Process Flow Diagrams
RC-100
Non-Hazardous Waste
TK-100
101
15319
0.4
28
11513
105
188
52
30
102
SS
25
104 28
165
C-101
60
14
21
108
1
45
80 80
To Stage 2
Catalyst Regeneration Exhaust to E-105
CWS
160
1
S-101
CWR
E-106
CWS
S-100
E-100
P-100
SS 165
3858
16512
30
106
11430 E-100
TK-101
88
73
109
C-100
4977
111
P-104
14 160
CR
P-41 106a
E-101
35
103
88
124
88
E-103
R-100
T-100
1
106b P-42
CR
CWR
To Atmosphere E-101
E-105
15
P-103
R-101 107b
104b
4925
45
34 205
P-102
1
0.4
60
60 107a
104a
150 E-104
3806 E-102
35
34
107
110
4998
205
NG BUT
1119
104
E-102
E-103
248
1 106c P-40
P-101
R-102
1
107c
34
104c
205
STREAM IDENTIFICATION NO.
NOTES:
101
102
103
104
105
106
107
108
wt%
wt%
wt%
wt%
wt%
wt%
wt%
wt%
20.0
0.4
79.2
81.5
0.0
0.0
20.1
80.0
99.6
20.8
16.1
0.0
4.5
0.0
0.0
0.0
0.0
100.0
0.0
0.0
0.0
2.4
0.0
109
110
111
wt%
wt%
wt%
0.0
20.2
89.4
0.1
25.3
15.8
25.3
0.0
32.6
95.3
0.4
83.6
0.0
0.0
0.0
0.2
54.3
0.6
54.5
10.6
67.3
STREAM DESCRIPTION
FORMULA
COMPONENTS Levulinic Acid
CH3C(O)CH2CH2CO2H
Water
H2O
Hydrogen Gamma-valerolactone
H2 C5H8O2
SS – Steam supply CWS – Cooling water supply CR – Condensate return CWR – Cooling water return BUT – Butene NG – Natural Gas REVISIONS
LEGEND REV
Temperature (°C) Absolute Pressure (bar) Mass Flow (lb/hr)
DATE
DESCRIPTION
1
2-24-13
Initial Design
2
2-25-13
Updated MB
3
3-12-13
Utility Requirements
4 5
4-1-13 4-4-13
Process Improvements Finalized
Stream Number
University of Michigan TOTAL MASS FLOW RATE (LB/HR) TOTAL MOL FLOW RATE (LB-MOL/HR) MAX PRESSURE (BAR) MAX TEMPERATURE (C)
15318.6
11512.9
3805.7
4924.4
52.4
73.5
4998.9
21.1
4976.8
1118.7
3858.1
706.5
636.6
69.9
79.7
25.93
34.84
114.5
8.9
105.6
9.8
95.8
1
0.4
1
35
34
25
34
34
34
1
2
88
88
88
124
25
35
205
25
25
248
104
DEPARTMENT OF CHEMICAL ENGINEERING
COURSE NO. DRAWN BY
ChE 487 GROUP NO.
Team 10
DATE
4-4-2013
PROCESS FLOW DIAGRAM (PFD)
DRAWING TITLE
Stage 1: Hydrogenation of Levulinic Acid
REV.
5
Waste To E-105 From Stage 2
34
206 2244 50 2244
35
CWS
R-300
97 CWS
30 306
302
6424
60 SS
34
418
12
50
160
S-300
T-300
304
P-301
50
E-300 153
625
7
170 E-102
43
431
30 180
C-300
Waste
50
301
2
7
40
CWR
To Atmosphere
98
C-301 45
E-102
303 60
1813 CWR
E-103
307
P-300
E-301
50 34
E-105
S-301
1298 25
BUT
305 234
7 CR
1395
60
7
7
TK-300
STREAM IDENTIFICATION NO.
NOTES:
206
301
302
303
304
305
306
wt%
wt%
wt%
wt %
wt%
wt%
wt %
wt%
64.2
6.4
4.3
6.9
14.8
4.5
58.7
0.5
0.6
0.6
0.3
0.7
1.2
0.6
2.6
0.4
307
STREAM DESCRIPTION
COMPONENTS Butene
FORMULA C4H8
Water
H2O
Carbon Dioxide
CO2
35.2
35.2
94.9
20.9
82.0
2.7
38.5
0.0
Octene
C8H16
0.0
17.3
0.4
21.4
1.9
27.2
0.1
29.2
Dodecene
C12H24
0.0
15.0
0.0
18.6
0.0
24.1
0.0
25.9
Hexadecene
C16H32
0.0
14.4
0.0
17.9
0.0
23.2
0.0
25.0
C20+
0.0
11.0
0.0
13.6
0.0
17.7
0.0
19.0
Eicosene
SS – Steam supply CWS – Cooling water supply CR – Condensate return CWR – Cooling water return BUT – Butene REVISIONS
LEGEND REV
Temperature (° C)
1
DATE
DESCRIPTION
2-24-13
Initial Design
Absolute Pressure (bar)
2
3-12-13
Utility Requirements
3 4
4-1-13
Process Improvements
Mass Flow (lb/hr)
4-4-13
Finalized Design
Stream Number
University of Michigan TOTAL MASS FLOW RATE (LB/HR) TOTAL MOL FLOW RATE (LB-MOL/HR) MAX PRESSURE (BAR) MAX TEMPERATURE (C)
2243.7
2243.6
430.9
1812.7
417.7
1395.0
96.7
1298.3
44.4
29.1
9.7
19.4
9.2
10.1
2.0
8.1
2
34
34
34
7
7
7
7
170
180
50
50
60
60
43
234
DEPARTMENT OF CHEMICAL ENGINEERING
COURSE NO. DRAWN BY
ChE 487 GROUP NO.
Team 10
DATE
4-4-13
PROCESS FLOW DIAGRAM (PFD)
DRAWING TITLE
Stage 3: Oligomerization of Butene
REV.
4
From Stage 1 111
3858 104
To Atmosphere
1
E-100
R-200 P-200
206
2 2
202
2244
50
S-201
4182 E-105
375
204
201
S-200
375
4182
NG
2568
E-200
101
207
2
50
203
339
324
35
50
E-105
BUT
2
205
E-100
50 1614
S-202
36 35
E-200
To Atmosphere
1
44
35
To Stage 3
2
50
3
P-201 208
STREAM IDENTIFICATION NO.
FORMULA
Levulinic Acid
201
202
203
204
wt %
wt %
wt %
wt %
wt %
205
206
207
wt %
wt %
wt%
208
Water
0.1
0.6
0.6
0.2
0.9
7.1
0.0
trace
0.3
31.5
31.5
77.1
2.8
17.6
0.6
4.0
96.5
H2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
C5H8O2
67.3
65.8
4.0
0.4
6.2
48.6
0.1
0.0
0.5
0.0
1.7
28.9
21.7
33.4
21.6
35.1
95.0
2.2
0.0
0.4
35.1
0.6
56.7
5.2
64.2
1.0
0.5
H2O
Hydrogen Gamma-valerolactone Carbon Dioxide Butene
CO2 C4H8
Non-Hazardous Waste
1275
SS – Steam supply CWS – Cooling water supply CR – Condensate return CWR – Cooling water return BUT – Butene NG – Natural Gas
wt %
32.6
CH3C(O)CH2CH2CO2H
1
NOTES:
111
STREAM DESCRIPTION
COMPONENTS
44
REVISIONS
LEGEND REV
Temperature (° C) Absolute Pressure (bar) Mass Flow (lb/hr)
1
DATE
DESCRIPTION
2-26-13
Initial Design
2
3-12-13
3
3-13-13
4 5
4-1-13
Process Improvements
4-4-13
Finalized Design
Utility Requirements Updated MB
Stream Number
University of Michigan TOTAL MASS FLOW RATE (LB/HR) TOTAL MOL FLOW RATE (LB-MOL/HR) MAX PRESSURE (BAR) MAX TEMPERATURE (C)
3858.1
4182.1
4182.1
1614.4
2567.7
324.0
2243.7
338.6
1275.4
95.8
102.6
128.5
77.3
51.2
6.8
44.4
8.1
69.2
2
36
35
35
35
2
2
1.0
1.0
104
375
331
50
50
50
50
44.0
44.0
DEPARTMENT OF CHEMICAL ENGINEERING
COURSE NO. DRAWN BY
ChE 487 GROUP NO.
Team 10
DATE
4-4-13
PROCESS FLOW DIAGRAM (PFD)
DRAWING TITLE
Stage 2: Conversion of gamma-Valerolactone to Butene
5
REV.
Non-Hazardous Waste
TK-100
101
15319
0.4
28
11513
105
188
52
30
102
SS
25
104 28
165
C-101
60
14
21
108
1
45
80 80
To Stage 2
Catalyst Regeneration Exhaust to E-105
CWS
160
1
S-101
CWR
E-106
CWS
S-100
E-100
P-100
SS 165
3858
16512
30
106
11430 E-100
TK-101
88
73
109
C-100
4977
111
P-104
14 160
CR
P-41 106a
E-101
35
103
88
124
88
E-103
R-100
T-100
1
106b P-42
CR
CWR
To Atmosphere E-101
E-105
15
P-103
R-101 107b
104b
4925
45
34 205
P-102
1
0.4
60
60 107a
104a
150 E-104
3806 E-102
35
34
107
110
4998
205
NG BUT
1119
104
E-102
E-103
248
1 106c P-40
P-101
R-102
1
107c
34
104c
205
STREAM IDENTIFICATION NO.
NOTES:
101
102
103
104
105
106
107
108
wt%
wt%
wt%
wt%
wt%
wt%
wt%
wt%
20.0
0.4
79.2
81.5
0.0
0.0
20.1
80.0
99.6
20.8
16.1
0.0
4.5
0.0
0.0
0.0
0.0
100.0
0.0
0.0
0.0
2.4
0.0
109
110
111
wt%
wt%
wt%
0.0
20.2
89.4
0.1
25.3
15.8
25.3
0.0
32.6
95.3
0.4
83.6
0.0
0.0
0.0
0.2
54.3
0.6
54.5
10.6
67.3
STREAM DESCRIPTION
FORMULA
COMPONENTS Levulinic Acid
CH3C(O)CH2CH2CO2H
Water
H2O
Hydrogen Gamma-valerolactone
H2 C5H8O2
SS – Steam supply CWS – Cooling water supply CR – Condensate return CWR – Cooling water return BUT – Butene NG – Natural Gas REVISIONS
LEGEND REV
Temperature (°C) Absolute Pressure (bar) Mass Flow (lb/hr)
DATE
DESCRIPTION
1
2-24-13
Initial Design
2
2-25-13
Updated MB
3
3-12-13
Utility Requirements
4 5
4-1-13 4-4-13
Process Improvements Finalized
Stream Number
University of Michigan TOTAL MASS FLOW RATE (LB/HR) TOTAL MOL FLOW RATE (LB-MOL/HR) MAX PRESSURE (BAR) MAX TEMPERATURE (C)
15318.6
11512.9
3805.7
4924.4
52.4
73.5
4998.9
21.1
4976.8
1118.7
3858.1
706.5
636.6
69.9
79.7
25.93
34.84
114.5
8.9
105.6
9.8
95.8
1
0.4
1
35
34
25
34
34
34
1
2
88
88
88
124
25
35
205
25
25
248
104
DEPARTMENT OF CHEMICAL ENGINEERING
COURSE NO. DRAWN BY
ChE 487 GROUP NO.
Team 10
DATE
4-4-2013
PROCESS FLOW DIAGRAM (PFD)
DRAWING TITLE
Stage 1: Hydrogenation of Levulinic Acid
REV.
5
Waste To E-105 From Stage 2
34
206 2244 50 2244
35
CWS
R-300
97 CWS
30 306
302
6424
60 SS
34
418
12
50
160
S-300
T-300
304
P-301
50
E-300 153
625
7
170 E-102
43
431
30 180
C-300
Waste
50
301
2
7
40
CWR
To Atmosphere
98
C-301 45
E-102
303 60
1813 CWR
E-103
307
P-300
E-301
50 34
E-105
S-301
1298 25
BUT
305 234
7 CR
1395
60
7
7
TK-300
STREAM IDENTIFICATION NO.
NOTES:
206
301
302
303
304
305
306
wt%
wt%
wt%
wt %
wt%
wt%
wt %
wt%
64.2
6.4
4.3
6.9
14.8
4.5
58.7
0.5
0.6
0.6
0.3
0.7
1.2
0.6
2.6
0.4
307
STREAM DESCRIPTION
COMPONENTS Butene
FORMULA C4H8
Water
H2O
Carbon Dioxide
CO2
35.2
35.2
94.9
20.9
82.0
2.7
38.5
0.0
Octene
C8H16
0.0
17.3
0.4
21.4
1.9
27.2
0.1
29.2
Dodecene
C12H24
0.0
15.0
0.0
18.6
0.0
24.1
0.0
25.9
Hexadecene
C16H32
0.0
14.4
0.0
17.9
0.0
23.2
0.0
25.0
C20+
0.0
11.0
0.0
13.6
0.0
17.7
0.0
19.0
Eicosene
SS – Steam supply CWS – Cooling water supply CR – Condensate return CWR – Cooling water return BUT – Butene REVISIONS
LEGEND REV
Temperature (° C)
1
DATE
DESCRIPTION
2-24-13
Initial Design
Absolute Pressure (bar)
2
3-12-13
Utility Requirements
3 4
4-1-13
Process Improvements
Mass Flow (lb/hr)
4-4-13
Finalized Design
Stream Number
University of Michigan TOTAL MASS FLOW RATE (LB/HR) TOTAL MOL FLOW RATE (LB-MOL/HR) MAX PRESSURE (BAR) MAX TEMPERATURE (C)
2243.7
2243.6
430.9
1812.7
417.7
1395.0
96.7
1298.3
44.4
29.1
9.7
19.4
9.2
10.1
2.0
8.1
2
34
34
34
7
7
7
7
170
180
50
50
60
60
43
234
DEPARTMENT OF CHEMICAL ENGINEERING
COURSE NO. DRAWN BY
ChE 487 GROUP NO.
Team 10
DATE
4-4-13
PROCESS FLOW DIAGRAM (PFD)
DRAWING TITLE
Stage 3: Oligomerization of Butene
REV.
4
From Stage 1 111
3858 104
To Atmosphere
1
E-100
R-200 P-200
206
2 2
202
2244
50
S-201
4182 E-105
375
204
201
S-200
375
4182
NG
2568
E-200
101
207
2
50
203
339
324
35
50
E-105
BUT
2
205
E-100
50 1614
S-202
36 35
E-200
To Atmosphere
1
44
35
To Stage 3
2
50
3
P-201 208
STREAM IDENTIFICATION NO.
FORMULA
Levulinic Acid
201
202
203
204
wt %
wt %
wt %
wt %
wt %
205
206
207
wt %
wt %
wt%
208
Water
0.1
0.6
0.6
0.2
0.9
7.1
0.0
trace
0.3
31.5
31.5
77.1
2.8
17.6
0.6
4.0
96.5
H2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
C5H8O2
67.3
65.8
4.0
0.4
6.2
48.6
0.1
0.0
0.5
0.0
1.7
28.9
21.7
33.4
21.6
35.1
95.0
2.2
0.0
0.4
35.1
0.6
56.7
5.2
64.2
1.0
0.5
H2O
Hydrogen Gamma-valerolactone Carbon Dioxide Butene
CO2 C4H8
Non-Hazardous Waste
1275
SS – Steam supply CWS – Cooling water supply CR – Condensate return CWR – Cooling water return BUT – Butene NG – Natural Gas
wt %
32.6
CH3C(O)CH2CH2CO2H
1
NOTES:
111
STREAM DESCRIPTION
COMPONENTS
44
REVISIONS
LEGEND REV
Temperature (° C) Absolute Pressure (bar) Mass Flow (lb/hr)
1
DATE
DESCRIPTION
2-26-13
Initial Design
2
3-12-13
3
3-13-13
4 5
4-1-13
Process Improvements
4-4-13
Finalized Design
Utility Requirements Updated MB
Stream Number
University of Michigan TOTAL MASS FLOW RATE (LB/HR) TOTAL MOL FLOW RATE (LB-MOL/HR) MAX PRESSURE (BAR) MAX TEMPERATURE (C)
3858.1
4182.1
4182.1
1614.4
2567.7
324.0
2243.7
338.6
1275.4
95.8
102.6
128.5
77.3
51.2
6.8
44.4
8.1
69.2
2
36
35
35
35
2
2
1.0
1.0
104
375
331
50
50
50
50
44.0
44.0
DEPARTMENT OF CHEMICAL ENGINEERING
COURSE NO. DRAWN BY
ChE 487 GROUP NO.
Team 10
DATE
4-4-13
PROCESS FLOW DIAGRAM (PFD)
DRAWING TITLE
Stage 2: Conversion of gamma-Valerolactone to Butene
5
REV.
