Liquid Power Multi-Purpose Cleaner - Citrus Lemon Safety Data Sheet
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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1. Identification of the substance/ mixture and of the company/undertaking 1.1 Product: Liquid Power Multi- Purpose Cleaner - Citrus Lemon 1.2 Use of the preparation: A acidic general purpose hard surface cleaner 1.3 Company: Gompels HealthCare 1 Swift Way Bowerhill Ind Est Melksham SN12 6GX 0345 450 2420 1.4 Emergency Telephone: 0345 450 2420
2. Hazards Identification 2.1 Classification of the substance or mixture Classification Physical Hazards:- Not Classified Health Hazards:- Eye Irritant 2 – H319 Elicitation – EUH 208 Environmental Hazards- Not Classified 2.2 Label elements Pictogram
Signal word
WARNING
Hazard statements
H319 Causes serious eye irritation EUH208 Contains Methylchloroisothiazolinone/ Methylisothiazolinone. May produce an allergic reaction.
Precautionary statements
P102 Keep out of reach of children P264 Wash exposed skin thoroughly after handling P273 Avoid release to the environment. P332 + P313 If skin irritation occurs: Get medical advice/ attention P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention P501 Dispose of contents/container in accordance with local requirements for domestic waste disposal
Detergent labelling
< 5% Cationic surfactants, Non-ionic surfactants. Also contains: Perfume, Limonen, Disinfectant – Benzalkonium Chloride 0.5g per 100g, Methylchloroisothiazolinone, Methylisothiazolinone Supplementary precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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2.3 Other hazards This product does not contain any substances classified as PBT or vPvB
3. Composition/ Information on Ingredients 3.2 Mixtures Quaternary ammonium compounds, benzyl-C12-14 (even numbered)-alkyldimethyl, chlorides 0.5 - 3002000 Based on available data the classification criteria are not met Species Rat Raw material suppliers' information. Based on available data the classification criteria are not met. Disodium salt of ethylenediaminetetraacetic acid dehydrate Acute toxicity - oral Acute toxicity oral ( LD50 mg/kg) 2000 Species Rat ATE oral (mg/kg) 2000 Inhalation Ingestion Skin contact Eye contact
Harmful by inhalation. May cause discomfort if swallowed. Powder may irritate skin. Particles in the eyes may cause irritation and smarting.
(L) Lactic Acid Acute toxicity - oral Acute toxicity oral ( LD50 mg/kg) 3543 Based on available data the classification criteria are not met Species Rat
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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Acute toxicity - dermal Acute toxicity dermal (LD50 mg/kg) >2000 Based on available data the classification criteria are not met Species Rabbit Acute toxicity - inhalation Acute toxicity inhalation ( LC50 mg/l -4hrs) 7.94 Species Rat Skin Corrosion/Irritation Cause irritation on the skin Serious eye damage/ irritation Cause serious eye damage 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one Acute toxicity - oral Acute toxicity oral ( LD50 mg/kg) 4467 Based on available data the classification criteria are not met Species Rat Acute toxicity - dermal Acute toxicity dermal (LD50 mg/kg) >5000 Based on available data the classification criteria are not met Species Rat Skin Corrosion/Irritation Causes caustic effect on skin and mucous membrane Serious eye damage/ irritation Cause serious eye damage Skin Sensitisation Sensitization by skin contact
12. Ecological Information 12.1. Toxicity Large or frequent spills may have an adverse effect on the environment. Aquatic toxicity is unlikely to occur. However, large or frequent spills may have hazardous effects on the environment Ecological information on ingredients. Quaternary ammonium compounds, benzyl-C12-14 (even numbered)-alkyldimethyl, chlorides Fish CL50 0.515 mg/l Daphnia CE50 0.016mg/l Alga CI50 0.03 mg/l Alga NOEC 0.009mg/l LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1 M factor (Acute) 10 Chronic aquatic toxicity NOEC 0.001 < NOEC ≤ 0.01 M factor (Chronic) 1
Fish Daphnia Alga Alga
CL50 CE50 CI50 NOEC
Amines, C12-14 (even numbered)-alkyldimethyl, N-oxides 2.67 mg/l 3.1mg/l 0.143 mg/l 0.067mg/l
M factor (Acute) 1
Fish
LC50, 96hrs
Fish Daphina Alga
LC50, 96hrs EC 50, 48hrs IC 50, 72hrs
Alcohol ethoxylate with 6.5MEO 1 -10 mg/l Disodium salt of ethylenediaminetetraacetic acid dehydrate >100mg/l >100mg/l >100mg/l
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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Fish (Lepomis macrochirus -Bluegill) Daphina (Daphnia magna) Aquatic Plants
LC50, 96hrs EC 50, 48hrs EC 50, 72hrs
(L) Lactic Acid 130mg/l 130mg/l 2800mg/l
5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one Fish (rainbow trout) EC50, 96hrs 14.6mg/l Daphina EC 50, 48hrs 6.7mg/l Alga (Pseudokirchneriella subcapitata) EC 50, 72hrs 3.2mg/l
12.2. Persistence and degradability Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. Ecological information on ingredients. Quaternary ammonium compounds, benzyl-C12-14 (even numbered)-alkyldimethyl, chlorides Persistence and degradability The product is readily biodegradable. Alcohol ethoxylate with 6.5MEO Persistence and degradability This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents Disodium salt of ethylenediaminetetraacetic acid dehydrate Persistence and degradability The product is not readily biodegradable. 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one Persistence and degradability The product is not readily biodegradable. 12.3 Bioaccumulaive potential No data available on bioaccumulation. Partition coefficient Not available Ecological information on ingredients. Alcohol ethoxylate with 6.5MEO No bioaccumulation potential Disodium salt of ethylenediaminetetraacetic acid dehydrate No data bioaccumulation potential
Log Kow
5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one -0.71: +0.75 (n-Octanol/ water) BCF 3.6 (calculated)
12.4 Mobility in soil The product is soluble in water Ecological information on ingredients. Alcohol ethoxylate with 6.5MEO The product is mobile in water Disodium salt of ethylenediaminetetraacetic acid dehydrate The product is mobile in water
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one
No data available 12.5 Results of PBT and vPvB assessment This product does not contain any substances classified as PBT or vPvB 12.6 Other adverse effects None known
13. Disposal Considerations 13.1. Waste treatment methods Disposal methods : Dispose of contents/container in accordance with national regulations
14. Transport Information General
The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID).
14.1. UN number : Not applicable. 14.2. UN proper shipping name: Not applicable. 14.3. Transport hazard class(es): No transport warning sign required. 14.4. Packing group: Not applicable. 14.5. Environmental hazards: Environmentally hazardous substance/marine pollutant: No. 14.6. Special precautions for user: Not applicable. 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code : Not applicable.
15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations EH40/2005 Workplace exposure limits. The Chemical (Hazard Information and Packaging for Supply) Regulation 2009 (SI 2009 No. 716) EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No. 1907/2006 of the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) Regulation (EC) No. 648/2004 of the European Parliament and of the Council of 31st March 2004 on detergents. 15.2 Chemical safety assessment: No Chemical Safety Assessment has been carried out.
16. Other Information Revision Comments Format and content change to conform Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended) Revision Date 27.4.2015 Revision 04
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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Risk Phrases In Full R11 Highly Flammable R20 Harmful by inhalation R22 Harmful if swallowed R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R38 Irritating to skin R41 Risk of serious damage to eyes R43 May cause sensitisation by skin contact R50 Very toxic to aquatic organisms R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Hazard Statements In Full H225 Highly flammable liquid and vapour H301 Toxic if swallowed H302 Harmful if swallowed H311 Toxic in contact with skin H314 Causes severe burns and eye damage H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H331 Toxic if inhaled H332 Harmful if inhaled H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long-lasting effects Disclaimer The information contained in this data sheet is, to the best of our knowledge and belief, accurate and is based upon our technical knowledge of the product and the date of issue. No warranty or representation, express or implied, is made as to its accuracy, reliability or completeness. MPM Consumer Products Ltd will not be responsible for any damage or injury resulting from any inherent hazard of the material, the abnormal use of the material or from failure to adhere to recommendation
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
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1. Identification of the substance/ mixture and of the company/undertaking 1.1 Product: Liquid Power Multi- Purpose Cleaner - Citrus Lemon 1.2 Use of the preparation: A acidic general purpose hard surface cleaner 1.3 Company: Gompels HealthCare 1 Swift Way Bowerhill Ind Est Melksham SN12 6GX 0345 450 2420 1.4 Emergency Telephone: 0345 450 2420
2. Hazards Identification 2.1 Classification of the substance or mixture Classification Physical Hazards:- Not Classified Health Hazards:- Eye Irritant 2 – H319 Elicitation – EUH 208 Environmental Hazards- Not Classified 2.2 Label elements Pictogram
Signal word
WARNING
Hazard statements
H319 Causes serious eye irritation EUH208 Contains Methylchloroisothiazolinone/ Methylisothiazolinone. May produce an allergic reaction.
Precautionary statements
P102 Keep out of reach of children P264 Wash exposed skin thoroughly after handling P273 Avoid release to the environment. P332 + P313 If skin irritation occurs: Get medical advice/ attention P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention P501 Dispose of contents/container in accordance with local requirements for domestic waste disposal
Detergent labelling
< 5% Cationic surfactants, Non-ionic surfactants. Also contains: Perfume, Limonen, Disinfectant – Benzalkonium Chloride 0.5g per 100g, Methylchloroisothiazolinone, Methylisothiazolinone Supplementary precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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2.3 Other hazards This product does not contain any substances classified as PBT or vPvB
3. Composition/ Information on Ingredients 3.2 Mixtures Quaternary ammonium compounds, benzyl-C12-14 (even numbered)-alkyldimethyl, chlorides 0.5 - 3002000 Based on available data the classification criteria are not met Species Rat Raw material suppliers' information. Based on available data the classification criteria are not met. Disodium salt of ethylenediaminetetraacetic acid dehydrate Acute toxicity - oral Acute toxicity oral ( LD50 mg/kg) 2000 Species Rat ATE oral (mg/kg) 2000 Inhalation Ingestion Skin contact Eye contact
Harmful by inhalation. May cause discomfort if swallowed. Powder may irritate skin. Particles in the eyes may cause irritation and smarting.
(L) Lactic Acid Acute toxicity - oral Acute toxicity oral ( LD50 mg/kg) 3543 Based on available data the classification criteria are not met Species Rat
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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Acute toxicity - dermal Acute toxicity dermal (LD50 mg/kg) >2000 Based on available data the classification criteria are not met Species Rabbit Acute toxicity - inhalation Acute toxicity inhalation ( LC50 mg/l -4hrs) 7.94 Species Rat Skin Corrosion/Irritation Cause irritation on the skin Serious eye damage/ irritation Cause serious eye damage 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one Acute toxicity - oral Acute toxicity oral ( LD50 mg/kg) 4467 Based on available data the classification criteria are not met Species Rat Acute toxicity - dermal Acute toxicity dermal (LD50 mg/kg) >5000 Based on available data the classification criteria are not met Species Rat Skin Corrosion/Irritation Causes caustic effect on skin and mucous membrane Serious eye damage/ irritation Cause serious eye damage Skin Sensitisation Sensitization by skin contact
12. Ecological Information 12.1. Toxicity Large or frequent spills may have an adverse effect on the environment. Aquatic toxicity is unlikely to occur. However, large or frequent spills may have hazardous effects on the environment Ecological information on ingredients. Quaternary ammonium compounds, benzyl-C12-14 (even numbered)-alkyldimethyl, chlorides Fish CL50 0.515 mg/l Daphnia CE50 0.016mg/l Alga CI50 0.03 mg/l Alga NOEC 0.009mg/l LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1 M factor (Acute) 10 Chronic aquatic toxicity NOEC 0.001 < NOEC ≤ 0.01 M factor (Chronic) 1
Fish Daphnia Alga Alga
CL50 CE50 CI50 NOEC
Amines, C12-14 (even numbered)-alkyldimethyl, N-oxides 2.67 mg/l 3.1mg/l 0.143 mg/l 0.067mg/l
M factor (Acute) 1
Fish
LC50, 96hrs
Fish Daphina Alga
LC50, 96hrs EC 50, 48hrs IC 50, 72hrs
Alcohol ethoxylate with 6.5MEO 1 -10 mg/l Disodium salt of ethylenediaminetetraacetic acid dehydrate >100mg/l >100mg/l >100mg/l
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
-
Fish (Lepomis macrochirus -Bluegill) Daphina (Daphnia magna) Aquatic Plants
LC50, 96hrs EC 50, 48hrs EC 50, 72hrs
(L) Lactic Acid 130mg/l 130mg/l 2800mg/l
5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one Fish (rainbow trout) EC50, 96hrs 14.6mg/l Daphina EC 50, 48hrs 6.7mg/l Alga (Pseudokirchneriella subcapitata) EC 50, 72hrs 3.2mg/l
12.2. Persistence and degradability Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. Ecological information on ingredients. Quaternary ammonium compounds, benzyl-C12-14 (even numbered)-alkyldimethyl, chlorides Persistence and degradability The product is readily biodegradable. Alcohol ethoxylate with 6.5MEO Persistence and degradability This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents Disodium salt of ethylenediaminetetraacetic acid dehydrate Persistence and degradability The product is not readily biodegradable. 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one Persistence and degradability The product is not readily biodegradable. 12.3 Bioaccumulaive potential No data available on bioaccumulation. Partition coefficient Not available Ecological information on ingredients. Alcohol ethoxylate with 6.5MEO No bioaccumulation potential Disodium salt of ethylenediaminetetraacetic acid dehydrate No data bioaccumulation potential
Log Kow
5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one -0.71: +0.75 (n-Octanol/ water) BCF 3.6 (calculated)
12.4 Mobility in soil The product is soluble in water Ecological information on ingredients. Alcohol ethoxylate with 6.5MEO The product is mobile in water Disodium salt of ethylenediaminetetraacetic acid dehydrate The product is mobile in water
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
-
5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one
No data available 12.5 Results of PBT and vPvB assessment This product does not contain any substances classified as PBT or vPvB 12.6 Other adverse effects None known
13. Disposal Considerations 13.1. Waste treatment methods Disposal methods : Dispose of contents/container in accordance with national regulations
14. Transport Information General
The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID).
14.1. UN number : Not applicable. 14.2. UN proper shipping name: Not applicable. 14.3. Transport hazard class(es): No transport warning sign required. 14.4. Packing group: Not applicable. 14.5. Environmental hazards: Environmentally hazardous substance/marine pollutant: No. 14.6. Special precautions for user: Not applicable. 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code : Not applicable.
15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations EH40/2005 Workplace exposure limits. The Chemical (Hazard Information and Packaging for Supply) Regulation 2009 (SI 2009 No. 716) EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No. 1907/2006 of the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) Regulation (EC) No. 648/2004 of the European Parliament and of the Council of 31st March 2004 on detergents. 15.2 Chemical safety assessment: No Chemical Safety Assessment has been carried out.
16. Other Information Revision Comments Format and content change to conform Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended) Revision Date 27.4.2015 Revision 04
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
Liquid Power Multi-Purpose Cleaner Citrus Lemon Safety Data Sheet
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Risk Phrases In Full R11 Highly Flammable R20 Harmful by inhalation R22 Harmful if swallowed R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R38 Irritating to skin R41 Risk of serious damage to eyes R43 May cause sensitisation by skin contact R50 Very toxic to aquatic organisms R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Hazard Statements In Full H225 Highly flammable liquid and vapour H301 Toxic if swallowed H302 Harmful if swallowed H311 Toxic in contact with skin H314 Causes severe burns and eye damage H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H331 Toxic if inhaled H332 Harmful if inhaled H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long-lasting effects Disclaimer The information contained in this data sheet is, to the best of our knowledge and belief, accurate and is based upon our technical knowledge of the product and the date of issue. No warranty or representation, express or implied, is made as to its accuracy, reliability or completeness. MPM Consumer Products Ltd will not be responsible for any damage or injury resulting from any inherent hazard of the material, the abnormal use of the material or from failure to adhere to recommendation
Date of issue 27/4/2015
Revision Date: 27/4/2015
Issue 4
