SKC Environmental Sampling Guide for Active and Passive Methods

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Environmental Sampling Guide www.skcinc.com for updates

SKC Environmental Sampling Guide for Active and Passive Methods The easy-to-use SKC Environmental Sampling Guide provides a quick reference for the user to determine method parameters and active and passive collection media that meet the specifications for each method. SKC Method Updates SKC has published updates to the following methods: • EPA Method IP-6 (Formaldehyde and Other Aldehydes), an active method to which SKC added the UMEx 100 as a passive alternative (www.skcinc.com/instructions/IP6A.pdf ) • EPA Method IP-10A (Particulate Matter, Indoor Air), a method specifying a single-stage impactor to which SKC added the four-stage Sioutas Impactor for coarse, fine, and ultrafine particles (www.skcinc.com/instructions/IP10A.pdf ) • EPA Method TO-17 (VOCs in Ambient or Indoor Air), an active method to which SKC added the ULTRA samplers as a passive alternative (www.skcinc.com/instructions/1667.pdf ) Chemical Fact Files The Chem F File column contains numbers that correspond to specific Chemical Fact Files for Environmental Sampling. These single-page publications are simple abstracts of EPA air sampling methods that expand upon the information that appears in this Guide (see page 197 for more information on Chemical Fact Files). The SKC Environmental Sampling Guide is a reference only to assist users in finding the method, sampling equipment, and sampling media for a specific compound. The information in the Sampling Guide is not to be construed as a substitute for any sampling method. Users must consult the appropriate sampling method for the compound of interest before sampling.

Chemical Hazard Acetic acid

Sampling Environment

Agency Method

Ambient

EPA TO-17

Chem F File

Flow/Sampling Rate †

Sample Time or Air Analysis Volume

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L 15.2 ml/min

226-300 Series 41

SE, GC

690-105

Ambient

Internal EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Acrylonitrile

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Acrylonitrile

Ambient

Internal

20.4 ml/min

1-12 hrs

SE, GC

PS

575-001

Acrylonitrile

Ambient

Internal

20.4 ml/min

8-24 hrs

TD, GC £ PS

690-102

71

Aldehydes

Ambient

EPA TO-5

1671 100-1000 ml/min

< 80 L

HPLC-UV IMP 225-36-1

59

Benzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Benzene

Ambient

EPA TO-17

1689 16.0 ml/min

8-24 hrs

TD, GC £ PS

690-101

Benzene

Ambient

EPA TO-17

1689 0.83 ml/min

1-7 days

TD, GC £ PS

690-102

Benzene

Ambient

EPA TO-17

1689 16.0 ml/min

8 hrs-7 days TD, GC £ PS

690-102

Benzene

Ambient

Internal

7-30 days

575-001

2-Butanone

Ambient

EPA TO-17

2-Butanone

Ambient

Internal

2-Butoxyethanol acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

n-Butyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

n-Butyl acetate

Ambient

EPA TO-17

1689 12.6 ml/min

8-24 hrs

TD, GC £ PS

690-102

n-Butyl acetate

Ambient

Internal

12.6 ml/min

1-12 hrs

SE, GC

690-105

t-Butyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L 16.88 ml/min

1-12 hrs

or PS

690-105

71

IT

225-22

59

TH

224-26-02 47

CPC 224-26CPC-10 47

withPS

690-300

71

or PS

690-105

71

71

226-300 Series 41

SE, GC

690-105

PS

65

71

TD, GC £ ST PS

575-001

CPC 224-26CPC-10 47

Ambient

PS

or PS

224-26-02 47

Acetonitrile

SE, GC

PS

TH

Acetone

16.0 ml/min

1-12 hrs

SKC Collection Media and Page No.

TD, GC £ ST

TH or PS

224-26-02 47 575-001

CPC 224-26CPC-10 47

65

71 or PS

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

575-001

65

TH

224-26-02 47

CPC 224-26CPC-10 47

t-Butyl acetate

Ambient

EPA TO-17

1689 12.9 ml/min

8-24 hrs

TD, GC £ PS

690-102

n-Butyl alcohol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

t-Butyl methyl ether (MTBE)

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

t-Butyl methyl ether (MTBE)

Ambient

Internal

SE, GC

690-105

or PS

SKC Ltd.

Phone: +44 (0)1258 480188

13.6 ml/min

1-30 days

PS

71

575-001

65

See page 196 for abbreviations.

190

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Environmental Sampling Guide www.skcinc.com for updates

Agency Method

Carbon tetrachloride

Ambient

EPA TO-17

Carbon tetrachloride

Ambient

Internal

Chlorobenzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Chlorobenzene

Ambient

EPA TO-17

1689 18.7 ml/min

Chlorobenzene

Ambient

Internal

Cresols

Ambient

EPA TO-8

1668 100-1000 ml/min

Cumene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Cumene

Ambient

EPA TO-17

1689 12.8 ml/min

8-24 hrs

TD, GC £ PS

690-104

Cumene

Ambient

Internal

1-8 hrs

SE, GC

690-105

Cyclohexanone

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Cyclohexanone

Ambient

EPA TO-17

1689 15.6 ml/min

8-24 hrs

TD, GC £ PS

690-102

Cyclohexanone

Ambient

Internal

1-8 hrs

SE, GC

690-105

n-Decane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

n-Decane

Ambient

EPA TO-17

1689 10.2 ml/min

8-24 hrs

TD, GC £ PS

690-104

1-8 hrs

SE, GC

690-105

Chemical Hazard

Chem F File

Sample Time or Air Analysis Volume

Sampling Environment

Flow/Sampling Rate †

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L 14.1 ml/min

18.7 ml/min

12.8 ml/min

15.6 ml/min

10.2 ml/min

1-8 hrs

SKC Collection Media and Page No.

TD, GC £ ST

226-300 Series 41

SE, GC

690-105

PS

8-24 hrs

TD, GC £ PS

690-102

1-8 hrs

SE, GC

690-105

< 80 L

HPLC-UV IMP 225-36-1‡

PS

PS

PS

or PS TH

224-26-02 47 575-001

CPC 224-26CPC-10 47

65

224-26-02 47

CPC 224-26CPC-10 47

71 or PS 59

575-001

65

IT

225-22

59

TH

224-26-02 47

CPC 224-26CPC-10 47

71 or PS TH

575-001

65

224-26-02 47

CPC 224-26CPC-10 47

71 or PS TH

575-001

65

224-26-02 47

CPC 224-26CPC-10 47

71

n-Decane

Ambient

Internal

1,2-Dichloroethane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

1,2-Dichloroethane

Ambient

EPA TO-17

1689 10.3 ml/min

8-24 hrs

TD, GC £ PS

690-102

1,2-Dichloroethane

Ambient

Internal

14.2 ml/min

1-12 hrs

SE, GC

690-105

Dichloromethane (methylene chloride)

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Dichloromethane (methylene chloride)

Ambient

EPA TO-17

1689 14.7 ml/min

TD, GC £ PS

690-102

Dichloromethane (methylene chloride)

Ambient

Internal

14.7 ml/min

1 hr-3 days SE, GC

PS

690-105

or PS

575-001

65

Dichloromethane (methylene chloride)

Ambient

Internal

0.99 ml/min

7 days

SE, GC

PS

690-105

withPS

690-300

71

Dioxin (including, PHDDs, PCDDs, PBDDs)

Ambient

EPA TO-9A

1673 200-280 L/min

24 hrs

HRGCHRMS

PUF 226-131

n-Dodecane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Ethanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Ethanol

Ambient

Internal

SE, GC

690-105

2-Ethoxyethanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

2-Ethoxyethyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Ethyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Ethyl acetate

Ambient

EPA TO-17

1689 13.1 ml/min

8-24 hrs

TD, GC £ PS

690-102

1-8 hrs

SE, GC

690-105

20.0 ml/min

13.1 ml/min

4-8 hrs

1-8 hrs

PS

TH

PS

PS

or PS

43

Internal EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Ethyl acrylate

Ambient

EPA TO-17

1689 13.7 ml/min

8-24 hrs

TD, GC £ PS

690-102

Ethyl acrylate

Ambient

Internal

13.7 ml/min

1-12 hrs

SE, GC

690-105

Ethyl alcohol

Ambient

EPA TO-17

Ethyl alcohol

Ambient

Internal

Ethyl benzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Ethyl benzene

Ambient

EPA TO-17

1689 12.9 ml/min

8-24 hrs

TD, GC £ PS

690-101

71

Ethyl benzene

Ambient

EPA TO-17

1689 12.9 ml/min

8 hrs-7 days TD, GC £ PS

690-102

71

Ethyl benzene

Ambient

Internal

7-30 days

690-105

12.9 ml/min

65

224-26-02 47

CPC 224-26CPC-10 47

TH

224-26-02 47

CPC 224-26CPC-10 47

TH

224-26-02 47

CPC 224-26CPC-10 47

TH

or PS

SE, GC

690-105

PS

575-001

575-002

65

575-001

65

224-26-02 47

CPC 224-26CPC-10 47

71

226-300 Series 41

SE, GC

CPC 224-26CPC-10 47

FLT 225-1821 43

or PS

TD, GC £ ST PS

65

71

Ambient

1-8 hrs

TH

or PS

Ambient

20.0 ml/min

575-001

224-26-02 47

81

Ethyl acrylate

PS

TH

71

Ethyl acetate

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

PS

or PS

TH or PS TH

PS

575-002

65

224-26-02 47 575-002

CPC 224-26CPC-10 47

65

224-26-02 47

CPC 224-26CPC-10 47

575-001 See page 196 for abbreviations.

SKC Inc.

Phone: +1-724-941-9701

www.skcinc.com

191

Environmental Sampling Guide www.skcinc.com for updates

Agency Method

2-Ethyl toluene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

3-Ethyl toluene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

4-Ethyl toluene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Ethylene dichloride

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Ethylene dichloride

Ambient

EPA TO-17

1689 14.2 ml/min

Formaldehyde

Ambient

EPA TO-11A 1082 100-2000 ml/min

Chemical Hazard

Chem F File

Sample Time or Air Analysis Volume

Sampling Environment

Flow/Sampling Rate †

SKC Collection Media and Page No.

8 hrs-24 hrs TD, GC £ PS

690-102

varies

HPLC-UV ST

226-119

71

Formaldehyde

Ambient (outdoor) EPA TO-11A 1082 28.6 ml/min

15 min-24 hrs HPLC-UV PS

500-100

67

Formaldehyde

Ambient (outdoor) EPA TO-11A 1082 28.6 ml/min

15 min-8 hrs HPLC-UV PS

500-100

67

Formaldehyde

Ambient (outdoor) EPA TO-11A 1082 28.6 ml/min

7 days

HPLC-UV PS

500-100

67

or ST

226-120

37

or ST

226-120

37

Formaldehyde

Indoor

EPA IP-6A

1664 100-1000 ml/min

5 min-24 hrs HPLC-UV ST

226-119

Formaldehyde

Indoor

EPA IP-6C

1664 20.4 ml/min

1-7 days

HPLC-UV PS

500-100

67

Formaldehyde

Indoor

EPA IP-6C

1664 20.4 ml/min

15 min-8 hrs HPLC-UV PS

500-100

67

Formaldehyde

Indoor

EPA IP-6C

1664 20.4 ml/min

7 days

HPLC-UV PS

500-100

86

Furans (including PHDFs, PCDFs, PBDFs)

Ambient

EPA TO-9A

1673 200-280 L/min

24 hrs

HRGCHRMS

PUF 226-131

43

Furfural

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

n-Heptane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

n-Heptane

Ambient

EPA TO-17

1689 13.9 ml/min

8-24 hrs

TD, GC £ PS

690-102

n-Heptane

Ambient

Internal

13.9 ml/min

1-12 hrs

SE, GC

690-105

n-Hexane

Ambient

EPA TO-17

n-Hexane

Ambient

Internal

Hexone

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Isobutanol (isobutyl alcohol)

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L 14.3 ml/min

1-12 hrs

PS

71 or PS

TD, GC £ ST

226-300 Series 41

SE, GC

690-105

PS

FLT 225-1821 43

TH or PS

575-001

65

224-26-02 47 575-001

CPC 224-26CPC-10 47

65

Isobutyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Isobutyl alcohol (isobutanol)

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Isophorone

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Isopropanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Isopropanol

Ambient

EPA TO-17

1689 20.0 ml/min

8-24 hrs

TD, GC £ PS

690-102

1-8 hrs

SE, GC

690-105

20.0 ml/min

Isopropanol

Ambient

Internal

Isopropyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Isopropyl alcohol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Isopropyl alcohol

Ambient

EPA TO-17

1689 20.0 ml/min

8-24 hrs

TD, GC £ PS

690-102

Isopropyl alcohol

Ambient

Internal

1-8 hrs

SE, GC

690-105

20.0 ml/min

PS

71

PS

Isopropyl benzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

Ketones

Ambient

EPA TO-5

1671 100-1000 ml/min

HPLC-UV IMP 225-36-1

Maleic anhydride

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

Mesitylene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

Methanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

< 80 L

or PS

575-002

65

71 or PS

226-300 Series 41

575-002

65

TH

224-26-02 47

IT

225-22

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

59

CPC 224-26CPC-10 47

59

2-Methoxyethanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

2-Methoxyethyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methoxypropanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methyl acrylate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

See page 196 for abbreviations.

192

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SKC Ltd.

Phone: +44 (0)1258 480188

Environmental Sampling Guide www.skcinc.com for updates

Sampling Environment

Agency Method

Methyl acrylate

Ambient

EPA TO-17

Methyl acrylate

Ambient

Internal

Methyl alcohol

Ambient

EPA TO-17

Chemical Hazard

Chem F File

Flow/Sampling Rate †

Sample Time or Air Analysis Volume

SKC Collection Media and Page No.

1689 15.7 ml/min

8-24 hrs

TD, GC £ PS

690-102

15.7 ml/min

1-12 hrs

SE, GC

690-105

PS

71 or PS

575-002

65

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methyl chloroform

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methyl ethyl ketone

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methyl ethyl ketone

Ambient

Internal

SE, GC

690-105

Methyl isobutyl ketone

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Methyl isobutyl ketone

Ambient

EPA TO-17

1689 13.5 ml/min

8-24 hrs

TD, GC £ PS

690-102

Methyl isobutyl ketone

Ambient

Internal

1-8 hrs

SE, GC

690-105

Methyl methacrylate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Methyl methacrylate

Ambient

EPA TO-17

1689 13.1 ml/min

8-24 hrs

TD, GC £ PS

690-102

Methyl methacrylate

Ambient

Internal

1-8 hrs

SE, GC

690-105

Methyl styrene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Methyl styrene

Ambient

EPA TO-17

1689 12.3 ml/min

8-24 hrs

TD, GC £ PS

690-104

1-8 hrs

SE, GC

690-105

16.9 ml/min

13.5 ml/min

13.1 ml/min

12.3 ml/min

1-12 hrs

PS

PS

PS

TH

575-002

65

224-26-02 47

CPC 224-26CPC-10 47

71 or PS TH

575-002

65

224-26-02 47

CPC 224-26CPC-10 47

71 or PS TH

575-002

65

224-26-02 47

CPC 224-26CPC-10 47

71

Methyl styrene

Ambient

Internal

1-Methyl-2-ethyl benzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

1-Methyl-3-ethyl benzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

1-Methyl-4-ethyl benzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methyl-t-butyl-ether (MTBE)

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Methyl-t-butyl-ether (MTBE)

Ambient

Internal

SE, GC

690-105

Methylene chloride (dichloromethane)

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Methylene chloride (dichloromethane) (see dichloromethane)

Ambient

EPA TO-17

1689 14.7 ml/min

4-8 hrs

TD, GC £ PS

690-102

Methylene chloride (dichloromethane) (see dichloromethane)

Ambient

Internal

0.99 ml/min

7 days

SE, GC

PS

690-105

withPS

690-300

71

Methylene chloride (dichloromethane)(see dichloromethane)

Ambient

Internal

14.7 ml/min

8 hrs-3 days

SE, GC

PS

690-105

or PS

575-001

65 59

13.6 ml/min

1-30 days

PS

or PS TH

575-001

575-001

65

65

224-26-02 47

CPC 224-26CPC-10 47

71

Methylphenols

Ambient

EPA TO-8

1668 100-1000 ml/min

IT

225-22

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Nonane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Nonane

Ambient

EPA TO-17

1689 10.6 ml/min

8-24 hrs

TD, GC £ PS

690-104

Nonane

Ambient

Internal

1-8 hrs

SE, GC

690-105

n-Octane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

n-Octane

Ambient

EPA TO-17

1689 12.7 ml/min

8-24 hrs

TD, GC £ PS

690-104

n-Octane

Ambient

Internal

1-8 hrs

SE, GC

690-105

12.7 ml/min

HPLC-UV IMP 225-36-1‡

or PS

Nitrobenzene

10.6 ml/min

< 80 L

PS

or PS

PS

PS

59

71 or PS TH

575-001

65

224-26-02 47

CPC 224-26CPC-10 47

71 or PS

575-001

65

Octanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Octyl alcohol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

PCBs (polychlorinated biphenyls)

Ambient

EPA TO-4A

1670 200-280 L/min

varies

n-Pentane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

n-Pentane

Ambient

Internal

Perchloroethylene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Perchloroethylene

Ambient

EPA TO-17

1689 13.1 ml/min

8-24 hrs

TD, GC £ PS

690-102

or PS

690-101

Perchloroethylene

Ambient

Internal

0.563 ml/min

1-7 days

TD, GC £ PS

690-101

or PS

690-102

Perchloroethylene

Ambient

Internal

13.1 ml/min

1-30 days

SE, GC

690-105

or PS

575-001

14.9 ml/min

24 hrs

1-8 hrs

PUF 226-131

43

TD, GC £ ST

226-300 Series 41

SE, GC

690-105

PS

PS

FLT 225-1821 43 TH or PS TH

224-26-02 47 575-001

CPC 224-26CPC-10 47

65

224-26-02 47

CPC 224-26CPC-10 47

71 with PS

690-300

65 See page 196 for abbreviations.

SKC Inc.

Phone: +1-724-941-9701

www.skcinc.com

193

Environmental Sampling Guide www.skcinc.com for updates

Chemical Hazard

Sampling Environment

Agency Method

Perchloroethylene

Indoor

EPA IP-1B

Pesticides

Ambient

Pesticides

Indoor

EPA IP-8

Pesticides, organochlorine

Ambient

Phenol

Ambient

Phenol

Ambient

Phosgene

Ambient

Chem F File

Flow/Sampling Rate †

1689 13.1 ml/min

EPA TO-10A 1675 1-5 L/min

Sample Time or Air Analysis Volume

SKC Collection Media and Page No.

8-24 hrs

TD, GC £ PS

690-102

or PS

690-101

71

4-24 hrs

GC-ECD PUF 226-92

or PUF 226-124

42

1675 1-5 L/min

4-24 hrs

GC-ECD PUF 226-92

or PUF 226-124

42

EPA TO-4A

1670 200-280 L/min

24 hrs

varies

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

EPA TO-8

1668 100-1000 ml/min

< 80 L

HPLC-UV IMP 225-36-1‡

EPA TO-6

1669 100-1000 ml/min

PUF 226-131

43

226-300 Series 41 59

FLT 225-1821 43 TH

224-26-02 47

IT

225-22

59

225-22

59

< 50 L

HPLC-UV IMP 225-36-1

59

IT

PM2.5

Indoor

EPA IP-10A 1663 9 L/min

24 hrs

GR

CI

100

FLT 225-2708 100

PM2.5

Indoor

EPA IP-10A 1663 10 L/min

24 hrs

GR

PEM 761-203B

98

FLT 225-1709 74

Polycyclic aromatic hydrocarbons (PAHs)

Ambient

EPA TO-13A 1672 220 L/min

24 hrs

GC-MS

PUF 226-131

43

FLT 225-1821 43

Polycyclic aromatic hydrocarbons (PAHs)

Indoor

30,000 L

GC-FID, PUF 226-131 -MS, HPLC

43

FLT 225-1821 43

EPA IP-7

20 L/min

225-370

CPC 224-26CPC-10 47

FLT 225-1709

74

n-Propanol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Propionitrile

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

n-Propyl acetate

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Propyl alcohol

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

n-Propyl benzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Pyridine

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Styrene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Styrene

Ambient

EPA TO-17

1689 13.7 ml/min

8-24 hrs

TD, GC £ PS

690-102

Styrene

Ambient

Internal

13.7 ml/min

1-8 hrs

SE, GC

PS

690-105

Styrene

Ambient

OSHA 1014

13.6 ml/min

1-8 hrs

SE, GC

PS

575-006

1,1,1,2-Tetrachloroethane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

1,1,2,2-Tetrachloroethane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

1,1,2,2-Tetrachloroethane

Ambient

EPA TO-17

1689 11.8 ml/min

8-24 hrs

TD, GC £ PS

690-102

or PS

8 hrs

SE, GC

690-105

or PS

11.8 ml/min

or PS

575-001

65

65

1,1,2,2-Tetrachloroethane

Ambient

Internal

Tetrachloroethylene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Tetrachloroethylene

Ambient

EPA TO-17

1689 13.1 ml/min

TD, GC £ PS

690-102

8-24 hrs

PS

71

TH

224-26-02 47

CPC 224-26CPC-10 47

TH

224-26-02 47

CPC 224-26CPC-10 47

TH or PS

690-104

71

575-001

65

224-26-02 47 690-101

71

Tetrachloroethylene

Ambient

Internal

0.563 ml/min

1-7 days

TD, GC £ PS

690-101

or PS

690-102

Tetrachloroethylene

Ambient

Internal

13.1 ml/min

1-30 days

SE, GC

PS

690-105

or PS

575-001

65

or PS

690-101

71

Tetrachloroethylene

Indoor

EPA IP-1B

1689 13.1 ml/min

8-24 hrs

TD, GC £ PS

690-102

Toluene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Toluene

Ambient

EPA TO-17

1689 14.5 ml/min

8-24 hrs

TD, GC £ PS

690-101

or PS

1-30 days

SE, GC

690-105

or PS

14.5 ml/min

with PS

224-26-02 47 690-102

71

575-001

65

690-300

CPC 224-26CPC-10 47

Toluene

Ambient

Internal

1,1,1-Trichloroethane

Ambient

EPA TO-17

1,1,1-Trichloroethane

Ambient

Internal

1,1,2-Trichloroethane

Ambient

EPA TO-17

1,1,2-Trichloroethane

Ambient

Internal

Trichloroethylene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

Trichloroethylene

Ambient

EPA TO-17

1689 14.9 ml/min

8-24 hrs

TD, GC £ PS

690-102

Trichloroethylene

Ambient

Internal

1-8 hrs

SE, GC

690-105

1,2,4-Trimethylbenzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

1,3,5-Trimethylbenzene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L 14.1 ml/min

1-8 hrs

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L 12.5 ml/min

14.9 ml/min

1-8 hrs

PS

TH

CPC 224-26CPC-10 47

TD, GC £ ST

226-300 Series 41

SE, GC

690-105

PS

or PS

TD, GC £ ST

226-300 Series 41

SE, GC

690-105

PS

PS

TH

TH or PS TH

224-26-02 47 575-001

65

224-26-02 47 575-001

CPC 224-26CPC-10 47

CPC 224-26CPC-10 47

65

224-26-02 47

CPC 224-26CPC-10 47

71 or PS

575-001

65

See page 196 for abbreviations.

194

www.skcltd.com

SKC Ltd.

Phone: +44 (0)1258 480188

Environmental Sampling Guide www.skcinc.com for updates

Chemical Hazard 3,5,5-Trimethylcyclohex-2-enone (isophorone)

Sampling Environment

Agency Method

Ambient

EPA TO-17

Chem F File

Flow/Sampling Rate †

Sample Time or Air Volume Analysis

SKC Collection Media and Page No.

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

n-Undecane

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Vinyl toluene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

CPC 224-26CPC-10 47

Volatile organic compounds (VOCs) (canister)

Ambient

EPA TO-14A 1676 varies

varies

GC-MS

CAN 228 Series

PK

228 Series

Volatile organic compounds (VOCs) (canister)

Ambient

EPA TO-15

1676 varies

varies

GC-MS

CAN 228 Series

PK

228 Series

Volatile organic compounds (VOCs) (canister)

Indoor

EPA IP-1A

1676 varies

varies

GC-MS

CAN 228 Series

PK

228 Series

Volatile organic compounds (VOCs) (sample bag)

Stack Gas

EPA 0040

1665 250-1000 ml/min

1-2 hrs

GC-MS

VAC 231-939 SB 232-939

Volatile organic compounds (VOCs) (sorbent tube)

Indoor

EPA IP-1B

1689 1 L/min

1 hr

TD, GC £ ST

refer to method

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

TH

224-26-02 47

TD, GC-MS

226-134∆

44

ST

226-133

TH

224-26-02 47

Volatile organic compounds (VOCs) (thermal desorption tube) VOST (volatile organic sampling train)

EPA 0031 Stack Gas, Incinerators, stationary sources

1 L/min

20 min

ST

or VAC 231-940 or SB 236-001

with SB or SB

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

m-Xylene

Ambient

EPA TO-17

1689 12.5 ml/min

8-24 hrs

TD, GC £ PS

690-102

or PS

m-Xylene

Ambient

Internal

7-30 days

SE, GC

690-105

or PS

o-Xylene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

TD, GC £ ST

226-300 Series 41

o-Xylene

Ambient

EPA TO-17

1689 11.9 ml/min

8-24 hrs

TD, GC £ PS

690-102

or PS

690-101

71

o-Xylene

Ambient

Internal

7-30 days

SE, GC

690-105

or PS

575-001

65

p-Xylene

Ambient

EPA TO-17

1689 16.7 ml/min & 66.7 ml/min 1 L & 4 L

p-Xylene

Ambient

EPA TO-17

1689 12.8 ml/min

p-Xylene

Ambient

Internal

11.9 ml/min

12.8 ml ml/min

† Outdoor sampling rates are shown. For indoor (low air velocity) sampling rates at < 5 cm/sec, go to www.skcinc.com/instructions/1811.pdf. ‡ Use two impingers.

PS

PS

TD, GC £ ST

226-300 Series 41

TH

TH

690-101

71

575-001

65

224-26-02 47

224-26-02 47

8-24 hrs

TD, GC £ PS

690-102

or PS

690-101

71

7-30 days

SE, GC

690-105

or PS

575-001

65

PS

or 58

CPC 224-26CPC-10 47

44

m-Xylene

12.5 ml/min

236-004 232-01

CPC 224-26CPC-10 47

CPC 224-26CPC-10 47

CPC 224-26CPC-10 47

∆ Collect six samples at 20 minutes each. Use two Cat. No. 226-134 tubes per sample. £ TD, GC - Samples are extracted by thermal desorption then analyzed by gas chromatography.

See page 196 for abbreviations.

SKC Inc.

Phone: +1-724-941-9701

www.skcinc.com

195