PhD Abstract ID# 392

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Graduate Category: Engineering and Technology Degree Level: PhD Abstract ID# 392

Environmental Life Cycle Assessment of Nanosilver-Enabled Bandages Leila Pourzahedi and Matthew Eckelman For hundreds of years, silver has been widely used in a range of technologies for its physical and chemical properties, such as high electrical conductivity, photosensitivity, and bioactivity. Production and applications of nanosilver have also existed for more than a century, typically in colloidal form, first for ingestion as a medicinal tonic, and later for direct application as a biocidal agent.

(production vs. releases)

Pesticide, fertilizer & transport in potato harvesting

High silver input and electricity

Significant use of ethylene glycol

CR-TSC

CR-SB

CR-EG

CR-Starch

FSP

LFS

PA

100% 80% 60% 40% Eckelman et al., New perspectives on nanomaterial aquatic ecotoxicity, Environ. Sci. Technol., 2012

0% Medical

~400 metric tons produced in 2010

30% of the nanosilver globally produced are incorporated into medical supplies and devices due to their bactericidal properties, yet there has been limited research on the fate of nanosilver used in health care settings, or on the significance of the life cycle impacts of these nanoparticles in the context of medical devices.

20%

OD

30%

WIP

GW

PS

AC

EU

HHC

EC

FF

Impacts from silver mining (machinery and electricity) and air freight

Impacts from sulfidic mining emissions

CR-TSC AgNPs Ecotoxicity FSP AgNPs 1% emissions to air Keller et al., Global life cycle releases of engineered nanomaterials, J Nanopart Res, 2013

CR-TSC AgNPs FSP AgNPs 0% Nano silver

20% HDPE

40% Polyester

60% Paper, supercalendred

Plasma Arc

104 mg silver

12.6 mg silver

Ecotoxicity

111 mg silver

80% 100% Electricity mix

Our first question finally answered …

From 1% silver release

Chemical Reduction

HHCR

(does being nano-enabled matter?)

Global Warming

Flame Spray Pyrolysis

HHNC

Global warming

Silvercel

Aquacel

Acticoat 7

100% 80% 60% 40% 20% 0% OD

GW

PS

AC

EU

HHC

HHNC

HHCR

EC

FF