SEMICONDUCTOR PHYSICS & DEVICES

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Electron & Hole Density:

SEMICONDUCTOR PHYSICS & DEVICES

⏞ ( ) ( ) ( ) ( ) ( )) ( : Fermi-Dirac-Probability, : density of states in cond. band ( ) ( ) ( )

Summary of the lectures held by Prof. Dr. A. Schenk

(

CONSTANTS & MATERIAL PARAMETER S

Planck’s constant: Dielectric constant (für cm):

(

(

)



)

) (



)

(

(

)

)

(



)

(

(



)

)



)

(

)

for

)

(

)

( ⏟

(

)



(

( (

) (

)

(

MATERIAL-PARAMETER GERMA NIUM Relative permittivity: Intrinsic carrier concentration:

MATERIAL-PARAMETER ANDERE

(

)

(

)

(

)

)

4. SEMICONDUCT OR IN EQU ILI BRIUM direct semicond.: if the minimum of the conduction band is at the same place like the maximum of the valence band. indirect semicond.: if it is not a direct semiconductor. This means a phonon is also needed actually get an electron from valence to conduction band. Problematic in optical systems. intrinsic: no impurities, lattices defects, ... noted as , extrinsic: aritificially doped semiconductor thermal equilibrium: no applied voltage or current,noted as donor atoms: create n-type semiconductor ⁄ fermi level: with ( ) eff. mass approx.: so quantum effects can be neglected

CHARGE NEUTRALITY

In case of an applied voltage we get

CHARGE CARRIERS I N S EMICONDUCTORS

and :

for n-type at low injection (

) and

:

( ⏟



(

( ) ( )

( )

( ( )

. )

(

)

)

(

)

(

)

⁄ ( ) for abd ( )⁄ ⁄ ( ) ( ) { ⁄ ( ) Appilcation 4: finite number of electron-hole pairs is generated at , but for . n-type semicond. with constant applied E-field in direction. Solution:

Application 3:

)

(



(

)

)

Diffusion Length: →

and get

)→

)



)

)

we have

(

(

Derivation: (

( )

)



)→

)

( )

konst and

POSITION OF THE FERMI -ENERGY -LEVEL

(

)

) and

(

Einstein Relation:

In the special case

(



( ) ( ) ⁄ Application 2: homogeneous n-type semicond. zero applied electr. field, therm. eq. for , uniform gen. rate for

)

(

and

for p-type at low injection (

(

GRADED I MPURITY DISTRI BUTION

√(

)

)

Application 1: n-type semicond., uniform conc. of excess holes:

TOTAL CURRENT DE NSIT Y

Complete ionization, if above expression is Doping of Semiconductors: p-doping: e.g. Boron with 3 instead of 4 valene electr. n-doping: e.g. Phosphorus, 5 instead of 4 valence electrons near degenerate: conducts always metallic

]

(



( ⏟

⏞ ⏟



APPLICATIONS OF AMBI POLA R TRANSPORT

charge neutrality in thermal equilibr. at complete ionisation: [

)

CARRIER DIFFUSI ON

Relative number of electrons/holes on the doping energy levels relative to the overall number of charge carriers.

hole mobility: effective electron mass: effective hole mass:

⁄ ⁄

( ⏟



)

IONIZATION & FREEZE OUT

)



with )

( )

:

Ambipolar Transport for p-type (for n-type replace n with p)

5. CARRIER TRANSPORT PH ENOMENA

)

⏟(

( )

and

( )

AMBIPOLAR TRANSPORT

)

CARRIER DRIFT

for intrinsic case:

electron mobility:

) material at low-level injection ( )

Continuity Equations: p.195ff

nt ns c cas

Relative permittivity: Intrinsic electron concentration: Eff. state density in conduct. band: Eff. state density in valence band: band gap: electron affinity:

Rel. permittivity of Doping density

for p-type (

-PRODUCT

MATERIAL-PARAMETER SILIZIU M jeweils bei



(

(

∫ (

)

)

hole conc.

Elementary charge: Boltzmann’s constant:

(



electron conc. (

CARRIER GE NERATION & RECOMBINATION

)

Electron & Hole Concentration:

Lukas Cavigelli, July 2011 [email protected]

(Materialparameter

: excess minority carrier electron lifetime : excess electron and hole recombination rates

-

( )

( )

( )

( )

( )

√ →

( )

( )

Hall Effect: left out, see p.177ff

6. NON-EQUILIBRIUM EXCESS CARRIERS Thermal equilibrium: ⏟



: excess electron and hole generation rates : excess electron concentration



Dielectric Relaxation Time Constant: time it takes to until neutrality is achieved after a burst of excess carriers: ⁄

OTHER SUBTOPICS Quasi-Fermi Energy Levels: see p.216ff Excess-Carrier Lifetime (Shockley-Read-Hall): p.219ff

⁄ : minority carriers conc. in p-region, th. equ. ⁄ : min. carriers (holes) c. in n-region, th. equ. : total minority carrier conc. in p-region, analogous ( ): min. carrier conc. in p-region at space charge edge : excess min. carrier conc. in p-region

7. PN JUNCTION BASIC STRUCTURE p-region ( n-region ( In fact we reassign

) ) ,

in p-region, …

CARRIER DE NSITIES WI TH FORWARD VOLTAGE Boundary Conditions:

Polarity: in case of n-type semicond.: reverse-biased is +-pole connected to semiconductor Ideal Junction Properties:

Zener Breakdown: Electrons start tunneling through the potential barrier.

)

(

)

(

(

)

)

)

(

(

( )

( (

: We have a reverse voltage, if n-region is connected to higher potential than the n region. Very little current flows. ; Forward voltage. p-region connected to higher potential. Large current flows.

( ( )

)

)



(

)

)

(

)

)

(

(

(



(

)

Remark: is the cutoff current “Sp Small Signal Model: p. 286ff

: distance from potential maximum to the junction : reduction of the Schottky barrier )

) √

)

st om”

GENERATION-RECOMBINATION CURREN TS

BASIC PROPERTIES

Reverse-Bias Generation Current: (p. 297)

Built-in potential (Diffusionsspannung): (

(

)

)

(

)

(

{



Special cases with interfacial layer: p. 336 Current Voltage Relationship:

Forward-Bias Recombination Current: (p. 300)

Derivation: ∫



{

)

(

(

Space Charge Width:

)

(

)

( (

)

)

)

(

)

Diode Current-Voltage Relationship: √

)

)

Minority Carrier Distribution: p.275ff Ideal pn Junction Current: ( )

(

Schottky-Effect, “Bildkrafteffekt”: Maximum cutoff voltage declines with higher applied reverse voltage.

heterojunction: junction with different semicond. materials (

)



9. METAL-SEMICONDUCTOR JU NCTIONS

(

(



(

(

)

(

)

)

)



Schottky-Diode: ( ) Ohmic contact: with n-type, or with p-type This can be achieved through heavy doping. See page 345ff Heterojunctions: see p. 349

if p-semicond. band is bent down instead of up; electr. in semicond., holes in metal

Capacitance:

SCHOTTKY BARRIER DI O DE (

)(

)

One-Sided Junctions: for -junction: For non-uniformly doped junctions: redo all from scratch

8. PN JUNCTION DIODE

JUNCTION BREAKDOWN Voltage for Avalanche Breakdown in one-sided junction: p.305

: Donor conc. in n-region

: ideal Schottky barrier height, potential barrier seen by electrons moving from metal into the semiconductor : metal work function (table) : electron affinity of the semiconductor (table) : potential difference between conduction band and Fermienergy of the n-type semiconductor (

: Acceptor conc. p-region, maj. carrier hole density in p-region in thermal equilibrium with and

: doping conc. in weak doped half of the junction ( ) has to be looked up in a table.

)

METAL-SEMICONDUCTOR O HMIC CONTACTS

)

Maximum Electric Field: (for reverse applied bias) (

(

: Richardson constant Comparison Schottky pn Diode: p.341

: ideality factor. large diffusion dominates if small recombination dominates (



)

Remark: This does not really work out in terms of its units. Feel free to exchange eV and V (no calculation needed).

SCHOTTKY V. PN -DIODE

Forward Voltage Cutoff Current Max. Cutoff Voltage Switching Speed

Schottky

pn

to very good, just a few ps

multiple kV Diffusion Capacity, reverserecovery effect

Punch-Through Breakdown Voltage: p. 208 if B-C space charge region increases until it reaches the B-E space chage region. ( ) ( )

LOW-FREQUENCY CURRENT GA IN

10. BIPOLAR TRANSIST OR by region:

Currents:

: : :

√ (

with

)

Avalanche Breakdown:

(Alpha-)Cutoff Frequency: |



whereby is determined empirically.

where the BE diode is conducting and the CB diode is not. In act v mod , th BE d od s th “actual” pn junct on wh as the CB junction is just used to suck off the electrons.

SIMPLIFIED CURRENT RELATIONS ( ) ⏟

(

)

this formula is only valid if recombination in the collector can be neglected (which should usually be the case) : thermal equilibrium electron conc. in the base : base width; : electron diffusion coefficient

: common-base current gain; : common-emitter current gain ) Attention: the calculation of is extremely sensitive!! ( Modes of Operation: Cutoff: almost no cu nt, “sw tch d off” Forward active: usual mode, lin. amplification control volt.: , large curr.: Saturation: “sw tch d on”, no fu th ampl f. forward-active:

⁄ Beta-Cutoff frequency: : or respectively at low frequency Large Signal Switching, Schottky-Clamped Transistor, other bipolar Transistor Structures: see book Possible Implementation:

: diffusion of minority carrier electrons in the base at : diffusion of minority carrier electrons in the base at : recombination of excess minority carrier electrons with majority carrier holes in the base. is the flow of holes into the base to replace recombined holes. : diffusion of minority carrier hole in the emitter at : recomb. of cerriers in the forward-biased B-E junction : diffusion of min. carrier holes in the collector at : generation of carriers in reverse-biased B-C junction Currents are B-E junction currents only. Currents are B-C junction current only. Derivation of Current Gain:

: breakdown voltage between C and B, with E unconnected

all factors should be for strong amplification. emitter injection efficiency factor :

MINORITY CARRIER DIS TRIBUTI ONS

( (

⁄ ⁄

) )



Other Effects: high injection (p. 401), emitter bandgap narrowing (p. 403), current crowding (p. 405), non-uniform base doping (p. 406) Open Circuit Calculation: p. 411

EQUIVALENT CIRCUIT M ODE LS - Ebers-Moll Model: p. 412 - Gummel-Poon Model: p. 416 - Hybrid-Pi Model: p. 418

EXAMPLE

CALCULATION

( (

⁄ ⁄



→ (

)

(



( )

)

recombination factor : ( ( (

)

) )

Early-Effect / Base Width Modulation: p.397 shows effects of not constant, but ( )

(



)

( )

( )

( )

(

(

)

((

(

(

(

)

)(

)

)

)(

) (

) )



)

)

) √

(

: excess minority electron concentration in the base : minority electron conc. in the base in thermal equilibrium ( ): total minority electron conc. in the base

) √

( (

) )

FREQUENCY LIMITATION S : emitter-to-collector delay, : emitter-base junction capacity charge time, : base transit time, : collector depletion region transit time, : collector capacity charge time (

: Early voltage; saturation:

⁄ ⁄

: diffusion length; : real width of the base/emitter (i.e. and ) base transport factor :

NON-IDEAL EFFECTS

cutoff:

|→

)

(

)

Note: the npn transistor only works due to its geometry (small base)

: output conductance (



)

(

MOS-CAPACITOR

)

Exam: only n-channel = p-type MOSFET.

( (

)

)

( (

MODES OF OPERATION

)

Non-Saturation:

)

MOS-FET: NON-IDEALITIES

depends on

.

Miller-Effect:

𝐼𝐷𝑆

Everything below is for this case.

√ : maximum width of the space charge region in inversion

MODES OF OPERATION BY MOS -CAP Accumulation: negative voltage at gate holes accumulate in channel region channel fills up with holes not conducting Depletion: pos. voltage at gate not yet enough electrons in channel region to be conducting Threshold: pos. voltage at gate ( ) #electr. in space charge region = #holes in substrate as if channel region not doped Inversion: gate voltage more electrons than holes in channel region like n-doped material, although actually p

DEPLETION LAYER THIC KNESS (

Saturation: does not depend on anymore. Linear ( amplification of . Usually the mode wanted.

)

𝑡 Miller-Plateau Other non-idealities:  subthreshold conduction MOSFET already conducts for voltages  channel-width modulation

accumulation: Meaning of the Threshold Voltage:



)

depletion: not accumulation, but not conducting (

)

MOS-FET: CURRENT -VOLTAGE CHARACT. Currents: MOS-FET conducts, if inversion: conducting,



( ) ( ( ) ( ) : channel length; : channel width; {

Threshold Inversion Point: point of maximum space charge with

. At this point:

) ( ( : drain current



. Then:

)

(√

(

)



(

))

 oxide breakthrough  avalanche breakdown in the blocking pn-diode (source-drain)  punch-through breakdown the source-drain space charge region extends until it touches the other pn-junction short circuit

Work Function Differences: - metal gate -

gate

(

p-substrate: (

p-substrate:

)

Random Stuff: nmos (normally not conducting):

)

MOS-FET

-

gate p-substrate: : metal to semiconductor work function difference Flat-Band Voltage: ⁄

Exam: only n-channel = p-type MOSFET. Everything below is for this case.



: trapped oxide charge per unit area Threshold Voltage (Schwellspannung): when ( (

)

(

)

{

) : max. space charge density per unit area of depl. region (

)

advantage of MOSFET: no control power needed

Transconductance: influence of gate voltage on drain current:



ADMINISTRATIVE STUFF

)

MOS-FET: OTHER STUFF Cutoff-Frequency:

CAPACITANCE -VOLTAGE CHARACTERIST ICS

(

(

)

Exam: 4 KP, 2.5 h, with calculator, all writen material allowed In the calculator: use nnc instead of nc (variable used) to do: define additional units in the calculator