LED Light Sources complete with optical filters Easily interchangeable Sample Holders complete with optical filters (for solids or liquids) Easily interchangeable Spectrometers coupled to system electronics
The New Wilson Open Platform System
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Tracing with Fluorescent Dyes (Water Flows, Oil Soluble Products)
•Less than 1 ppb detection limit for FL dyes •Dyes only follow the solvent, not the actives
www.wilsonanalytical.com
Direct Environmental Measurements in the Field • ppm level detection limits for petroleum and its conjugated aromatic compounds (PAH’s, NA’s, TPH) in water
Tailings Ponds Oil Spills
Oilfield Fluorescence-Based Measurements
• Intrinsically Fluorescent Materials (Corrosion Inhibitors)
www.wilsonanalytical.com
•Reliable data can be obtained within minutes of sampling •Custom designed, intuitive software makes it easy to use
www.wilsonanalytical.com
• 1 ppm detection limit for most continuously applied corrosion inhibitors containing APQ’s
• No sample preparation other than filtration and dilution
Oilfield Fluorescence-Based Measurements
• No APQ’s ? Using other bases? Fluorescent Imidazolines!
www.wilsonanalytical.com
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
• Intrinsically Fluorescent Materials (Corrosion Inhibitors)
Batch Inhibitors are Next www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•
Intrinsically Fluorescent Materials (Frac Tracers)
www.wilsonanalytical.com
www.wilsonanalytical.com
Fluorescent Silica Nanoparticles (FSNP)
For more info, contact Dr. David Antoniuk [email protected] Tel: (780) 554-7398 www.wilsonanalytical.com
Fluorescent Silica Nanoparticles (FSNP) • Applied Quantum Materials has developed a suite of nanoparticles for the oil industry that can be used as a non-toxic, thermally stable reservoir tracer. • AQM’s materials are designed to be stable at downhole temperatures of 250 ᵒC, and are made to be compatible with fracking solutions by adjusting their surface chemistry. • Appropriately sized silica nanoparticles infused into a fracture fluid can penetrate the newly opened fractures during the pressurized fracturing stage. • Detection of FSNP to ppb can be made with Wilson Analytical spectrometers. www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Fluorescently-tagged Actives (Kemira Scale Inhibitors)
• Polyacrylamides? www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Nanochemistry-based fluorescent reagents (sulfide in water)
A Retrievable and Highly Selective Fluorescent Probe for Monitoring Sulfide and Imaging in Living Cells Fengping Hou, Liang Huang, Pinxian Xi, Ju Cheng, Xuefei Zhao, Guoqiang Xie,Yanjun Shi, Fengjuan Cheng,Xiaojun Yao, Decheng Bai, and Zhengzhi Zeng. Inorg. Chem. 2012, 51, 2454−2460
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Nanochemistry-based fluorescent reagents (Scale Inhibitors) Aluminum-Morin Complex: •FL signal is quenched by Scale Inhibitor Binding to Al (a Turn-Off reagent) •Working FL Turn-On Reagents
www.wilsonanalytical.com
The Future of Wilson Instrumentation • In-instrument sample mixture separation • Detection of multiple analytes at one time using a single instrument www.wilsonanalytical.com
Current Oilfield Water Analysis
www.wilsonanalytical.com
The WaterBox
Full Oilfield Water Analysis at the Point of Sampling www.wilsonanalytical.com
The WaterBox •
Based on Capillary Electrophoresis, which uses electrical separation of anions (-ve ions) and cations (+ve ions) in water with optical detection • Designed to give accurate results under field conditions, even with brines • Full oilfield water chemical analysis of all cations and anions, corrosion and scale inhibitor residuals • Answers in less than 30 minutes directly in the field
www.wilsonanalytical.com
The WaterBox •Advanced anion profiles for Corrosion Work and Pipelines Organic Acids Sulphur speciation (sulphide, sulphate, sulphite, …)
•
Advanced ion profiles for Fracturing Applications Borates Nitrates Multiple Simultaneous Frac Tracers (64+)
•
Advanced anion profiles for Oilsands applications Silicates Napthenic Acids www.wilsonanalytical.com
Portable H2S Analyzer for Liquid Hydrocarbons H2S Off-Gassing Potential?
Transport Canada to Regulate www.wilsonanalytical.com
Portable H2S Analyzer for Liquid Hydrocarbons
www.wilsonanalytical.com
Contact us: Ken Schmidt Phone: (780) 702-0610 Email: [email protected]
www.wilsonanalytical.com
You collect the samples in the field…
But where do you analyze them?
Inherent Problems with the Status Quo: Central Laboratory Analysis • Sampling and chain of custody errors
• Degradation of sample quality with time • High cost of third-party analyses or maintaining in-house lab infrastructure
• Poor statistics, as the number of samples taken and transported is usually minimized
• Delays in problem diagnosis and hence remedial action www.wilsonanalytical.com
The Solution: Rugged, Portable Analytical Equipment Excellence Required in:
• • • • •
Chemical Analysis
Mechanical Design and Fabrication Optical and Electronic Design Miniaturization of equipment Field Robustness and Ease of Use
Final Integration into a complete analytical solution www.wilsonanalytical.com
Optical Spectroscopy : Rapid Chemical Analysis of Liquids UV/Visible Absorbance: Colorimetric Analysis
• Must have coloured samples or colour-change reagents
•
Moderate sensitivity and prone to interference
www.wilsonanalytical.com
UV/Visible Absorbance: Colorimetric Analysis
www.wilsonanalytical.com
Oilfield Absorbance-Based Measurements
• • • •
Chloroform Extraction-Dye Coupling (Corrosion Inhibitors) pH and titrations Sample digestion followed by purple phosphate-molybdate complex formation (Scale Inhibitors) Other reagent-based analyses (Hach Tests)
www.wilsonanalytical.com
Optical Spectroscopy : Rapid Chemical Analysis of Liquids Fluorescence Emission Analysis
• Must have fluorescent samples or fluorescent reagents
•
Excellent sensitivity and fairly immune to interference
www.wilsonanalytical.com
Fluorescence Emission Analysis
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
• Tracing with Fluorescent Dyes (Water Flows and Solvents) • Intrinsically Fluorescent Materials (Corrosion Inhibitors) • Fluorescently-tagged Analytes (Scale Inhibitors) • Nanochemistry-based fluorescent reagents (In Progress)
www.wilsonanalytical.com
Absorbance and Fluorescence Measurements Out of the Lab
How www.wilsonanalytical.com
Wilson Analytical’s rugged technology brings the accuracy of laboratory instruments directly to the field or to a process lab location
www.wilsonanalytical.com
Wilson Instruments use Dependable LED Technology for Light Sources No flash lamps or other delicate light sources Monochromatic Inherently Robust Versatile
In combination with a USB-driven micro-spectrometer for Detection Small No moving parts Full spectrum detection
Lab on a Tailgate
www.wilsonanalytical.com
Wilson Analytical’s unique QuatBox technology brings the accuracy of laboratory fluorescence methods directly to the field in one easy-to-use, ruggedized package
www.wilsonanalytical.com
The Wilson LabBox • Lab model, no field-use
• • •
• • •
features Same high performance as the QuatBox Same internal ruggedness Fluorescence or Absorbance measurements Attractively priced Well suited to “rough” labs Perfect for process control measurements
The Wilson X-Probebox • Highly stabilized, high• •
• •
www.wilsonanalytical.com
output LED Light Source Integrated Spectrometer Works with fiber optic probes Dipping, reflection, fluorescence or other For external samples or inline process analysis systems
The New Wilson Open Platform System • Easily interchangeable
•
•
www.wilsonanalytical.com
highly stabilized, highoutput LED Light Sources complete with optical filters Easily interchangeable Sample Holders complete with optical filters (for solids or liquids) Easily interchangeable Spectrometers coupled to system electronics
The New Wilson Open Platform System
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Tracing with Fluorescent Dyes (Water Flows, Oil Soluble Products)
•Less than 1 ppb detection limit for FL dyes •Dyes only follow the solvent, not the actives
www.wilsonanalytical.com
Direct Environmental Measurements in the Field • ppm level detection limits for petroleum and its conjugated aromatic compounds (PAH’s, NA’s, TPH) in water
Tailings Ponds Oil Spills
Oilfield Fluorescence-Based Measurements
• Intrinsically Fluorescent Materials (Corrosion Inhibitors)
www.wilsonanalytical.com
•Reliable data can be obtained within minutes of sampling •Custom designed, intuitive software makes it easy to use
www.wilsonanalytical.com
• 1 ppm detection limit for most continuously applied corrosion inhibitors containing APQ’s
• No sample preparation other than filtration and dilution
Oilfield Fluorescence-Based Measurements
• No APQ’s ? Using other bases? Fluorescent Imidazolines!
www.wilsonanalytical.com
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
• Intrinsically Fluorescent Materials (Corrosion Inhibitors)
Batch Inhibitors are Next www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•
Intrinsically Fluorescent Materials (Frac Tracers)
www.wilsonanalytical.com
www.wilsonanalytical.com
Fluorescent Silica Nanoparticles (FSNP)
For more info, contact Dr. David Antoniuk [email protected] Tel: (780) 554-7398 www.wilsonanalytical.com
Fluorescent Silica Nanoparticles (FSNP) • Applied Quantum Materials has developed a suite of nanoparticles for the oil industry that can be used as a non-toxic, thermally stable reservoir tracer. • AQM’s materials are designed to be stable at downhole temperatures of 250 ᵒC, and are made to be compatible with fracking solutions by adjusting their surface chemistry. • Appropriately sized silica nanoparticles infused into a fracture fluid can penetrate the newly opened fractures during the pressurized fracturing stage. • Detection of FSNP to ppb can be made with Wilson Analytical spectrometers. www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Fluorescently-tagged Actives (Kemira Scale Inhibitors)
• Polyacrylamides? www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Nanochemistry-based fluorescent reagents (sulfide in water)
A Retrievable and Highly Selective Fluorescent Probe for Monitoring Sulfide and Imaging in Living Cells Fengping Hou, Liang Huang, Pinxian Xi, Ju Cheng, Xuefei Zhao, Guoqiang Xie,Yanjun Shi, Fengjuan Cheng,Xiaojun Yao, Decheng Bai, and Zhengzhi Zeng. Inorg. Chem. 2012, 51, 2454−2460
www.wilsonanalytical.com
Oilfield Fluorescence-Based Measurements
•Nanochemistry-based fluorescent reagents (Scale Inhibitors) Aluminum-Morin Complex: •FL signal is quenched by Scale Inhibitor Binding to Al (a Turn-Off reagent) •Working FL Turn-On Reagents
www.wilsonanalytical.com
The Future of Wilson Instrumentation • In-instrument sample mixture separation • Detection of multiple analytes at one time using a single instrument www.wilsonanalytical.com
Current Oilfield Water Analysis
www.wilsonanalytical.com
The WaterBox
Full Oilfield Water Analysis at the Point of Sampling www.wilsonanalytical.com
The WaterBox •
Based on Capillary Electrophoresis, which uses electrical separation of anions (-ve ions) and cations (+ve ions) in water with optical detection • Designed to give accurate results under field conditions, even with brines • Full oilfield water chemical analysis of all cations and anions, corrosion and scale inhibitor residuals • Answers in less than 30 minutes directly in the field
www.wilsonanalytical.com
The WaterBox •Advanced anion profiles for Corrosion Work and Pipelines Organic Acids Sulphur speciation (sulphide, sulphate, sulphite, …)
•
Advanced ion profiles for Fracturing Applications Borates Nitrates Multiple Simultaneous Frac Tracers (64+)
•
Advanced anion profiles for Oilsands applications Silicates Napthenic Acids www.wilsonanalytical.com
Portable H2S Analyzer for Liquid Hydrocarbons H2S Off-Gassing Potential?
Transport Canada to Regulate www.wilsonanalytical.com
Portable H2S Analyzer for Liquid Hydrocarbons
www.wilsonanalytical.com
Contact us: Ken Schmidt Phone: (780) 702-0610 Email: [email protected]
www.wilsonanalytical.com
