'~'fl':
MA TERIALSAFETY
DATA<SHEE'T
(MSDS)
1 - IDENTIFICATION Product
name:
Product
code:
FABRIC SHIELD 43951
Supplier: Advanced Technology Processing Brazennose House lincoln Square Manchester M2 5BL , England 2 - COMPOSITION PREPARA
European telephone Number For Information: 00334785507 43 European Emergency Medical Teleprone Number: 0033478550743 Emergency 24 hour Telephone numb.er: (800) 424,9300 (USA) Date Preparedl: 04.27,2006 Name Of Laboratory Assistant: Aurelie BEROUD
/ INFORMATION
ON THE CONSTITUENTS
T/ON
Chemical
nature:
Constituents
Copolymers
contributing
Polyfluorides
+ UV collectors
to risks:
~
Butyl acetate
or generic
CAS 12386,~.
name
Hazard
Concentration orrange of concentration
,6% 30%:: 20% 45% .
'
Isopropyl alcohol CAS 67.6f.O>.VI Isododecane "',.0, Butane / propane 2 5 CAS1.D'6'9}:B 3 - IDENTIFICATION
\.
-.'
I
Chemical
'(
labeling
i R ,12 F+ highly flammable R36 XI eye irritant
OF THE DANGERS
.
' 1'1'
Principa~ dangers:,Ext:emely
inflammable.
.
1
Effects harmful to health: St?6ng60n'o;enj rations can cause irritation.The cornea and the respiratory tracts may becomeirritated: nar'cotism, h~adaches anct~pther effects can belf\'l,t on the nervous system' Physical
4 - FIRST
"
",'
and chemical
AID
1
dangers I I
._/;)-.v~
1'1111
i!hiBrral~ecompositiO~ . II I'
,'I:'
1
_
,.'
gives off toxic products . '
,
,
(fluorides)
"
'~'fl':
Call a doctor. Whilst awaiting hi5a~~lyal • Inhalation: inhalation of mist: take"lthe person outside, provide oxygen or artificial respiration if necessary and call for a doctor. Contact with the skin: wash with Iplent:y of water and soap; remove soiled clothing and wash thoroughly before reuse' " Contact with the. eyes immediately wpshfthe person's eyes with plenty of water for at least 15 minutes and call for a doctor. " " i' ",. ",'.., ,". Ingestion: do not encourage vomiting, keep the person·calm·~·nd call for a doctor 5 - FIRE-FIGHTING Means of extinction:
MEASURES
Appropriate : Powder, foam, fine spray of water, carbon dioxide (C02) . Large fire: spraynozzle fire hoses (the cyclone of air and atomized water formed by the nozzle dilutes the gas to below the lower limit of inflammability). Inadvisable: Solid jet of water. the firefighters should be equipped with breathing apparatus as the fumes emitted are toxic (fluorides). 6 - MEASURES Individual vapors.
TO BE TAKEN
precautions:
IN CASE OF ACCIDENTAL
LEAKAGE
remove any fire hazard, avoid eye and skin contact and inhalation of the
Precautions for protection of the environment : Do not allow the product to spread into the environment. If the product has spilled into a water course or the drains, or has contaminated the soil or vegetation, notify the police. Take all useful measures to reduce the effects upon ground water. Method of cleaning: absorb with inert materials, place into drums. Consult a specialist regarding the incineration of the waste. 7 - HANDLING
AND STORAGE
HANDLING Appropriate technique al measures: Work in well ventilated areas. Observe the protective measures against electrical and electrostatic energy discharges. Use anti-spark tools. The electrical circuit must be flameproof. Wear cotton work clothes that do not contain acrylics or synthetic materials. Precautions: Avoid the build-up or diffusion of mist into the air. STORAGE Contact to be avoided: oxidizers (so as to prevent aerosols from oxidizing and explodlnq). Technical requirements:
use an appropriate earth connection.
Precautions: do not expose to temperatures above SO°C. Keep in a cool place away from sunlight. Packaging materials: - recommended:
stainless steel, polyethylene, polypropylene, Teflon, original packaging.
- to be avoided: natural rubber, butyl rubber, EPDM, polystyrene. 8 - CONTROL OF INDIVIDUAL technique:
EXPOSURE/PROTECTION
arrange for air renewal or for adequate air extraction in the workshops.
Control parameters (limit values) : 200 ppm.
'.\
.,
Individual protection equipment: standard protective measures when working with aerosols. Respiratory protection: for work involvinq aerosols, wear breathing apparatus with a specific cartridge. Hand protection: gloves. Eye protection: safety goggles. * specific health and safety precautions: avoid eye and skin contact and inhalation of the vapors.
9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: clear fluid liquid. Smell: butyl acetate Boiling point: < 10°C Flash point: < 70°C Self-ignition temperature: > 405°C Explosivity characteristics: Limits in air < 1,8% v/v > 9,5% v/v Vapor pressure: (20°C) 2,5 bars Solubility: insoluble in water 10 - STABILITY AND REACTIVITY Stability: stable under normal conditions of use. The aerosol subject to temperatures show signs of distortion, explode and be projected over a considerable distance.
above 50°C can
Substances to avoid: strong oxidizing agents. thermal decomposition
gives off toxic fluorides.
11 - TOXICOLOGICAL
INFORMATION
* high toxicity: inhalation: in the presence of a high concentration of solvent vapors I mist: headache, drowsiness, nausea, depression of the central nervous system. ingestion: unlikely in the form of an aerosol, low toxicity. contact with the skin: can cause slight skin irritation, however frequent or lengthy exposure can provoke serious skin irritation and dermatitis due to the grease removing properties of the product. 12 - ECOLOGICAL
INFORMATION
Persistence/deqradability
: the active product is not easily biodegradable
13 - CONSIDERATIONS
CONCERNING
DISPOSAL
Disposal via incineration in accordance with the standard regulations. 14 -INFORMATION REGULATIONS ROUTES CLASS CHIFFRE IMDG ASSIMILATION
., LABEL
CONCERNING
TRANSPORT
OVERLAND ADR / RID 2 5°F Bottled inflammable gas under pressure with more than 45% by weight inflammable content
INTERNA TIONAL MARITIME IMDG 2
AIR OACI! lATA 2.1
NATIONAL
2102 Aerosol of capacity less than or equal to 1000 cm3
aerosols, nsa, (not exceeding one litter each)
Obligatory to mention aerosol
Flammable gas W 1950
RTMDR 2 5°F
.,;
Bottled inflammable gas under pressure with more than 45% by weight inflammable content
Inflammable W 3 flame mention aerosol 1950
N° 3 flame mention aerosol 1950
i
3/~
15 STATUTORY
INFORMATION
Community regulations Label. Symbol:
F+ extremely inflammable XI irritating
Phase R •
R 12 extremely inflammable R 36 irritating for eyes
Phase S • Phase (s) safety.
S S S S S
2 : Keep out of the reach of children. 9 : Store the container in a well ventilated area. 16 : Store in a fire free area - Do not smoke. 23 : Do not breathe in the vapors. 33 : Avoid the build-up of electrostatic energy.
Pressurized container. Protect from direct sunlight. Do not expose to temperatures above 50°C. Do not pierce or burn even when empty. Do not spray on flames or incandescent materials. Use and store away from flames, possible sources of ignition, electrical appliances in operation Do not smoke. Keep out of the reach of children. Press in short bursts and avoid prolonged vaporization. Ensure that premises are sufficiently ventilated after use of the product. 16 ADDITIONAL Recommended
INFORMATION usage: protection against soiling and UV light.
DATA<SHEE'T
(MSDS)
1 - IDENTIFICATION Product
name:
Product
code:
FABRIC SHIELD 43951
Supplier: Advanced Technology Processing Brazennose House lincoln Square Manchester M2 5BL , England 2 - COMPOSITION PREPARA
European telephone Number For Information: 00334785507 43 European Emergency Medical Teleprone Number: 0033478550743 Emergency 24 hour Telephone numb.er: (800) 424,9300 (USA) Date Preparedl: 04.27,2006 Name Of Laboratory Assistant: Aurelie BEROUD
/ INFORMATION
ON THE CONSTITUENTS
T/ON
Chemical
nature:
Constituents
Copolymers
contributing
Polyfluorides
+ UV collectors
to risks:
~
Butyl acetate
or generic
CAS 12386,~.
name
Hazard
Concentration orrange of concentration
,6% 30%:: 20% 45% .
'
Isopropyl alcohol CAS 67.6f.O>.VI Isododecane "',.0, Butane / propane 2 5 CAS1.D'6'9}:B 3 - IDENTIFICATION
\.
-.'
I
Chemical
'(
labeling
i R ,12 F+ highly flammable R36 XI eye irritant
OF THE DANGERS
.
' 1'1'
Principa~ dangers:,Ext:emely
inflammable.
.
1
Effects harmful to health: St?6ng60n'o;enj rations can cause irritation.The cornea and the respiratory tracts may becomeirritated: nar'cotism, h~adaches anct~pther effects can belf\'l,t on the nervous system' Physical
4 - FIRST
"
",'
and chemical
AID
1
dangers I I
._/;)-.v~
1'1111
i!hiBrral~ecompositiO~ . II I'
,'I:'
1
_
,.'
gives off toxic products . '
,
,
(fluorides)
"
'~'fl':
Call a doctor. Whilst awaiting hi5a~~lyal • Inhalation: inhalation of mist: take"lthe person outside, provide oxygen or artificial respiration if necessary and call for a doctor. Contact with the skin: wash with Iplent:y of water and soap; remove soiled clothing and wash thoroughly before reuse' " Contact with the. eyes immediately wpshfthe person's eyes with plenty of water for at least 15 minutes and call for a doctor. " " i' ",. ",'.., ,". Ingestion: do not encourage vomiting, keep the person·calm·~·nd call for a doctor 5 - FIRE-FIGHTING Means of extinction:
MEASURES
Appropriate : Powder, foam, fine spray of water, carbon dioxide (C02) . Large fire: spraynozzle fire hoses (the cyclone of air and atomized water formed by the nozzle dilutes the gas to below the lower limit of inflammability). Inadvisable: Solid jet of water. the firefighters should be equipped with breathing apparatus as the fumes emitted are toxic (fluorides). 6 - MEASURES Individual vapors.
TO BE TAKEN
precautions:
IN CASE OF ACCIDENTAL
LEAKAGE
remove any fire hazard, avoid eye and skin contact and inhalation of the
Precautions for protection of the environment : Do not allow the product to spread into the environment. If the product has spilled into a water course or the drains, or has contaminated the soil or vegetation, notify the police. Take all useful measures to reduce the effects upon ground water. Method of cleaning: absorb with inert materials, place into drums. Consult a specialist regarding the incineration of the waste. 7 - HANDLING
AND STORAGE
HANDLING Appropriate technique al measures: Work in well ventilated areas. Observe the protective measures against electrical and electrostatic energy discharges. Use anti-spark tools. The electrical circuit must be flameproof. Wear cotton work clothes that do not contain acrylics or synthetic materials. Precautions: Avoid the build-up or diffusion of mist into the air. STORAGE Contact to be avoided: oxidizers (so as to prevent aerosols from oxidizing and explodlnq). Technical requirements:
use an appropriate earth connection.
Precautions: do not expose to temperatures above SO°C. Keep in a cool place away from sunlight. Packaging materials: - recommended:
stainless steel, polyethylene, polypropylene, Teflon, original packaging.
- to be avoided: natural rubber, butyl rubber, EPDM, polystyrene. 8 - CONTROL OF INDIVIDUAL technique:
EXPOSURE/PROTECTION
arrange for air renewal or for adequate air extraction in the workshops.
Control parameters (limit values) : 200 ppm.
'.\
.,
Individual protection equipment: standard protective measures when working with aerosols. Respiratory protection: for work involvinq aerosols, wear breathing apparatus with a specific cartridge. Hand protection: gloves. Eye protection: safety goggles. * specific health and safety precautions: avoid eye and skin contact and inhalation of the vapors.
9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: clear fluid liquid. Smell: butyl acetate Boiling point: < 10°C Flash point: < 70°C Self-ignition temperature: > 405°C Explosivity characteristics: Limits in air < 1,8% v/v > 9,5% v/v Vapor pressure: (20°C) 2,5 bars Solubility: insoluble in water 10 - STABILITY AND REACTIVITY Stability: stable under normal conditions of use. The aerosol subject to temperatures show signs of distortion, explode and be projected over a considerable distance.
above 50°C can
Substances to avoid: strong oxidizing agents. thermal decomposition
gives off toxic fluorides.
11 - TOXICOLOGICAL
INFORMATION
* high toxicity: inhalation: in the presence of a high concentration of solvent vapors I mist: headache, drowsiness, nausea, depression of the central nervous system. ingestion: unlikely in the form of an aerosol, low toxicity. contact with the skin: can cause slight skin irritation, however frequent or lengthy exposure can provoke serious skin irritation and dermatitis due to the grease removing properties of the product. 12 - ECOLOGICAL
INFORMATION
Persistence/deqradability
: the active product is not easily biodegradable
13 - CONSIDERATIONS
CONCERNING
DISPOSAL
Disposal via incineration in accordance with the standard regulations. 14 -INFORMATION REGULATIONS ROUTES CLASS CHIFFRE IMDG ASSIMILATION
., LABEL
CONCERNING
TRANSPORT
OVERLAND ADR / RID 2 5°F Bottled inflammable gas under pressure with more than 45% by weight inflammable content
INTERNA TIONAL MARITIME IMDG 2
AIR OACI! lATA 2.1
NATIONAL
2102 Aerosol of capacity less than or equal to 1000 cm3
aerosols, nsa, (not exceeding one litter each)
Obligatory to mention aerosol
Flammable gas W 1950
RTMDR 2 5°F
.,;
Bottled inflammable gas under pressure with more than 45% by weight inflammable content
Inflammable W 3 flame mention aerosol 1950
N° 3 flame mention aerosol 1950
i
3/~
15 STATUTORY
INFORMATION
Community regulations Label. Symbol:
F+ extremely inflammable XI irritating
Phase R •
R 12 extremely inflammable R 36 irritating for eyes
Phase S • Phase (s) safety.
S S S S S
2 : Keep out of the reach of children. 9 : Store the container in a well ventilated area. 16 : Store in a fire free area - Do not smoke. 23 : Do not breathe in the vapors. 33 : Avoid the build-up of electrostatic energy.
Pressurized container. Protect from direct sunlight. Do not expose to temperatures above 50°C. Do not pierce or burn even when empty. Do not spray on flames or incandescent materials. Use and store away from flames, possible sources of ignition, electrical appliances in operation Do not smoke. Keep out of the reach of children. Press in short bursts and avoid prolonged vaporization. Ensure that premises are sufficiently ventilated after use of the product. 16 ADDITIONAL Recommended
INFORMATION usage: protection against soiling and UV light.
