SOLUTIONS-JEE Mains TS-10-2013

Vidyamandir Classes

Solutions to JEE Mains/Test Series - 10/IITJEE - 2013 [CHEMISTRY]

1.(C) 4.(A)

2.(B)

H2O

3.(A)

∆Tf = i K f m

20 172 50 1000

2 = i × 1.72 ×

5.(D)

O || → CH 3 − C − CH 3 CH 3 − C ≡ CH  HgSO 4 / H 2SO 4

Simple Cubic:

Hence, i is 0.5

2r = a r = a/2

4r = 3 a

BCC:

3 a 4

r= 4r =

FCC:

r=

2a a

2 2

6.(D) ••

7.(C)

••

In N H 3 , lone pairs are localised in sp3 orbitals but in P H 3 they are delocalised over the d-orbitals hence lese available for donating.

8.(A)

CuS & HgS (due to minimum Ksp values). 4 2 He

+

27 13 Al

+

1 1p

 →

30 15 P



9.(A) 30 14 Si

+

↓ 30 14

Si + 10e

Cl −

10.(B) Ni

1 0n

CN −

+2

H 2O

NiCl4−2

sp3 : Tetrahedral −2

Ni ( CN )4

 Ni ( H 2O )  6 

dsp2 : +2

square planar

sp3d 2 : octahedral

11.(B)

N2 in added to reduce possibility of formation of higher oxide P4O10.

12.(A)

Kt = 2.303 log

a a−x

Kt = log a − log ( a − x ) 2.303 K + log a log ( a − x ) = − 2.303 Also T50 remains same for first order reaction. Hence I, II and III are correct.

VMC/JEE-2013/Solutions

1

JEE Mains/Test Series-10/ACEG

Vidyamandir Classes 13.(B)

14.(C) Magnetic quantum number (m) can take values from − to +  including O. Hence C is incorrect.

15.(C) 16.(A)

CH 4 + 2O2 → CO2 + 2H 2 3 CH 3OH + O 2 → CO2 + 2H 2 O 2 Now for the given reaction ∆ H = ∆H 1 − ∆H 2 − x + y = − ve

17.(C)



2e −

→ Cu C2u+ 

∆H 2 = − y

x > y.

∆G  = − 2F ( 0.337 )

E = 0.337

1e −

→ Cu + C2u+ 

∆G  = − F ( 0.153)

E = 0.153



(1) – (2)

∆H1 = − x

∆G  = − F ( 0.674 ) + F ( 0.153)

= − F (.521) ∴

18.(B)

Most Volatile:

E = .521 CH4

(No H-Bonding Applicable in This Group)

19.(D)

20.(D)

21.(D)

22.(D)

23.(A)

CH 3CH 2− > NH 2− > CH ≡ C > OH

24.(A) Fe is in + 1 oxidation state as NO is NO+, here Remember! Famous Brown Ring Test compound.

Co-ordination compound has d7 configuration ⇒ 3 unpaired e − . 25.(C)

O / Zn

3 → HCHO CH 2 = CH − R  Vinyl.

26.(D) For a reaction : ∆G = ∆H − T∆S When ∆H = + ve & ∆S = − ve ⇒ 27.(C)

∆G = + ve (Reaction will not be spontaneous)

 2NO2 (g) N 2 O4 (g)  a a (1 − α )

Kp =

2 PNO 2

PN 2O4

0 2aα

 2aα  P  a (1 + α )  =  a (1 − α ) P a (1 + α )

VMC/JEE-2013/Solutions

2

=

4 α2 P

1−α



2

2

α2 =

KP K P + 4P

JEE Mains/Test Series-10/ACEG

Vidyamandir Classes

No. of π bonds = 4 No. of σ bonds = 14

28.(C)

HNO

2→ 

C3 H 9 N

29.(C)

(orPropylamine isopropylamine )

(

C 3 H 8O Must be 2 Alcohol

K Cr O

)

2 2 7  → H SO 2

4

(

CH 3COOH Ketone willalso get oxidiszed due tost.oxi.Agent & heat

)

30.(C) Except (1), all have chiral carbon.

Solutions to JEE Mains/Test Series - 10/IITJEE - 2013 [PHYSICS] 31.(D)

No. of photons / sec = =

32.(B)

total energy radiated / sec Energy of one photon

100 6.67 × 10−34 3 × 10−10

= 3 × 1020

Photon flux = no. of photons per unit area.

3 × 1020

=

4π ( 5)

2

≈ 1018

33.(D) 48 years means two half-life of X and three half-life of Y ⇒ total activity = 34.(A)

x ( x − y ) = 1 − 5 cos ωt



x 2 − 4 x + 4 = 5 − 5 cos ωt



x − 2 = 10 sin ⇒

+ VR2



VR = 98V

VR 98 = = 1.96 A R 50 50 V Also i = c ⇒ 1.96 = Xc  1     2π fc 



C = 104 µ F



q0 = CV0



q=

⇒ 35.(B)

A 22

(x − 2 )

2 2

(110 )2 = ( 50 )2

ωt   = 5  2 sin 2 2  

+

A 22

= 3A / 8

S.H .M

i=

36.(A)

37.(A)

C ( 2V0 ) 2 Let q : new charge on each capacity q0 =



 C ( KC )    ( 2V0 ) = q  C + K C 



N = mg cos θ + F sin θ

2k ( CV0 ) k +1

N µ + F cos θ = mg sin θ



mg sin θ − F cos θ µ= and sin θ = cos θ = 1 / 2 mg cos θ + F sin θ =

38.(C)

KE =

1  mL  2  3

2

150 − 50 = 1/ 2 150 + 50

…(i)

=

2kq0 k +1



N

F

mg

 2 mL ω  ω = 6 

VMC/JEE-2013/Solutions

2 2

3

JEE Mains/Test Series-10/ACEG

Vidyamandir Classes 39.(D) Loss in KE = gain in GPE

mL2ω 2 = mgh 6

⇒ 40.(B)

L2ω 2 6g

h=

F − mg = mω 2 r & r = L / 2 mω 2 L 2 x1 = a sin ωt & x2 = a sin (ωt + φ )

F = mg +

⇒ 41.(B)



x2 − x1 = a sin (ωt + φ ) − a sin ωt = 2 a sin max value = 2a sin φ / 2 =

⇒ 42.(A)

I =

1 ρ c a 2ω 2 2

2

cos ( wt + φ / 2 )

φ



2a

a  Ii =  i Ir  ar 



φ

2

( R / 2 )2

+ H2

= u cos 2 θ +

 u 2 sin θ cos θ    + 2   u sin 2 θ g

=

T /2

π



4

φ =π /2

2

2

43.(C) Average velocity =

=

 u 2 sin 2 θ   2g

  

2

u u sin 2 θ = 4 cos 2 θ + 1 − cos 2 θ = 1 + 3 cos 2 θ 2 2 4

44.(A) 45.(A)

U max = ∈0 Em2 = 8.85 × 10−12 × ( 50 ) = 2.21 × 10−8 J / m3

46.(B)

α =

2

β =

47.(B)

∆ Ic ∆ IE

⇒ α =

α 1−α

=

1 1.013

1 1 = = 76.92 1/ α − 1 0.013

3∆a 3∆b ∆x ∆c = + + x a b c

48.(A)

α

The bolt falls vertically downwards has displacement  / cos α before hitting at bottom



d

⇒ 49.(B)

∆x × 100 = ( 3 × 2) + ( 2 × 1) + ( 4 ) = 12% x



t=

2h = g

2 g cos α

S = Sx1 + Sx2 =

2h v + g

2h v 2



g .S 8h

50.(C) (Pascals Law). 51.(B)

Acl resistances are in parallel, have same potential deff. ⇒ heat dissipated is maximum in the resistance of minimum value ( ic 2Ω ) .

52.(B)

1 mv 2 = eVs = hv − φ0 2

h ( v − v0 ) e graph between Vs are v is straight line not passing through origin, and slop of the line is h/e, but the reason that is does not pass through origin is work function of the metal

= hv − hv0



VMC/JEE-2013/Solutions



vs =

4

JEE Mains/Test Series-10/ACEG

Vidyamandir Classes 53.(B)

The focal length of the spectacles lens has to be in such a way that the rays fro indefinites appears to come from a distance of 200 cm. 1 1 1 − = v u f

1 1 1 − = −2 ∞ f





f = − 2m

1 = −0.5D [Lens to be used is concave lens] f

p=

54.(C) As the rod is plastic, no emf will develop across the rod. 55.(B)

tan θ =

dy = 2kx dx N cos θ = mg N sin θ = ma

56.(C)



a = g tan θ



2kx = a / g



x=

H = H' =

57.(C)

θ

θ

N

x mg

a 2kg

KA ( T1 − T2 ) 2

K ( 2 A ) ( T1 − T2 )





H ' = 4H

1 MR 2ω + MVR & U = Rω 2 3 ⇒ L = MR 2ω 2

L=

58.(A) a = A sin kx

 = N2

A : amplitude at antinode





k =

2π x 3



2mm = 4 sin



2π x π 5π = , 3 6 6



x2 − x1 = 1m



a = A sin



sin



2π 5π − π x2 − x1 ) = ( 3 6

2π x 1 = 3 2

59.(A)

1  1. 5 1  1 = − 1  −  f  1.75   −R R 

60.(B)

12ω1 = xω2



2π 3

λ = 3m



f = + 3.5 R

12λ1 = xλ2

12 × 600 = x × 400

VMC/JEE-2013/Solutions



2π x 3



x = 18

5

JEE Mains/Test Series-10/ACEG

Vidyamandir Classes

Solutions to JEE Mains/Test Series - 10/IITJEE - 2013 [MATHEMATICS] 61.(B)

If we take f (x) = 1, then f ( y ) ≠ 1 as the function is one-one. So f ( x ) ≠ 1 . If f (z) = 1, then statements 2 and 3 both are true, so f ( z ) ≠ 1 hence f (y) = 1 and f −1 (1) = y . [Note f (x) = 2, f (y) = 1, f (z) = 3]

(

)

(

)

62.(B)

x f (0) = 2 and lim f ( x ) = lim e[ ] − e x e − x + A = e −1 − 1 + A

63.(B)

For

x→0 −



π 2

x→0−

< x ≤ 0, f ( x ) = − p sin x + qe − x − rx 3 , so f ( x ) − f ( 0)

f ′ ( 0 − ) = lim

x−0

x→0 −

 p sin x   e − x − 1 2 = lim  − − q  − rx  x→0 −  x   −x  

= −p −q

0< x
0, y = f (x) represents a parabola which open upwards. See figure :

Also,

f (b) = b − d < 0 f ( c ) = c − d < 0 , and f ( d ) = a ( d − b )( d − c ) > 0

Thus, 72.(C)

z= ∴

f ( x ) = 0 has a root between −∞ and b and a root between c and d.

π π 7 − i ( 7 − i )( 3 + 4i ) 25 + 25i  = = = 1 + i = 2  cos + i sin   3 − 4i 9 + 16 25 4 4   14π   7π   7π    14π   7 7 z14 = 27 cos  + i sin  + i sin   = 2 cos     = −2 i    2   4    2    4 

73.(D) Since R and S are symmetric relations so R −1 = R and S −1 = S . But

( RoS )−1 = S −1oR −1 = SoR . Thus RoS is

symmetric if and only if RoS = SoR. 74.(C)

C0 + C1w + C2 w2 + C3 + C4 w + C5 w2 + . . . 3n

=

∑ Ck wk = (1 + w)3n = ( −w2 )

3n

= ( −1)

3n

w6 n

k =0 n

( −1) (1) = ( −1)n . Statement 2 is false as area of triangle formed by cube roots of unity is 75.(B)

3 3 square units. 4

We can choose 4 novels out of 6 in 6 C4 ways and 1 dictionary out of 3 in 3 C1 ways. We can arrange 4 novels and 1 dictionary in the middle in 4! ways. Thus, required number of ways

= 76.(C)

( C ) ( C ) ( 4!) = 1080 > 1000 6

3

4

1

a b = ad − bc . c d Each of the elements can take two values, therefore total number of ways = 16. But ad − bc ≠ 0 if and only ad = x 2 and bc = − x 2 or ad = − x 2 and bc = x 2 But ad = x 2 and bc = − x 2



( a = d = x or a = d = − x )

and ( b = x, c = − x or b = − x, c = x )

That is, there are four ways Similarly, ad = − x 2 and bc = x 2 in four ways. Thus, required probability =

VMC/JEE-2013/Solutions

4+4 1 = 16 2

8

JEE Mains/Test Series-10/ACEG

Vidyamandir Classes P ( A ) = 0.18 + 0.24 + 0.24 + 0.14 = 0.8

77.(C) Note that

P ( B ) = 0.06 + 0.06 + 0.24 + 0.24 = 0.6 P ( C ) = 0.06 + 0.14 + 0.24 + 0.06 = 0.5 P ( B ∩ C ) = 0.24 + 0.06 = 0.3 = P ( B ) P ( C ) P ( C ∩ A ) = 0.14 + 0.24 = 0.38 ≠ P ( C ) P ( A) P ( A ∩ B ) = 0.24 + 0.24 = 0.48 = P ( A ) P ( B ) P ( A ∩ B ∩ C ) = 0.24 = P ( A ) P ( B ∩ C )  78.(C) Let b = α ˆi + β ˆj + γ kˆ

ˆi   We have a × b = 0

ˆj



1

−1 = ( β + γ ) ˆi − α ˆj − α kˆ

α β

(

As

γ

   a × b + c = 0 , we get :

)

( β + γ + 1) ˆi − (α + 1) ˆj − (α + 1) kˆ = 0   Also, as a . b = 3 , we get β − γ = 3



β + γ + 1 = 0 , α = −1

α = −1, β = 1, γ = −2  Hence, b = −ˆi + ˆj − 2kˆ Thus



79.(D)

80.(B)









(a × b ) × (a × c ) . d              = ( a × b ) . ( ( a × c ) × d ) = ( a × b ) . ( a . d ) c − ( c . d ) a           (The last scalar product is zero) = ( a . d ) a b c  Only the point ( −1, − 1, − 1) in (B) lies on the first line.

81.(C) Direction ratios of the line are 1, − 1, 1 and that of the normal to the plane are 2 , − 1, 1

So

sin θ =

2 +1+1 3

6

=

sin θ + 2 cos θ = 82.(C) Putting



4 18 4

18

, cos θ = +

2 18

=

2 18 6

18

= 2

φ (u ) y du dy du . The given differential equation can be written as u + x =u+x =u+2 = u we have x dx dx dx φ ′ (u ) x

φ (u) φ ′ (u) du dx du = 2 =2 ⇒ dx x φ ′ (u) φ (u)

y   83.(D) The degree of the equations in (A), (B), (C) is clearly 1. The equation in (D) can be written as Integrating, we get log φ ( u ) = log x 2 + log k , so φ ( u ) = kx 2

( y − 2 y1 )2 = ( y1 + y ) 84.(C)

i.e.

φ   = kx 2 , k being an arbitrary constant x

which is of degree 2.

 x  + { x} = x and { x} = 0 θ 2 sin 2   × sin θ  2 1 − cos θ = tan θ tan (θ / 2 ) sec θ − 1 = = cos θ cos θ × 2 sin (θ / 2 ) cos (θ / 2 ) Given equation reduces to cos θ = 1 ⇒ θ = 2nπ , n ∈ I Number of solutions in −2011π , 2011π  is 2011.

VMC/JEE-2013/Solutions

9

JEE Mains/Test Series-10/ACEG

Vidyamandir Classes 85.(B)

86.(C)

Let L and M be the tops of the poles at A and B respectively. Angle of elevation of P at A and M be α , and at B and L be β . Then

OA = h cot α = ( h − a ) cot β

and

OB = h cot β = ( h − b ) cot α



h−a h ab = ⇒ =h h h−b a+b

P ^ ~ R stands for

Suman is brilliant and dishonest. Thus, P ^ ~ R ↔ Q stands for Suman is brilliant and dishonest if and only if Suman is rich. Its negation is ~ ( P ^ ~ R ↔ Q ) or ~ ( Q ↔ P ^ ~ R )

n n n 87.(A) We have P ( x ) = 1 +   x +   x 2 + . . . . +   x n 1  2 n



⇒ ∴

n n n P ′ ( x ) =   + 2   x + . . . . + n   x n −1 1 2     n

n P ′ ( 0 ) =   = coefficient of x in the expansion of P(x) 1 Statement 2 is true.

Note that ∆ ( x ) consists of 6 terms of the form (1 + x ) . n

Thus, coefficients of x in ∆ ( x ) = ∆ ′ ( 0 ) But ∆ ′ ( 0 ) =

88.(B)

a1b1

a1b2

a1b3

1

1

1

1

1

1

1

1

+ a2 b1

1

a2 b2

1

1

1

1

1

1

1

1

a3b1

a3b2

a3b3

a2 b3 + 1

(

=0

)

Since AI = IA, we have ( A + I ) + ( A − I ) − 6 A = 2 A3 + 2 3 AI 2 − 6 A = 2 I + 6 A − 6 A = 2 I 3

89.(D) Let

2

6 10 14 + 2 + 3 + 4 +.... 3 3 3 3

S = 1+

1 3 2 3

S=

3

1

2 6 10 + 2 + 3 + 4 +.... 3 3 3 3 1

4 4 4 + 2 + 3 + 4 +.... 3 3 3 3

S = 1+ = 1+

1

+

4 / 32

3 1−1 3

=

4 3

+

2 3

=2



S=3

90.(C) Eccentricity of the ellipse is

e2 = ⇒ ⇒

e=

a 2 − b2 a 3

2

=

4 −1 4

=

3 4

2

 3  coordinates of the focii of the ellipse are  ±2 × , 0 = ± 3 , 0 2  

Length of the latus rectum of the ellipse is

(

)

2 ×1

1 1   = 1 . So the coordinates of P are  3 ,  and of Q are  − 3 ,    2 2 2

(Note Two such parabolas are there)

VMC/JEE-2013/Solutions

10

JEE Mains/Test Series-10/ACEG