safety data sheet - AgIC
SAFETY DATA SHEET Effective Date: February 1. 2017 Revision Number: 1
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: NoSolder Recommended use:
Glue electric components
Manufacturer Name: AgIC Inc.
High Tech Hongo Bldg. 1F, 5-25-18 Hongo, Bunkyo, Tokyo, 1130033 Japan Phone: +81-3-3815-8333
2. HAZARDS IDENTIFICATION
Hazard communication elements Health hazards
Hazard category
Eye damage/irritation
2
Skin Sensitization
1
Respiratory sensitization
Carcinogenicity
Specific target organ toxicity (Single exposure)
Specific target organ toxicity (Repeated exposure)
Environmental hazards
Hazardous to the aquatic environment (Acute)
Hazardous to the aquatic environment (Chronic)
Signal word:
1 2 1 1 2 3
Danger
Hazard statement:
Serious eye irritation
May cause an allergic skin reaction
May cause allergic, asthmatic symptoms, or breathing difficulties if inhaled Suspected of causing cancer Causes damage to organs
Causes damage to organs through prolonged or repeated exposure Toxic to aquatic life
Toxic to aquatic life with long lasting effects
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3. COMPOSITION/INFORMATION ON INGREDIENTS Component
Cas.
%
Silver and its soluble compounds
7440-22-4
35
Metamorphic silicone Nickel and its compounds
10–20
7440-02-0
22
Silica
10–20
Paraffin
1–10
Harmful Substances Subject to Be Indicated their Names, etc.
(Industrial Safety and Health Act)
Silver and its soluble compounds, nickel and its compounds, silica
Harmful Substances Whose Names, etc. Should Be Notified
(Industrial Safety and Health Act)
Silver and its soluble compounds, nickel and its compounds, silica
Designated Chemical Substances
(PRTR)
Silver and its soluble compounds, nickel and its compounds
4. FIRST AID MEASURES INHALATION:
Move exposed person to fresh air. Keep him or her at rest in a position comfortable for breathing. if breathing is irregularor if respiratory arrest occurs, call a doctor.
SKIN CONTACT:
Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
EYE CONTACT:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Get medical attention if any discomfort continues.
INGESTION:
Rinse mouth.
Call a doctor if you feel unwell.
IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT:
Special treatment is needed.
5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA:
Carbon dioxide, dry chemical, chemical foam.
Wear fireproof clothing.
Keep unnecessary personnel away.
FIRE FIGHTING PROCEDURES:
IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT: 6. ACCIDENTAL RELEASE MEASURES
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Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away.
Ensure adequate ventilation until spilled material is collected. Use appropriate protective equipment.
To avoid contact with skin and eys, wear protective equipment such as impervious gloves. 7. HANDLING AND STORAGE HANDLING:
Do not inhale dust, smoke, gas, mist, vapor or spray.
Obtain instruction before use.
Avoid inhaling dust, smoke, gas, mist, vapor or spray. Do not handle material before understanding instruction. Wear protective goggles, mask, gloves and clothing.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: Store in well-ventilated place. Close the cap tightly. Store locked up.
Store between 5–10° C. Keep refrigerated.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION CONTROL PARAMETERS:
Occupational exposure limits
Nickel and its compounds 1mg /m3 (Japan Society of Occupational Health 1967)
Nickel and its compounds 1.5mg /m3 (ACGIH 1996 TWA)
Silver and its soluble compounds 0.01mg-Ag/m3 (Japan Society of Occupational Health 1991)
Silver and its soluble compounds 0.1mg-Metal Ag/m3 (AGCIH 1992 TWA)
APPROPRIATE ENGINEERING CONTROLS:
Wash contaminated area throughly.
Contaminated work clothing must not be allowed out of the workplace.
Do not smoke or drink.
Remove contaminated clothing and wash it before reuse.
PERSONAL PROTECTIVE EQUIPMENTS:
Respiratory protection: Wear air-purifying respirators if ventilation is impaired.
Skin protection: Wear protective gloves and gloves.
Eye protection: Wear protective mask and goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Pale yellow liquid Odor : Faint distinct odor Flash Point: 81 °C
Density: 2.35 g/cm3 3/6
10. STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable
11. TOXICOLOGICAL INFORMATION Acute toxicity: No data
Skin corrosion/irritation:
Silver and its soluble compounds - Category 1 (ACGIH, 2001)
Nickel and its compounds - Category 1 (NITE Initial Risk Assessment Report, Ver. 1.0, No. 69, 2008)
Respiratory sensitization:
Nickel and its compounds - Category 1 (MAK/BAT No 43, 2007)
Germ cell mutagenicity: No data Carcinogenicity:
Silica:
Nickel and its compounds:
IARC Gr. 3: Not classifiable as to its carcinogenicity to humans
IARC (1990) - Gr. 2B: Possibly carcinogenic to humans
EU - Category 2: Suspected human carcinogens
ACGIH (1996) - A6: Not suspected as a human carcinogen
Reproductive toxicity: No data Teratogenesis: No data STOT-single exposure:
Category 1:
Silver and its soluble compounds:
Nickel and its compounds
Respiratory system (ACGIH, 2001)
Respiratory system, the kidneys (NITE Initial Risk Assessment Report No 69, 2008)
Category 3:
Paraffin:
Respiratory tract irritation (PATTY 5th, 2001)
STOT-repeated exposure
Category 1:
Silver and its soluble compounds:
Eye (ACGIH, 2001)
Respiratory system: inhalation (HSDB, 2003)
Nickel and its compounds:
Respiratory system (NITE Initial Risk Assessment Report No. 69, 2008)
Aspiration hazard: No data
12. ECOLOGICAL INFORMATION Aquatic toxity:
Toxic to aquatic life
Acute toxic ingredients:
Toxic to aquatic life with long lasting effects
Paraffin:
Crustacea (Daphnia magna) EC50 = 0.011 mg/L/48hr (Ministry of the Environment, Japan, eco-toxicity 4/6
tests 2004)
Solubility in water:
Nickel and its compounds:
Silver and its soluble compounds:
Insoluble (ICSC, 2001)
Insoluble (ICSC, 1997)
Persistence and egradabtlity: No data Bioaccumulative potential:
Paraffin:
log Pow = 6.5 (PHYSPROP Database, 2011)
Mobility in soil: No data
Ozone depletion potential: No data 13. DISPOSAL CONSIDERATION
Should not be released into the environment.
Before disposal, consult appropriate local and national regulatory agencies to ascertain proper procedures.
According to Waste Management and Public Cleansing Act, this material is a mixture of waste oil, which is a special controlled industrial waste, and waste plastics, and its disposal should be entrusted to a waste disposer
who has received a permission. The empty package is a mixture of metal scraps, which is a industrial waste, and waste plastics if the adhesive is cured. 14. TRANSPORT INFORMATION U.N. number: N.A.
Special controlled industrial waste:
Ensure no leakage. Do not tip over, drop or break. Ensure to prevent the cargo from shifting.
15. REGULATORY INFORMATION
Special controlled industrial waste:
Poisonous and Deleterious Substances Control Act:
Industrial Safety and Health Act:
N/A
Not applicable to organic solvents
Harmful Substances Subject to Be Indicated their Names, etc. (Order for Enforcement, Article 18):
Silver and its soluble compounds, nickel and its compounds, silica
Harmful Substances Whose Names, etc. Should Be Notified (Article 57-2, Order for Enforcement Article 18-2,
Attached table 9)
Silver and its soluble compounds, nickel and its compounds, silica
Law concerning Pollutant Release and Transfer Register:
Class I Designated Chemical Substances:
Silver and its soluble compounds (35%), nickel and its compounds (22%)
Fire Service Act:
Pneumoconiosis Act:
Air Pollution Control Act:
Combustible liquids (Notified amount 2m3)
Silica
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Hazardous Air Pollutants (Central Environment Council, Ministry of the Environment of Japan 9th Report)
Silver and its soluble compounds, nickel and its compounds
Water Pollution Control Law:
Specified Facilities:
Nickel and its compounds (
16. OTHER INFORMATION Reference:
Globally Harmonized System of classification and labelling of chemicals, (5th ed., 2013), UN Recommendations on the TRANSPORT OF DANGEROUS GOODS 18th edit., 2013 UN
Classification, labelling and packaging of substances and mixtures (table3-1 ECNO6182012) 2012 EMERGENCY RESPONSE GUIDEBOOK(US DOT) 2015 TLVs and BEIs. (ACGIH)
http://monographs.iarc.fr/ENG/Classification/index.php JIS Z 7253 (2012) JIS Z 7252 (2014)
2015 Recommendation of Occupational Exposure Limits (Japan Society of Occupational Health) Supplier's data/information General Disclaimer
The information contained herein is correct to the best of our knowledge, information and belief at the date of its
publication. Users should consider the given information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources
to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. The given information is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: NoSolder Recommended use:
Glue electric components
Manufacturer Name: AgIC Inc.
High Tech Hongo Bldg. 1F, 5-25-18 Hongo, Bunkyo, Tokyo, 1130033 Japan Phone: +81-3-3815-8333
2. HAZARDS IDENTIFICATION
Hazard communication elements Health hazards
Hazard category
Eye damage/irritation
2
Skin Sensitization
1
Respiratory sensitization
Carcinogenicity
Specific target organ toxicity (Single exposure)
Specific target organ toxicity (Repeated exposure)
Environmental hazards
Hazardous to the aquatic environment (Acute)
Hazardous to the aquatic environment (Chronic)
Signal word:
1 2 1 1 2 3
Danger
Hazard statement:
Serious eye irritation
May cause an allergic skin reaction
May cause allergic, asthmatic symptoms, or breathing difficulties if inhaled Suspected of causing cancer Causes damage to organs
Causes damage to organs through prolonged or repeated exposure Toxic to aquatic life
Toxic to aquatic life with long lasting effects
1/6
3. COMPOSITION/INFORMATION ON INGREDIENTS Component
Cas.
%
Silver and its soluble compounds
7440-22-4
35
Metamorphic silicone Nickel and its compounds
10–20
7440-02-0
22
Silica
10–20
Paraffin
1–10
Harmful Substances Subject to Be Indicated their Names, etc.
(Industrial Safety and Health Act)
Silver and its soluble compounds, nickel and its compounds, silica
Harmful Substances Whose Names, etc. Should Be Notified
(Industrial Safety and Health Act)
Silver and its soluble compounds, nickel and its compounds, silica
Designated Chemical Substances
(PRTR)
Silver and its soluble compounds, nickel and its compounds
4. FIRST AID MEASURES INHALATION:
Move exposed person to fresh air. Keep him or her at rest in a position comfortable for breathing. if breathing is irregularor if respiratory arrest occurs, call a doctor.
SKIN CONTACT:
Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
EYE CONTACT:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Get medical attention if any discomfort continues.
INGESTION:
Rinse mouth.
Call a doctor if you feel unwell.
IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT:
Special treatment is needed.
5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA:
Carbon dioxide, dry chemical, chemical foam.
Wear fireproof clothing.
Keep unnecessary personnel away.
FIRE FIGHTING PROCEDURES:
IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT: 6. ACCIDENTAL RELEASE MEASURES
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Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away.
Ensure adequate ventilation until spilled material is collected. Use appropriate protective equipment.
To avoid contact with skin and eys, wear protective equipment such as impervious gloves. 7. HANDLING AND STORAGE HANDLING:
Do not inhale dust, smoke, gas, mist, vapor or spray.
Obtain instruction before use.
Avoid inhaling dust, smoke, gas, mist, vapor or spray. Do not handle material before understanding instruction. Wear protective goggles, mask, gloves and clothing.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: Store in well-ventilated place. Close the cap tightly. Store locked up.
Store between 5–10° C. Keep refrigerated.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION CONTROL PARAMETERS:
Occupational exposure limits
Nickel and its compounds 1mg /m3 (Japan Society of Occupational Health 1967)
Nickel and its compounds 1.5mg /m3 (ACGIH 1996 TWA)
Silver and its soluble compounds 0.01mg-Ag/m3 (Japan Society of Occupational Health 1991)
Silver and its soluble compounds 0.1mg-Metal Ag/m3 (AGCIH 1992 TWA)
APPROPRIATE ENGINEERING CONTROLS:
Wash contaminated area throughly.
Contaminated work clothing must not be allowed out of the workplace.
Do not smoke or drink.
Remove contaminated clothing and wash it before reuse.
PERSONAL PROTECTIVE EQUIPMENTS:
Respiratory protection: Wear air-purifying respirators if ventilation is impaired.
Skin protection: Wear protective gloves and gloves.
Eye protection: Wear protective mask and goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Pale yellow liquid Odor : Faint distinct odor Flash Point: 81 °C
Density: 2.35 g/cm3 3/6
10. STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable
11. TOXICOLOGICAL INFORMATION Acute toxicity: No data
Skin corrosion/irritation:
Silver and its soluble compounds - Category 1 (ACGIH, 2001)
Nickel and its compounds - Category 1 (NITE Initial Risk Assessment Report, Ver. 1.0, No. 69, 2008)
Respiratory sensitization:
Nickel and its compounds - Category 1 (MAK/BAT No 43, 2007)
Germ cell mutagenicity: No data Carcinogenicity:
Silica:
Nickel and its compounds:
IARC Gr. 3: Not classifiable as to its carcinogenicity to humans
IARC (1990) - Gr. 2B: Possibly carcinogenic to humans
EU - Category 2: Suspected human carcinogens
ACGIH (1996) - A6: Not suspected as a human carcinogen
Reproductive toxicity: No data Teratogenesis: No data STOT-single exposure:
Category 1:
Silver and its soluble compounds:
Nickel and its compounds
Respiratory system (ACGIH, 2001)
Respiratory system, the kidneys (NITE Initial Risk Assessment Report No 69, 2008)
Category 3:
Paraffin:
Respiratory tract irritation (PATTY 5th, 2001)
STOT-repeated exposure
Category 1:
Silver and its soluble compounds:
Eye (ACGIH, 2001)
Respiratory system: inhalation (HSDB, 2003)
Nickel and its compounds:
Respiratory system (NITE Initial Risk Assessment Report No. 69, 2008)
Aspiration hazard: No data
12. ECOLOGICAL INFORMATION Aquatic toxity:
Toxic to aquatic life
Acute toxic ingredients:
Toxic to aquatic life with long lasting effects
Paraffin:
Crustacea (Daphnia magna) EC50 = 0.011 mg/L/48hr (Ministry of the Environment, Japan, eco-toxicity 4/6
tests 2004)
Solubility in water:
Nickel and its compounds:
Silver and its soluble compounds:
Insoluble (ICSC, 2001)
Insoluble (ICSC, 1997)
Persistence and egradabtlity: No data Bioaccumulative potential:
Paraffin:
log Pow = 6.5 (PHYSPROP Database, 2011)
Mobility in soil: No data
Ozone depletion potential: No data 13. DISPOSAL CONSIDERATION
Should not be released into the environment.
Before disposal, consult appropriate local and national regulatory agencies to ascertain proper procedures.
According to Waste Management and Public Cleansing Act, this material is a mixture of waste oil, which is a special controlled industrial waste, and waste plastics, and its disposal should be entrusted to a waste disposer
who has received a permission. The empty package is a mixture of metal scraps, which is a industrial waste, and waste plastics if the adhesive is cured. 14. TRANSPORT INFORMATION U.N. number: N.A.
Special controlled industrial waste:
Ensure no leakage. Do not tip over, drop or break. Ensure to prevent the cargo from shifting.
15. REGULATORY INFORMATION
Special controlled industrial waste:
Poisonous and Deleterious Substances Control Act:
Industrial Safety and Health Act:
N/A
Not applicable to organic solvents
Harmful Substances Subject to Be Indicated their Names, etc. (Order for Enforcement, Article 18):
Silver and its soluble compounds, nickel and its compounds, silica
Harmful Substances Whose Names, etc. Should Be Notified (Article 57-2, Order for Enforcement Article 18-2,
Attached table 9)
Silver and its soluble compounds, nickel and its compounds, silica
Law concerning Pollutant Release and Transfer Register:
Class I Designated Chemical Substances:
Silver and its soluble compounds (35%), nickel and its compounds (22%)
Fire Service Act:
Pneumoconiosis Act:
Air Pollution Control Act:
Combustible liquids (Notified amount 2m3)
Silica
5/6
Hazardous Air Pollutants (Central Environment Council, Ministry of the Environment of Japan 9th Report)
Silver and its soluble compounds, nickel and its compounds
Water Pollution Control Law:
Specified Facilities:
Nickel and its compounds (
16. OTHER INFORMATION Reference:
Globally Harmonized System of classification and labelling of chemicals, (5th ed., 2013), UN Recommendations on the TRANSPORT OF DANGEROUS GOODS 18th edit., 2013 UN
Classification, labelling and packaging of substances and mixtures (table3-1 ECNO6182012) 2012 EMERGENCY RESPONSE GUIDEBOOK(US DOT) 2015 TLVs and BEIs. (ACGIH)
http://monographs.iarc.fr/ENG/Classification/index.php JIS Z 7253 (2012) JIS Z 7252 (2014)
2015 Recommendation of Occupational Exposure Limits (Japan Society of Occupational Health) Supplier's data/information General Disclaimer
The information contained herein is correct to the best of our knowledge, information and belief at the date of its
publication. Users should consider the given information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources
to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. The given information is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
6/6
