SiO2 beads decorated with SrO nanoparticles for biodiesel production ...
Electronic Supplementary Information, ESI
SiO2 beads decorated with SrO nanoparticles for biodiesel production from waste cooking oil using microwave irradiation Alex Tangy,a Indra Neel Pulidindi,a and Aharon Gedankena,b* a
Department of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel and
b
Department of Materials Science and Engineering, National Cheng Kung University, Tainan
70101, Taiwan Tel: +972-3-5318315; Fax: +972-3-7384053; *E-mail: [email protected]
Figure S1. Modified domestic microwave oven
1
SrO SrCO3
16000
Intensity (a.u.)
12000
8000
4000
0 10
20
30
40 50 2θ (degree)
60
70
Figure S2. The XRD pattern of the material obtained after calcination of SrCO3@SiO2 at 900 °C for 2 h in air
2
Sr(OH)2
SrCO3
SrO
Intensity (a.u.)
5 min.
3 min. 1 min.
30 sec.
10
20
30
40 50 2θ (degree)
60
70
Figure S3. The effect of calcination temperature (900 °C, 3 h) on the conversion of SrCO3@SiO2 to SrO@SiO2
3
Figure S4. The XRD pattern of commercial SrO (standard) from Sigma-Aldrich
4
Figure S5. Pictorial representation of the catalyst (SrO@SiO2) preparation under microwave irradiation
5
Figure S6. Product obtained from the transesterification reaction
Figure S7. A typical 1H NMR of FAME obtained from transesterification of cooked oil with SrO@SiO2 yielding 99.4 wt. % conversion
6
SiO2 beads decorated with SrO nanoparticles for biodiesel production from waste cooking oil using microwave irradiation Alex Tangy,a Indra Neel Pulidindi,a and Aharon Gedankena,b* a
Department of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel and
b
Department of Materials Science and Engineering, National Cheng Kung University, Tainan
70101, Taiwan Tel: +972-3-5318315; Fax: +972-3-7384053; *E-mail: [email protected]
Figure S1. Modified domestic microwave oven
1
SrO SrCO3
16000
Intensity (a.u.)
12000
8000
4000
0 10
20
30
40 50 2θ (degree)
60
70
Figure S2. The XRD pattern of the material obtained after calcination of SrCO3@SiO2 at 900 °C for 2 h in air
2
Sr(OH)2
SrCO3
SrO
Intensity (a.u.)
5 min.
3 min. 1 min.
30 sec.
10
20
30
40 50 2θ (degree)
60
70
Figure S3. The effect of calcination temperature (900 °C, 3 h) on the conversion of SrCO3@SiO2 to SrO@SiO2
3
Figure S4. The XRD pattern of commercial SrO (standard) from Sigma-Aldrich
4
Figure S5. Pictorial representation of the catalyst (SrO@SiO2) preparation under microwave irradiation
5
Figure S6. Product obtained from the transesterification reaction
Figure S7. A typical 1H NMR of FAME obtained from transesterification of cooked oil with SrO@SiO2 yielding 99.4 wt. % conversion
6
