Sampling Guide
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Abietic acid Absidia species (fungi, molds, spores) Absidia species (fungi, molds, spores) Acenaphthene (polynuclear aromatic hydrocarbons by GC-MS) Acenaphthene (polynuclear aromatic hydrocarbons by GC) Acenaphthene (polynuclear aromatic hydrocarbons by HPLC) Acenaphthylene (polynuclear aromatic hydrocarbons by GC-MS) Acenaphthylene (polynuclear aromatic hydrocarbons by GC) Acenaphthylene (polynuclear aromatic hydrocarbons by HPLC) Acetaldehyde Acetaldehyde Acetaldehyde Acetaldehyde Acetaldehyde (aldehydes, screening) Acetamide Acetates (screening) Acetic acid Acetic acid Acetic acid Acetic anhydride Acetic anhydride Acetic anhydride Acetoin Acetoin (acetyl methyl carbinol) Acetoin (acetyl methyl carbinol) Acetone Acetone Acetone (ketones I) Acetone (ketones I) Acetonitrile Acetophenone Acetyl methyl carbinol (acetoin) 2-Acetylaminofluorene Acetylene Acetylene tetrabromide Acetylene tetrabromide (1,1,2,2-tetrabromoethane) Acetylsalicylic acid Acid black 128 Acid blue 9 Acid orange 74 Acid red 114 Acid yellow 34 Acid yellow 42 Acid/base (skin)
Agency Reference
TWA (ppm)
CLG/STEL (ppm)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-UV
ASTM D 6209
350 m (max)
225 L/min
1-24
GC-MS
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-UV
ASTM D 5197
varies 10 60 3 5
500-1200 20 125 50 50 10
5 min-24 hrs 8 8 1 15 8
HPLC-UV
20(50) 20 50 200 200 1000 50 50 10-200 50 50 500-1200 50 20 10-200 20(50) 100 10-200 1000
8(3.3) 4 8 4 4 1.5 2.5 15 15 min varies 3 15 3 15 5 min-24 hrs 1 100 min 15 varies 8(3.3) 2 varies 4
GC-NPD
3
LFC NIOSH 3507 LFC OSHA 68 1007 200 NIOSH 2539 LFC NIOSH 2538
10 10
NIOSH 1603 OSHA ID 186SG
15
OSHA PV2119
5
NIOSH 3506 OSHA 102 OSHA 82
1392 5 1391 5
NIOSH 2558
0.05 0.05
OSHA 1012 OSHA 1013 ASTM D 5197
1000 250
OSHA 69 NIOSH 1300 NIOSH 2555
TWA (hrs)
ASTM D 6209
NIOSH 2549
TWA
www.skcinc.com for updates
Time
CLG/ STEL
HPLC-UV
OSHA PV2084
TWA
Rate (ml/min)
1.6 2 5 min 1-24
OSHA CSI
CLG/ STEL
2000 1000 28,300 225 L/min
OSHA CSI
Vol. (liter)
200 120 141.5 350 m3 (max)
OSHA CSI
20
NIOSH 1606 OSHA PV2003 NIOSH 2558 OSHA CSI
10 5 24 48 48 90 7.5 0.75 1-10 9 9 varies 3 2 0.5-3 10 12 1-10 240
0.75
7.5
3 3
0.75
500
200 200
50
varies varies GC-MS
OSHA CSI
GC-FID HPLC GC-NPD GC-FID & GC-MS GC-MS GC-FID IC or GC-FID IC or GC-FID VAS GC-NPD GC-NPD GC-FID GC-FID GC-FID HPLC-UV GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID HPLC-UV DET TB
1
OSHA CSI
96 96 120 200 100 200 120 100 100
NIOSH 2003 OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI
200 200 1000 1000 1000 1000 1000 1000 1000
8 8 2 3.3 100 min 3.3 2 100 min 100 min
GC-FID GC-FID HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-FD CI
Acid/base (surface) Acids, inorganic (see specific compounds) Acremonium species (fungi, molds, spores) Acremonium species (fungi, molds, spores) Acridine
CI NIOSH 7903 1016
48 120 141.5 960
OSHA CSI OSHA CSI
Acrolein Acrolein Acrolein (aldehydes, screening)
OSHA 58
1077 0.2 mg/m3
NIOSH 2501
0.1 0.1 0.1
OSHA 52 NIOSH 2539
Acrylamide
OSHA 21
Acrylic acid Acrylic acid Acrylonitrile Acrylonitrile Actinomycetes, thermophilic Adipic acid Adiponitrile Aerobic bacteria (by GC-FAME) Alcohols (screening) Alcohols combined Alcohols I (see specific compounds) Alcohols II (see specific compounds)
Chem F File
0.3 mg/m3
NON 10 OSHA 28
NIOSH 1604 1266 1 OSHA 37
1265 2
NIOSH 0800 OSHA CSI OSHA CSI NIOSH 0801 NIOSH 2549 NIOSH 1405 NIOSH 1400 NIOSH 1401
varies varies varies
0.3 0.3
24 48 5
200 1000 28,300 2000 3 3
120 48 24 10 (15 min) 10 10 20 varies 96 10 50-300 5 varies varies varies varies
3 6
varies
50 100 10
4 2 5 min 8 200 200
8 8 8
IC varies varies GR & HPLCFD, or GR & HPLC-UV
15 15
GC-NPD GC-NPD GC-FID & GC-MS
1000
2
GC-NPD
100 100 20(50) 200 28,300 200 20(50) 28,300 20 10-200 varies varies
8 4 8(3.3) 15 100 min 15 varies 8 8(3.3) varies 4 varies varies varies 8
GC
200 400
10-200
HPLC-UV GC-FID GC-NPD varies GC-FID GC-FID GC-FID GC-MS GC-FID GC-FID GC-FID
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
F/CST F/CST BI PUF
225-709 225-3-01 225-9611 226-131
79 C/HLD 77 C/HLD 103 43 FLT
F/CST C/HLD F/CST C/HLD PUF
225-1713 225-1 225-1713 225-1 226-131
74 87 74 87 43
F/CST C/HLD F/CST C/HLD ST ST IMP ST ST
225-1713 225-1 225-1713 225-1 226-120 226-27 225-36-2 226-27 226-118
74 87 74 87 or 35 59 35 37
ST ST ST ST ST IMP CF/CST CF/CST ST ST ST ST ST ST ST ST ST ST F/CST DT ST ST F/CST F/CST F/CST F/CST F/CST F/CST F/CST PCH TK W ST F/CST BI FLT C/HLD
226-10 226-330 226-01 226-01 226-01 225-36-2 225-9010 †† 225-9009 NA SKC 226-183 226-183 226-120 NA SKC 226-01 NA SKC 226-09 226-35 NA SKC 225-706 810-171 226-10 226-10 225-709 225-706 225-706 225-706 225-709 225-706 225-706 769-3006 769-1006 769-1024 226-10-03 225-3-01 225-9611 225-7 225-1
35 35 79 79 79 79 79 79 79 or 122 or 35 77 103 79 87
ST ST ST
226-118 226-117 226-118
37 37 37
ST CST ST ST ST ST BI ST ST BI ST ST ST ST
226-10 225-32 226-70A 226-30-08 226-01 226-01 225-9611 226-30-16 226-01 225-9611 226-330 226-01 226-01 226-01
35 FLT 87 36 35 35 35 103 35 35 103 39 35 35 35
A
225-1 225-1
87 87
225-1821
79
ST
226-30-04
35
ST
226-30-04
35
FLT
225-1821
79
ST
226-30-04
35
ST
226-30-04
35
ST
226-119
37
IT
225-22
59
35 39 35 35 35 59 61 61
IT C/HLD C/HLD
225-22 225-1 225-1
59 87 87
38 38 or
ST
226-119
37
C/HLD
225-1
87
C/HLD C/HLD C/HLD C/HLD C/HLD C/HLD C/HLD W
225-1 225-1 225-1 225-1 225-1 225-1 225-1 769-1036
87 87 87 87 87 87 87 or
TK
769-1006
122
C/HLD
225-1
87
CST
225-2LF
86
225-16
79
35 35 35 79
References and abbreviations are found on pages 196-197.
www.skcinc.com
139
Sampling Guide SAMPLING ∞
www.skcinc.com for updates A
Chemical Hazard
Alcohols III (see specific compounds) Alcohols IV (see specific alcohol) Aldehydes (screening) Aldehydes (screening) Aldehydes (see Environmental Sampling Guide) Aldicarb (organonitrogen pesticides) Aldicarb (Temik) Aldrin Aldrin
Passive Guide
Agency Reference
Agency Standard Chem F File
NIOSH 1403 NIOSH 2539
NIOSH 2549
CLG/STEL (ppm)
varies varies varies
NIOSH 1402
TWA (ppm)
Vol. (liter) TWA
Rate (ml/min)
CLG/ STEL
TWA
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
varies varies 5
varies varies 20
8 varies 4
GC-FID
ST ST ST
226-01 226-01 226-118
35 35 37
5
20
4
GC-MS
ST
226-330
39
1000 1000 1000-5000 500
4 8 4-24 8
HPLC-UV
4
GC-ECN
ST ST PUF F/CST IT F/CST IT ST FLT C/HLD
226-58 226-30-16 226-92 225-709 225-22 225-709 225-22 226-330 225-17-01 225-1
or 35 42 79 59 79 59 39 74 87
1000
226-92 226-01 226-01 226-01 226-01 226-01 226-01 226-35-03 226-110 500-400 225-3-01 225-9611 225-3-01 225-01-02 225-8-01 225-8-01 225-2LF 225-105 225-3LF 225-8-01 225-2LF 225-3-01 225-1 225-3-01
42 35 35 35 35 35 35 36 37 66 77 103 77 95 73 73 86 94 86 73 86 or 87 77
GC-FID GC-FID & GC-MS
EPA TO-5
NIOSH 5502
0.25 mg/m3
240 480 240-7200 240
OSHA CSI
0.25 mg/m3
240
NIOSH 5601 OSHA 74
1399
ASTM D 4861
Aldrin Aliphatic hydrocarbons (screening) Alkaline dusts
5
NIOSH 2549
20 30
NIOSH 7401
GC-NPD GC-ECD GC-ECN
4 2000
GC-MS
15
TITRA
NIOSH 0500 1035
120
2000
1
GR
59 87 59 87
CST
225-3LF
86
C/HLD
225-1
87
C/HLD C/HLD CST C/HLD
225-1 225-1 225-3LF 225-1
87 87 86 87
FLT C/HLD C/HLD
225-8-01 225-1 225-1
73 87 87
F/CST
225-803
73
C/HLD
225-1
87
varies
varies
GR
alpha-Alumina (total dust)
OSHA CSI
15 mg/m3
960
2000
8
GR
5-100
1000-4000
varies
ICP-AES
2-10,000
1000-4000
varies
ICP-AES
5-100
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
varies
varies
varies
GR
FLT CST
225-8-01 225-3LF
73 86
CYC C/HLD
225-105 225-1
94 87
FLT CST F/CST F/CST FLT CST FLT CST F/CST F/CST ST
225-8-01 225-2LF 225-3-01 225-3-01 225-8-01 225-2LF 225-8-01 225-2LF 225-709 225-709 226-10
73 86 77 77 73 86 73 86 79 79 35
C/HLD
225-1
87
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
C/HLD
225-1
87
C/HLD C/HLD
225-1 225-1
87 87
ST PCH TK W PCH TK
226-10 769-3005 769-1005 769-1025 769-3001 769-1001
35 or W 122 or TK or W 122
769-1035
or
769-1005 769-1031
122 or
W ST ST CF/CST ST IMP ST ST IMP ST ST FLT C/HLD
769-1021 226-10 226-30-16 225-9004 226-10-04 225-36-1 226-30-18 226-10-04 225-36-1 226-30-18 226-98 225-17-01 225-1
or 35 35 61 35 59 35 35 59 35 37 74 87
TK
769-1001
122
C/HLD
225-1
87
IT
225-22
59
IT
225-22
59
CST
225-3LF
86
Aluminum (respirable fraction)
2 5 min 6 2.5
225-36-2 225-1 225-36-2 225-1
varies
Aluminum (elements by ICP HNO3/HClO4 ashing)
1000 28,300 1000 2500
varies
NIOSH 0600 1038
120 141.5 360 375
IMP C/HLD IMP C/HLD
5 mg/m3
Aluminum (elements by ICP HNO3 digestion)
4-24 8(3.3) 15 200 min varies varies 8(3.3) 15 15 8(3.3) 15 2 15 8(3.3)
35
OSHA CSI
Aluminum (elements by ICP Aqua Regia ashing)
1000-5000 20(50) 200 50 10-200 10-200 20(50) 200 1000 20(50) 200 50 200 20(50)
226-30-16
alpha-Alumina (respirable fraction)
Alumina (particulates, total)
240-7200 10 3 10 1-10 1-10 10 3 15 10 3 6 3 10
ST
PUF ST ST ST ST ST ST ST ST PS F/CST BI F/CST CYC FLT FLT CST CYC CST FLT CST F/CST C/HLD F/CST
Allethrin Allyl alcohol Allyl alcohol Allyl alcohol (alcohols combined) Allyl alcohol (alcohols III) Allyl chloride Allyl chloride Allyl glycidyl ether Allyl propyl disulfide Allyll amine Alternaria species (fungi, molds, spores) Alternaria species (fungi, molds, spores) Alumina (aluminum & compounds [total dust as Al]) Alumina (particulates, respirable)
ASTM D 4861
2 OSHA PV2140 2 (skin) NIOSH 1405 2 NIOSH 1402 2 NIOSH 1000 1 OSHA 07 1126 1 NIOSH 2545 5 OSHA PV2086 2 OSHA CSI
4 (skin) 4 2 10
HPLC-UV GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FPD HPLC-UV
OSHA CSI OSHA CSI
10 mg/m3
NIOSH 7013
NIOSH 7301 ¥
10 mg/m3 (total dust) NIOSH 7303 10 mg/m3 (total dust) 5 mg/m3 (respirable fume) NIOSH 7300 1455 10 mg/m3 (total dust) 5 mg/m3 (respirable fume) OSHA CSI 5 mg/m3
varies AA-F GR
OSHA CSI
15 mg/m3
960
2000
8
GR
NIOSH 7013
10 mg/m3
1000 2000 2000
6 8 8
AA-F
OSHA CSI
360 960 960
Aluminum, pyro powders
OSHA CSI
960
2000
8
GR
Alupent Amiben Amines
OSHA CSI
2000 1000 40
6 4 8
HPLC-UV
50
8
GC-FID
Aluminum (total dust) Aluminum & compounds (total dust as Al) Aluminum soluble salts Aluminum welding fumes
Amines, aliphatic Amines, aliphatic (skin)
OSHA ID 121
NIOSH 2002
varies
720 240 20
NIOSH 2010
varies
24
OSHA CSI
Amines, aromatic (surface) 2-Amino-2-methy-1-propanol 2-Amino-2-methy-1-propanol 4-Aminobiphenyl 2-Aminoethanol 2-Aminoethanol 2-Aminoethanol Aminoethanol compounds I (see specific compounds) Aminoethanol compounds II (see specific compounds) Aminoethylethanolamine N-Aminoethylpiperazine p-Aminophenylarsonic acid (arsenic, organo-)
AA or AES GR
HPLC-UV GC-FID or GC-NSD CI
Amines, aliphatic (surface) Amines, aromatic (skin)
CI CI CI OSHA CSI OSHA PV2145 OSHA 93 NIOSH 2007 NIOSH 3509 OSHA PV2111 NIOSH 2007 NIOSH 3509
1233 3 3 3 varies varies
6 6
OSHA PV2116 OSHA CSI NIOSH 5022
9 10 100 10 240 10 varies 240 10 9 960
1.5
100 100 1000 20 1000 100 varies 1000 100 100 2000
100
90 min 100 min 100 min 8 4 100 min 15 8 4
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GC-NPD HPLC-UV GC-ECD GC-FID IC HPLC-UV GC-FID IC HPLC-UV
90 min 8
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
140
Analytical Method SKC Collecting Equipment & Page Number
GC-NPD IC-AA
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
2-Aminopyridine 2-Aminopyridine 3-Aminopyridine 4-Aminopyridine Amitrole Ammonia Ammonia Ammonia Ammonia (by IC) Ammonium chloride (fume) Ammonium hydroxide (see ammonia) Ammonium metavanadate (see vanadium oxides) Ammonium nitrate
Agency Reference
Chem F File
TWA (ppm)
0.5 0.5
OSHA CSI OSHA PV2143 OSHA PV2143 OSHA PV2143 OSHA PV2006
25
NIOSH 6015
35
NON 41 OSHA ID 188 1008 50
25
NIOSH 6016
35
OSHA ID 188
OSHA CSI
Ammonium sulfamate (respirable dust)
5 mg/m
Ammonium sulfamate (total dust)
OSHA CSI OSHA ID 188
o-Anisaldehyde Anisidine Anisidine (o- & p-isomers) Anthophyllite fibers (see asbestos fibers) Anthracene Anthracene (polynuclear aromatic hydrocarbons by GC-MS) Anthracene (polynuclear aromatic hydrocarbons by GC) Anthracene (polynuclear aromatic hydrocarbons by HPLC) Antimony (elements by ICP Aqua Regia ashing) Antimony (elements by ICP HNO3 digestion) Antimony (elements by ICP HNO3/HClO4 ashing) Antimony (ICP analysis of metal/metalloid particulates from solder operations) Antimony & compounds (as Sb) Antimony & compounds (as Sb) ANTU (alphanaphthyl thiourea) Apron Aqua fortis (acids, inorganic) Aroclor Aroclor Aroclor 1242 Aroclor 1242 (42% Cl) (see polychlorobiphenyls) Aroclor 1254 Aroclor 1254 (54% Cl) (see polychlorobiphenyls) Aroclor 1260 Aromatic hydrocarbons (screening) Arsenic (elements by ICP Aqua Regia ashing)
Vol. (liter) TWA
12 240 240 240 60 72 18 24 48 960
Rate (ml/min)
CLG/ STEL
3 5 7.5 3 30
TWA
200 1000 1000 1000 1000 150 75 100 100 2000
200 500 500 200 2000
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
1 4 4 4 1 8 4 4 8 8
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
ST CF/CST CF/CST CF/CST IMP ST ST ST ST F/CST
226-35-02 225-9004 225-9004 225-9004 225-36-1 226-10-06 226-61 226-29 226-10-06 225-3-01
35 61 61 61 59 35 36 35 35 77
FLT CST CYC FLT GR FLT CST GR & IC-ECN F/CST GC-FID ST GC-FID ST GC-FID ST GC-FID PS GC-FID PS HPLC-UV ST GC-FID CF/CST GC-FID ST GC-FID or ST
225-8-01 225-2LF 225-105 225-8-01 225-8-01 225-2LF 225-3-01 226-01 226-01 226-01 575-002 575-001 226-01 225-9004 226-98 226-10
73 86 94 73 73 86 77 35 35 35 64 64 35 61 37 35
226-30 226-30-05 226-30-05
35 35 35
225-7 225-1
GC-FID GC-NPD GC-NPD GC-NPD HPLC-UV
15 10 15 15 15
VAS CLR IC-ECN IC IC-ECN
C/HLD C/HLD C/HLD IT F/CST
225-1 225-1 225-1 225-22 225-3-01**
87 87 87 59 77
F/CST C/HLD
225-3-01** 225-1
77 87
2000
8
GR GR
C/HLD
225-1
87
C/HLD CST C/HLD
225-1 225-3LF 225-1
87 86 87
C/HLD
225-1
87
ST
226-15
35
79 87
CST
225-2LF
86
varies
varies
varies
15 mg/m
960
2000
8
15 mg/m 100 125 100
3
960 10 10 1-10
2000 20(50) 20(50) 10-200
8 8(3.3) 8(3.3) varies
8 24 24 24
50 200 50 50
2.5 2 8 8
200 1000 1000
8 4 4
HPLC-UV
0.5 mg/m3 0.5 mg/m3
96 240 240
1075 0.2 mg/m
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
ASTM D 6209
350 m3 (max)
225 L/min
1-24
GC-MS
PUF
226-131
43
FLT
225-1821
79
NIOSH 5515
480
2000
4
GC-FID
35
2000
4
HPLC-UV
74 87 74 87 or 87 77 77 77
226-30-04
480
225-1713 225-1 225-1713 225-1 225-3-01 225-1 225-3-01 225-3-01 225-3-01
ST
NIOSH 5506
F/CST C/HLD F/CST C/HLD F/CST C/HLD F/CST F/CST F/CST
ST
226-30-04
35
F/CST
225-803
73
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
225-3-01 225-3-01 225-1 225-17-01 225-1 225-709 226-10-03 226-92 226-58 226-92
77 or 87 74 87 79 35 42 36 42
C/HLD F/CST
225-1 225-3100
87 77
CST
225-2LF
86
C/HLD
225-1
87
F/CST
225-803
73
C/HLD C/HLD TMP
225-1 225-1 225-2403
87 87 or
C/HLD C/HLD CST
225-1 225-1 225-2LF
87 87 86
C/HLD CST
225-1 225-2LF
87 86
OSHA 07 OSHA 07 NIOSH 1450
3
OSHA CSI
960
3
LFC OSHA PV2079 5 NIOSH 2002 1058 LFC NIOSH 2017
OSHA CSI NIOSH 2514 OSHA CSI
GC-NSD
ST ST ST
HPLC-UV HPLC-UV
NIOSH 7400 OSHA 58
3
NIOSH 7301 ¥
0.5 mg/m3
50-2000
1000-4000
varies
ICP-AES
NIOSH 7303
0.5 mg/m3
1000-4000 1000-4000 2000
varies varies 4
ICP-AES
OSHA ID 206
0.5 mg/m3
3-100,000 50-2000 480
OSHA ID 121
0.5 mg/m3 0.5 mg/m3
960 480
2000 2000
8 4
AA or AES
OSHA ID 125G OSHA CSI
0.3 mg/m3
480
2000
4
HPLC-UV
60 48 240-7200 480 240-7200
1000 200 1000-5000 1000 1000-5000
1 4 4-24 8 4-24
HPLC-UV
GC-ECD
F/CST F/CST C/HLD FLT C/HLD F/CST ST PUF ST PUF
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
240-7200 5
1000-5000 20
4-24 4
GC-ECD
PUF ST F/CST C/HLD F/CST F/CST W TMP F/CST F/CST FLT C/HLD CF/CST FLT C/HLD ST
226-92 226-330 225-3-01 225-1 225-3-01 225-3-01 225-2414 225-2415 225-3-01 225-3-01 225-5 ‡ 225-1 225-9001 225-17-01 225-1 226-01
42 39 or 87 77 77 124 124 77 77 76 87 61 74 87 35
NIOSH 7300 1455 0.5 mg/m3
OSHA PV2102 NIOSH 7903 1016 2
4
ASTM D 4861 NIOSH 5602 ASTM D 4861
ICP-AES ICP-AES
ICP-AES
IC GC-ECD GC-ECD
NIOSH 5503 ASTM D 4861 NIOSH 5503 ASTM D 4861 NIOSH 2549 NIOSH 7301 ¥
Arsenic (elements by ICP HNO3 digestion) Arsenic (elements by ICP HNO3/HClO4 ashing) Arsenic (elements on wipes)
NIOSH 7303
Arsenic (inorganic compounds as As) Arsenic & compounds (as As) Arsenic trioxide as AS
OSHA ID 105
0.002 mg/m3
5-2000
1000-4000
0.002 mg/m3 8-5,000,000 0.002 mg/m3 (C) 5-2000 wipe
1000-4000
2000
NIOSH 7901
0.01 mg/m 960 2 μg/m3 (15 min) 3 2 mg/m (15 min)
Arsenic, inorganic (volatile compounds as As) Arsenic, organo-
OSHA ID 105
0.01 mg/m
Arsine Arylam (see carbaryl)
NIOSH 6001 1278
NIOSH 7300 1040 NIOSH 9102
NIOSH 7900
3
NIOSH 5022
3
2 μg/m3 (15 min) 10
varies 1000-4000 varies
ICP-AES ICP-AES ICP-AES
8 2000 2000
2000 2000 3
varies
ICP-AES
30 30
960 960
GC-MS
20
AAS-HGA
15 15 8 8
200
8
AA-F AAS-GF AAS-HGA IC-AA
15
AAS-GF
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
A
NIOSH 7504
OSHA CSI
Ammonium sulfamate (total dust) n-Amyl acetate sec-Amyl acetate (2-pentyl acetate) n-Amyl acetate (esters I) n-Amyl alcohol t-Amyl methyl ether (methyl tert-amyl ether) Amyl nitrite Aniline Aniline Aniline (amines, aromatic)
CLG/STEL (ppm)
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
141
Sampling Guide SAMPLING ∞
www.skcinc.com for updates A
Chemical Hazard
Passive Guide
Agency Reference
Agency Standard Chem F File
TWA (ppm)
CLG/STEL (ppm)
Vol. (liter)
Rate (ml/min)
CLG/ STEL
TWA
TWA
Time
CLG/ STEL
TWA (hrs)
Asbestos
OSHA ID 160 1301 0.1 fbr/cc 1 fbr/cc EL 25-1200 25-1200 500-2500 500-2500 varies
Asbestos ([bulk] by PLM) Asbestos (by TEM) Asbestos (chrysotile) Asbestos (mass concentrations) Asbestos (structure number concentrations) Asbestos fibers
NIOSH 9002
1% (bulk) 0.1 fbr/cc/400L
NIOSH 7400 1033 0.1 fbr/cc/400L
2000 2000 varies
2 min (minimum) 2 min (minimum) varies
NIOSH 5031
480
1000
8
1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000
2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 6
NIOSH 9000 ASTM D 5756 1440 ASTM D 5755 1440
Aspergillus flavipes species (fungi, molds, spores) Aspergillus flavipes species (fungi, molds, spores) Aspergillus flavus species (fungi, molds, spores) Aspergillus flavus species (fungi, molds, spores) Aspergillus fumigatus species (fungi, molds, spores) Aspergillus fumigatus species (fungi, molds, spores) Aspergillus glaucus species (fungi, molds, spores) Aspergillus glaucus species (fungi, molds, spores) Aspergillus nidulans species (fungi, molds, spores) Aspergillus nidulans species (fungi, molds, spores) Aspergillus niger species (fungi, molds, spores) Aspergillus niger species (fungi, molds, spores) Aspergillus ochraceus (fungi, molds, spores) Aspergillus ochraceus (fungi, molds, spores) Aspergillus versicolor (fungi, molds, spores) Aspergillus versicolor (fungi, molds, spores) Asphalt fume (benzene-soluble & total particulate)
varies
bulk 960 bulk varies varies varies
NIOSH 7402
Aspartame
CLG/STEL (ppm)
120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 3 5 mg/m 360 (15 min) (C) 960 960
OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI NIOSH 5042
Analytical Method SKC Collecting Equipment & Page Number PCM
8
TEM
60
4000
15
NIOSH 5506
480
2000
4
HPLC-FD
ASTM D 5197
varies
500-1200
5 min-24 hrs
HPLC-UV
Barium sulfate (total dust) Baygon (propoxur) Baygon (propoxur) Bendiocarb Bendiocarb (Ficam ) Benomyl (organonitrogen pesticides) Benomyl (respirable dust) Benomyl (total dust) Bentonite (see dust, total & respirable nuisance) Benz(a)anthracene Benz(a)anthracene (polynuclear aromatic hydrocarbons by GC-MS) Benz(a)anthracene (polynuclear aromatic hydrocarbons by GC) Benz(a)anthracene (polynuclear aromatic hydrocarbons by HPLC) Benzaldehyde
OSHA ID 121 1217 15 mg/m
0.5 mg/m3 OSHA ID 121 0.5 mg/m3 NIOSH 7056 0.5 mg/m3 OSHA ID 204 1216 5 mg/m3 NIOSH 7056
3
ASTM D 4861 OSHA PV2007 ASTM D 4861 OSHA PV2008 NIOSH 5601 OSHA CSI OSHA PV2107
5 mg/m 15 mg/m3 3
OSHA CSI
www.skcltd.com
GC-ECD HPLC-UV HPLC-UV varies varies varies varies GC-FID GC-FPD GC-FPD GC-FPD HPLC-UV varies GC-FID varies ICP-AES
ICP-AES
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
142
87
C/HLD
225-1
87
SP
225-27
87
C/HLD CST
225-1 225-2LF
87 86
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
C/HLD
225-1
87
C/HLD
225-1
87
VT ◊ F/CST
225-9598A 225-803
105 73
C/HLD TMP
225-1 225-2403
87 or
C/HLD C/HLD C/HLD C/HLD C/HLD
225-1 225-1 225-1 225-1 225-1
87 87 87 87 87
C/HLD
225-1
87
ST CYC
226-30-16 225-105
35 94
37
GC-FID
OSHA ID 121
225-1
226-119
4
Barium (insoluble compounds) Barium (soluble compounds) Barium (soluble compounds) Barium chloride (barium, soluble compounds) Barium sulfate (respirable fraction)
NIOSH 9102
C/HLD
ST
2000
NIOSH 7303
87
35
480
Barium (elements by ICP HNO3 digestion) Barium (elements on wipes)
225-1
226-30-04
NIOSH 5515
0.5 mg/m3
C/HLD
ST
8 1-24
NIOSH 7301 ¥
87
35
2000 225 L/min
NON 48
225-1
226-30-04
960 350 m3 (max)
HPLC-UV
ASTM D 6209
NIOSH 0801
C/HLD
ST
AA or AES
NIOSH 0800
87
74 87 74 87 or
8 4-24 8 4-24 4 4 varies 1
OSHA CSI
225-1
225-1713 225-1 225-1713 225-1 226-120
2000 1000-5000 100 1000-5000 1000 1000 varies 1000
0.2 mg/m3 0.2 mg/m3
C/HLD
F/CST C/HLD F/CST C/HLD ST
960 240-7200 48 240-7200 240 240 varies 60
NIOSH 5600
87
87 79
AA or AES
OSHA PV2087
225-1
225-1 225-1821
8 8 8 8 varies
OSHA CSI
C/HLD
C/HLD FLT
2000 2000 2000 2000 varies
NIOSH 5019
87
79 43
960 960 960 960 varies
OSHA CSI
225-1
225-709 226-131
ICP-AES
OSHA CSI
C/HLD
F/CST PUF
varies
OSHA CSI
87
42 36 79 79 77 103 77 103 73 35 35 36 35 103 103 105 or 87 77 124 124 77 77 77 77 94 77 73 42 35 42 35 or 35 35
1000-4000
OSHA CSI
225-1
226-92 226-58 225-706 225-709 225-3-01 225-9611 225-3-01 225-9611 225-803 226-30-16 226-30-16 226-58 226-30-16 225-9611 225-9611 225-9595 225-3-01 225-1 225-3-01 225-2414 225-2415 225-3-01 225-3-01 225-3-01 225-3-01 225-105 225-3-01 225-802 226-92 226-30-16 226-92 226-30-16 226-58 226-30-16 226-30-16
1-100,000 wipe
OSHA CSI
C/HLD
PUF ST F/CST F/CST F/CST BI F/CST BI F/CST ST ST ST ST BI BI BS F/CST C/HLD F/CST W TMP F/CST F/CST F/CST F/CST CYC F/CST F/CST PUF ST PUF ST ST ST ST
GC-NPD
OSHA CSI
or 77 86
125 125 or or 74 87 77 103 77 103 77 103 77 103 77 103 77 103 77 103 77 103 74 86 74 79 87
HPLC-UV
5
FLT/CL 225-326 FLT/CL 225-327 CST 225-2LF
225-322 225-322 225-321 225-321A 225-17-01 225-1 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-27-07 225-2LF 225-1713 225-7 225-1
4-24 8 4 100 min 2 5 min 2 5 min 8 8 8 4 1.5 varies varies 5-30 varies
NIOSH 5602
or 77
MVC MVC PCM FLT/CL FLT/CL HPLC-UV FLT C/HLD varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI GR FLT CST GR F/CST GR & HPLC- FLT FD, or GR & C/HLD TEM
1000-5000 1000 1000 1000 1000 28,300 1000 28,300 2000 1000 1000 1000 1000 28,300 28,300 12500 + 1000-4000
ASTM D 4861
1078
77
TEM
240-7200 480 240 100 120 141.5 120 141.5 960 480 480 240 90 varies 50-300 62.5-375 50-2000
Atrazine Atrazine Atrazine Auramine Aureobasidium pullulans (fungi, molds, spores) Aureobasidium pullulans (fungi, molds, spores) Aureobasidium species (fungi, molds, spores) Aureobasidium species (fungi, molds, spores) Azelaic acid Azinphos-ethyl Azinphos-methyl Azinphos-methyl (organophosphorus pesticides) 1,1’-Azobisformamide Bacteria Bacteria (by GC-FAME) Bacteria (in air) Barium (elements by ICP Aqua Regia ashing)
OSHA 58
FLT/CL 225-327
FLT/CL 225-326 FLT/CL 225-327
XRD
8 8
ASTM D 6494
or or
PLM
2000
2000 2000
Asphalt fume particulate Asphalt fumes (petroleum)
FLT/CL 225-321 FLT/CL 225-321A
AA AA or AES AA GR & XRF
HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV
GC-MS
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Benzaldehyde Benzene Benzene Benzene Benzene Benzene (by portable GC) Benzene (hydrocarbons, aromatic) alpha-Benzene hexachloride beta-Benzene hexachloride gamma-Benzene hexachloride Benzene-soluble & total particulate (asphalt fume)
Agency Reference
Chem F File
TWA (ppm)
CLG/STEL (ppm)
ASTM D 5466
1749 OSHA 1005 1749 OSHA 12 1009 NIOSH 3700 1029 OSHA 1005
NIOSH 1501
1 1 1 0.1 0.1
5 5 5 1 (15 min) 1
ASTM D 4861 ASTM D 4861 NIOSH 5042 ASTM D 4600 1416
1,2-Benzenedicarboxylic acid Benzidine Benzidine Benzidine dyes (dyes, benzidine)
LFC
OSHA 65 NIOSH 5013
Benzidine-based dyes
1239 LFC
Benzo(a)pyrene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(a)pyrene (polynuclear aromatic hydrocarbons by GC) Benzo(a)pyrene (polynuclear aromatic hydrocarbons by HPLC) Benzo(b)fluoranthene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(b)fluoranthene (polynuclear aromatic hydrocarbons by GC) Benzo(b)fluoranthene (polynuclear aromatic hydrocarbons by HPLC) Benzo(e)pyrene Benzo(e)pyrene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(e)pyrene (polynuclear aromatic hydrocarbons by GC) Benzo(e)pyrene (polynuclear aromatic hydrocarbons by HPLC) Benzo(g,h,i)perylene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(g,h,i)perylene (polynuclear aromatic hydrocarbons by GC) Benzo(g,h,i)perylene (polynuclear aromatic hydrocarbons by HPLC) Benzo(k)fluoranthene (polynuclear aromatic hydrocarbons by GC) Benzo(k)fluoranthene (polynuclear aromatic hydrocarbons by HPLC) Benzoalphapyrene
ASTM D 6209 NIOSH 5515
0.1 mg/m
TWA (hrs)
CLG/STEL (ppm)
8
GR
1000 200 1000 1000
4 8 100 min 8
GC-FID
1000
8
HPLC-UV
350 m (max)
225 L/min
1-24
GC-MS
480
2000
4
GC-FID
2000
4
HPLC-FD
50
15
Analytical Method SKC Collecting Equipment & Page Number
2000
0.75
3
3
TWA
14.1 varies 50
www.skcinc.com for updates
Time
CLG/ STEL
200 200 20-5000 10-200 10-200 1000-5000 1000-5000 1000-5000 1000 4000
6 12
480
OSHA CSI
Rate (ml/min)
8 varies 4 8 50 min varies varies 4-24 4-24 4-24 6
240 96 100 480
OSHA CSI NIOSH 5509
TWA
CLG/ STEL
10 3 varies 5-30 5-30 240-7200 240-7200 240-7200 5 mg/m3 360 60 (15 min) (C) 960
ASTM D 4861
Benzene-soluble particulate matter
Vol. (liter)
PS CAN ST PS ST SB ST PUF PUF PUF FLT CST FLT CST ST FLT CF/CST FLT C/HLD FLT C/HLD PUF PEM F/CST C/HLD F/CST C/HLD PUF PEM F/CST C/HLD F/CST C/HLD F/CST PUF
500-100 228 Series 226-01 575-002 226-01 232 Series 226-01 226-92 226-92 226-92 225-27-07 225-2LF 225-7 225-2LF 226-56 225-16 225-9004 225-17A 225-1 225-17-04 225-1 226-131 761-200B 225-1713 225-1 225-1713 225-1 226-131 761-203B 225-1713 225-1 225-1713 225-1 225-706 226-131
35 64 35 50 35 42 42 42 74 86 79 86 36 79 61 74 87 74 87 43 98 74 87 74 87 43 98 74 87 74 87 79 43
F/CST C/HLD F/CST C/HLD PUF
225-1713 225-1 225-1713 225-1 226-131
74 87 74 87 43
F/CST C/HLD HPLC-FD F/CST C/HLD GC-FID F/CST C/HLD HPLC-FD F/CST C/HLD GR & HPLC- FLT FD, or GR & C/HLD
225-1713 225-1 225-1713 225-1 225-1713 225-1 225-1713 225-1 225-7 225-1
74 87 74 87 74 87 74 87 79 87
ST ST ST ST FLT C/HLD F/CST C/HLD F/CST ST PS
226-30 226-115 226-56 226-110 225-17-04 225-1 225-1713 225-1 225-706 226-35-03 575-001
35 37 36 37 74 87 74 87 79 36 or
IMP F/CST ST ST DT CAN ST ST F/CST C/HLD F/CST F/CST
225-36-1 225-3-01 226-73 226-95 810-136L 228 Series 226-01 226-01 225-3-01 225-1 225-3-01 225-3-01
59 77 36 37
W TMP
225-2414 225-2415
124 TMP 124
HPLC-UV GC-MS
15 15 15
GC-FID GC-FID GC-FID P GC-PID
varies
GC-FID GC-ECD GC-ECD GC-ECD
15
GR
HPLC-UV GC-ECD HPLC
NIOSH 5506
480
ASTM D 6209
350 m (max)
225 L/min
1-24
GC-MS
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-FD
960 350 m3 (max)
2000 225 L/min
8 1-24
HPLC-UV
ASTM D 6209 NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-FD
ASTM D 6209
350 m (max)
225 L/min
1-24
GC-MS
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
NIOSH 5515
480
2000
4
480
2000
4
960
2000
8
3
OSHA CSI
3
NIOSH 5506 OSHA 58
0.2 mg/m
3
GC-MS
HPLC-UV
2,3-Benzofuran Benzoic acid Benzophenone Benzophenone Benzophenonetetracarboxylic acid dianhydride
8 4 8 4 100 min
NIOSH 2550
480
1000
8
GC-SCD
OSHA CSI
240 12
2000 200
2 1
HPLC-UV
OSHA CSI NON 39 OSHA PV2130
Benzothiazole in asphalt fume 2-Benzothiazolethiol Benzotrichloride Benzotrifluoride (trifluoromethyl benzene, OXSOL 2000) Benzoyl chloride Benzoyl peroxide Benzyl acetate Benzyl alcohol Benzyl bromide Benzyl chloride Benzyl chloride Benzyl chloride (hydrocarbons, halogenated) Beryllium (elements by ICP Aqua Regia ashing)
200 100 1000 200 1000
HPLC-UV
OSHA CSI
96 24 480 48 100
OSHA CSI
0.5 mg/m3
OSHA ID 216SG
GC-FID GC-FID HPLC
GC-FID
100 OSHA CSI NIOSH 5009
GC-FID
5 mg/m3
OSHA PV2124 OSHA PV2009
GC-FID
90 90 10 24
1000 1500 100 100
1.5 1 100 min 4
GC-ECD HPLC-UV GC-FID GC-FID
OSHA CSI
DET TB
ASTM D 5466 OSHA 07 NIOSH 1003 NIOSH 7301 ¥
1187 1 1 0.0005 mg/m3
6 10
varies 20(50)
10 1250-2000
1000-4000
varies
ICP-AES
1000-4000 1000-4000
varies varies
ICP-AES
Beryllium (elements by ICP HNO3 digestion) Beryllium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7303 NIOSH 7300 1455 0.0005 mg/m3
35-25,000,000 1250-2000
Beryllium (elements on wipes)
NIOSH 9102
wipe
varies 8(3.3) 10-200
GC-MS GC-FID
varies
GC-FID
ICP-AES ICP-AES
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
B
67
35 35 or 87 77 77
PK
228 Series
SP
225-27
87
SP C/HLD
225-27 225-1
87 87
CST C/HLD CST
225-32 225-1 225-3LF
87 87 86
CST
225-3LF
86
FLT FLT ST
225-1821 225-1709 226-30-04
79 74 35
ST
226-30-04
35
FLT FLT ST
225-1821 225-1709 226-30-04
79 74 35
ST
226-30-04
35
C/HLD FLT
225-1 225-1821
87 79
ST
226-30-04
35
ST
226-30-04
35
FLT
225-1821
79
ST
226-30-04
35
ST
226-30-04
35
ST
226-30-04
35
ST
226-30-04
35
CST
225-2LF
86
CST
225-2LF
86
ST
226-30-04
35
C/HLD
225-1
87
PS
575-002
64
IT C/HLD
225-22 225-1
59 87
PK
228 Series
F/CST
225-803
73
C/HLD C/HLD
225-1 225-1
87 87
225-2403
or
References and abbreviations are found on pages 196-197.
www.skcinc.com
143
Sampling Guide SAMPLING ∞
www.skcinc.com for updates B
Chemical Hazard
Passive Guide
Agency Reference
Agency Standard Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
TWA
Beryllium (ICP analysis of metal/metalloid particulates from solder operations)
OSHA ID 206
2 mg/m3
5 mg/m3 (C)
480
Beryllium (in air by portable fluorometry)
NIOSH 7704
2 mg/m3
5 mg/m3 (C)
240-2000
OSHA ID 125G
2 μg/m3
5 μg/m3
480
Beryllium & compounds Beryllium & compounds (as Be)
NIOSH 7102
Betasan
Rate (ml/min)
CLG/ STEL
10
TWA
2000
Time
CLG/ STEL
2000
TWA (hrs)
4
CLG/STEL (ppm)
5
1000-4000 60
2000
2000
4
15
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
P FLUOR UV/VIS
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
C/HLD
225-1
87
225-9598A
105
C/HLD
225-1
87
0. 5 μg/m3 960
2000
8
AA-GF
F/CST
225-3-01
77
480
1000
8
GC-FPD
ST
226-30-16
35
OSHA CSI
BHC (alpha-, beta-, gamma-)
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Bioaerosol sampling
NIOSH 0800
varies
28,300
varies
varies
BI
225-9611
103
Bioaerosols Bioaerosols
NON 48
Biphenyl (diphenyl)
0.2
NIOSH 2530
15-150
15000
1-10 min
varies
STC
225-9820
81
62.5-375
12500 +
5-30
varies
BS
225-9595
105 VT ◊
10
20(50)
8(3.3)
GC-FID
ST
226-35-01
35
Bipolaris species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Bipolaris species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
HPLC
ST C/HLD
226-30-05 225-1
35 87
F/CST
225-706
79
NON 26
96
Bis (tributyltin) oxide (tin, organic compounds [as Sn])
OSHA CSI
960
2000
8
AA-GF
F/CST
225-709
79
C/HLD
225-1
87
Bismuth
OSHA CSI
960
2000
8
AA
F/CST
225-3-01
77
C/HLD
225-1
87
1-10,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
960
2000
8
AA or AES
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
varies
varies
varies
GR & AA or GR & AES
CYC FLT
225-105 225-8-01
94 73
C/HLD CST
225-1 225-3LF
87 86
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
4,4’-Bipyridine (vapor & aerosol)
2
200
200
8
10
Bismuth (elements by ICP HNO3 digestion)
NIOSH 7303
Bismuth telluride, Se-doped
OSHA ID 121
5 mg/m3
Bismuth telluride, undoped (respirable dust)
OSHA ID 121
5 mg/m
Bismuth telluride, undoped (total dust)
OSHA CSI
15 mg/m
Bisphenol A
OSHA CSI
360
1500
4
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Bladex
OSHA CSI
100
1000
100 min
HPLC-UV
IMP
225-36-1
59
IT
225-22
59
OSHA ID 125G
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
OSHA CSI
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
Borates tetrasodium salts (anhydrous, decahydrate & pentahydrate) Boric acid (total dust) Boron (elements by ICP HNO3 digestion)
3
3
1-3300
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA CSI
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
Boron carbide
NIOSH 7506
600
2500
4
XRD
F/CST CYC
225-803 225-01-02
73 95
C/HLD
225-1
87
Boron oxide (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
C/HLD CST
225-1 225-3LF
87 86
Boron oxide (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
480
2000
4
ICP-AES
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
NIOSH 7303
Boron (total dust)
Boron oxide (total dust)
OSHA CSI
15 mg/m3
5
1000
5
IC
IMP
225-36-2
59
IT
225-22
59
15
1000
15
ISE
IMP
225-36-2
59
IT
225-22
59
6.7
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
50 min
HPLC-UV
IMP
225-36-1
59
IT
225-22
59
Boron tribromide
OSHA CSI
Boron trifluoride
OSHA CSI
Botran
OSHA CSI
400
1000
Bromacil
OSHA CSI
50
1000
1 (C)
Bromine
NIOSH 6011 1329 0.1
Bromine
OSHA ID 108
0.3
0.1
240
15
1000
1000
4
15
IC
CF/CST 225-9006
61
C/HLD
225-1
87
120
7.5
500
500
4
15
IC
IMP
225-36-2
59
IT
225-22
59
OSHA CSI
48
200
4
IC
ST
226-10-03
35
Bromoethane (ethyl bromide)
NIOSH 1011
4
20(50)
3.3(1.3)
GC-FID
ST
226-01
35
Bromoform
OSHA 07
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
10
10-200
varies
GC-FID
ST
226-01
35
0.1-12
10-200
varies
GC-FID
ST
226-01
35
12
100
2
GC-FID
ST
226-01
35
0.1-12
10-200
varies
GC-FID
ST
226-01
35
12
100
2
GC-FID
ST
226-01
35
0.3
20
15 min
GC-FID
ST
226-09
Bromine pentafluoride
Bromoform (hydrocarbons, halogenated)
NIOSH 1003
1-Bromopropane
NIOSH 1025
1-Bromopropane
OSHA PV2061
2-Bromopropane
NIOSH 1025
2-Bromopropane
OSHA PV2062
1127 0.5 0.5 (skin)
Bromotrifluoromethane (trifluorobromomethane)
NIOSH 1017
35
ST
226-01
35
Bromoxynil
NIOSH 5010
240
1000
4
HPLC-UV
F/CST
225-1713
74
C/HLD
225-1
87
Bromoxynil octanoate
NIOSH 5010
240
1000
4
HPLC-UV
F/CST
225-1713
74
C/HLD
225-1
87
Bronkosol
OSHA CSI
480
1000
8
HPLC
F/CST
225-706
79
C/HLD
225-1
87
Brucine
OSHA CSI
180
1000
3
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
varies
varies
varies
GC-FID
ST
226-01
35
BTEX (hydrocarbons, aromatic. See benzene, toluene, ethylbenzene, & xylene)
NIOSH 1501
1,3-Butadiene
1,3-Butadiene
1000
varies
NIOSH 1024 1010 LFC OSHA 56
1011 1
5
10
20
8
GC-FID
ST
226-37
36
3
50
1
GC-FID
ST
226-73
36 35
Butane
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
1,3-Butanediol
OSHA CSI
60
2000
30 min
GC-FID
ST
226-57
36
1
50
15
GC-FPD
ST
226-109
37 35
1-Butanethiol (butyl mercaptan) n-Butanol (alcohols combined)
0.5
NIOSH 2525
2-Butanone 2-Butanone (ketones I)
NIOSH 1405
50 (skin)
2-10
10-200
varies
GC-FID
ST
226-01
OSHA 1004
200
12
50
4
GC-FID
ST
NA SKC
GC-FID
ST
NA SKC
GC-FID
ST
226-81A
36
GC-FID
PS
575-002
64
ST
226-10
35
1-10
NIOSH 2555
2-Butanone (methyl ethyl ketone)
NIOSH 2500 1012 200
2-Butanone (methyl ethyl ketone)
OSHA 1004
2-Butanone (methyl ethyl ketone)
OSHA 16
300
10
10-200 3
200 1282 200
20(50)
varies 200
16.88 3
1.5
100
8(3.3)
15
8 100
30 min
15
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
144
Analytical Method SKC Collecting Equipment & Page Number
www.skcltd.com
GC-FID
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
2-Butanone (methyl ethyl ketone)
Agency Reference
Chem F File
Vol. (liter)
CLG/STEL (ppm)
200
OSHA 84
Butene
TWA (ppm)
TWA
3
OSHA CSI
Rate (ml/min)
CLG/ STEL
0.75
TWA
50
50
TWA (hrs)
1
15
Analytical Method SKC Collecting Equipment & Page Number GC-FID
ST
NA SKC
1
20
50 min
GC-FID
ST
226-01
35
10-50
varies
GC-FID
ST
226-01
35
48
100
8
GC-FID
ST
226-01
35
48
100
8
GC-FID
ST
226-01
35 35
2-Butoxyethanol (butyl CELLOSOLVE solvent)
OSHA 83
2-Butoxyethanol acetate (butyl CELLOSOLVE acetate)
OSHA 83
n-Butyl acetate
OSHA 07
n-Butyl acetate
n-Butyl acetate
sec-Butyl acetate
OSHA 07
200
10
sec-Butyl acetate
OSHA 1009
1750 200
12
sec-Butyl acetate
OSHA 1009
1750 200
t-Butyl acetate
OSHA 07
200
10
t-Butyl acetate
OSHA 1009
1750 200
12
t-Butyl acetate
OSHA 1009
1750 200
n-Butyl acetate (esters I)
NIOSH 1450 1272 150
sec-Butyl acetate (esters I)
NIOSH 1450
200
1-10
10-200
varies
t-Butyl acetate (esters I)
NIOSH 1450
200
1-10
10-200
Butyl acrylate
OSHA PV2011
12
50
n-Butyl acrylate
NON 54
5
n-Butyl alcohol
OSHA 07
sec-Butyl alcohol
t-Butyl alcohol
n-Butyl alcohol (alcohols combined)
sec-Butyl alcohol (alcohols combined)
50
CLG/STEL (ppm)
2-10
2-Butoxyethanol (alcohols IV)
NIOSH 1403 1275 5 (skin)
www.skcinc.com for updates
Time
CLG/ STEL
150
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
OSHA 1009
1750 150
12
0.75
50
50
4
15
GC-FID
ST
226-01
35
OSHA 1009
1750 150
13.07
13.07
8
15
GC-FID
PS
575-002
64
GC-FID
ST
226-01
35
50
50
4
15
GC-FID
ST
226-01
35
12.74
12.74
8
15
GC-FID
PS
575-002
64
GC-FID
ST
226-01
35
50
50
4
15
GC-FID
ST
226-01
35
13.09
13.09
8
15
GC-FID
PS
575-002
64
10-200
10-200
varies
varies
GC-FID
ST
226-01
35
GC-FID
ST
226-01
35
varies
GC-FID
ST
226-01
35
4
GC-FID
ST
226-73
36
200
8(3.3)
20(50) 0.75 1-10
8(3.3)
10
3
20
200
8
15
GC-FID
ST
226-81A
36
100
10
1
20
200
8
5
GC-FID
ST
226-01
35
OSHA 07
150
10
GC-FID
ST
226-01
35
OSHA 07
100
10
200
8(3.3)
GC-FID
ST
226-01
35
NIOSH 1405
50 (skin)
2-10
GC-FID
ST
226-01
35
NIOSH 1405
100
150
2-10
GC-FID
ST
226-01
35
t-Butyl alcohol (alcohols I)
NIOSH 1400
100
150
10
GC-FID
ST
226-01
35
n-Butyl alcohol (alcohols II)
NIOSH 1401
50
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
35
sec-Butyl alcohol (alcohols II)
NIOSH 1401
150
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
35
Butyl benzyl phthalate
100
15
1-10
20(50) 0.75
20(50) 3
20(50)
8(3.3)
10-200 2-10
10-200
15
varies 10-200
20(50)
varies
varies
8(3.3)
OSHA CSI
180
1000
3
HPLC-UV
F/CST
225-706
79
Butyl butryrate
OSHA PV2090
10
200
50 min
GC-FID
ST
226-01
35
Butyl carbitol
OSHA PV2095
10
200
50 min
GC-FID
ST
226-01
35
Butyl carbitol acetate
OSHA PV2095
10
200
50 min
GC-FID
ST
226-01
35
960
2000
IC-UV
F/CST
225-802 Ω
73
GC-FID
PS
575-001
64
Butyl CELLOSOLVE acetate (see 2-butoxyethanol acetate)
Butyl CELLOSOLVE solvent (see 2-butoxyethanol)
t-Butyl chromate (as CrO3)
n-Butyl glycidyl ether
NIOSH 1616
n-Butyl glycidyl ether
OSHA 07
5.6 (15 min) 1125 50
3
15
GC-FID
ST
226-01
35
10
20(50)
200 8(3.3)
15
GC-FID
ST
226-01
35 35
t-Butyl glycidyl ether
OSHA CSI
10
200
50 min
GC-FID
ST
226-01
Butyl isocyanate
OSHA CSI
15
50
5
HPLC-UV
ST
NA SKC
GC-FID
ST
226-01
35
GC-FPD
ST
226-109
37
GC-FPD
ST
226-109
37
GC-FPD
CF/CST 225-9007
61
10
OSHA PV2080
0.5
NIOSH 2525
Butyl mercaptan (butanethiol)
10
OSHA CSI NIOSH 2542 1330
n-Butyl mercaptan (mercaptans) t-Butyl methyl ether
Butyl ziram N-t-Butyl-2-benzothiazolesulfenamide Butylamine
n-Butylamine
Butylated hydroxytoluene
1.5
50 min 50
25 12
100
15 1
200
8
60
OSHA CSI
96
200
8
GC-FID
ST
226-37
36
OSHA PV2065
180
1000
3
HPLC-UV
ST
226-30-16
35
OSHA CSI
120
1000
2
HPLC-UV
F/CST
225-709
79
5
GC-FID
ST
226-53
36
15
5 (C)
OSHA CSI
5
5
NIOSH 2012 OSHA CSI NIOSH 5523 1404
1,3-Butylene glycol (glycols)
200 1
0.5 (15 min) 48
OSHA PV2108
sec-Butylbenzene
1000
GC-FID
ST
226-53
36
100
15 1000
1000 100 min
GC-FID
ST
226-57
36
6
100
1
GC-FID
ST
226-01
35
60
1000
1
GC-FID
ST
226-57
36 37
o-sec-Butylphenol
OSHA CSI
10
100
1.6
HPLC-UV
ST
226-95
p-tert-Butylphenol
OSHA PV2085
20
200
100 min
GC-FID
ST
226-95
37
Butyltin trichloride
OSHA ID 217SG
240
1000
4
AA-GF
ST
226-30-16
35
p-tert-Butyltoluene
OSHA 07
p-tert-Butyltoluene (hydrocarbons, aromatic)
NIOSH 1501
1129 10 10
20
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
35
1-29
1-29
10-200
10-200
varies
varies
GC-FID
ST
226-01
35
Butyraldehyde
ASTM D 5197
varies
500-1200
5 min-24 hrs
HPLC-UV
ST
226-120
or
Butyraldehyde (aldehydes, screening)
NIOSH 2539
5
20
4
GC-FID & GC-MS
ST
226-118
37
16.5
4
HPLC-UV
PS
500-100
67
OSHA CSI
18
100
3
GC-FID
ST
226-15
35
OSHA CSI
9.6
20
8
GC-FID
ST
226-01
35
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Butyraldehyde
Butyric acid beta-Butyrolactone gamma-Butyrolactone
225-1
87
C/HLD
225-1
87
C/HLD
225-1
87
C/HLD
225-1
87
ST
226-119
37
OSHA 83
t-Butyl ethyl ether (ethyl tert-butyl ether)
n-Butyl mercaptan
C/HLD
OSHA 83 OSHA ID 215 (V2) 1439 0.005 mg/m3
n-Butyl lactate
B
8
Cadmium
OSHA ID 189 1456 5 μg/m3
960
2000
8
AA
F/CST
225-3-01
77
C/HLD
225-1
87
Cadmium (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
LFC
13-2000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Cadmium (elements by ICP HNO3 digestion)
NIOSH 7303
3-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cadmium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1280 LFC
13-2000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cadmium (elements on wipes)
NIOSH 9102
wipe
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
Cadmium & compounds (as Cd)
NIOSH 7048 1467 LFC
Cadmium dust (as Cd)
OSHA ID 121
480
30
1000
2000
8
15
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
0.2 mg/m3 0.5 mg/m3 960
30
2000
2000
8
15
AA
F/CST
225-3-01
77
C/HLD
225-1
87
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
145
Sampling Guide SAMPLING ∞
www.skcinc.com for updates C
Chemical Hazard
Passive Guide
Agency Reference
Agency Standard Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
Rate (ml/min)
CLG/ STEL
TWA
0.2 mg/m3 0.5 mg/m3 960
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA ID 206
0.1 mg/m3 0.3 mg/ m3 (C)
480
2000
4
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
varies
5-200
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Calcium (elements by ICP HNO3 digestion)
NIOSH 7303
2-10,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 varies
5-200
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium (see specific compounds)
NIOSH 7020
varies
varies
varies
varies
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium & compounds (as Ca)
NIOSH 7020
varies
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
600
2000
5
AA-GF
F/CST
225-3-01
77
C/HLD
225-1
87 87
OSHA CSI
8
15
Analytical Method SKC Collecting Equipment & Page Number
OSHA ID 206
Calcium bromide (see dust, total & respirable nuisance)
2000
CLG/STEL (ppm)
Cadmium fume (ICP analysis of metal/metalloid particulates from solder operations)
OSHA CSI
2000
TWA (hrs)
Cadmium dust (as Cd)
Calcium arsenate (as As)
30
TWA
Time
CLG/ STEL
Calcium carbonate
OSHA ID 121
15 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
Calcium carbonate (calcium)
NIOSH 7020
2 mg/m3
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium carbonate (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
C/HLD CST
225-1 225-3LF
87 86
Calcium carbonate (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
Calcium carbonate (see dust, total & respirable nuisance) Calcium cyanamide
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium hydroxide
OSHA ID 121
5 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium hydroxide (calcium)
NIOSH 7020
2 mg/m3
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium oxide
OSHA ID 121
5 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium oxide (calcium)
NIOSH 7020
2 mg/m3
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium oxide (elements by ICP HNO3 digestion)
NIOSH 7303
2 mg/m3
3-10,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium silicate (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT
225-8-01
73
C/HLD
225-1
87
Calcium silicate (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
35
CST
225-32
87
Calcium hydroxide (see dust, total & respirable nuisance)
Calcium sulfate (see dust, total & respirable nuisance) Camphor
Camphor (ketones II ) Camphor (ketones II)
Caprolactam Capsaicin Captafol (difolatan)
OSHA 07
1130 2 mg/m3
10
20(50)
8(3.3)
GC-FID
ST
226-01
NIOSH 2553
2
1-25
10-200
varies
GC-FID
ST
NA SKC
NIOSH 1301
2
10
20(50)
8(3.3)
GC-FID
ST
226-01
OSHA PV2012
100
1000
100 min
HPLC-UV
ST
226-57
36
NIOSH 5041
480
HPLC-FD
FLT
225-16
79
OSHA CSI
240
1000
4
GC-ECD
ST
226-30-16
35
15
1000
1000
8
15
35
Captan
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Captan
OSHA PV2093
60
1000
1
HPLC-UV
ST
226-30-16
35
240
1000
4
HPLC-UV
ST
226-58
or
ST
226-30-16
35
120
1000
2
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
Captan (organonitrogen pesticides)
5 mg/m3
NIOSH 5601
Carbadox
OSHA CSI
Carbaryl
ASTM D 4861
Carbaryl (organonitrogen pesticides)
NIOSH 5601
5 mg/m3
240
1000
4
HPLC-UV
ST
226-58
or
ST
226-30-16
35
Carbaryl (Sevin)
NIOSH 5006
5 mg/m3
240
1000
4
VAS
F/CST
225-706
79
C/HLD
225-1
87
Carbaryl (Sevin)
OSHA 63
5 mg/m3
60
1000
1
HPLC-UV
ST
226-30-16
35 36 ST
226-30-16
35
OSHA CSI
120
1000
2
GC-FID
ST
226-56
NIOSH 5601
240
1000
4
HPLC-UV
ST
226-58
or
Carbitol
OSHA PV2013
10
200
50 min
GC-FID
ST
226-01
35
Carbitol acetate
OSHA PV2013
10
200
50 min
GC-FID
ST
226-01
35
Carbofuran
ASTM D 4861
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
Carbofuran (organonitrogen pesticides)
NIOSH 5601
0.1 mg/m3
240
1000
4
HPLC-UV
ST
226-58
or
ST
226-30-16
35
Carbon black
NIOSH 5000
3.5 mg/m3
360
1500
4
GR
FLT SCN
225-8-01 225-26
73 87
CST C/HLD
225-3LF 225-1
86 87
Carbon black
OSHA ID 196
3.5 mg/m3
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
SB
263-03
52
Carbazol Carbendazim (organonitrogen pesticides)
Carbon dioxide
OSHA ID 172 1026 5000
Carbon dioxide (by portable GC)
NIOSH 6603 1027 5000 NIOSH 1600
1
Carbon monoxide
OSHA ID 209
50
Carbon monoxide
OSHA ID 210 1021 50
Carbon tetrachloride
Carbon tetrachloride
OSHA 07
Carbon tetrachloride (hydrocarbons, halogenated)
NIOSH 1003
Carbon disulfide
Carbon tetrabromide
varies
varies
10-50
300
4-8
15
GC-TCD
SB
253-03
or
30,000
varies
varies
20-100
20-100
varies
varies
P GC-TCD
SB
232 Series
50
10
10
3
20(50)
200
8(3.3)
15
GC-FPD
ST
226-01
35
DRT
226-44
36
DRI
DRI
805-18972 SB SB
253-10 263-10
or 52
PK
228 Series
varies
varies
10-50
1000
OSHA CSI
9
3
50
200
ASTM D 5466
6 1131 10
25
15
2 (1 hr)
varies 3
50
15
varies
varies
GC-DID
SB SB
252-10 262-10
or or
3
15
GC-ECD
ST
226-93
37
GC-MS
CAN
228 Series
15
GC-FID
ST
226-01
35
varies
GC-FID
ST
226-01
35
varies 200
5
10-200
Carbon, activated (see dust, total nuisance) Carbonyl fluoride
OSHA CSI
480
2000
4
ISE
IMP
225-36-2
59
IT
225-22
59
Carboxin
OSHA CSI
200
1000
3.3
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
NIOSH 1552
24
50
8
GC-FID
ST
226-01
35
C/HLD CST
225-1 225-3LF
87 86
3-Carene (terpenes)
Catechol (pyrocatechol)
OSHA PV2014
Cell fragments (bioaerosols) CELLOSOLVE acetate (see 2-ethoxyethyl acetate)
CELLOSOLVE solvent (see 2-ethoxyethanol) (alcohols IV)
Cellulose (paper fiber) (particulates, respirable)
100
1000
100 min
HPLC-UV
ST
226-57
36
15-150
15000
1-10 min
varies
STC
225-9820
81
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
NIOSH 1403 1273 NIOSH 0600 1038
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
146
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Cellulose (paper fiber) (particulates, total)
Agency Reference
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
Rate (ml/min)
CLG/ STEL
TWA
TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
Cellulose insulation
NIOSH 7404
varies
1000
varies
SEM
FLT/CL 225-1604
78
Cerium
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
Cesium hydroxide
OSHA CSI
960
2000
8
AA
F/CST
225-3-01
Chaetomium species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
Chaetomium species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
C
C/HLD
225-1
87
77
C/HLD
225-1
87
77
C/HLD
225-1
87
225-3-01
77
C/HLD
225-1
87
225-9611
103
Cellulose (see dust, total or respirable nuisance)
Chloramphenicol
OSHA CSI
Chlordane
0.5 mg/m3
NIOSH 5510
Chlordane
1000
1
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
150
1000
2.5
GC-ECD
ST CST C/HLD
226-107 225-2LF 225-1
37 86 87
FLT SCN
225-5 225-26
76 87
480
1000
8
GC-ECD
ST
226-30-16
35
Chlordane (non-occupational exposure)
ASTM D 4947 1417
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Chlordane (technical)
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Chlorinated & organonitrogen herbicides
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
Chlorinated & organonitrogen herbicides (hand wash)
NIOSH 9200
Chlorinated camphene (toxaphene)
NIOSH 5039
LFC
30
Chlorinated diphenyl ether (chlorinated diphenyl oxide)
NIOSH 5025
0.5 mg/m3
180
1000
Chlorinated diphenyl oxide
NIOSH 5025
0.5 mg/m3
90
Chlorinated hydrocarbons (screening)
NIOSH 2549
5
OSHA 67
1013 0.5 mg/m3
60
15
NA SKC F/CST
225-3-01
77
C/HLD
225-1
87
3
GC-ECD
F/CST
225-3-01
77
C/HLD
225-1
87
1000
1.5
GC-ECD
F/CST
225-3-01
77
C/HLD
225-1
87
20
4
GC-MS
ST
226-330
39
225-706
87
1000
15
GC-ECD
F/CST
79
C/HLD
225-1
NIOSH 6011 1332 0.5
1
90
15
1000
1000
1.5
15
IC
CF/CST 225-9006
61
C/HLD
225-1
87
Chlorine
OSHA ID 101 1052
1 (C)
240
15
1000
1000
4
15
ISE
IMP
225-36-2
59
IT
225-22
59
Chlorine (prefiltered)
OSHA ID 101 1289
1 (C)
240
15
1000
1000
4
15
ISE
IMP CST FLT
225-36-2 225-3-23** 225-2708**
59 86 74
IT SP
225-22 225-2901**
59 87
Chlorine dioxide
OSHA ID 202 1462 0.1
120
7.5
500
500
4
15
IC-ECN
IMP
225-36-2
59
IT
225-22
59
15
ISE
IMP
225-36-2
59
IT
225-22
59
GC-FID
ST
226-113
37
GC-FID
PS
575-001
or
PS
575-002
64
CYC
225-105
94
PK
228 Series
CST
225-32
PK
228 Series
IT
225-22
NIOSH 5014
Chlorine trifluoride
OSHA CSI
1-Chloro-1-nitropropane
OSHA CSI
1-Chloro-2-methyl benzene (o-chlorotoluene, OXSOL 10)
20
12
0.75 mg/m3 0.23 mg/m3 50
NON 55
15
8
1000 50
4
50
5-Chloro-2-methyl-4-isothiazolin-3-one (Kathon 886) 1-Chloro-4-(trifluoromethyl)benzene (parachlorobenzotrifluoride)
0.1
1500
0.5
Chlorine
Chlorinated terphenyl (60% chlorine)
720
GC-ECD GC-ECD
1000
7.5
6
OSHA CSI
200
500
100
4
HPLC-UV
ST
226-99
37
1
15
GC-FID
ST
226-01
35
2-Chloro-6-trichloromethyl pyridine (respirable dust)
OSHA CSI
15 mg/m3
480
1000
8
HPLC-UV
ST
226-30-16
35
2-Chloro-6-trichloromethyl pyridine (total dust)
OSHA CSI
5 mg/m3
varies
varies
varies
HPLC-UV
ST
226-30-16
35 35
Chloroacetaldehyde
NIOSH 2015
Chloroacetaldehyde
OSHA 76
Chloroacetic acid
1
3
200
15
GC-ECD
ST
226-15GWS
1 (C)
2.5
500
5
GC-ECD
ST
226-15GWS
35
NIOSH 2008
0.05
48
100
8
IC-ECN
ST
226-47-01
36 35
alpha-Chloroacetophenone (phenacylchloride)
OSHA CSI
12
200
1
HPLC-UV
ST
226-35-02
Chloroacetyl chloride
OSHA CSI
10
50
3.3
HPLC-UV
ST
NA SKC
o-Chloroaniline
OSHA CSI
5
20
4
HPLC-UV
ST
226-10
35
p-Chloroaniline
OSHA PV2109
6
100
1
HPLC-UV
ST
226-10
35
6
varies
varies
GC-MS
CAN
228 Series
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Chlorobenzene (monochlorobenzene)
ASTM D 5466
Chlorobenzene (monochlorobenzene)
OSHA 07
Chlorobenzene (monochlorobenzene) (hydrocarbons, halogenated)
NIOSH 1003
10
10-200
varies
GC-FID
ST
226-01
35
4-Chlorobenzotrifluoride
NIOSH 1026
0.1-10.0
10-200
varies
GC-FID
ST
226-01
35
4-Chlorobenzotrifluoride
OSHA CSI
6
100
1
GC-FID
ST
226-01
35
p-Chlorobenzotrifluoride
NIOSH 1026
0.1-10.0
10-200
varies
GC-FID
ST
226-01
35
p-Chlorobenzotrifluoride
OSHA CSI
6
100
1
GC-FID
ST
226-01
35
0.001 mg/m3 (10 hr)
48
100(200)
8(4)
GC-ECD
FLT ST
225-16 226-39
79 36
Chlorobiphenyl
1132 75
NIOSH 5503
Chlorobromomethane
OSHA CSI
200
5
20
4
GC-FID
ST
226-01
35
Chlorobromomethane (hydrocarbons, halogenated)
NIOSH 1003
200
5
10-200
varies
GC-FID
ST
226-01
35
Chlorodifluoromethane
OSHA CSI
1
50
20 min
GC-FID
ST
NA SKC
Chlorodiphenyl
OSHA CSI
60
1000
1
GC-ECD
ST
226-30-16
35
Chlorodiphenyl (21% Cl) (see polychlorinated biphenyls)
OSHA CSI
1
60
1000
1
GC-ECD
ST
226-30-16
35
0.5
60
1000
1
GC-ECD
ST
226-30-16
35
3
50
1
GC-FID
ST
226-09
35
1
10
20(50)
8(3.3)
GC-FID
ST
226-81A
36
6
varies
varies
GC-MS
CAN
228 Series
10
200
50 min
GC-FID
ST
226-01
GC-FID
ST
226-01
35
GC-ECD
IMP
225-36-2
59
GC-ECD
ST
226-125
38
Chlorodiphenyl (32% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chlorodiphenyl (42% Cl)
OSHA PV2089
Chlorodiphenyl (42% Cl) (see polychlorinated biphenyls)
NIOSH 5503
Chlorodiphenyl (48% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chlorodiphenyl (54% Cl)
OSHA PV2088
Chlorodiphenyl (54% Cl) (see polychlorinated biphenyls)
NIOSH 5503
Chlorodiphenyl (60% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chlorodiphenyl (62% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chloroethane (ethyl chloride)
NIOSH 2519
2-Chloroethanol (ethylene chlorohydrin)
NIOSH 2513
Chloroform (trichloromethane)
ASTM D 5466
Chloroform (trichloromethane)
OSHA 05
Chloroform (trichloromethane) (hydrocarbons, halogenated)
1062
NIOSH 1003 1269
bis-Chloromethyl ether
OSHA 10
Chloromethyl methyl ether
NON 29
50 (C) 2
15 50
1251
2.4
10-200 500
0.3
10
varies 100 min
20
4
15
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
87
Phone: +1-724-941-9701
35 59
References and abbreviations are found on pages 196-197.
www.skcinc.com
147
Sampling Guide SAMPLING ∞
www.skcinc.com for updates C
Chemical Hazard
Passive Guide
Chloromethyl methyl ether
Agency Reference
Agency Standard Chem F File
TWA (ppm)
CLG/STEL (ppm)
OSHA 10
4-Chloronitrobenzene (nitrobenzenes)
0.1 ppm
NIOSH 2005
Vol. (liter)
Rate (ml/min)
CLG/ STEL
TWA
Time
CLG/ STEL
TWA
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
50
500
100 min
GC-ECD
IMP
225-36-2
59
96
200
8
GC-FID
ST
226-10
35
Chloropentafluoroethane
OSHA CSI
2.5
50
50 min
GC-FID
ST
226-01
35
Chlorophene
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-35
35
o-Chlorophenol
OSHA CSI
40
200
3.3
HPLC-UV
ST
226-10
35
p-Chlorophenol
NIOSH 2014
24
50
8
HPLC-UV
ST
226-10
35
144
100
24
GC-MSD
ST
226-175
38
GC-ECD
ST
226-93
37
GC-FID
ST
226-01
35 35
Chloropicrin
NON 51
0.1
Chloropicrin
OSHA PV2103
0.1
NIOSH 1002
beta-Chloroprene
OSHA 07
1133 25
beta-Chloroprene
OSHA 112
25
o-Chlorostyrene
3 1 (15 min)
beta-Chloroprene
15 min 100
15
10
20(50)
8(3.3)
GC-FID
ST
226-01
6
50
2
GC-ECD
ST
226-111A
37
100 min 15
GC-FID
ST
226-01
35
20
OSHA CSI
200 1.5
3
200
200
Chlorothalonil
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Chlorothalonil
OSHA CSI
180
1000
3
HPLC-UV
F/CST
225-709
79
OSHA CSI
20
200
100 min
GC-FID
ST
226-01
35
o-Chlorotoluene Chlorotoluron
IT
225-22
59
C/HLD
225-1
87
ST
226-30-16
35
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
OSHA CSI
10
200
50 min
GC-FID
ST
226-01
35
Chlorpropham (organonitrogen pesticides)
NIOSH 5601
240
1000
4
HPLC-UV
ST
226-58
or
Chlorpyrifos (Dursban)
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
480
1000
8
GC-FPD
ST
226-30-16
35
240
1000
4
GC-FPD
ST
226-58
36
960
2000
8
IC-UV
F/CST
225-802 Ω
73
C/HLD
225-1
87
1000
4
VAS
F/CST
225-803
73
C/HLD
225-1
87
Chlorotrifluoroethylene
Chlorpyrifos (Dursban) Chlorpyrifos (organophosphorus pesticides) Chromic acid & chromates (as CrO3)
ASTM D 4861
OSHA 62 NIOSH 5600
1394 0.2 mg/m3
OSHA ID 215 (V2) 1439 0.005 mg/m3
15
Chromic acid & chromates (chromium hexavalent)
NIOSH 7600
1 μg/m3 (10 hr)
240
Chromic acid & chromates (chromium hexavalent)
NIOSH 7604
1 μg/m3 (10 hr)
960
2000
8
IC-ECN
F/CST
225-803
73
C/HLD
225-1
87
Chromium & compounds (as Cr)
NIOSH 7024 1457 0.5 mg/m3
10 - 1000
1000 - 3000
varies
AA-F
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-8410
77
Chromium (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
0.5 mg/m3
5-1000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
0.5 mg/m
Chromium (elements by ICP HNO3 digestion)
NIOSH 7303
8-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 0.5 mg/m3
5-1000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium (elements on wipes)
NIOSH 9102
wipe
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
3
Chromium acetate
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium carbonate
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium metal & insoluble compounds
OSHA ID 121 1043 1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77 87
Chromium metal & insoluble compounds
OSHA ID 125G
Chromium phosphate
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
Chromium soluble salts (except hexavalent)
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
960
2000
8
IC-UV
F/CST
225-802 Ω
73
C/HLD
225-1
87
varies
1000-5000
varies
IC
F/CST F/CST
225-802 225-709
or or
F/CST F/CST
225-1713 225-401
or 79
240
1000
4
VAS
F/CST
225-802
73
C/HLD
225-1
87
240
1000
4
IC-ECN
F/CST
225-802
73
C/HLD
225-1
87
Chromium trioxide (CR(VI))
OSHA ID 215 (V2) 1439 0.005 mg/m3
Chromium, hexavalent
ASTM D 6832
Chromium, hexavalent
NIOSH 7600 1032 1 μg/m3
(10 hr) Chromium, hexavalent
NIOSH 7604 1032 1 μg/m3
(10 hr) Chromium, hexavalent
NIOSH 7605
0.001 mg/m3 (10 hr)
1-400
1000-4000
varies
IC-PCD-UV
F/CST
225-802
73
C/HLD
225-1
87
Chromium, hexavalent
NIOSH 7703
0.001 mg/m3 (10 hr)
10-1200
1000-4000
varies
P VAS
F/CST
225-802
73
C/HLD
225-1
87
DPP
F/CST
225-802
73
C/HLD
225-1
87
IC-UV
FLT
225-8-01-1
or
FLT
225-1822
79
IC-UV
F/CST
225-802 Ω
73
C/HLD
225-1
87
225-7 225-1
79 87
CST
225-2LF
86
Chromium, hexavalent
OSHA ID 103
0.005 mg/m3 (C) 960
Chromium, hexavalent
OSHA W4001
0.005 mg/m3 (C)
Chromium, hexavalent (CR(VI)) Chromium, hexavalent (in settled dust) Chrysene
OSHA ID 215 (V2) 1439 0.005 mg/m3
OSHA 58
960 bulk
NIOSH 9101
0.2 mg/m3
30
2000 2000
2000
8
15
8
bulk
CLR or VAS or IC
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
Chrysene (polynuclear aromatic hydrocarbons by GC-MS)
ASTM D 6209
350 m3 (max)
225 L/min
1-24
GC-MS
PUF
226-131
43
FLT
225-1821
79
Chrysene (polynuclear aromatic hydrocarbons by GC)
NIOSH 5515
LFC
480
2000
4
GC-FID
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
Chrysene (polynuclear aromatic hydrocarbons by HPLC)
NIOSH 5506
LFC
480
2000
4
HPLC-UV
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
C/HLD
225-1
87
C/HLD
225-1
87
Chrysosporium species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Chrysosporium species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
Chrysotile (see asbestos fibers)
NIOSH 9000
bulk
Chrysotile fibers (see asbestos fibers)
NIOSH 7400
XRD
Cladosporium species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Cladosporium species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
Clopidol (respirable fraction)
OSHA CSI
5 mg/m3
varies
varies
varies
HPLC-UV
F/CST CYC
225-706 225-105
79 94
C/HLD
225-1
87
15 mg/m3
120
1000
2
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
480
1000
8
GC-FPD
ST
226-30-16
35
varies
varies
varies
GR
FLT CYC
225-8-01 225-105
73 94
C/HLD CST
225-1 225-3LF
87 86
Clopidol (total dust)
OSHA CSI
Co-Ral (coumaphos)
OSHA CSI
Coal dust (< 5% SiO2)
OSHA CSI
2.4 mg/m3/ (%SiO2+2)
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
148
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Agency Reference
Coal dust (> 5% SiO2)
OSHA ID 142
Coal tar naphtha (naphthas) Coal tar pitch volatiles
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
TWA
Rate (ml/min)
CLG/ STEL
TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
(10 mg/m3)/ (%SiO2+2)
varies
varies
varies
GR & XRD
F/CST CYC
NIOSH 1550
100
3
20
2.5
GC-FID
ST
OSHA 58
1076 0.2 mg/m3
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
225-803 225-105
73 94
C
C/HLD CST
225-1 225-3LF
87 86
225-2LF
86
226-01
35
225-7 225-1
79 87
CST
Cobalt
OSHA ID 213
0.1 mg/m3
480
2000
6
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
0.5 mg/m3 (dust, fume)
25-2000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Cobalt (elements by ICP HNO3 digestion)
NIOSH 7303
0.5 mg/m3 (dust, fume)
3-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 0.05 mg/m3
25-2000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt (elements on wipes)
NIOSH 9102
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
Cobalt & compounds (as Co)
NIOSH 7027
(dust, fume) wipe 960
2000
8
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt acetate
OSHA ID 125G
0.05 mg/m
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
Cobalt carbonyl
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt hydrocarbonyl
OSHA ID 121 1193 0.1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
0.1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
OSHA ID 121 1210 0.1 mg/m3
960
2000
8
AA or AES
F/CST
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
3
(as Co) Cobalt metal, dust & fume
OSHA ID 125G
Cobalt metal, dust & fume (as Co) Coke oven emissions
OSHA 58
0.15 mg/m3
225-3-01
77
C/HLD
225-1
87
225-7 225-1
79 87
CST
225-2LF
86
Command (dimethazone)
OSHA PV2066
60
1000
1
GC-ECD
ST
226-30-16
35
Copper (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
1 mg/m3 (dust) 0.1 mg/m3 (fume)
5-1000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Copper (elements by ICP HNO3 digestion)
NIOSH 7303
1 mg/m3 (dust) 0.1 mg/m3 (fume)
15-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Copper (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 1 mg/m3 (dust)
5-1000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Copper (elements on wipes)
NIOSH 9102
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
Copper dust Copper dusts & mists
0.1 mg/m3 (fume) wipe
NIOSH 7029
1 mg/m
3
480
1000
8
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA ID 125G
1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
Copper dusts & mists (as Cu)
OSHA ID 121 1205 1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Copper fume
NIOSH 7029
0.1 mg/m3
480
1000
8
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Copper fume
OSHA ID 121 1206 0.1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA ID 125G
0.1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
OSHA ID 206
0.1 mg/m3
480
2000
4
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
960
2000
8
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Copper fume Copper fume (ICP analysis of metal/metalloid particulates from solder operations) Corn starch (see dust, respirable nuisance) Coronene
OSHA CSI
Corundum (Al2O3) (see alpha-alumina [total dust]) Corundum (emery) (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
C/HLD CST
225-1 225-3LF
87 86
Corundum (emery) (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
141.5
28,300
5 min
varies
BI
225-9611
103
2664
7.4
6
GR
FLT
225-8-01
73
CST
225-3LF
86
225-8-01-1 73 SP 225-381 ♠ and IS 225-386 ♠ 96
Corynebacterium species (bacteria)
OSHA CSI
Cotton dust (raw)
OSHA CSI
1 mg/m3 1 mg/m3
Cotton Dust (raw)
OSHA CSI
Coumarin
OSHA CSI
Crag herbicide (respirable dust)
OSHA CSI
5 mg/m3
Crag herbicide (total dust)
OSHA CSI
15 mg/m
p-Cresidine (see 5-methyl-o-anisidine)
OSHA CSI
960
3
2
8
GR
FLT PPI PPI
225-27 225-388
with or
96
200
8
HPLC-UV
ST
226-30-04
35
varies
varies
varies
CLR
F/CST CYC
225-803 225-105
73 94
C/HLD
225-1
87
90
1500
1
CLR
F/CST
225-3-01
77
C/HLD
225-1
87
di-tert-butyl-p-Cresol
OSHA PV2108
100
1000
100 min
GC-FID
ST
226-57
36
Cresol (all isomers)
NIOSH 2546
10 mg/m3
24
100
4
GC-FID
ST
226-95
37
Cresol (all isomers)
OSHA 32
5 mg/m3
24
100
4
HPLC-UV
ST
226-95
37
Cresols (see Environmental Sampling Guide)
EPA TO-8
Cresylil acid (see cresol, all isomers)
VERT. ELUTRIATOR (NA SKC) and
OSHA CSI
Cristobalite
OSHA ID 142
varies
varies
varies
GR & XRD
F/CST CYC
225-803 225-105
73 94
C/HLD
225-1
87
NIOSH 7500 1370 0.05 mg/m
3
Cristobalite (silica, crystalline [respirable] by XRD )
400-1000
2500
varies
XRD
F/CST C/HLD
225-803 225-1
73 87
CYC
225-01-02
95
0.05 mg/m
3
Cristobalite (silica, crystalline by IR)
NIOSH 7602
400-800
2500
varies
IR
F/CST CYC
225-803 225-01-02
73 95
C/HLD
225-1
87
Cristobalite (silica, crystalline by VAS)
NIOSH 7601 1041 0.05 mg/m
3
400-800
2500
varies
VAS
F/CST CYC
225-803 225-01-02
73 95
C/HLD
225-1
87
Crocidolite fibers (see asbestos fibers)
NIOSH 7400
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
149
Sampling Guide SAMPLING ∞
www.skcinc.com for updates C
Agency Standard TWA (ppm)
CLG/STEL (ppm)
Rate (ml/min)
Chemical Hazard
Agency Reference
Crotonaldehyde
ASTM D 5197
varies
500-1200
5 min-24 hrs
HPLC-UV
ST
226-120
or
ST
226-119
37
Crotonaldehyde
NIOSH 3516
2
48
200
4
DPP
IMP
225-36-2
59
IT
225-22
59
Crotonaldehyde
OSHA 81
2
6
100
1
HPLC-UV
CF/CST 225-9019
61
C/HLD
225-1
87
Crotonaldehyde (aldehydes, screening)
NIOSH 2539
2
5
20
4
GC-FID & GC-MS
ST
226-118
37
226-30-16
35 C/HLD
225-1
87
OSHA PV2015
Cryolite (fluorides)
2.5 mg/m3
NIOSH 7902
Cumene (isopropyl benzene)
OSHA 07
Cumene (isopropyl benzene)
OSHA PV2137
Cumene (isopropyl benzene) (hydrocarbons, aromatic)
NIOSH 1501
1065 50
CLG/ STEL
Time
Passive Guide
Crufomate
Chem F File
Vol. (liter) TWA
TWA
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
60
1000
1
GC-FPD
ST
480
1000
8
ISE
CF/CST 225-9001
61
10
20(50)
8(3.3)
GC-FID
ST
226-01
35 35
50
24
200
2
GC-FID
ST
226-01
50 (skin)
1-30
10-200
8(3.3)
GC-FID
ST
226-01
35
Cumene hydroperoxide
OSHA CSI
120
1000
2
HPLC-UV
IMP
225-36-1
59
IT
225-22
59
Cunninghamella species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
C/HLD
225-1
87
Cunninghamella species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
960
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
C/HLD
225-1
87
Cupric carbonate as Cu (elements by ICP HNO3/ HClO4 ashing)
NIOSH 7300 1455
Curvularia species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Curvularia species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
Cyanamide
OSHA CSI
10
100
100 min
HPLC-UV
ST
226-30-18
35
Cyanazine
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
Cyanide (as Cn)
OSHA ID 120
120
1000
2
ISE
F/CST IT
225-3-01 225-22
77 59
IMP
225-36-2
59
Cyanides, aerosol & gas
NIOSH 7904
120
500
4
ISE
FLT IMP C/HLD
225-2705 ∆ 225-36-2 225-1
74 59 87
CST IT
225-2LF 225-22
86 59
GC-NPD
ST
226-117
37
GC-NPD
ST
226-117
37 C/HLD
225-1
87
C/HLD
225-1
87
C/HLD
225-1
87
ST
226-30
35
Cyanogen
5 mg/m3 5 mg/m (10 min) 3
12
OSHA PV2104
Cyanogen chloride
200 1
OSHA CSI
Cyanuric acid
NIOSH 5030
5
480
1000
8
HPLC-UV
F/CST
225-802
73
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
2.5-5
10-200
varies
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35 35
Cyclohexane (hydrocarbons, BP 36 to 216 C)
Cyclohexanol
OSHA 07
Cyclohexanol (alcohols combined)
NIOSH 1405
50 (skin)
1-10
10-200
varies
GC-FID
ST
226-01
Cyclohexanol (alcohols III)
NIOSH 1402
50
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Cyclohexanone
OSHA 01
1073 50
10
20(50)
8(3.3)
GC-FID
ST
226-110
37
Cyclohexanone (ketones I)
NIOSH 1300
25
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
1-10
10-200
varies
GC-FID
ST
NA SKC
1124 300
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
300
5-7
10-200
varies
GC-FID
ST
226-01
35
OSHA CSI
480
2000
4
HPLC-UV
F/CST
225-709
79
Cyclohexylamine
OSHA PV2016
20
200
100 min
GC-FID
ST
226-98
37
Cyclonite (RDX)
OSHA CSI
120
1000
2
HPLC-UV
F/CST
225-709
79
Cyclopentane
OSHA CSI
5
200
25 min
GC-FID
ST
226-01
35
Cyhexatin
OSHA ID 197SG
480
2000
4
AA-GF
F/CST C/HLD
225-709 225-1
79 87
OSHA PV2063
60
1000
60 min
GC-ECD
ST
226-30-16
35
2,4-D (2-butoxyethyl ester)
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D (2-butoxyethyl ester)
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D (2,4-dichlorophenoxyacetic acid)
NIOSH 5001
10 mg/m3
180
1000
3
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
2,4-D (2,4-dichlorophenoxyacetic acid)
OSHA CSI
10 mg/m3
180
3000
1
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
D & C red #19
OSHA CSI
240
1000
4
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
480
1000
8
GC-ECD
ST
226-58
36
C/HLD
225-1
87
OSHA 07
1134 300
1 200
Cyclohexane
Cyclohexanone (ketones I)
NIOSH 1500 1268 300
1135 50
NIOSH 2555
Cyclohexene
OSHA 07
Cyclohexene (hydrocarbons, BP 36 to 216 C)
NIOSH 1500
N-Cyclohexyl-2-benzothiazolesulfenamide
Cypermethrin
1.5 mg/m3 (skin)
2,4-D acid
NIOSH 5602
2,4-D, BE
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D, EH
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D, ME (2,4-dichlorophenoxyacetic acid)
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
Dacthal
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
60
1000
1
GC-FID
ST
226-30-16
35
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
90
1500
1
GC-ECD
F/CST
225-709
79
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
GC-ECD
PUF
226-92
42
ICP
F/CST
225-3-01
77
C/HLD
225-1
87
225-1822 225-2LF
79 86
SP
225-27
87
C/HLD
225-1
87
87
DAP (diallyl phthalate)
10
OSHA CSI
DBP (see dibutyl phthalate)
OSHA 104
p,p-DDE
ASTM D 4861
DDT
OSHA CSI
p,p-DDT
ASTM D 4861
DDVP (dichlorvos)
ASTM D 4861
Decaborane
OSHA CSI
Decabromodiphenyl oxide
1 mg/m3
240-7200 0.05
NIOSH 2559
Decabromodiphenyl oxide
Decyl alcohol
480
1000-5000 30
2000
4-24 2000
4
15
48-960
2000
varies
HPLC-UV
FLT CST
200
1000
3
GC-ECD
F/CST
225-709
79
NIOSH 1500
2
10-50
varies
GC-FID
ST
226-01
35
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
OSHA CSI
n-Decane (hydrocarbons, BP 36 to 216 C) DEHP (see di-2-ethylhexyl phthalate)
OSHA 104
Dehydroabietic acid
OSHA CSI
180
2000
1.5
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
Dehydroisoandrosterone
OSHA CSI
240
1000
4
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
SCN ST
225-26 226-30-05
87 35
C/HLD
225-1
87
NIOSH 5514
0.1 mg/m3
480
1000
8
GC-FPD
FLT CST C/HLD
225-5 225-2LF 225-1
76 86 87
Demeton (Systox)
OSHA CSI
0.1 mg/m3
480
1000
8
GC-FPD
ST
226-30-16
35
Demosan
OSHA CSI
960
2000
8
GC-ECD
F/CST
225-709
79
Demeton
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
150
Analytical Method SKC Collecting Equipment & Page Number
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
DEP (see diethyl phthalate)
Agency Reference
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
Rate (ml/min)
CLG/ STEL
TWA
TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
D
OSHA 104
Desflurane
Di-(2-ethylhexyl) adipate
OSHA 106
1760
OSHA CSI
Di-(2-ethylhexyl) phthalate
5 mg/m3
3
50
1
GC-FID
ST
226-81A
36
180
1000
3
GC-FID
FLT C/HLD
225-17-04 225-1
74 87 35
GC-FID
ST
226-30-16
NIOSH 5020
180
1000
3
GC-FID
F/CST
225-3-01
77
OSHA PV2076
240
1000
4
GC-FID
ST
226-56
36
Di-n-octyl phthalate (DNOP)
OSHA 104
240
1000
4
GC-FID
ST
226-56
36
Di-n-octyl-phthalate (DNOP)
OSHA CSI
90
1000
1.5
GC-ECD
ST
226-56
36
OSHA CSI
Di-(2-ethylhexyl) phthalate (DEHP) Di-n-hexyl phthalate
60
15
1000
1000
1
15
CST
225-3LF
86
C/HLD
225-1
87
Di-sec-octyl phthalate (see di-[2-ethylhexy] phthalate) Di(ethyleneglycol) ethyl ether acrylate
1 mg/m3
OSHA PV2132
Diacetone alcohol
OSHA 07
Diacetone alcohol (alcohols combined)
NIOSH 1405
Diacetone alcohol (alcohols III)
NIOSH 1402
48
200
4
GC-FID
ST
226-110
37
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
50
1-10
10-200
varies
GC-FID
ST
226-01
35
50
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
6
100
1
GC
ST
NA SKC
1123 50
Diacetyl
NIOSH 2557
Diacetyl
OSHA 1012
0.05
9
3
50
200
3
15
GC-FID
ST
226-183
38
Diacetyl
OSHA 1013
0.05
9
3
50
200
3
15
GC-FID
ST
226-183
38
Diallyl disulfide
OSHA PV2086
10
20(50)
8(3.3)
GC-FPD
ST
226-110
37
Diallyl phthalate
OSHA CSI
60
1000
1
GC-FID
ST
226-30-16
35
226-30-18
35
1,2-Diaminoethane
NIOSH 2540
o-Dianisidine
OSHA 71
o-Dianisidine dyes (dyes, benzidine)
1235 LFC
NIOSH 5013
o-Dianisidine-based dyes
OSHA CSI
Diazinon
ASTM D 4861
Diazinon
OSHA 62
10
100
1.7
HPLC-UV
ST
100
1000
100 min
GC-ECD
CF/CST 225-9004
61
C/HLD
225-1
87
480
1000
8
HPLC-UV
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
480
1000
8
HPLC-UV
FLT C/HLD
225-17-04 225-1
74 87
CST
225-3LF
86
240-7200 1396
GC-NPD
PUF
226-92
42
480
1000
1000-5000 4-24 8
GC-FPD
ST
226-30-16
35
Diazinon (organophosphorus pesticides)
NIOSH 5600
0.1 mg/m3
240
1000
4
GC-FPD
ST
226-58
36
Diazomethane
NIOSH 2515
0.2
10
200
50 min
GC-FID
ST
226-23
35
Diazomethane
OSHA CSI
0.2
10
200
50 min
GC-FID
ST
226-23
35
Dibenz(a,h)anthracene
OSHA CSI
960
2000
8
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Dibenz(a,h)anthracene (polynuclear aromatic hydrocarbons by GC-MS)
ASTM D 6209
350 m3 (max)
225 L/min
1-24
GC-MS
PUF
226-131
43
FLT
225-1821
79
Dibenz(a,h)anthracene (polynuclear aromatic hydrocarbons by GC)
NIOSH 5515
480
2000
4
GC-FID
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
Dibenz(a,h)anthracene (polynuclear aromatic hydrocarbons by HPLC)
NIOSH 5506
480
2000
4
HPLC-FD
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
Diborane
NIOSH 6006
120
1000
2
PES
ST CST
226-151 225-32
38 87
FLT
NA SKC
and
35
PK
228 Series
IT
225-22
59
0.1
Dibrom
OSHA CSI
3 mg/m
60
1000
1
GC-FPD
ST
226-30-16
1,2-Dibromo-3-chloropropane (DBCP)
OSHA CSI
1 ppb
10
20(50)
8(3.3)
GC-ECD
ST
226-81A
36
100
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
GC-MS
CAN
228 Series
GC-ECD
ST
226-01
35
Dibromodifluoromethane (difluorodibromomethane)
NIOSH 1012
1,2-Dibromoethane (ethylene dibromide)
ASTM D 5466
1,2-Dibromoethane (ethylene dibromide)
NIOSH 1008
Dibutyl amine
3
6 0.045
0.13
50
varies 200
8
15
120
1000
2
GC-NPD
IMP
225-36-2
59
20(50)
8(3.3)
GC-FID
ST
226-10-04
35
240
2000
2
GC-FPD
FLT C/HLD
225-17-01 225-1
74 87
CST
225-2LF
86
NIOSH 5020
5 mg/m
3
100
1000
100 min
GC-FID
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA 104
5 mg/m3
240
1000
4
GC-FID
ST
226-56
36
0.1 mg/m3
480
1000
8
HPLC & AA-GF
ST C/HLD
226-30 225-1
35 87
F/CST
225-709
79 87
NIOSH 2007
2
Dibutyl phosphate
NIOSH 5017
1
Dibutyl phthalate Dibutyltin bis (isooctyl mercaptoacetate) (organotin compounds as Sn)
varies 3
10
OSHA CSI
2-Dibutyl aminoethanol (aminoethanol compounds I)
Dibutyl phthalate (DBP)
24
NIOSH 5504
2
Dibutyltin dilaurate (as Sn)
OSHA ID 218SG
500
1000
500 min
AA
F/CST
225-3-01
77
C/HLD
225-1
Dibutyltin maleate (as Sn)
OSHA ID 224SG
200
1000
200 min
AA-GF
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA CSI
200
1000
3.3
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Dicamba sodium salt
OSHA CSI
200
1000
3.3
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
1,1-Dichloro-1-fluoroethane
OSHA 113
1
50
20 min
GC-FID
ST
NA SKC
1,1-Dichloro-1-nitroethane
NIOSH 1601
GC-FID
ST
226-81A
36
1,1-Dichloro-1-nitroethane
OSHA 07
10
GC-FID
ST
226-81A
36
1,1-Dichloro-1-nitroethane
OSHA CSI
10
C/HLD
225-1
87
PK
228 Series
PK
228 Series
PK
228 Series
C/HLD
225-1
Dicamba
2
10
20(50) 15
8(3.3) 1000
15
10
20
8
GC-FID
ST
226-81A
36
NON 50
9
50
3
GC-FID
ST
226-09
35
3,3-Dichloro-1,1,1,2,2-pentafluoropropane
OSHA CSI
9
50
3
GC-FID
ST
226-01
35
1,3-Dichloro-1,1,2,2,3-pentafluoropropane
OSHA CSI
9
50
3
GC-FID
ST
226-01
35
Dichloroacetylene
OSHA CSI
GC-FID
ST
226-01
35
3,4-Dichloroaniline
OSHA CSI
73
2,2-Dichloro-1,1,1-trifluoroethane
1
200
5
100
1000
1.5
HPLC
F/CST
225-803
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
m-Dichlorobenzene
m-Dichlorobenzene
OSHA CSI
10
200
50 min
GC-FID
ST
226-01
o-Dichlorobenzene
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
o-Dichlorobenzene
OSHA 07
GC-FID
ST
226-01
p-Dichlorobenzene
ASTM D 5466
p-Dichlorobenzene
OSHA 07
o-Dichlorobenzene (hydrocarbons, halogenated)
NIOSH 1003
p-Dichlorobenzene (hydrocarbons, halogenated)
NIOSH 1003
3,3’-Dichlorobenzidine
OSHA 65
1122
50 (C)
3 6
1121 75
3 50
1.7 (LOQ) 1238
200 varies
0.75
20
3
15 varies
50
2.5
10-200
Phone: +1-724-941-9701
35
GC-MS
CAN
228 Series
15
GC-FID
ST
226-01
35
varies
GC-FID
ST
226-01
35
3
10-200
varies
GC-FID
ST
226-01
35
100
1000
100 min
GC-ECD
CF/CST 225-9004
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
35
61
87
References and abbreviations are found on pages 196-197.
www.skcinc.com
151
Sampling Guide SAMPLING ∞
www.skcinc.com for updates D
Chemical Hazard
Passive Guide
Dichlorodifluoroethane
TWA (ppm)
OSHA 07 ASTM D 5466
1,1-Dichloroethane (ethylidene chloride)
OSHA 07
1,1-Dichloroethane (hydrocarbons, halogenated)
1119 50
100
100
NIOSH 1003 1267 100
Dichloroethyl ether
NIOSH 1004
Dichloroethyl ether
OSHA 07
1,2-Dichloroethylene
OSHA 07
cis-1,2-Dichloroethylene
ASTM D 5466
1,2-Dichloroethylene (hydrocarbons, halogenated)
NIOSH 1003
trans-1,2-Dichloroethylene
NIOSH 2516
Dichlorofluoromethane Dichloromethane
Dichloromethane (see methylene chloride)
NIOSH 2516
Dichloromonofluoromethane (dichlorofluoromethane)
OSHA CSI
2,4-Dichlorophenoxyacetic acid (2,4-D)
5
1,2-Dichloropropane (propylene dichloride)
ASTM D 5466
1,2-Dichloropropane (propylene dichloride)
NIOSH 1013
1,3-Dichloropropene
TWA
Time
CLG/ STEL
TWA
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
3
100
30 min
GC-FID
ST
226-01
35
3
20
2.5
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
6
varies
varies
GC-MS
CAN
228 Series
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
10
10-200
varies
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
15
10
GC-FID
ST
226-01
35 35
1118 200
NIOSH 5001
Rate (ml/min)
CLG/ STEL
10
15
20
1000
8
15
3
20
2.5
GC-FID
ST
226-01
6
varies
varies
GC-MS
CAN
228 Series
200
3
10-200
varies
GC-FID
ST
226-01
DT
810-174D
10
3
20
2.5
GC-FID
ST
226-25
6
varies
varies
GC-MS
CAN
228 Series
ASTM D 5466
Dichloromonofluoromethane (dichlorofluoromethane)
Vol. (liter)
CLG/STEL (ppm)
1000
NIOSH 1018
1,1-Dichloroethane (ethylidene chloride)
cis-1,3-Dichloropropene
Chem F File
OSHA CSI
Dichlorodifluoromethane 1,2-Dichloroethane (ethylene dichloride)
Agency Reference
Agency Standard
226-09
PK
228 Series
PK
228 Series
PK
228 Series
35
35 35
10
3
20
2
GC-FID
ST
226-09
1000
3
20
2.5
GC-FID
ST
226-09 ♠
35
10 mg/m3
180
1000
3
HPLC-UV
F/CST
225-709
79
6
varies
varies
GC-MS
CAN
228 Series
LFC
ST
35
3
20
2.5
GC-ECN
ST
226-81A
36
OSHA CSI
5
200
25 min
GC-FID
ST
226-01
35
C/HLD
225-1
PK
228 Series
87
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
PK
228 Series
trans-1,3-Dichloropropene
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
PK
228 Series
3,4-Dichloropropionanilide
OSHA CSI
W
FLT
225-7
79
2,2-Dichloropropionic acid
OSHA PV2017
10
200
50 min
HPLC-UV
ST
226-10
35
Dichlorotetrafluoroethane
OSHA CSI
3
50
1
GC-FID
ST
226-09
35
ST
226-01
35
1,1-Dichlorotetrafluoroethane
OSHA CSI
2
50
40 min
GC-FID
ST
226-01
35
ST
226-09
35
1,2-Dichlorotetrafluoroethane (dichlorodifluoromethane)
NIOSH 1018
3
20
2.5
GC-FID
ST
226-01
35
ST
226-09
35
35
Dichlorotrifluoroethane
1000
NON 50
Dichlorvos (DDVP)
ASTM D 4861
Dichlorvos (DDVP)
OSHA 62
1395 1 mg/m3
9
50
3
GC-FID
ST
226-09
240-7200
1000- 5000
4-24
GC-ECD
PUF
226-92
42
480
1000
8
GC-FPD
ST
226-30-16
35 42
Dicloran
ASTM D 4861
240-7200
1000- 5000
4-24
GC-ECD
PUF
226-92
Dicofol
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Dicofol
OSHA CSI
W
SM TB
225-24
124
Dicrotophos
ASTM D 4861
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
Dicrotophos (Bidrin)
OSHA PV2099
480
1000
8
GC-FPD
ST
226-30-16
35
240
1000
4
GC-FPD
ST
226-58
36
10
100
100 min
GC-FID
ST
226-01
35
varies
varies
GR
FLT CST
225-8-01 225-3LF
73 86
C/HLD
225-1
87
C/HLD
225-1
87
Dicrotophos (organophosphorus pesticides) Dicyclopentadiene Dicyclopentadienyl iron (respirable dust) Dicyclopentadienyl iron (total dust) Dieldrin
OSHA PV2098 OSHA CSI
5 mg/m3
varies
OSHA CSI
15 mg/m3
960
2000
8
AA
F/CST
225-3-01
77
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
180
1500
2
GC-ECD
F/CST
225-709
79
C/HLD
225-1
87
ASTM D 4861
Dieldrin
0.25 mg/m3
OSHA CSI
Diesel emissions (see elemental carbon)
NIOSH 5040
Diesel exhaust particles (see elemental carbon)
NIOSH 5040
Diesel particulate matter
ASTM D 6877
Diesel particulate matter
MSHA 30CFR57
Diesel particulate matter
MSHA 30CFR57
Diethanolamine
TOA-FID TOA-FID
varies
1000-4000
varies
EGA-TOS
DPM
225-317
or
F/CST
225-401
84
350 μg/m3 (total carbon)
varies
2000
varies
TOA-FID
DPM C/HLD
225-317 225-1
84 87
CYC
225-105
85
350 μg/m (total carbon)
varies
varies
varies
TOA-FID
F/CST C/HLD
225-401 225-1
84 87
CYC
225-100
94
IT
225-22
59
IT
225-22
59
C/HLD
225-1
87
3
10
100
100 min
HPLC-UV
ST
226-30-18
35
NIOSH 3509 1006 3
240
1000
4
IC
IMP
225-36-1
59
NIOSH 1610
0.25-3
10-200
varies
GC-FID
ST
226-01
35
OSHA PV2018
Diethanolamine (DEA) (aminoethanol compounds II) Diethyl ether (ethyl ether)
0.25 mg/m3
NIOSH 5600
Diethyl ketone (3-pentanone)
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
NA SKC
Diethyl phthalate (DEP)
OSHA 104
240
1000
4
GC-FID
ST
226-56
36
Diethyl sulfate
OSHA CSI
15
1000
15 min
GC-FID
ST
226-10
35 37
1697 25
10
3
200
200
50 min
15
HPLC
ST
226-96
24
3
50
200
8
15
GC-FID
ST
226-10
35
2
GC-FID
ST
226-10-04
35
20(50)
8(3.3)
GC-FID
ST
226-10-04
35
1000
100 min
GC-NPD
IMP
225-36-1
59
Diethylamine
OSHA 41
Diethylamine (amines, aliphatic)
NIOSH 2010
10
OSHA CSI
10
24
200
NIOSH 2007
10
10 100
2-Diethylaminoethanol 2-Diethylaminoethanol (aminoethanol compounds I) Diethylaminopropylamine (DEP)
25
OSHA CSI
Diethylene dioxide (see dioxane) Diethylene ether (see dioxane) Diethylene glycol (glycols)
60
1000
1
GC-FID
ST
226-57
36
Diethylene glycol methyl ether
NIOSH 5523 1387 OSHA CSI
10
100
100 min
GC-FID
ST
226-01
35
Diethylene glycol monobutyl ether acetate
OSHA CSI
9.6
100
1.6
GC-FID
ST
226-01
35
Diethylene glycol monoethyl ether
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Diethylenetriamine
OSHA 60
10
100
100 min
HPLC-UV
ST
226-30-18
35
1285
Difluorodibromomethane
NIOSH 1012
100
6
50
2
GC-FID
ST
226-01
35
Difluorodibromomethane
OSHA 07
100
10
20
8
GC-FID
ST
226-01
35
Diglycidyl ether of bisphenol A
OSHA CSI
240
1000
4
HPLC-UV
F/CST
225-709
79
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
152
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Diglycolamine Diglyme
Agency Reference
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
TWA
OSHA CSI
20
Rate (ml/min)
CLG/ STEL
TWA
100
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
3
GC-NPD
IMP
225-36-1
59 35
OSHA CSI
20
200
100 min
GC-FID
ST
226-01
Dihexyl phthalate
OSHA PV2076
240
1000
4
GC-FID
ST
226-56
36
Dihydrocapsaicin
NIOSH 5041
480
HPLC-FD
FLT
225-16
79
8(3.3)
GC-FID
ST
226-01
35 35
Diisobutyl ketone
OSHA 07
Diisobutyl ketone (ketones I)
NIOSH 1300
Diisobutyl ketone (ketones I)
OSHA 42
1000
1000
8
15
1116 50
10
20(50)
25
10
20(50)
8(3.3)
GC-FID
ST
226-01
1-10
10-200
varies
GC-FID
ST
NA SKC
NIOSH 2555
Diisocyanates
15
1458
240
1000
1000
4
15
HPLC-UV or CF/CST 225-9002 HPLC-FD C/HLD 225-1
225-22
59
CST
225-32
87
or 87
CF/CST 225-9013
61
IT
225-22
59
120
1000
2
GC-FID
IMP
225-36-1
59
Dimethazone
OSHA PV2066
60
1000
1
GC-ECD
ST
226-30-16
35
Dimethoate
OSHA PV2113
480
1000
8
GC-FPD
ST
226-30-16
35
OSHA CSI
17
50
5.7
HPLC-UV
ST
226-30-04
35
1000
2
20
1.5
GC-FID
ST
226-01
35
1115 1000
2
20
1.5
GC-FID
ST
226-01
35
OSHA PV2019
20
200
100 min
GC-FID
ST
226-01
35
NIOSH 5022
960
2000
8
IC-AA
FLT C/HLD
225-17-01 225-1
74 87
CST
225-2LF
86
12
1000
12 min
GC-FPD
SB
253-10
or
SB
263-10
52
6
100
1
GC-FID
ST
226-01
35
C/HLD IT
225-1 225-22
87 59
ST
226-119
37
Diisopropylamine
5
15
D
IT
OSHA CSI
2,5-Dimethoxyaniline Dimethoxymethane (methylal)
NIOSH 1611
Dimethoxymethane (methylal)
OSHA 07
Dimethyl adipate Dimethyl arsenic acid (arsenic, organo-) Dimethyl disulfide
NON 42
Dimethyl disulfide
OSHA CSI
Dimethyl glutarate
OSHA PV2020
Dimethyl phthalate (DMP)
1413
5 mg/m3
OSHA 104
Dimethyl succinate
OSHA PV2021
Dimethyl sulfate
NIOSH 2524 1284 0.1 (8 hrs.)
Dimethyl sulfate
OSHA PV2147
Dimethyl sulfide
NON 42
Dimethyl sulfide
OSHA CSI
Dimethyl sulfoxide
OSHA CSI
Dimethyl-1,2-dibromo-2,2-dichloroethyl phosphate
OSHA CSI
1 1413
3 mg/m3
200
100 min
GC-FID
ST
226-01
35
240
1000
4
GC-FID
ST
226-56
36
20
200
100 min
GC-FID
ST
226-01
35
12
50
4
GC-ECN
ST
226-114
37 37
10
100
100 min
GC-FPD
ST
226-115
12
1000
12 min
GC-FPD
SB
263-10
52
5
20
4
GC-FPD
ST
226-01
35
10
100
100 min
GC-FID
ST
226-01
35
60
1000
1
GC-FPD
ST
226-30-16
35
10
200
50 min
GC-ECD
ST
226-35-03
36
N,N-Dimethyl-p-toluidine (amines, aromatic)
NIOSH 2002 1055
96
200
8
GC-FID or GC-NSD
ST
226-10
35
Dimethylacetamide
NIOSH 2004 1695 10
48
100
8
GC-FID
ST
226-10
35
OSHA CSI
10
60
1000
1
GC-FID
ST
226-10
35
10
24
50
8
GC-FID
ST
226-10
35
1696 10
10
20
8
HPLC
ST
226-96
37
2,3-Dimethyl-2,3-dinitrobutane
0.15 mg/m3 OEL
20
NON 44
Dimethylacetamide Dimethylamine
NIOSH 2010
Dimethylamine
OSHA 34
2-Dimethylamino ethanol
NIOSH 2561
10-24
20-100
varies
GC-FID
ST
226-94
37
1-Dimethylamino-2-propanol
NIOSH 2561
10-24
20-100
varies
GC-FID
ST
226-94
37
4-Dimethylaminoazobenzene
OSHA CSI
60
1000
1
HPLC-UV
F/CST IMP
225-706 225-36-1
79 59
Dimethylaminobenzene 2,4-Dimethylaminobenzene (amines, aromatic)
OSHA CSI
5
24
50
8
GC-FID
ST
226-10
35
NIOSH 2002
2
24
50
8
GC-FID or GC-NSD
ST
226-10
35
GC-FID
ST
226-01
35
GC-FID
ST
226-98
37
15
GC-FID or GC-NSD
ST
226-10
35
N,N-Dimethylaniline
OSHA 07
5
10
N,N-Dimethylaniline
OSHA PV2064
5
30
N,N-Dimethylaniline (amines, aromatic)
2,5-Dimethylbenzaldehyde
NIOSH 2002 1054 5
trans-1,2-Dimethylcyclohexane
N,N-Dimethylethanolamine N,N-Dimethylethylamine
3
50
8(3.3)
15
2.5 200
8
500-1200
5 min-24 hrs
HPLC-UV
ST
226-120
or
20(50)
8(3.3)
GC-FID
ST
226-01
35
GC-FID
PS
575-001
64
10-24
20-100
varies
GC-FID
ST
226-94
37
OSHA CSI
24
50
8
GC-FID
ST
226-10-04
35
OSHA PV2096
40
100
40 min
GC-NPD
ST
226-18
35
10
24
50
8
GC-FID
ST
226-10
35
1271 10
9.6
GC-NPD
ST
226-01
35
N,N-Dimethylformamide
NIOSH 2004
N,N-Dimethylformamide
OSHA 66
1,1-Dimethylhydrazine
NIOSH 3515
1,1-Dimethylhydrazine
OSHA CSI
Dimethyltin dichloride
NIOSH 5526
Dinitolmide
OSHA CSI
Dinitro-o-cresol
OSHA CSI
4,6-Dinitro-o-sec-butyl phenol
OSHA CSI
Dinitrobenzene (all isomers)
OSHA CSI
2-(2,4-Dinitrophenoxy)ethanol
OSHA CSI
Dinitrotoluene (DNT)
OSHA 44
n-Dioctyl phthalate (DNOP)
OSHA 104
Dioxane (diethylene dioxide)
NIOSH 1602
Dioxane (diethylene dioxide)
OSHA 07
Dioxathion (Delnav)
OSHA CSI
Dioxins (including PHDDs, PCDDs, PBDDs) (see Environmental Sampling Guide)
EPA TO-9A
Diphenyl ether
200
200
10
OSHA CSI NIOSH 2561
N,N-Dimethylethanolamine
24
20(50)
varies
ASTM D 5197
trans-1,4-Dimethylcyclohexane
Diphenyl
10
3
3
20
200
8
15
0.06 (120 min)
60
1000
1
VAS
IMP
225-36-2
59
IT
225-22
59
0.5
96
200
8
CLR
IMP
225-36-2
59
IT
225-22
59
0.1 mg/m3
60
GC-FPD
ST
226-30-16
35
0.2 mg/m3
1 mg/m3 1.5 mg/m3 1 (30 min) 1114 100
60
250
1000
4
60
240
1000
4
HPLC
F/CST
225-706
79
C/HLD
225-1
87
180
1500
2
HPLC-UV
F/CST IT
225-3-01 225-22
77 59
IMP
225-36-1
59
24
50
8
HPLC-UV
ST
226-95
37
60
1000
1
HPLC-UV
ST
226-30-16
35
10
20(50)
8(3.3)
HPLC-UV
ST
226-10
35
60
1000
1
GC-TEA
ST
226-56
36
240
1000
4
GC-FID
ST
226-56
36
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
480
1000
8
GC-FPD
ST
226-30-16
35
NIOSH 2530
0.2
30
100
5
GC-FID
ST
226-35-01
35
OSHA PV2022
0.2
20
200
100 min
GC-FID
ST
226-95
37
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
153
Sampling Guide SAMPLING ∞
www.skcinc.com for updates D
Chemical Hazard
Passive Guide
Agency Reference
p,p-Diphenyl methane diisocyanate (MDI) (see methylene bisphenyl isocyanate)
OSHA 47
2-Diphenylacetyl-1,3-indandione
OSHA CSI
Diphenylamine
OSHA 78
5,5-Diphenylhydantoin
OSHA CSI
Diphenylmethane-4,4’-diisocyanate (4,4-methylene bisphenyl isocyanate) (isocyanates)
Agency Standard Chem F File
TWA (ppm)
CLG/STEL (ppm)
1229
NIOSH 5521 1001 50 μg/m3
Vol. (liter)
Rate (ml/min)
CLG/ STEL
TWA
TWA
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
480
2000
4
HPLC-UV
F/CST
79
C/HLD
225-1
100
1000
100 min
HPLC-UV
CF/CST 225-9004
61
C/HLD
225-1
87
60
1000
1
HPLC-UV
FLT C/HLD
225-7 ‡ 225-1
79 87
CST
225-3LF
86
225-36-1
59
IT
225-22
59
37
87
200 μg/m3 480 (10 min) C
10
1000
1000
8
10
HPLC-ELCHM IMP & HPLC-UV
225-706
Dipropyl disulfide
OSHA PV2086
10
20(50)
8(3.3)
GC-FPD
ST
226-110
Dipropyl ketone
OSHA CSI
10
20
8
GC-FID
ST
NA SKC
87
Dipropylene glycol methyl ether
OSHA 07
1113 100
10
GC-FID
ST
226-01
35
Dipropylene glycol methyl ether
OSHA 101
100
10
100
100 min
GC-FID
ST
226-01
35
Dipropylene glycol methyl ether (glycol ethers)
NIOSH 2554
3-25
100-200
varies
GC-FID
ST
226-81A
36
Dipropylene glycol monomethyl ether (glycol ethers)
NIOSH 2554
3-25
100-200
varies
GC-FID
ST
226-81A
36
Diquat
OSHA CSI
120
1000
2
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
Direct black 38
OSHA CSI
100
1000
100 min
HPLC
F/CST
225-706
79
C/HLD
225-1
87
480
1000
8
HPLC
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
Direct black 38 (dyes, benzidine)
NIOSH 5013
LFC
3
20(50)
200
8(3.3)
15
Direct blue
OSHA CSI
60
1000
1
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Direct blue 2
OSHA CSI
100
1000
100 min
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Direct blue 6
OSHA CSI
100
1000
100 min
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Direct blue 6 (dyes, benzidine)
NIOSH 5013
LFC
480
1000
8
HPLC
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
Direct blue 8 (dyes, benzidine)
NIOSH 5013
LFC
480
1000
8
HPLC
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
1000 1000 1000 1000
3 3 100 min 8
HPLC-UV
LFC
180 180 100 480
F/CST F/CST F/CST FLT C/HLD F/CST FLT C/HLD FLT C/HLD F/CST F/CST F/CST ST ST ST F/CST PUF ST ST ST
225-706 225-706 225-709 225-17A 225-1 225-709 225-17A 225-1 225-17A 225-1 225-709 225-709 225-709 226-30-16 226-58 226-30-16 225-706 226-92 226-58 226-73 226-01
79 79 79 74 87 79 74 87 74 87 79 79 79 35 36 35 79 42 or 36 35
C/HLD C/HLD C/HLD CST
225-1 225-1 225-1 225-3LF
87 87 87 86
C/HLD CST
225-1 225-3LF
87 86
CST
225-3LF
86
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
C/HLD
225-1
87
ST
226-30-16
35
ST ST ST ST STC FLT CYC FLT CYC FLT CYC FLT CST FLT CST FLT CST FLT C/HLD ST DPM F/CST C/HLD F/CST C/HLD F/CST F/CST W TMP
226-56 226-01 226-30 226-58 225-9820 225-8-01 225-01-02 225-8-01 225-105 225-8-01 225-01-02 225-8-01 225-2LF 225-8-01 225-2LF 225-8-01 225-2LF 225-17A 225-1 226-30-16 225-317 225-401 225-1 225-3-01 225-1 225-3-01 225-3-01 225-2414 225-2415
36 35 35 36 81 73 95 73 94 73 95 73 86 73 86 73 86 74 87 35 84 79 87 or 87 77 77 124 124
C/HLD CST C/HLD CST C/HLD CST C/HLD
225-1 225-3LF 225-1 225-3LF 225-1 225-3LF 225-1
87 86 87 86 87 86 87
C/HLD
225-1
87
C/HLD
225-1
87
CST
225-3LF
86
CYC CYC
225-105 225-100
85 84
F/CST
225-803
73
C/HLD C/HLD TMP
225-1 225-1 225-2403
87 87 or
Direct blue 98 Direct brown 31 Direct brown 95 Direct brown 95 (dyes, benzidine)
NIOSH 5013
Direct red 2 Direct red 2 (dyes, benzidine)
LFC
120 480
1000 1000
2 8
HPLC-UV
NIOSH 5013
Direct red 28 (dyes, benzidine)
NIOSH 5013
LFC
480
1000
8
HPLC
100 100 120 480 240 480 480 240-7200 240 12 2.5
1000 1000 1000 1000 1000 1000 2000 1000-5000 1000 50 20
100 100 min 2 8 4 8 4 4-24 4 4 2
HPLC-UV
1000 20(50) 1000 1000 15000 2500
1 8(3.3) 2 4 1-10 min varies
GC-TEA
varies
varies
varies
GR
375
2500
2.5
GR
720
1500
8
GR
Direct red 81 Disperse yellow 3 Disulfiram (tetraethylthiuram disulfide) Disulfoton Disulfoton (organophosphorus pesticides) Disyston 2,2’-Dithiobis(benzothiazole) Diuron Diuron (organonitrogen pesticides) Divinyl benzene Divinyl sulfide DMP (see dimethyl phthalate) DNOP (see di-n-octyl phthalate) DNT (dinitrotoluene) Dodecyl alcohol (lauryl alcohol) Dodine Dursban (chlorpyrifos)(organophosphorus pesticides) Dust, inorganic Dust, respirable (in workplace atmospheres) Dust, respirable nuisance Dust, respirable nuisance (particulates) Dust, total nuisance
OSHA CSI OSHA CSI OSHA CSI
OSHA CSI
OSHA CSI OSHA CSI OSHA CSI OSHA PV2105 NIOSH 5600
0.1 mg/m3
OSHA CSI OSHA CSI ASTM D 4861 NIOSH 5601
10 mg/m3
OSHA 89 OSHA CSI
HPLC-UV HPLC-UV HPLC
HPLC
HPLC-UV HPLC-UV GC-FPD GC-FPD GC-FPD HPLC-UV HPLC-UV HPLC-UV GC-FID GC
OSHA 104 OSHA 104
60 10 OSHA CSI 240 NIOSH 5600 0.2 mg/m3 0.6 mg/m3 240 15-150 ASTM D 4532 1418 varies OSHA 44
1.5 mg/m3
OSHA CSI
OSHA CSI
5.0 mg/m3
NIOSH 0600 1038 OSHA CSI
15 mg/m3
GC-FID HPLC-UV GC-FPD
varies GR
Dust, total nuisance (particulates)
NIOSH 0500 1035
120
2000
1
GR
Dust, total, particulates not otherwise regulated
NIOSH 0500 1035
120
2000
1
GR
Dyes, benzidine, o-tolidine, o-dianisidine
NIOSH 5013
480
1000
8
HPLC-UV
480 varies varies
1000 varies varies
8 varies varies
GC-FPD
Dyfonate Elemental carbon (diesel exhaust) Elemental carbon (diesel exhaust)
LFC
OSHA CSI MSHA NIOSH 5040
EGA-TOS TOA-FID
Elements by ICP Aqua Regia ashing (see specific element)
NIOSH 7301 ¥
varies
varies
1000-4000
varies
ICP-AES
Elements by ICP HNO3 digestion (see specific element) Elements by ICP HNO3/HClO4 ashing (see specific element) Elements on wipes (see specific element)
NIOSH 7303
varies
varies varies wipe
1000-4000 1000-4000
varies varies
ICP-AES
NIOSH 7300 1455 varies NIOSH 9102
www.skcltd.com
ICP-AES ICP-AES
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
154
Analytical Method SKC Collecting Equipment & Page Number
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Agency Reference
Elements qualitative Emery (corundum) (particulates, respirable)
OSHA ID 204
Emery (corundum) (particulates, total)
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
CLG/ STEL
TWA
Rate (ml/min) TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
2000 2500
8 2.5
XRF
NIOSH 0600 1038
480 375
NIOSH 0500 1035
120
2000
1
GR
F/CST FLT CYC FLT CST FLT CYC FLT CST ST BS CST SCN C/HLD ST ST ST
GR
225-3-01 225-8-01 225-01-02 225-8-01 225-2LF 225-8-01 225-105 225-8-01 225-3LF 226-30-16 225-9595 225-2LF 225-26 225-1 226-81A 226-01 226-170
77 73 95 73 86 73 94 73 86 35 105 86 87 87 36 35 38
225-2705 225-01-02
FLT CYC ST ST F/CST BI F/CST ST ST PUF ST F/CST F/CST F/CST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST CAN ST ST PS ST ST ST ST ST ST PS CAN ST ST
Emery (respirable dust)
OSHA CSI
5 mg/m3
varies
varies
varies
GR
Emery (total dust)
OSHA CSI
15 mg/m3
960
2000
8
GR
1000 12500 + 1000
1 5-30 4
GC-ECD
0.1 mg/m3
60 62.5-375 240
12 10 90-720
50 20 1500
4 8 1-8
GC-FID
ASTM D 5955 1419
varies
varies
varies
GR & FLT HPLC-UV & CYC HPLC-FD
ASTM D 6271
1503600 10 20 120 141.5 480 480 10
2500
1-24
HPLC-UV
Endosulfan (Thiodan) Endotoxins (bacteria in air) Endrin
OSHA PV2023 NON 48 NIOSH 5519
Enflurane (ethrane) Enflurane (ethrane) Environmental tobacco smoke (nicotine & 3-ethenylpyridine) Environmental tobacco smoke (respirable particles) Environmental tobacco smoke (solanesol, respirable particles) Epichlorohydrin Epichlorohydrin Epicoccum species (fungi, molds, spores) Epicoccum species (fungi, molds, spores) EPN EPN 1,2-Epoxyethylbenzene 1,2-Epoxypropane (see propylene oxide) 2,4,D-Esters Esters I (see specific compounds) Estradiol Estriol Estrone 1,2-Ethanediol (ethylene glycol) (glycols) 1,2-Ethanediol dinitrate 2-(2-methoxyethoxy)Ethanol Ethanolamine 3-Ethenylpyridine 3-Ethenylpyridine & nicotine Ethion (nialate) Ethion (organophosphorus pesticides) Ethoprop (organophosphorus pesticides) 1-Ethoxy-2-propanol 2-Ethoxyethanol (alcohols IV) 2-Ethoxyethanol (CELLOSOLVE solvent) 2-Ethoxyethanol (CELLOSOLVE solvent) (alcohols IV) 2-Ethoxyethyl acetate (CELLOSOLVE acetate) 2-Ethoxyethyl acetate (esters I) Ethrane (enflurane) Ethyl 2-cyanoacrylate Ethyl acetate Ethyl acetate Ethyl acrylate Ethyl acrylate Ethyl acrylate (esters I) Ethyl alcohol (ethanol) Ethyl alcohol (ethanol) Ethyl alcohol (ethanol) (alcohols I) Ethyl amyl ketone Ethyl benzene Ethyl benzene Ethyl benzene Ethyl benzene Ethyl benzene (hydrocarbons, aromatic) Ethyl bromide (bromoethane) Ethyl bromide (bromoethane) Ethyl butyl ketone (3-heptanone) Ethyl butyl ketone (3-heptanone) (ketones II ) Ethyl butyl ketone (3-heptanone) (ketones II) Ethyl CELLOSOLVE solvent (2-ethoxyethanol) Ethyl chloride Ethyl chloride Ethyl chloride
OSHA 103
1348
OSHA 29 NON 49
NIOSH 1010 OSHA 07
LFC 1112 5
OSHA CSI OSHA CSI
0.5 mg/m3 0.5 mg/m3
NIOSH 5012 OSHA CSI OSHA CSI
3
20(50) 100 1000 28,300 1000 1000 20(50)
200
8(3.3) 3.3 2 5 min 8 8 8(3.3)
varies GC-ECD
GC-FID GC-NSD
15
GC-FID GC-FID varies varies GC-FPD GC-FPD GC-FID
225-1 225-1 225-3LF 225-1
87 87 86 87
C/HLD CST C/HLD
225-1 225-3LF 225-1
87 86 87
VT ◊ FLT ST
225-9598A 225-5 226-104
105 76 37
74 95
C/HLD CST
225-1 225-3LF
87 86
225-2705 225-01-02 226-01 226-01 225-3-01 225-9611 225-709 226-30-16 226-35
74 95 35 35 77 103 79 35 35
CST C/HLD
225-3LF 225-1
86 87
C/HLD
225-1
87
C/HLD
225-1
87
226-92 226-01 225-706 225-706 225-706 226-57 226-35-03 226-01 226-30-18 226-170 226-93 226-30-16 226-58 226-58 226-01 226-01 226-01 226-01 226-01 226-01 226-01 226-98 226-01 226-01 226-81A 226-73 226-01 226-01 226-82 226-01 226-01 228 Series 226-01 226-01 575-002 226-01 226-01 226-01 226-01 NA SKC 226-01 575-001 228 Series 226-25 226-01
42 35 79 79 79 36 36 35 35 38 37 35 36 36 35 35 35 35 35 35 35 37 35 35 36 36 35 35 37 35 35
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
PK
228 Series
PK
228 Series
240-7200 1-10 240 60 60 24
ASTM D 4861
varies
NIOSH 1450 OSHA PV2001 OSHA PV2001 OSHA PV2001 NIOSH 5523 1401
0.2 (C)
OSHA 43 OSHA CSI
3
OSHA PV2111 NON 49 ASTM D 5075 1427 OSHA CSI
0.4 mg/m
NIOSH 5600
3
NIOSH 5600 OSHA CSI
NIOSH 1403 1273 0.5 (skin)
1277 200 NIOSH 1403 1273 0.5 (skin) OSHA 79 1277 100 NIOSH 1450 0.5 (skin) OSHA 79
OSHA 29 OSHA 55
NIOSH 1457 OSHA 07
1111
NON 54 OSHA 92 NIOSH 1450 OSHA 07 OSHA 100
1109 1283
NIOSH 1400 OSHA 07
1158
400 400 5 25 4 (LOQ) 1000 1000 1000 25
15
ASTM D 5466
1108 OSHA 1002 1746 OSHA 1002 1746 NIOSH 1501 1053 OSHA 07
100 100 100 100
NIOSH 1011
1107 200 OSHA 07 1106 50 NIOSH 2553 50 NIOSH 1301 50 OSHA 07
125
1000-5000 varies 1000 1000 1000 100 15
6 10 90-720 90-2160 480 240 240 48 1-6 48 1-6 48 1-10 10 12 10 5 10 12 1-10 1 12 1 10 6 10 12 1-24 4 5 10 1-25 24
1.5
15 15
3 0.75
3
1-24 3
4-24 varies 4 1 1 4 1000
100 100 1500 1500 1000 1000 1000 100 10-50 100 10-50 100 10-200 100 100 20 20 20 50 10-200 50 50 50 20(50) varies 20(50) 50 13.83 10-200 20 20 20(50) 10-200 200
100
1000 1000
200 50
200
10-200 200
GC-ECD GC-FID HPLC-UV HPLC-UV HPLC-UV GC-FID
15 1 100 min 1-8 1-24 8 4 4 8 varies 8 varies 8 varies 1.6 2 8 4 8 4 varies 20 min 4 20 min 8(3.3) varies 8(3.3) 4 8 varies 3.3 4 8(3.3) varies 2
HPLC-TEA GC-FID
15
HPLC-UV GC-NSD GC-NPD GC-FPD GC-FPD GC-FPD GC-FID GC-FID
15
GC-FID GC-FID
15
GC-FID GC-FID GC-FID HPLC-UV GC-FID GC-FID
15 15
GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-MS
15
GC-FID GC-FID GC-FID
varies
GC-FID GC-FID
15
GC-FID GC-FID GC-FID GC-FID
GC-FID ASTM D 5466 NIOSH 2519 OSHA 07
1000
6 3 3
varies 50 50
varies 1 1
GC-MS GC-FID GC-FID
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
E
C/HLD C/HLD CST C/HLD
Phone: +1-724-941-9701
35 35 64 35 35 35 35 35 64 35 35
References and abbreviations are found on pages 196-197.
www.skcinc.com
155
Sampling Guide SAMPLING ∞
www.skcinc.com for updates E
Chemical Hazard
Ethyl ether (diethyl ether) Ethyl ether (ethyl ether) Ethyl formate Ethyl formate Ethyl lactate Ethyl mercaptan Ethyl mercaptan (mercaptans) Ethyl methacrylate Ethyl methacrylate Ethyl O-(p-nitrophenyl) phenylphosphonothionate (EPN) Ethyl parathion Ethyl propionate Ethyl silicate Ethyl tert-butyl ether (tert-butyl ethyl ether) Ethyl vinyl benzene Ethyl-3-ethoxypropionate Ethylamine Ethylene Ethylene chlorohydrin Ethylene chlorohydrin Ethylene dibromide (1,2-dibromoethane) Ethylene dibromide (1,2-dibromoethane) Ethylene dichloride (1,2-dichloroethane) Ethylene dichloride (1,2-dichloroethane) (hydrocarbons, halogenated) Ethylene glycol (glycols) Ethylene glycol dinitrate Ethylene glycol dinitrate (nitroglycerine) Ethylene glycol isopropyl ether (isopropyl CELLOSOLVE solvent) Ethylene glycol monohexyl ether Ethylene oxide Ethylene oxide Ethylene oxide Ethylene oxide Ethylene oxide (by portable GC) Ethylene oxide (Qazi-Ketcham) Ethylene thiourea Ethylene thiourea Ethylenediamine Ethylenediamine Ethylenimine 2-Ethylhexanol Ethylhexyl acetate 2-Ethylhexyl acrylate di-2-Ethylhexyl phthalate (DEHP) N-Ethylmorpholine ETS (see environmental tobacco smoke) Exserohilum species (fungi, molds, spores) Exserohilum species (fungi, molds, spores) Fenamiphos Fenamiphos (organophosphorus pesticides) Fenarimol Fensulfothion (Dansanit) Fenthion Fenvalerate Ferbam Ferric chloride (see iron salts, soluble as Fe) Ferrovanadium dust
Passive Guide
Agency Standard
Agency Reference
Chem F File
OSHA 07
1105 400
CLG/STEL (ppm)
NIOSH 1452 OSHA 07
100 1104 100
OSHA PV2081
Rate (ml/min)
CLG/ STEL
TWA
3 0.25-3 10 10 10
NIOSH 1610
3
10 (C) 120 NIOSH 2542 1330 0.5 (15 min) 48 12 NIOSH 2537 1-8 OSHA PV2100 10 NIOSH 5012 0.5 mg/m3 480 ASTM D 4861 240-7200 OSHA CSI 10 OSHA CSI 100 9
TWA
20 10-200 20 20(50) 200
OSHA CSI
100 10-50 20(50) 1000 1000-5000 20(50) 50
Time
CLG/ STEL
200
1000 200
TWA (hrs)
2.5 varies 8 8(3.3) 50 min 8 varies 8(3.3) 8 4-24 8(3.3) 3
CLG/STEL (ppm)
15
OSHA PV2025
10
OSHA 36
GC-FID GC-FID GC-FID
120 60
1
10 20 0.13 (15 min) 10 30 10 100 10 2 3
1159 5 NIOSH 1008 0.045 OSHA 02 1072 20 OSHA 03 1063 50 NIOSH 1003 1 NIOSH 5523 1401
50 100 200
NIOSH 2507
ASTM D 5578
0.1 1751 1 NIOSH 3702 1031 0.1 NIOSH 1614 OSHA 1010 NON 14
LFC
NIOSH 5011 OSHA 95
10 1287 10
NIOSH 3514 OSHA CSI OSHA CSI OSHA PV2026 OSHA 104 OSHA CSI
5 mg/m3 20
20(50) 40 20(50) 20(50) 200 10-200
GC-FID GC-FPD GC-NPD GC GC-FID
4 100 min 50 min
200 200 200 200 10-200
1000 15 15
10 6 9.6 5 (10 min) 24 5.0 EL 12 5 (10 min) varies 10 480 480 10 10 48 48 10 12 240 10
OSHA CSI ASTM D 4413
OSHA 60
3 1 3 3
9
OSHA CSI
NIOSH 2540
3
60 0.2 (C) 0.1 mg/m3
OSHA 43
GC-FID GC-FID HPLC-UV
200 100 20 100 50 20-4000 20(50) 2000 2000 100 100 200 200 20(50) 100 1000 20(50)
15
50 min 1 8 4 4 varies 8(3.3) 4 4 1.7 100 min 4 4 8(3.3) 2 4 8(3.3)
GC-ECD GC-ECD GC-ECD GC-FID GC-FID
15 15 1.5
200 100 150 50 varies
GC-FID GC-FID
15 5 15 varies
1 1000 1000
100
3 1.5 1.5 0.75 varies
8(3.3) 8 8(3.3) 8(3.3) 1 varies
HPLC-TEA GC-ECD GC-FID GC-FID
15 15 10 15 varies
GC-FID GC-ECD GC-ECD GC-ECD P GC-PID GC VAS HPLC-UV HPLC-UV HPLC-UV HPLC-UV GC-FID GC-FID GC-FID GC-FID GC-FID
ST ST ST ST ST CF/CST CF/CST ST ST F/CST PUF ST ST PS ST ST ST DT DT ST ST ST ST ST ST
226-01 226-01 226-01 226-01 226-01 225-9007 225-9007 226-30-06 226-01 225-709 226-92 226-01 226-30-04 575-001 226-73 226-01 226-96 800-28051 800-01331 226-81A 226-81A 226-01 226-01 226-01GWS 226-01
35 35 35 35 35 61 61 35 35 79 42 35 35 64 36 35 37 or or 36 36 35 35 35 35
ST ST ST ST
226-57 226-35-03 226-35-03 226-01
36 36 36 35
ST ST ST ST ST SB ST F/CST F/CST ST ST IMP ST ST ST ST ST
226-01 226-16 226-178 226-178 226-178 232 Series 226-36 225-802 225-706 226-30-18 226-30-18 225-36-2 226-01 226-01 226-73 226-56 226-10
35 or 38 38 38 50 36 73 79 35 35 59 35 35 36 36 35
F/CST BI ST ST ST ST ST PUF ST
C/HLD C/HLD
225-1 225-1
87 87
C/HLD
225-1
87
DT DT
810-172 810-172L
or
ST
226-36
36
C/HLD C/HLD
225-1 225-1
87 87
IT
225-22
59
225-3-01 225-9611 226-30-16 226-58 226-30-16 226-30-16 226-30-16 226-92 226-30-16
77 C/HLD 103 35 36 35 35 35 42 35
225-1
87
F/CST C/HLD STC
225-3-01 225-1 225-9820
or 87 81
F/CST
225-3100
77
FLT CYC FLT CST F/CST
225-8-01 225-01-02 225-8-01 225-2LF 225-8204
73 95 73 86 73
C/HLD CST C/HLD
225-1 225-3LF 225-1
87 86 87
C/HLD
225-1
87
IMP PUF F/CST PUF
225-36-2 226-92 225-706 226-131
59 42 79 43
IT
225-22
59
C/HLD FLT
225-1 225-1821
87 79
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
NON 49 OSHA CSI OSHA CSI OSHA CSI NIOSH 5600
0.1 mg/m3
OSHA CSI OSHA CSI OSHA CSI ASTM D 4861 OSHA CSI
15 mg/m3
120 141.5 480 240 30 480 480 240-7200 480
1000 28,300 1000 1000 1000 1000 1000 1000-5000 1000
2 5 min 8 4 30 min 8 8 4-24 8
varies varies GC-FPD GC-FPD HPLC-UV GC-FPD GC-FPD HPLC-UV HPLC-UV
OSHA ID 121 OSHA ID 125G 1218 1 mg/m3
NIOSH 0600 1038
Fibrous glass (particulates, total)
NIOSH 0500 1035
480
30
2000
2000
4
15
ICP-AES
15-150
15000
1-10 min
varies
375
2500
2.5
GR
120
2000
1
GR
960
2000
8
GR
1000 1000-5000 2000 225 L/min
2 4-24 8 1-24
ISE
ASTM D 6209
120 240-7200 960 350 m3 (max)
NIOSH 5515
480
2000
4
GC-FID
OSHA CSI
15 mg/m
3
OSHA CSI OSHA CSI ASTM D 4861 OSHA CSI
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
156
GC-FPD
DET TB
OSHA 07
GC-FPD GC-FID
OSHA CSI NIOSH 2513
GC-FID
GC-FID 12 10 10
OSHA 89
Analytical Method SKC Collecting Equipment & Page Number GC-FID
Fibers (bioaerosols) Fibers (see specific compounds) Fibrous glass (particulates, respirable)
Fibrous glass dust Flax dust (see dust, total & respirable nuisance) Fluoboric acid Fluometuron Fluoranthene Fluoranthene (polynuclear aromatic hydrocarbons by GC-MS) Fluoranthene (polynuclear aromatic hydrocarbons by GC)
TWA (ppm)
Vol. (liter)
www.skcltd.com
HPLC-UV HPLC-UV GC-MS
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Fluoranthene (polynuclear aromatic hydrocarbons by HPLC) Fluorene Fluorene (polynuclear aromatic hydrocarbons by GC-MS) Fluorene (polynuclear aromatic hydrocarbons by GC)
Agency Reference
Chem F File
TWA (ppm)
CLG/ STEL
TWA
Rate (ml/min) TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
2000
4
HPLC-FD
2000 225 L/min 2000
8 1-24 4
HPLC-UV
NIOSH 5515
960 350 m3 (max) 480
NIOSH 5506
480
2000
4
HPLC-UV
OSHA CSI ASTM D 6209
ASTM D 5197 1442
Formaldehyde Formaldehyde Formaldehyde (aldehydes, screening)
0.75 1020 0.75 NIOSH 2539 0.016
Formic acid Freon 11 Freon 113 Freon 113 (1,1,2-Trichloro-1,2,2-trifluoroethane) Freon 114 Freon 12 Freon 123 Freon 141b Fumarin Fungi Fungi (in air) Fungi (in air) (BioSampler method) Furans (including PHDFs, PCDFs, PBDFs) (see Environmental Sampling Guide) Furfural Furfural Furfural (aldehydes, screening)
Vol. (liter)
480
NIOSH 5506
Fluorene (polynuclear aromatic hydrocarbons by HPLC) Fluorides Fluorides (aerosol & gas by ISE) Fluorides (as F) Fluorine Fluorotrichloromethane (trichlorofluoromethane) 5-Fluorouracil Folpet Fonofos (dyfonate) Fonofos (organophosphorus pesticides) Formaldehyde Formaldehyde Formaldehyde Formaldehyde
Formaldehyde (see Environmental Sampling Guide) Formaldehyde (see Environmental Sampling Guide) Formaldehyde (see Environmental Sampling Guide) Formaldehyde on dust (textile or wood) Formamide Formetanate (organonitrogen pesticides) Formic acid
CLG/STEL (ppm)
ASTM D 4765 1421 NIOSH 7902 1226 2.5 mg/m3 6 (HF) OSHA ID 110 1227 2.5 mg/m OSHA CSI
3
0.1 1000
NIOSH 1006
NIOSH 3500
0.016
OSHA 1007 OSHA 52
varies 8 1 8
20
ISE
15 15
ISE ISE ISE
240
GC-FID HPLC-UV
0.1 (C) 0.1 (C) 0.1
2 2 0.1
13.8 24 5
28.6 100 20
8 4 4
HPLC-UV
0.1
240 10 240 24
3
NIOSH 2541 1015 0.016
5
1500 1500
3 4-24 8 4 5 min-24 hrs varies varies 4 10 8 15
OSHA PV2027
NIOSH 2016 1761 0.016
2000 1000 1500 1000
1000 1000-5000 1000 1000 500-1200 30-500 30-500 100 100 200 1000
ASTM D 4861
0.1 mg/m
22.5 22.5
GC-FID
180 240-7200 480 240 varies 1-
Chemical Hazard
Abietic acid Absidia species (fungi, molds, spores) Absidia species (fungi, molds, spores) Acenaphthene (polynuclear aromatic hydrocarbons by GC-MS) Acenaphthene (polynuclear aromatic hydrocarbons by GC) Acenaphthene (polynuclear aromatic hydrocarbons by HPLC) Acenaphthylene (polynuclear aromatic hydrocarbons by GC-MS) Acenaphthylene (polynuclear aromatic hydrocarbons by GC) Acenaphthylene (polynuclear aromatic hydrocarbons by HPLC) Acetaldehyde Acetaldehyde Acetaldehyde Acetaldehyde Acetaldehyde (aldehydes, screening) Acetamide Acetates (screening) Acetic acid Acetic acid Acetic acid Acetic anhydride Acetic anhydride Acetic anhydride Acetoin Acetoin (acetyl methyl carbinol) Acetoin (acetyl methyl carbinol) Acetone Acetone Acetone (ketones I) Acetone (ketones I) Acetonitrile Acetophenone Acetyl methyl carbinol (acetoin) 2-Acetylaminofluorene Acetylene Acetylene tetrabromide Acetylene tetrabromide (1,1,2,2-tetrabromoethane) Acetylsalicylic acid Acid black 128 Acid blue 9 Acid orange 74 Acid red 114 Acid yellow 34 Acid yellow 42 Acid/base (skin)
Agency Reference
TWA (ppm)
CLG/STEL (ppm)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-UV
ASTM D 6209
350 m (max)
225 L/min
1-24
GC-MS
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-UV
ASTM D 5197
varies 10 60 3 5
500-1200 20 125 50 50 10
5 min-24 hrs 8 8 1 15 8
HPLC-UV
20(50) 20 50 200 200 1000 50 50 10-200 50 50 500-1200 50 20 10-200 20(50) 100 10-200 1000
8(3.3) 4 8 4 4 1.5 2.5 15 15 min varies 3 15 3 15 5 min-24 hrs 1 100 min 15 varies 8(3.3) 2 varies 4
GC-NPD
3
LFC NIOSH 3507 LFC OSHA 68 1007 200 NIOSH 2539 LFC NIOSH 2538
10 10
NIOSH 1603 OSHA ID 186SG
15
OSHA PV2119
5
NIOSH 3506 OSHA 102 OSHA 82
1392 5 1391 5
NIOSH 2558
0.05 0.05
OSHA 1012 OSHA 1013 ASTM D 5197
1000 250
OSHA 69 NIOSH 1300 NIOSH 2555
TWA (hrs)
ASTM D 6209
NIOSH 2549
TWA
www.skcinc.com for updates
Time
CLG/ STEL
HPLC-UV
OSHA PV2084
TWA
Rate (ml/min)
1.6 2 5 min 1-24
OSHA CSI
CLG/ STEL
2000 1000 28,300 225 L/min
OSHA CSI
Vol. (liter)
200 120 141.5 350 m3 (max)
OSHA CSI
20
NIOSH 1606 OSHA PV2003 NIOSH 2558 OSHA CSI
10 5 24 48 48 90 7.5 0.75 1-10 9 9 varies 3 2 0.5-3 10 12 1-10 240
0.75
7.5
3 3
0.75
500
200 200
50
varies varies GC-MS
OSHA CSI
GC-FID HPLC GC-NPD GC-FID & GC-MS GC-MS GC-FID IC or GC-FID IC or GC-FID VAS GC-NPD GC-NPD GC-FID GC-FID GC-FID HPLC-UV GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID HPLC-UV DET TB
1
OSHA CSI
96 96 120 200 100 200 120 100 100
NIOSH 2003 OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI
200 200 1000 1000 1000 1000 1000 1000 1000
8 8 2 3.3 100 min 3.3 2 100 min 100 min
GC-FID GC-FID HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-FD CI
Acid/base (surface) Acids, inorganic (see specific compounds) Acremonium species (fungi, molds, spores) Acremonium species (fungi, molds, spores) Acridine
CI NIOSH 7903 1016
48 120 141.5 960
OSHA CSI OSHA CSI
Acrolein Acrolein Acrolein (aldehydes, screening)
OSHA 58
1077 0.2 mg/m3
NIOSH 2501
0.1 0.1 0.1
OSHA 52 NIOSH 2539
Acrylamide
OSHA 21
Acrylic acid Acrylic acid Acrylonitrile Acrylonitrile Actinomycetes, thermophilic Adipic acid Adiponitrile Aerobic bacteria (by GC-FAME) Alcohols (screening) Alcohols combined Alcohols I (see specific compounds) Alcohols II (see specific compounds)
Chem F File
0.3 mg/m3
NON 10 OSHA 28
NIOSH 1604 1266 1 OSHA 37
1265 2
NIOSH 0800 OSHA CSI OSHA CSI NIOSH 0801 NIOSH 2549 NIOSH 1405 NIOSH 1400 NIOSH 1401
varies varies varies
0.3 0.3
24 48 5
200 1000 28,300 2000 3 3
120 48 24 10 (15 min) 10 10 20 varies 96 10 50-300 5 varies varies varies varies
3 6
varies
50 100 10
4 2 5 min 8 200 200
8 8 8
IC varies varies GR & HPLCFD, or GR & HPLC-UV
15 15
GC-NPD GC-NPD GC-FID & GC-MS
1000
2
GC-NPD
100 100 20(50) 200 28,300 200 20(50) 28,300 20 10-200 varies varies
8 4 8(3.3) 15 100 min 15 varies 8 8(3.3) varies 4 varies varies varies 8
GC
200 400
10-200
HPLC-UV GC-FID GC-NPD varies GC-FID GC-FID GC-FID GC-MS GC-FID GC-FID GC-FID
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
F/CST F/CST BI PUF
225-709 225-3-01 225-9611 226-131
79 C/HLD 77 C/HLD 103 43 FLT
F/CST C/HLD F/CST C/HLD PUF
225-1713 225-1 225-1713 225-1 226-131
74 87 74 87 43
F/CST C/HLD F/CST C/HLD ST ST IMP ST ST
225-1713 225-1 225-1713 225-1 226-120 226-27 225-36-2 226-27 226-118
74 87 74 87 or 35 59 35 37
ST ST ST ST ST IMP CF/CST CF/CST ST ST ST ST ST ST ST ST ST ST F/CST DT ST ST F/CST F/CST F/CST F/CST F/CST F/CST F/CST PCH TK W ST F/CST BI FLT C/HLD
226-10 226-330 226-01 226-01 226-01 225-36-2 225-9010 †† 225-9009 NA SKC 226-183 226-183 226-120 NA SKC 226-01 NA SKC 226-09 226-35 NA SKC 225-706 810-171 226-10 226-10 225-709 225-706 225-706 225-706 225-709 225-706 225-706 769-3006 769-1006 769-1024 226-10-03 225-3-01 225-9611 225-7 225-1
35 35 79 79 79 79 79 79 79 or 122 or 35 77 103 79 87
ST ST ST
226-118 226-117 226-118
37 37 37
ST CST ST ST ST ST BI ST ST BI ST ST ST ST
226-10 225-32 226-70A 226-30-08 226-01 226-01 225-9611 226-30-16 226-01 225-9611 226-330 226-01 226-01 226-01
35 FLT 87 36 35 35 35 103 35 35 103 39 35 35 35
A
225-1 225-1
87 87
225-1821
79
ST
226-30-04
35
ST
226-30-04
35
FLT
225-1821
79
ST
226-30-04
35
ST
226-30-04
35
ST
226-119
37
IT
225-22
59
35 39 35 35 35 59 61 61
IT C/HLD C/HLD
225-22 225-1 225-1
59 87 87
38 38 or
ST
226-119
37
C/HLD
225-1
87
C/HLD C/HLD C/HLD C/HLD C/HLD C/HLD C/HLD W
225-1 225-1 225-1 225-1 225-1 225-1 225-1 769-1036
87 87 87 87 87 87 87 or
TK
769-1006
122
C/HLD
225-1
87
CST
225-2LF
86
225-16
79
35 35 35 79
References and abbreviations are found on pages 196-197.
www.skcinc.com
139
Sampling Guide SAMPLING ∞
www.skcinc.com for updates A
Chemical Hazard
Alcohols III (see specific compounds) Alcohols IV (see specific alcohol) Aldehydes (screening) Aldehydes (screening) Aldehydes (see Environmental Sampling Guide) Aldicarb (organonitrogen pesticides) Aldicarb (Temik) Aldrin Aldrin
Passive Guide
Agency Reference
Agency Standard Chem F File
NIOSH 1403 NIOSH 2539
NIOSH 2549
CLG/STEL (ppm)
varies varies varies
NIOSH 1402
TWA (ppm)
Vol. (liter) TWA
Rate (ml/min)
CLG/ STEL
TWA
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
varies varies 5
varies varies 20
8 varies 4
GC-FID
ST ST ST
226-01 226-01 226-118
35 35 37
5
20
4
GC-MS
ST
226-330
39
1000 1000 1000-5000 500
4 8 4-24 8
HPLC-UV
4
GC-ECN
ST ST PUF F/CST IT F/CST IT ST FLT C/HLD
226-58 226-30-16 226-92 225-709 225-22 225-709 225-22 226-330 225-17-01 225-1
or 35 42 79 59 79 59 39 74 87
1000
226-92 226-01 226-01 226-01 226-01 226-01 226-01 226-35-03 226-110 500-400 225-3-01 225-9611 225-3-01 225-01-02 225-8-01 225-8-01 225-2LF 225-105 225-3LF 225-8-01 225-2LF 225-3-01 225-1 225-3-01
42 35 35 35 35 35 35 36 37 66 77 103 77 95 73 73 86 94 86 73 86 or 87 77
GC-FID GC-FID & GC-MS
EPA TO-5
NIOSH 5502
0.25 mg/m3
240 480 240-7200 240
OSHA CSI
0.25 mg/m3
240
NIOSH 5601 OSHA 74
1399
ASTM D 4861
Aldrin Aliphatic hydrocarbons (screening) Alkaline dusts
5
NIOSH 2549
20 30
NIOSH 7401
GC-NPD GC-ECD GC-ECN
4 2000
GC-MS
15
TITRA
NIOSH 0500 1035
120
2000
1
GR
59 87 59 87
CST
225-3LF
86
C/HLD
225-1
87
C/HLD C/HLD CST C/HLD
225-1 225-1 225-3LF 225-1
87 87 86 87
FLT C/HLD C/HLD
225-8-01 225-1 225-1
73 87 87
F/CST
225-803
73
C/HLD
225-1
87
varies
varies
GR
alpha-Alumina (total dust)
OSHA CSI
15 mg/m3
960
2000
8
GR
5-100
1000-4000
varies
ICP-AES
2-10,000
1000-4000
varies
ICP-AES
5-100
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
varies
varies
varies
GR
FLT CST
225-8-01 225-3LF
73 86
CYC C/HLD
225-105 225-1
94 87
FLT CST F/CST F/CST FLT CST FLT CST F/CST F/CST ST
225-8-01 225-2LF 225-3-01 225-3-01 225-8-01 225-2LF 225-8-01 225-2LF 225-709 225-709 226-10
73 86 77 77 73 86 73 86 79 79 35
C/HLD
225-1
87
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
C/HLD
225-1
87
C/HLD C/HLD
225-1 225-1
87 87
ST PCH TK W PCH TK
226-10 769-3005 769-1005 769-1025 769-3001 769-1001
35 or W 122 or TK or W 122
769-1035
or
769-1005 769-1031
122 or
W ST ST CF/CST ST IMP ST ST IMP ST ST FLT C/HLD
769-1021 226-10 226-30-16 225-9004 226-10-04 225-36-1 226-30-18 226-10-04 225-36-1 226-30-18 226-98 225-17-01 225-1
or 35 35 61 35 59 35 35 59 35 37 74 87
TK
769-1001
122
C/HLD
225-1
87
IT
225-22
59
IT
225-22
59
CST
225-3LF
86
Aluminum (respirable fraction)
2 5 min 6 2.5
225-36-2 225-1 225-36-2 225-1
varies
Aluminum (elements by ICP HNO3/HClO4 ashing)
1000 28,300 1000 2500
varies
NIOSH 0600 1038
120 141.5 360 375
IMP C/HLD IMP C/HLD
5 mg/m3
Aluminum (elements by ICP HNO3 digestion)
4-24 8(3.3) 15 200 min varies varies 8(3.3) 15 15 8(3.3) 15 2 15 8(3.3)
35
OSHA CSI
Aluminum (elements by ICP Aqua Regia ashing)
1000-5000 20(50) 200 50 10-200 10-200 20(50) 200 1000 20(50) 200 50 200 20(50)
226-30-16
alpha-Alumina (respirable fraction)
Alumina (particulates, total)
240-7200 10 3 10 1-10 1-10 10 3 15 10 3 6 3 10
ST
PUF ST ST ST ST ST ST ST ST PS F/CST BI F/CST CYC FLT FLT CST CYC CST FLT CST F/CST C/HLD F/CST
Allethrin Allyl alcohol Allyl alcohol Allyl alcohol (alcohols combined) Allyl alcohol (alcohols III) Allyl chloride Allyl chloride Allyl glycidyl ether Allyl propyl disulfide Allyll amine Alternaria species (fungi, molds, spores) Alternaria species (fungi, molds, spores) Alumina (aluminum & compounds [total dust as Al]) Alumina (particulates, respirable)
ASTM D 4861
2 OSHA PV2140 2 (skin) NIOSH 1405 2 NIOSH 1402 2 NIOSH 1000 1 OSHA 07 1126 1 NIOSH 2545 5 OSHA PV2086 2 OSHA CSI
4 (skin) 4 2 10
HPLC-UV GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FPD HPLC-UV
OSHA CSI OSHA CSI
10 mg/m3
NIOSH 7013
NIOSH 7301 ¥
10 mg/m3 (total dust) NIOSH 7303 10 mg/m3 (total dust) 5 mg/m3 (respirable fume) NIOSH 7300 1455 10 mg/m3 (total dust) 5 mg/m3 (respirable fume) OSHA CSI 5 mg/m3
varies AA-F GR
OSHA CSI
15 mg/m3
960
2000
8
GR
NIOSH 7013
10 mg/m3
1000 2000 2000
6 8 8
AA-F
OSHA CSI
360 960 960
Aluminum, pyro powders
OSHA CSI
960
2000
8
GR
Alupent Amiben Amines
OSHA CSI
2000 1000 40
6 4 8
HPLC-UV
50
8
GC-FID
Aluminum (total dust) Aluminum & compounds (total dust as Al) Aluminum soluble salts Aluminum welding fumes
Amines, aliphatic Amines, aliphatic (skin)
OSHA ID 121
NIOSH 2002
varies
720 240 20
NIOSH 2010
varies
24
OSHA CSI
Amines, aromatic (surface) 2-Amino-2-methy-1-propanol 2-Amino-2-methy-1-propanol 4-Aminobiphenyl 2-Aminoethanol 2-Aminoethanol 2-Aminoethanol Aminoethanol compounds I (see specific compounds) Aminoethanol compounds II (see specific compounds) Aminoethylethanolamine N-Aminoethylpiperazine p-Aminophenylarsonic acid (arsenic, organo-)
AA or AES GR
HPLC-UV GC-FID or GC-NSD CI
Amines, aliphatic (surface) Amines, aromatic (skin)
CI CI CI OSHA CSI OSHA PV2145 OSHA 93 NIOSH 2007 NIOSH 3509 OSHA PV2111 NIOSH 2007 NIOSH 3509
1233 3 3 3 varies varies
6 6
OSHA PV2116 OSHA CSI NIOSH 5022
9 10 100 10 240 10 varies 240 10 9 960
1.5
100 100 1000 20 1000 100 varies 1000 100 100 2000
100
90 min 100 min 100 min 8 4 100 min 15 8 4
www.skcltd.com
GC-NPD HPLC-UV GC-ECD GC-FID IC HPLC-UV GC-FID IC HPLC-UV
90 min 8
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
140
Analytical Method SKC Collecting Equipment & Page Number
GC-NPD IC-AA
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
2-Aminopyridine 2-Aminopyridine 3-Aminopyridine 4-Aminopyridine Amitrole Ammonia Ammonia Ammonia Ammonia (by IC) Ammonium chloride (fume) Ammonium hydroxide (see ammonia) Ammonium metavanadate (see vanadium oxides) Ammonium nitrate
Agency Reference
Chem F File
TWA (ppm)
0.5 0.5
OSHA CSI OSHA PV2143 OSHA PV2143 OSHA PV2143 OSHA PV2006
25
NIOSH 6015
35
NON 41 OSHA ID 188 1008 50
25
NIOSH 6016
35
OSHA ID 188
OSHA CSI
Ammonium sulfamate (respirable dust)
5 mg/m
Ammonium sulfamate (total dust)
OSHA CSI OSHA ID 188
o-Anisaldehyde Anisidine Anisidine (o- & p-isomers) Anthophyllite fibers (see asbestos fibers) Anthracene Anthracene (polynuclear aromatic hydrocarbons by GC-MS) Anthracene (polynuclear aromatic hydrocarbons by GC) Anthracene (polynuclear aromatic hydrocarbons by HPLC) Antimony (elements by ICP Aqua Regia ashing) Antimony (elements by ICP HNO3 digestion) Antimony (elements by ICP HNO3/HClO4 ashing) Antimony (ICP analysis of metal/metalloid particulates from solder operations) Antimony & compounds (as Sb) Antimony & compounds (as Sb) ANTU (alphanaphthyl thiourea) Apron Aqua fortis (acids, inorganic) Aroclor Aroclor Aroclor 1242 Aroclor 1242 (42% Cl) (see polychlorobiphenyls) Aroclor 1254 Aroclor 1254 (54% Cl) (see polychlorobiphenyls) Aroclor 1260 Aromatic hydrocarbons (screening) Arsenic (elements by ICP Aqua Regia ashing)
Vol. (liter) TWA
12 240 240 240 60 72 18 24 48 960
Rate (ml/min)
CLG/ STEL
3 5 7.5 3 30
TWA
200 1000 1000 1000 1000 150 75 100 100 2000
200 500 500 200 2000
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
1 4 4 4 1 8 4 4 8 8
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
ST CF/CST CF/CST CF/CST IMP ST ST ST ST F/CST
226-35-02 225-9004 225-9004 225-9004 225-36-1 226-10-06 226-61 226-29 226-10-06 225-3-01
35 61 61 61 59 35 36 35 35 77
FLT CST CYC FLT GR FLT CST GR & IC-ECN F/CST GC-FID ST GC-FID ST GC-FID ST GC-FID PS GC-FID PS HPLC-UV ST GC-FID CF/CST GC-FID ST GC-FID or ST
225-8-01 225-2LF 225-105 225-8-01 225-8-01 225-2LF 225-3-01 226-01 226-01 226-01 575-002 575-001 226-01 225-9004 226-98 226-10
73 86 94 73 73 86 77 35 35 35 64 64 35 61 37 35
226-30 226-30-05 226-30-05
35 35 35
225-7 225-1
GC-FID GC-NPD GC-NPD GC-NPD HPLC-UV
15 10 15 15 15
VAS CLR IC-ECN IC IC-ECN
C/HLD C/HLD C/HLD IT F/CST
225-1 225-1 225-1 225-22 225-3-01**
87 87 87 59 77
F/CST C/HLD
225-3-01** 225-1
77 87
2000
8
GR GR
C/HLD
225-1
87
C/HLD CST C/HLD
225-1 225-3LF 225-1
87 86 87
C/HLD
225-1
87
ST
226-15
35
79 87
CST
225-2LF
86
varies
varies
varies
15 mg/m
960
2000
8
15 mg/m 100 125 100
3
960 10 10 1-10
2000 20(50) 20(50) 10-200
8 8(3.3) 8(3.3) varies
8 24 24 24
50 200 50 50
2.5 2 8 8
200 1000 1000
8 4 4
HPLC-UV
0.5 mg/m3 0.5 mg/m3
96 240 240
1075 0.2 mg/m
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
ASTM D 6209
350 m3 (max)
225 L/min
1-24
GC-MS
PUF
226-131
43
FLT
225-1821
79
NIOSH 5515
480
2000
4
GC-FID
35
2000
4
HPLC-UV
74 87 74 87 or 87 77 77 77
226-30-04
480
225-1713 225-1 225-1713 225-1 225-3-01 225-1 225-3-01 225-3-01 225-3-01
ST
NIOSH 5506
F/CST C/HLD F/CST C/HLD F/CST C/HLD F/CST F/CST F/CST
ST
226-30-04
35
F/CST
225-803
73
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
225-3-01 225-3-01 225-1 225-17-01 225-1 225-709 226-10-03 226-92 226-58 226-92
77 or 87 74 87 79 35 42 36 42
C/HLD F/CST
225-1 225-3100
87 77
CST
225-2LF
86
C/HLD
225-1
87
F/CST
225-803
73
C/HLD C/HLD TMP
225-1 225-1 225-2403
87 87 or
C/HLD C/HLD CST
225-1 225-1 225-2LF
87 87 86
C/HLD CST
225-1 225-2LF
87 86
OSHA 07 OSHA 07 NIOSH 1450
3
OSHA CSI
960
3
LFC OSHA PV2079 5 NIOSH 2002 1058 LFC NIOSH 2017
OSHA CSI NIOSH 2514 OSHA CSI
GC-NSD
ST ST ST
HPLC-UV HPLC-UV
NIOSH 7400 OSHA 58
3
NIOSH 7301 ¥
0.5 mg/m3
50-2000
1000-4000
varies
ICP-AES
NIOSH 7303
0.5 mg/m3
1000-4000 1000-4000 2000
varies varies 4
ICP-AES
OSHA ID 206
0.5 mg/m3
3-100,000 50-2000 480
OSHA ID 121
0.5 mg/m3 0.5 mg/m3
960 480
2000 2000
8 4
AA or AES
OSHA ID 125G OSHA CSI
0.3 mg/m3
480
2000
4
HPLC-UV
60 48 240-7200 480 240-7200
1000 200 1000-5000 1000 1000-5000
1 4 4-24 8 4-24
HPLC-UV
GC-ECD
F/CST F/CST C/HLD FLT C/HLD F/CST ST PUF ST PUF
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
240-7200 5
1000-5000 20
4-24 4
GC-ECD
PUF ST F/CST C/HLD F/CST F/CST W TMP F/CST F/CST FLT C/HLD CF/CST FLT C/HLD ST
226-92 226-330 225-3-01 225-1 225-3-01 225-3-01 225-2414 225-2415 225-3-01 225-3-01 225-5 ‡ 225-1 225-9001 225-17-01 225-1 226-01
42 39 or 87 77 77 124 124 77 77 76 87 61 74 87 35
NIOSH 7300 1455 0.5 mg/m3
OSHA PV2102 NIOSH 7903 1016 2
4
ASTM D 4861 NIOSH 5602 ASTM D 4861
ICP-AES ICP-AES
ICP-AES
IC GC-ECD GC-ECD
NIOSH 5503 ASTM D 4861 NIOSH 5503 ASTM D 4861 NIOSH 2549 NIOSH 7301 ¥
Arsenic (elements by ICP HNO3 digestion) Arsenic (elements by ICP HNO3/HClO4 ashing) Arsenic (elements on wipes)
NIOSH 7303
Arsenic (inorganic compounds as As) Arsenic & compounds (as As) Arsenic trioxide as AS
OSHA ID 105
0.002 mg/m3
5-2000
1000-4000
0.002 mg/m3 8-5,000,000 0.002 mg/m3 (C) 5-2000 wipe
1000-4000
2000
NIOSH 7901
0.01 mg/m 960 2 μg/m3 (15 min) 3 2 mg/m (15 min)
Arsenic, inorganic (volatile compounds as As) Arsenic, organo-
OSHA ID 105
0.01 mg/m
Arsine Arylam (see carbaryl)
NIOSH 6001 1278
NIOSH 7300 1040 NIOSH 9102
NIOSH 7900
3
NIOSH 5022
3
2 μg/m3 (15 min) 10
varies 1000-4000 varies
ICP-AES ICP-AES ICP-AES
8 2000 2000
2000 2000 3
varies
ICP-AES
30 30
960 960
GC-MS
20
AAS-HGA
15 15 8 8
200
8
AA-F AAS-GF AAS-HGA IC-AA
15
AAS-GF
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
A
NIOSH 7504
OSHA CSI
Ammonium sulfamate (total dust) n-Amyl acetate sec-Amyl acetate (2-pentyl acetate) n-Amyl acetate (esters I) n-Amyl alcohol t-Amyl methyl ether (methyl tert-amyl ether) Amyl nitrite Aniline Aniline Aniline (amines, aromatic)
CLG/STEL (ppm)
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
141
Sampling Guide SAMPLING ∞
www.skcinc.com for updates A
Chemical Hazard
Passive Guide
Agency Reference
Agency Standard Chem F File
TWA (ppm)
CLG/STEL (ppm)
Vol. (liter)
Rate (ml/min)
CLG/ STEL
TWA
TWA
Time
CLG/ STEL
TWA (hrs)
Asbestos
OSHA ID 160 1301 0.1 fbr/cc 1 fbr/cc EL 25-1200 25-1200 500-2500 500-2500 varies
Asbestos ([bulk] by PLM) Asbestos (by TEM) Asbestos (chrysotile) Asbestos (mass concentrations) Asbestos (structure number concentrations) Asbestos fibers
NIOSH 9002
1% (bulk) 0.1 fbr/cc/400L
NIOSH 7400 1033 0.1 fbr/cc/400L
2000 2000 varies
2 min (minimum) 2 min (minimum) varies
NIOSH 5031
480
1000
8
1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000 28,300 1000
2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 2 5 min 6
NIOSH 9000 ASTM D 5756 1440 ASTM D 5755 1440
Aspergillus flavipes species (fungi, molds, spores) Aspergillus flavipes species (fungi, molds, spores) Aspergillus flavus species (fungi, molds, spores) Aspergillus flavus species (fungi, molds, spores) Aspergillus fumigatus species (fungi, molds, spores) Aspergillus fumigatus species (fungi, molds, spores) Aspergillus glaucus species (fungi, molds, spores) Aspergillus glaucus species (fungi, molds, spores) Aspergillus nidulans species (fungi, molds, spores) Aspergillus nidulans species (fungi, molds, spores) Aspergillus niger species (fungi, molds, spores) Aspergillus niger species (fungi, molds, spores) Aspergillus ochraceus (fungi, molds, spores) Aspergillus ochraceus (fungi, molds, spores) Aspergillus versicolor (fungi, molds, spores) Aspergillus versicolor (fungi, molds, spores) Asphalt fume (benzene-soluble & total particulate)
varies
bulk 960 bulk varies varies varies
NIOSH 7402
Aspartame
CLG/STEL (ppm)
120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 120 141.5 3 5 mg/m 360 (15 min) (C) 960 960
OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI OSHA CSI NIOSH 5042
Analytical Method SKC Collecting Equipment & Page Number PCM
8
TEM
60
4000
15
NIOSH 5506
480
2000
4
HPLC-FD
ASTM D 5197
varies
500-1200
5 min-24 hrs
HPLC-UV
Barium sulfate (total dust) Baygon (propoxur) Baygon (propoxur) Bendiocarb Bendiocarb (Ficam ) Benomyl (organonitrogen pesticides) Benomyl (respirable dust) Benomyl (total dust) Bentonite (see dust, total & respirable nuisance) Benz(a)anthracene Benz(a)anthracene (polynuclear aromatic hydrocarbons by GC-MS) Benz(a)anthracene (polynuclear aromatic hydrocarbons by GC) Benz(a)anthracene (polynuclear aromatic hydrocarbons by HPLC) Benzaldehyde
OSHA ID 121 1217 15 mg/m
0.5 mg/m3 OSHA ID 121 0.5 mg/m3 NIOSH 7056 0.5 mg/m3 OSHA ID 204 1216 5 mg/m3 NIOSH 7056
3
ASTM D 4861 OSHA PV2007 ASTM D 4861 OSHA PV2008 NIOSH 5601 OSHA CSI OSHA PV2107
5 mg/m 15 mg/m3 3
OSHA CSI
www.skcltd.com
GC-ECD HPLC-UV HPLC-UV varies varies varies varies GC-FID GC-FPD GC-FPD GC-FPD HPLC-UV varies GC-FID varies ICP-AES
ICP-AES
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
142
87
C/HLD
225-1
87
SP
225-27
87
C/HLD CST
225-1 225-2LF
87 86
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
C/HLD
225-1
87
C/HLD
225-1
87
VT ◊ F/CST
225-9598A 225-803
105 73
C/HLD TMP
225-1 225-2403
87 or
C/HLD C/HLD C/HLD C/HLD C/HLD
225-1 225-1 225-1 225-1 225-1
87 87 87 87 87
C/HLD
225-1
87
ST CYC
226-30-16 225-105
35 94
37
GC-FID
OSHA ID 121
225-1
226-119
4
Barium (insoluble compounds) Barium (soluble compounds) Barium (soluble compounds) Barium chloride (barium, soluble compounds) Barium sulfate (respirable fraction)
NIOSH 9102
C/HLD
ST
2000
NIOSH 7303
87
35
480
Barium (elements by ICP HNO3 digestion) Barium (elements on wipes)
225-1
226-30-04
NIOSH 5515
0.5 mg/m3
C/HLD
ST
8 1-24
NIOSH 7301 ¥
87
35
2000 225 L/min
NON 48
225-1
226-30-04
960 350 m3 (max)
HPLC-UV
ASTM D 6209
NIOSH 0801
C/HLD
ST
AA or AES
NIOSH 0800
87
74 87 74 87 or
8 4-24 8 4-24 4 4 varies 1
OSHA CSI
225-1
225-1713 225-1 225-1713 225-1 226-120
2000 1000-5000 100 1000-5000 1000 1000 varies 1000
0.2 mg/m3 0.2 mg/m3
C/HLD
F/CST C/HLD F/CST C/HLD ST
960 240-7200 48 240-7200 240 240 varies 60
NIOSH 5600
87
87 79
AA or AES
OSHA PV2087
225-1
225-1 225-1821
8 8 8 8 varies
OSHA CSI
C/HLD
C/HLD FLT
2000 2000 2000 2000 varies
NIOSH 5019
87
79 43
960 960 960 960 varies
OSHA CSI
225-1
225-709 226-131
ICP-AES
OSHA CSI
C/HLD
F/CST PUF
varies
OSHA CSI
87
42 36 79 79 77 103 77 103 73 35 35 36 35 103 103 105 or 87 77 124 124 77 77 77 77 94 77 73 42 35 42 35 or 35 35
1000-4000
OSHA CSI
225-1
226-92 226-58 225-706 225-709 225-3-01 225-9611 225-3-01 225-9611 225-803 226-30-16 226-30-16 226-58 226-30-16 225-9611 225-9611 225-9595 225-3-01 225-1 225-3-01 225-2414 225-2415 225-3-01 225-3-01 225-3-01 225-3-01 225-105 225-3-01 225-802 226-92 226-30-16 226-92 226-30-16 226-58 226-30-16 226-30-16
1-100,000 wipe
OSHA CSI
C/HLD
PUF ST F/CST F/CST F/CST BI F/CST BI F/CST ST ST ST ST BI BI BS F/CST C/HLD F/CST W TMP F/CST F/CST F/CST F/CST CYC F/CST F/CST PUF ST PUF ST ST ST ST
GC-NPD
OSHA CSI
or 77 86
125 125 or or 74 87 77 103 77 103 77 103 77 103 77 103 77 103 77 103 77 103 74 86 74 79 87
HPLC-UV
5
FLT/CL 225-326 FLT/CL 225-327 CST 225-2LF
225-322 225-322 225-321 225-321A 225-17-01 225-1 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-3-01 225-9611 225-27-07 225-2LF 225-1713 225-7 225-1
4-24 8 4 100 min 2 5 min 2 5 min 8 8 8 4 1.5 varies varies 5-30 varies
NIOSH 5602
or 77
MVC MVC PCM FLT/CL FLT/CL HPLC-UV FLT C/HLD varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI varies F/CST varies BI GR FLT CST GR F/CST GR & HPLC- FLT FD, or GR & C/HLD TEM
1000-5000 1000 1000 1000 1000 28,300 1000 28,300 2000 1000 1000 1000 1000 28,300 28,300 12500 + 1000-4000
ASTM D 4861
1078
77
TEM
240-7200 480 240 100 120 141.5 120 141.5 960 480 480 240 90 varies 50-300 62.5-375 50-2000
Atrazine Atrazine Atrazine Auramine Aureobasidium pullulans (fungi, molds, spores) Aureobasidium pullulans (fungi, molds, spores) Aureobasidium species (fungi, molds, spores) Aureobasidium species (fungi, molds, spores) Azelaic acid Azinphos-ethyl Azinphos-methyl Azinphos-methyl (organophosphorus pesticides) 1,1’-Azobisformamide Bacteria Bacteria (by GC-FAME) Bacteria (in air) Barium (elements by ICP Aqua Regia ashing)
OSHA 58
FLT/CL 225-327
FLT/CL 225-326 FLT/CL 225-327
XRD
8 8
ASTM D 6494
or or
PLM
2000
2000 2000
Asphalt fume particulate Asphalt fumes (petroleum)
FLT/CL 225-321 FLT/CL 225-321A
AA AA or AES AA GR & XRF
HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV HPLC-UV
GC-MS
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Benzaldehyde Benzene Benzene Benzene Benzene Benzene (by portable GC) Benzene (hydrocarbons, aromatic) alpha-Benzene hexachloride beta-Benzene hexachloride gamma-Benzene hexachloride Benzene-soluble & total particulate (asphalt fume)
Agency Reference
Chem F File
TWA (ppm)
CLG/STEL (ppm)
ASTM D 5466
1749 OSHA 1005 1749 OSHA 12 1009 NIOSH 3700 1029 OSHA 1005
NIOSH 1501
1 1 1 0.1 0.1
5 5 5 1 (15 min) 1
ASTM D 4861 ASTM D 4861 NIOSH 5042 ASTM D 4600 1416
1,2-Benzenedicarboxylic acid Benzidine Benzidine Benzidine dyes (dyes, benzidine)
LFC
OSHA 65 NIOSH 5013
Benzidine-based dyes
1239 LFC
Benzo(a)pyrene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(a)pyrene (polynuclear aromatic hydrocarbons by GC) Benzo(a)pyrene (polynuclear aromatic hydrocarbons by HPLC) Benzo(b)fluoranthene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(b)fluoranthene (polynuclear aromatic hydrocarbons by GC) Benzo(b)fluoranthene (polynuclear aromatic hydrocarbons by HPLC) Benzo(e)pyrene Benzo(e)pyrene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(e)pyrene (polynuclear aromatic hydrocarbons by GC) Benzo(e)pyrene (polynuclear aromatic hydrocarbons by HPLC) Benzo(g,h,i)perylene (polynuclear aromatic hydrocarbons by GC-MS) Benzo(g,h,i)perylene (polynuclear aromatic hydrocarbons by GC) Benzo(g,h,i)perylene (polynuclear aromatic hydrocarbons by HPLC) Benzo(k)fluoranthene (polynuclear aromatic hydrocarbons by GC) Benzo(k)fluoranthene (polynuclear aromatic hydrocarbons by HPLC) Benzoalphapyrene
ASTM D 6209 NIOSH 5515
0.1 mg/m
TWA (hrs)
CLG/STEL (ppm)
8
GR
1000 200 1000 1000
4 8 100 min 8
GC-FID
1000
8
HPLC-UV
350 m (max)
225 L/min
1-24
GC-MS
480
2000
4
GC-FID
2000
4
HPLC-FD
50
15
Analytical Method SKC Collecting Equipment & Page Number
2000
0.75
3
3
TWA
14.1 varies 50
www.skcinc.com for updates
Time
CLG/ STEL
200 200 20-5000 10-200 10-200 1000-5000 1000-5000 1000-5000 1000 4000
6 12
480
OSHA CSI
Rate (ml/min)
8 varies 4 8 50 min varies varies 4-24 4-24 4-24 6
240 96 100 480
OSHA CSI NIOSH 5509
TWA
CLG/ STEL
10 3 varies 5-30 5-30 240-7200 240-7200 240-7200 5 mg/m3 360 60 (15 min) (C) 960
ASTM D 4861
Benzene-soluble particulate matter
Vol. (liter)
PS CAN ST PS ST SB ST PUF PUF PUF FLT CST FLT CST ST FLT CF/CST FLT C/HLD FLT C/HLD PUF PEM F/CST C/HLD F/CST C/HLD PUF PEM F/CST C/HLD F/CST C/HLD F/CST PUF
500-100 228 Series 226-01 575-002 226-01 232 Series 226-01 226-92 226-92 226-92 225-27-07 225-2LF 225-7 225-2LF 226-56 225-16 225-9004 225-17A 225-1 225-17-04 225-1 226-131 761-200B 225-1713 225-1 225-1713 225-1 226-131 761-203B 225-1713 225-1 225-1713 225-1 225-706 226-131
35 64 35 50 35 42 42 42 74 86 79 86 36 79 61 74 87 74 87 43 98 74 87 74 87 43 98 74 87 74 87 79 43
F/CST C/HLD F/CST C/HLD PUF
225-1713 225-1 225-1713 225-1 226-131
74 87 74 87 43
F/CST C/HLD HPLC-FD F/CST C/HLD GC-FID F/CST C/HLD HPLC-FD F/CST C/HLD GR & HPLC- FLT FD, or GR & C/HLD
225-1713 225-1 225-1713 225-1 225-1713 225-1 225-1713 225-1 225-7 225-1
74 87 74 87 74 87 74 87 79 87
ST ST ST ST FLT C/HLD F/CST C/HLD F/CST ST PS
226-30 226-115 226-56 226-110 225-17-04 225-1 225-1713 225-1 225-706 226-35-03 575-001
35 37 36 37 74 87 74 87 79 36 or
IMP F/CST ST ST DT CAN ST ST F/CST C/HLD F/CST F/CST
225-36-1 225-3-01 226-73 226-95 810-136L 228 Series 226-01 226-01 225-3-01 225-1 225-3-01 225-3-01
59 77 36 37
W TMP
225-2414 225-2415
124 TMP 124
HPLC-UV GC-MS
15 15 15
GC-FID GC-FID GC-FID P GC-PID
varies
GC-FID GC-ECD GC-ECD GC-ECD
15
GR
HPLC-UV GC-ECD HPLC
NIOSH 5506
480
ASTM D 6209
350 m (max)
225 L/min
1-24
GC-MS
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-FD
960 350 m3 (max)
2000 225 L/min
8 1-24
HPLC-UV
ASTM D 6209 NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
HPLC-FD
ASTM D 6209
350 m (max)
225 L/min
1-24
GC-MS
NIOSH 5515
480
2000
4
GC-FID
NIOSH 5506
480
2000
4
NIOSH 5515
480
2000
4
480
2000
4
960
2000
8
3
OSHA CSI
3
NIOSH 5506 OSHA 58
0.2 mg/m
3
GC-MS
HPLC-UV
2,3-Benzofuran Benzoic acid Benzophenone Benzophenone Benzophenonetetracarboxylic acid dianhydride
8 4 8 4 100 min
NIOSH 2550
480
1000
8
GC-SCD
OSHA CSI
240 12
2000 200
2 1
HPLC-UV
OSHA CSI NON 39 OSHA PV2130
Benzothiazole in asphalt fume 2-Benzothiazolethiol Benzotrichloride Benzotrifluoride (trifluoromethyl benzene, OXSOL 2000) Benzoyl chloride Benzoyl peroxide Benzyl acetate Benzyl alcohol Benzyl bromide Benzyl chloride Benzyl chloride Benzyl chloride (hydrocarbons, halogenated) Beryllium (elements by ICP Aqua Regia ashing)
200 100 1000 200 1000
HPLC-UV
OSHA CSI
96 24 480 48 100
OSHA CSI
0.5 mg/m3
OSHA ID 216SG
GC-FID GC-FID HPLC
GC-FID
100 OSHA CSI NIOSH 5009
GC-FID
5 mg/m3
OSHA PV2124 OSHA PV2009
GC-FID
90 90 10 24
1000 1500 100 100
1.5 1 100 min 4
GC-ECD HPLC-UV GC-FID GC-FID
OSHA CSI
DET TB
ASTM D 5466 OSHA 07 NIOSH 1003 NIOSH 7301 ¥
1187 1 1 0.0005 mg/m3
6 10
varies 20(50)
10 1250-2000
1000-4000
varies
ICP-AES
1000-4000 1000-4000
varies varies
ICP-AES
Beryllium (elements by ICP HNO3 digestion) Beryllium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7303 NIOSH 7300 1455 0.0005 mg/m3
35-25,000,000 1250-2000
Beryllium (elements on wipes)
NIOSH 9102
wipe
varies 8(3.3) 10-200
GC-MS GC-FID
varies
GC-FID
ICP-AES ICP-AES
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
B
67
35 35 or 87 77 77
PK
228 Series
SP
225-27
87
SP C/HLD
225-27 225-1
87 87
CST C/HLD CST
225-32 225-1 225-3LF
87 87 86
CST
225-3LF
86
FLT FLT ST
225-1821 225-1709 226-30-04
79 74 35
ST
226-30-04
35
FLT FLT ST
225-1821 225-1709 226-30-04
79 74 35
ST
226-30-04
35
C/HLD FLT
225-1 225-1821
87 79
ST
226-30-04
35
ST
226-30-04
35
FLT
225-1821
79
ST
226-30-04
35
ST
226-30-04
35
ST
226-30-04
35
ST
226-30-04
35
CST
225-2LF
86
CST
225-2LF
86
ST
226-30-04
35
C/HLD
225-1
87
PS
575-002
64
IT C/HLD
225-22 225-1
59 87
PK
228 Series
F/CST
225-803
73
C/HLD C/HLD
225-1 225-1
87 87
225-2403
or
References and abbreviations are found on pages 196-197.
www.skcinc.com
143
Sampling Guide SAMPLING ∞
www.skcinc.com for updates B
Chemical Hazard
Passive Guide
Agency Reference
Agency Standard Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
TWA
Beryllium (ICP analysis of metal/metalloid particulates from solder operations)
OSHA ID 206
2 mg/m3
5 mg/m3 (C)
480
Beryllium (in air by portable fluorometry)
NIOSH 7704
2 mg/m3
5 mg/m3 (C)
240-2000
OSHA ID 125G
2 μg/m3
5 μg/m3
480
Beryllium & compounds Beryllium & compounds (as Be)
NIOSH 7102
Betasan
Rate (ml/min)
CLG/ STEL
10
TWA
2000
Time
CLG/ STEL
2000
TWA (hrs)
4
CLG/STEL (ppm)
5
1000-4000 60
2000
2000
4
15
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
P FLUOR UV/VIS
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
C/HLD
225-1
87
225-9598A
105
C/HLD
225-1
87
0. 5 μg/m3 960
2000
8
AA-GF
F/CST
225-3-01
77
480
1000
8
GC-FPD
ST
226-30-16
35
OSHA CSI
BHC (alpha-, beta-, gamma-)
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Bioaerosol sampling
NIOSH 0800
varies
28,300
varies
varies
BI
225-9611
103
Bioaerosols Bioaerosols
NON 48
Biphenyl (diphenyl)
0.2
NIOSH 2530
15-150
15000
1-10 min
varies
STC
225-9820
81
62.5-375
12500 +
5-30
varies
BS
225-9595
105 VT ◊
10
20(50)
8(3.3)
GC-FID
ST
226-35-01
35
Bipolaris species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Bipolaris species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
HPLC
ST C/HLD
226-30-05 225-1
35 87
F/CST
225-706
79
NON 26
96
Bis (tributyltin) oxide (tin, organic compounds [as Sn])
OSHA CSI
960
2000
8
AA-GF
F/CST
225-709
79
C/HLD
225-1
87
Bismuth
OSHA CSI
960
2000
8
AA
F/CST
225-3-01
77
C/HLD
225-1
87
1-10,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
960
2000
8
AA or AES
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
varies
varies
varies
GR & AA or GR & AES
CYC FLT
225-105 225-8-01
94 73
C/HLD CST
225-1 225-3LF
87 86
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
4,4’-Bipyridine (vapor & aerosol)
2
200
200
8
10
Bismuth (elements by ICP HNO3 digestion)
NIOSH 7303
Bismuth telluride, Se-doped
OSHA ID 121
5 mg/m3
Bismuth telluride, undoped (respirable dust)
OSHA ID 121
5 mg/m
Bismuth telluride, undoped (total dust)
OSHA CSI
15 mg/m
Bisphenol A
OSHA CSI
360
1500
4
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Bladex
OSHA CSI
100
1000
100 min
HPLC-UV
IMP
225-36-1
59
IT
225-22
59
OSHA ID 125G
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
OSHA CSI
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
Borates tetrasodium salts (anhydrous, decahydrate & pentahydrate) Boric acid (total dust) Boron (elements by ICP HNO3 digestion)
3
3
1-3300
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA CSI
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
Boron carbide
NIOSH 7506
600
2500
4
XRD
F/CST CYC
225-803 225-01-02
73 95
C/HLD
225-1
87
Boron oxide (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
C/HLD CST
225-1 225-3LF
87 86
Boron oxide (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
480
2000
4
ICP-AES
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
NIOSH 7303
Boron (total dust)
Boron oxide (total dust)
OSHA CSI
15 mg/m3
5
1000
5
IC
IMP
225-36-2
59
IT
225-22
59
15
1000
15
ISE
IMP
225-36-2
59
IT
225-22
59
6.7
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
50 min
HPLC-UV
IMP
225-36-1
59
IT
225-22
59
Boron tribromide
OSHA CSI
Boron trifluoride
OSHA CSI
Botran
OSHA CSI
400
1000
Bromacil
OSHA CSI
50
1000
1 (C)
Bromine
NIOSH 6011 1329 0.1
Bromine
OSHA ID 108
0.3
0.1
240
15
1000
1000
4
15
IC
CF/CST 225-9006
61
C/HLD
225-1
87
120
7.5
500
500
4
15
IC
IMP
225-36-2
59
IT
225-22
59
OSHA CSI
48
200
4
IC
ST
226-10-03
35
Bromoethane (ethyl bromide)
NIOSH 1011
4
20(50)
3.3(1.3)
GC-FID
ST
226-01
35
Bromoform
OSHA 07
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
10
10-200
varies
GC-FID
ST
226-01
35
0.1-12
10-200
varies
GC-FID
ST
226-01
35
12
100
2
GC-FID
ST
226-01
35
0.1-12
10-200
varies
GC-FID
ST
226-01
35
12
100
2
GC-FID
ST
226-01
35
0.3
20
15 min
GC-FID
ST
226-09
Bromine pentafluoride
Bromoform (hydrocarbons, halogenated)
NIOSH 1003
1-Bromopropane
NIOSH 1025
1-Bromopropane
OSHA PV2061
2-Bromopropane
NIOSH 1025
2-Bromopropane
OSHA PV2062
1127 0.5 0.5 (skin)
Bromotrifluoromethane (trifluorobromomethane)
NIOSH 1017
35
ST
226-01
35
Bromoxynil
NIOSH 5010
240
1000
4
HPLC-UV
F/CST
225-1713
74
C/HLD
225-1
87
Bromoxynil octanoate
NIOSH 5010
240
1000
4
HPLC-UV
F/CST
225-1713
74
C/HLD
225-1
87
Bronkosol
OSHA CSI
480
1000
8
HPLC
F/CST
225-706
79
C/HLD
225-1
87
Brucine
OSHA CSI
180
1000
3
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
varies
varies
varies
GC-FID
ST
226-01
35
BTEX (hydrocarbons, aromatic. See benzene, toluene, ethylbenzene, & xylene)
NIOSH 1501
1,3-Butadiene
1,3-Butadiene
1000
varies
NIOSH 1024 1010 LFC OSHA 56
1011 1
5
10
20
8
GC-FID
ST
226-37
36
3
50
1
GC-FID
ST
226-73
36 35
Butane
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
1,3-Butanediol
OSHA CSI
60
2000
30 min
GC-FID
ST
226-57
36
1
50
15
GC-FPD
ST
226-109
37 35
1-Butanethiol (butyl mercaptan) n-Butanol (alcohols combined)
0.5
NIOSH 2525
2-Butanone 2-Butanone (ketones I)
NIOSH 1405
50 (skin)
2-10
10-200
varies
GC-FID
ST
226-01
OSHA 1004
200
12
50
4
GC-FID
ST
NA SKC
GC-FID
ST
NA SKC
GC-FID
ST
226-81A
36
GC-FID
PS
575-002
64
ST
226-10
35
1-10
NIOSH 2555
2-Butanone (methyl ethyl ketone)
NIOSH 2500 1012 200
2-Butanone (methyl ethyl ketone)
OSHA 1004
2-Butanone (methyl ethyl ketone)
OSHA 16
300
10
10-200 3
200 1282 200
20(50)
varies 200
16.88 3
1.5
100
8(3.3)
15
8 100
30 min
15
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
144
Analytical Method SKC Collecting Equipment & Page Number
www.skcltd.com
GC-FID
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
2-Butanone (methyl ethyl ketone)
Agency Reference
Chem F File
Vol. (liter)
CLG/STEL (ppm)
200
OSHA 84
Butene
TWA (ppm)
TWA
3
OSHA CSI
Rate (ml/min)
CLG/ STEL
0.75
TWA
50
50
TWA (hrs)
1
15
Analytical Method SKC Collecting Equipment & Page Number GC-FID
ST
NA SKC
1
20
50 min
GC-FID
ST
226-01
35
10-50
varies
GC-FID
ST
226-01
35
48
100
8
GC-FID
ST
226-01
35
48
100
8
GC-FID
ST
226-01
35 35
2-Butoxyethanol (butyl CELLOSOLVE solvent)
OSHA 83
2-Butoxyethanol acetate (butyl CELLOSOLVE acetate)
OSHA 83
n-Butyl acetate
OSHA 07
n-Butyl acetate
n-Butyl acetate
sec-Butyl acetate
OSHA 07
200
10
sec-Butyl acetate
OSHA 1009
1750 200
12
sec-Butyl acetate
OSHA 1009
1750 200
t-Butyl acetate
OSHA 07
200
10
t-Butyl acetate
OSHA 1009
1750 200
12
t-Butyl acetate
OSHA 1009
1750 200
n-Butyl acetate (esters I)
NIOSH 1450 1272 150
sec-Butyl acetate (esters I)
NIOSH 1450
200
1-10
10-200
varies
t-Butyl acetate (esters I)
NIOSH 1450
200
1-10
10-200
Butyl acrylate
OSHA PV2011
12
50
n-Butyl acrylate
NON 54
5
n-Butyl alcohol
OSHA 07
sec-Butyl alcohol
t-Butyl alcohol
n-Butyl alcohol (alcohols combined)
sec-Butyl alcohol (alcohols combined)
50
CLG/STEL (ppm)
2-10
2-Butoxyethanol (alcohols IV)
NIOSH 1403 1275 5 (skin)
www.skcinc.com for updates
Time
CLG/ STEL
150
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
OSHA 1009
1750 150
12
0.75
50
50
4
15
GC-FID
ST
226-01
35
OSHA 1009
1750 150
13.07
13.07
8
15
GC-FID
PS
575-002
64
GC-FID
ST
226-01
35
50
50
4
15
GC-FID
ST
226-01
35
12.74
12.74
8
15
GC-FID
PS
575-002
64
GC-FID
ST
226-01
35
50
50
4
15
GC-FID
ST
226-01
35
13.09
13.09
8
15
GC-FID
PS
575-002
64
10-200
10-200
varies
varies
GC-FID
ST
226-01
35
GC-FID
ST
226-01
35
varies
GC-FID
ST
226-01
35
4
GC-FID
ST
226-73
36
200
8(3.3)
20(50) 0.75 1-10
8(3.3)
10
3
20
200
8
15
GC-FID
ST
226-81A
36
100
10
1
20
200
8
5
GC-FID
ST
226-01
35
OSHA 07
150
10
GC-FID
ST
226-01
35
OSHA 07
100
10
200
8(3.3)
GC-FID
ST
226-01
35
NIOSH 1405
50 (skin)
2-10
GC-FID
ST
226-01
35
NIOSH 1405
100
150
2-10
GC-FID
ST
226-01
35
t-Butyl alcohol (alcohols I)
NIOSH 1400
100
150
10
GC-FID
ST
226-01
35
n-Butyl alcohol (alcohols II)
NIOSH 1401
50
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
35
sec-Butyl alcohol (alcohols II)
NIOSH 1401
150
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
35
Butyl benzyl phthalate
100
15
1-10
20(50) 0.75
20(50) 3
20(50)
8(3.3)
10-200 2-10
10-200
15
varies 10-200
20(50)
varies
varies
8(3.3)
OSHA CSI
180
1000
3
HPLC-UV
F/CST
225-706
79
Butyl butryrate
OSHA PV2090
10
200
50 min
GC-FID
ST
226-01
35
Butyl carbitol
OSHA PV2095
10
200
50 min
GC-FID
ST
226-01
35
Butyl carbitol acetate
OSHA PV2095
10
200
50 min
GC-FID
ST
226-01
35
960
2000
IC-UV
F/CST
225-802 Ω
73
GC-FID
PS
575-001
64
Butyl CELLOSOLVE acetate (see 2-butoxyethanol acetate)
Butyl CELLOSOLVE solvent (see 2-butoxyethanol)
t-Butyl chromate (as CrO3)
n-Butyl glycidyl ether
NIOSH 1616
n-Butyl glycidyl ether
OSHA 07
5.6 (15 min) 1125 50
3
15
GC-FID
ST
226-01
35
10
20(50)
200 8(3.3)
15
GC-FID
ST
226-01
35 35
t-Butyl glycidyl ether
OSHA CSI
10
200
50 min
GC-FID
ST
226-01
Butyl isocyanate
OSHA CSI
15
50
5
HPLC-UV
ST
NA SKC
GC-FID
ST
226-01
35
GC-FPD
ST
226-109
37
GC-FPD
ST
226-109
37
GC-FPD
CF/CST 225-9007
61
10
OSHA PV2080
0.5
NIOSH 2525
Butyl mercaptan (butanethiol)
10
OSHA CSI NIOSH 2542 1330
n-Butyl mercaptan (mercaptans) t-Butyl methyl ether
Butyl ziram N-t-Butyl-2-benzothiazolesulfenamide Butylamine
n-Butylamine
Butylated hydroxytoluene
1.5
50 min 50
25 12
100
15 1
200
8
60
OSHA CSI
96
200
8
GC-FID
ST
226-37
36
OSHA PV2065
180
1000
3
HPLC-UV
ST
226-30-16
35
OSHA CSI
120
1000
2
HPLC-UV
F/CST
225-709
79
5
GC-FID
ST
226-53
36
15
5 (C)
OSHA CSI
5
5
NIOSH 2012 OSHA CSI NIOSH 5523 1404
1,3-Butylene glycol (glycols)
200 1
0.5 (15 min) 48
OSHA PV2108
sec-Butylbenzene
1000
GC-FID
ST
226-53
36
100
15 1000
1000 100 min
GC-FID
ST
226-57
36
6
100
1
GC-FID
ST
226-01
35
60
1000
1
GC-FID
ST
226-57
36 37
o-sec-Butylphenol
OSHA CSI
10
100
1.6
HPLC-UV
ST
226-95
p-tert-Butylphenol
OSHA PV2085
20
200
100 min
GC-FID
ST
226-95
37
Butyltin trichloride
OSHA ID 217SG
240
1000
4
AA-GF
ST
226-30-16
35
p-tert-Butyltoluene
OSHA 07
p-tert-Butyltoluene (hydrocarbons, aromatic)
NIOSH 1501
1129 10 10
20
10
3
20(50)
200
8(3.3)
15
GC-FID
ST
226-01
35
1-29
1-29
10-200
10-200
varies
varies
GC-FID
ST
226-01
35
Butyraldehyde
ASTM D 5197
varies
500-1200
5 min-24 hrs
HPLC-UV
ST
226-120
or
Butyraldehyde (aldehydes, screening)
NIOSH 2539
5
20
4
GC-FID & GC-MS
ST
226-118
37
16.5
4
HPLC-UV
PS
500-100
67
OSHA CSI
18
100
3
GC-FID
ST
226-15
35
OSHA CSI
9.6
20
8
GC-FID
ST
226-01
35
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Butyraldehyde
Butyric acid beta-Butyrolactone gamma-Butyrolactone
225-1
87
C/HLD
225-1
87
C/HLD
225-1
87
C/HLD
225-1
87
ST
226-119
37
OSHA 83
t-Butyl ethyl ether (ethyl tert-butyl ether)
n-Butyl mercaptan
C/HLD
OSHA 83 OSHA ID 215 (V2) 1439 0.005 mg/m3
n-Butyl lactate
B
8
Cadmium
OSHA ID 189 1456 5 μg/m3
960
2000
8
AA
F/CST
225-3-01
77
C/HLD
225-1
87
Cadmium (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
LFC
13-2000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Cadmium (elements by ICP HNO3 digestion)
NIOSH 7303
3-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cadmium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1280 LFC
13-2000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cadmium (elements on wipes)
NIOSH 9102
wipe
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
Cadmium & compounds (as Cd)
NIOSH 7048 1467 LFC
Cadmium dust (as Cd)
OSHA ID 121
480
30
1000
2000
8
15
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
0.2 mg/m3 0.5 mg/m3 960
30
2000
2000
8
15
AA
F/CST
225-3-01
77
C/HLD
225-1
87
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
145
Sampling Guide SAMPLING ∞
www.skcinc.com for updates C
Chemical Hazard
Passive Guide
Agency Reference
Agency Standard Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
Rate (ml/min)
CLG/ STEL
TWA
0.2 mg/m3 0.5 mg/m3 960
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA ID 206
0.1 mg/m3 0.3 mg/ m3 (C)
480
2000
4
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
varies
5-200
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Calcium (elements by ICP HNO3 digestion)
NIOSH 7303
2-10,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 varies
5-200
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium (see specific compounds)
NIOSH 7020
varies
varies
varies
varies
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium & compounds (as Ca)
NIOSH 7020
varies
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
600
2000
5
AA-GF
F/CST
225-3-01
77
C/HLD
225-1
87 87
OSHA CSI
8
15
Analytical Method SKC Collecting Equipment & Page Number
OSHA ID 206
Calcium bromide (see dust, total & respirable nuisance)
2000
CLG/STEL (ppm)
Cadmium fume (ICP analysis of metal/metalloid particulates from solder operations)
OSHA CSI
2000
TWA (hrs)
Cadmium dust (as Cd)
Calcium arsenate (as As)
30
TWA
Time
CLG/ STEL
Calcium carbonate
OSHA ID 121
15 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
Calcium carbonate (calcium)
NIOSH 7020
2 mg/m3
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium carbonate (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
C/HLD CST
225-1 225-3LF
87 86
Calcium carbonate (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
Calcium carbonate (see dust, total & respirable nuisance) Calcium cyanamide
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium hydroxide
OSHA ID 121
5 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium hydroxide (calcium)
NIOSH 7020
2 mg/m3
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium oxide
OSHA ID 121
5 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium oxide (calcium)
NIOSH 7020
2 mg/m3
240
1000
4
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium oxide (elements by ICP HNO3 digestion)
NIOSH 7303
2 mg/m3
3-10,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Calcium silicate (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT
225-8-01
73
C/HLD
225-1
87
Calcium silicate (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
35
CST
225-32
87
Calcium hydroxide (see dust, total & respirable nuisance)
Calcium sulfate (see dust, total & respirable nuisance) Camphor
Camphor (ketones II ) Camphor (ketones II)
Caprolactam Capsaicin Captafol (difolatan)
OSHA 07
1130 2 mg/m3
10
20(50)
8(3.3)
GC-FID
ST
226-01
NIOSH 2553
2
1-25
10-200
varies
GC-FID
ST
NA SKC
NIOSH 1301
2
10
20(50)
8(3.3)
GC-FID
ST
226-01
OSHA PV2012
100
1000
100 min
HPLC-UV
ST
226-57
36
NIOSH 5041
480
HPLC-FD
FLT
225-16
79
OSHA CSI
240
1000
4
GC-ECD
ST
226-30-16
35
15
1000
1000
8
15
35
Captan
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Captan
OSHA PV2093
60
1000
1
HPLC-UV
ST
226-30-16
35
240
1000
4
HPLC-UV
ST
226-58
or
ST
226-30-16
35
120
1000
2
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
Captan (organonitrogen pesticides)
5 mg/m3
NIOSH 5601
Carbadox
OSHA CSI
Carbaryl
ASTM D 4861
Carbaryl (organonitrogen pesticides)
NIOSH 5601
5 mg/m3
240
1000
4
HPLC-UV
ST
226-58
or
ST
226-30-16
35
Carbaryl (Sevin)
NIOSH 5006
5 mg/m3
240
1000
4
VAS
F/CST
225-706
79
C/HLD
225-1
87
Carbaryl (Sevin)
OSHA 63
5 mg/m3
60
1000
1
HPLC-UV
ST
226-30-16
35 36 ST
226-30-16
35
OSHA CSI
120
1000
2
GC-FID
ST
226-56
NIOSH 5601
240
1000
4
HPLC-UV
ST
226-58
or
Carbitol
OSHA PV2013
10
200
50 min
GC-FID
ST
226-01
35
Carbitol acetate
OSHA PV2013
10
200
50 min
GC-FID
ST
226-01
35
Carbofuran
ASTM D 4861
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
Carbofuran (organonitrogen pesticides)
NIOSH 5601
0.1 mg/m3
240
1000
4
HPLC-UV
ST
226-58
or
ST
226-30-16
35
Carbon black
NIOSH 5000
3.5 mg/m3
360
1500
4
GR
FLT SCN
225-8-01 225-26
73 87
CST C/HLD
225-3LF 225-1
86 87
Carbon black
OSHA ID 196
3.5 mg/m3
960
2000
8
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
SB
263-03
52
Carbazol Carbendazim (organonitrogen pesticides)
Carbon dioxide
OSHA ID 172 1026 5000
Carbon dioxide (by portable GC)
NIOSH 6603 1027 5000 NIOSH 1600
1
Carbon monoxide
OSHA ID 209
50
Carbon monoxide
OSHA ID 210 1021 50
Carbon tetrachloride
Carbon tetrachloride
OSHA 07
Carbon tetrachloride (hydrocarbons, halogenated)
NIOSH 1003
Carbon disulfide
Carbon tetrabromide
varies
varies
10-50
300
4-8
15
GC-TCD
SB
253-03
or
30,000
varies
varies
20-100
20-100
varies
varies
P GC-TCD
SB
232 Series
50
10
10
3
20(50)
200
8(3.3)
15
GC-FPD
ST
226-01
35
DRT
226-44
36
DRI
DRI
805-18972 SB SB
253-10 263-10
or 52
PK
228 Series
varies
varies
10-50
1000
OSHA CSI
9
3
50
200
ASTM D 5466
6 1131 10
25
15
2 (1 hr)
varies 3
50
15
varies
varies
GC-DID
SB SB
252-10 262-10
or or
3
15
GC-ECD
ST
226-93
37
GC-MS
CAN
228 Series
15
GC-FID
ST
226-01
35
varies
GC-FID
ST
226-01
35
varies 200
5
10-200
Carbon, activated (see dust, total nuisance) Carbonyl fluoride
OSHA CSI
480
2000
4
ISE
IMP
225-36-2
59
IT
225-22
59
Carboxin
OSHA CSI
200
1000
3.3
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
NIOSH 1552
24
50
8
GC-FID
ST
226-01
35
C/HLD CST
225-1 225-3LF
87 86
3-Carene (terpenes)
Catechol (pyrocatechol)
OSHA PV2014
Cell fragments (bioaerosols) CELLOSOLVE acetate (see 2-ethoxyethyl acetate)
CELLOSOLVE solvent (see 2-ethoxyethanol) (alcohols IV)
Cellulose (paper fiber) (particulates, respirable)
100
1000
100 min
HPLC-UV
ST
226-57
36
15-150
15000
1-10 min
varies
STC
225-9820
81
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
NIOSH 1403 1273 NIOSH 0600 1038
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
146
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Cellulose (paper fiber) (particulates, total)
Agency Reference
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
Rate (ml/min)
CLG/ STEL
TWA
TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
Cellulose insulation
NIOSH 7404
varies
1000
varies
SEM
FLT/CL 225-1604
78
Cerium
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
Cesium hydroxide
OSHA CSI
960
2000
8
AA
F/CST
225-3-01
Chaetomium species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
Chaetomium species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
C
C/HLD
225-1
87
77
C/HLD
225-1
87
77
C/HLD
225-1
87
225-3-01
77
C/HLD
225-1
87
225-9611
103
Cellulose (see dust, total or respirable nuisance)
Chloramphenicol
OSHA CSI
Chlordane
0.5 mg/m3
NIOSH 5510
Chlordane
1000
1
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
150
1000
2.5
GC-ECD
ST CST C/HLD
226-107 225-2LF 225-1
37 86 87
FLT SCN
225-5 225-26
76 87
480
1000
8
GC-ECD
ST
226-30-16
35
Chlordane (non-occupational exposure)
ASTM D 4947 1417
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Chlordane (technical)
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Chlorinated & organonitrogen herbicides
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
Chlorinated & organonitrogen herbicides (hand wash)
NIOSH 9200
Chlorinated camphene (toxaphene)
NIOSH 5039
LFC
30
Chlorinated diphenyl ether (chlorinated diphenyl oxide)
NIOSH 5025
0.5 mg/m3
180
1000
Chlorinated diphenyl oxide
NIOSH 5025
0.5 mg/m3
90
Chlorinated hydrocarbons (screening)
NIOSH 2549
5
OSHA 67
1013 0.5 mg/m3
60
15
NA SKC F/CST
225-3-01
77
C/HLD
225-1
87
3
GC-ECD
F/CST
225-3-01
77
C/HLD
225-1
87
1000
1.5
GC-ECD
F/CST
225-3-01
77
C/HLD
225-1
87
20
4
GC-MS
ST
226-330
39
225-706
87
1000
15
GC-ECD
F/CST
79
C/HLD
225-1
NIOSH 6011 1332 0.5
1
90
15
1000
1000
1.5
15
IC
CF/CST 225-9006
61
C/HLD
225-1
87
Chlorine
OSHA ID 101 1052
1 (C)
240
15
1000
1000
4
15
ISE
IMP
225-36-2
59
IT
225-22
59
Chlorine (prefiltered)
OSHA ID 101 1289
1 (C)
240
15
1000
1000
4
15
ISE
IMP CST FLT
225-36-2 225-3-23** 225-2708**
59 86 74
IT SP
225-22 225-2901**
59 87
Chlorine dioxide
OSHA ID 202 1462 0.1
120
7.5
500
500
4
15
IC-ECN
IMP
225-36-2
59
IT
225-22
59
15
ISE
IMP
225-36-2
59
IT
225-22
59
GC-FID
ST
226-113
37
GC-FID
PS
575-001
or
PS
575-002
64
CYC
225-105
94
PK
228 Series
CST
225-32
PK
228 Series
IT
225-22
NIOSH 5014
Chlorine trifluoride
OSHA CSI
1-Chloro-1-nitropropane
OSHA CSI
1-Chloro-2-methyl benzene (o-chlorotoluene, OXSOL 10)
20
12
0.75 mg/m3 0.23 mg/m3 50
NON 55
15
8
1000 50
4
50
5-Chloro-2-methyl-4-isothiazolin-3-one (Kathon 886) 1-Chloro-4-(trifluoromethyl)benzene (parachlorobenzotrifluoride)
0.1
1500
0.5
Chlorine
Chlorinated terphenyl (60% chlorine)
720
GC-ECD GC-ECD
1000
7.5
6
OSHA CSI
200
500
100
4
HPLC-UV
ST
226-99
37
1
15
GC-FID
ST
226-01
35
2-Chloro-6-trichloromethyl pyridine (respirable dust)
OSHA CSI
15 mg/m3
480
1000
8
HPLC-UV
ST
226-30-16
35
2-Chloro-6-trichloromethyl pyridine (total dust)
OSHA CSI
5 mg/m3
varies
varies
varies
HPLC-UV
ST
226-30-16
35 35
Chloroacetaldehyde
NIOSH 2015
Chloroacetaldehyde
OSHA 76
Chloroacetic acid
1
3
200
15
GC-ECD
ST
226-15GWS
1 (C)
2.5
500
5
GC-ECD
ST
226-15GWS
35
NIOSH 2008
0.05
48
100
8
IC-ECN
ST
226-47-01
36 35
alpha-Chloroacetophenone (phenacylchloride)
OSHA CSI
12
200
1
HPLC-UV
ST
226-35-02
Chloroacetyl chloride
OSHA CSI
10
50
3.3
HPLC-UV
ST
NA SKC
o-Chloroaniline
OSHA CSI
5
20
4
HPLC-UV
ST
226-10
35
p-Chloroaniline
OSHA PV2109
6
100
1
HPLC-UV
ST
226-10
35
6
varies
varies
GC-MS
CAN
228 Series
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Chlorobenzene (monochlorobenzene)
ASTM D 5466
Chlorobenzene (monochlorobenzene)
OSHA 07
Chlorobenzene (monochlorobenzene) (hydrocarbons, halogenated)
NIOSH 1003
10
10-200
varies
GC-FID
ST
226-01
35
4-Chlorobenzotrifluoride
NIOSH 1026
0.1-10.0
10-200
varies
GC-FID
ST
226-01
35
4-Chlorobenzotrifluoride
OSHA CSI
6
100
1
GC-FID
ST
226-01
35
p-Chlorobenzotrifluoride
NIOSH 1026
0.1-10.0
10-200
varies
GC-FID
ST
226-01
35
p-Chlorobenzotrifluoride
OSHA CSI
6
100
1
GC-FID
ST
226-01
35
0.001 mg/m3 (10 hr)
48
100(200)
8(4)
GC-ECD
FLT ST
225-16 226-39
79 36
Chlorobiphenyl
1132 75
NIOSH 5503
Chlorobromomethane
OSHA CSI
200
5
20
4
GC-FID
ST
226-01
35
Chlorobromomethane (hydrocarbons, halogenated)
NIOSH 1003
200
5
10-200
varies
GC-FID
ST
226-01
35
Chlorodifluoromethane
OSHA CSI
1
50
20 min
GC-FID
ST
NA SKC
Chlorodiphenyl
OSHA CSI
60
1000
1
GC-ECD
ST
226-30-16
35
Chlorodiphenyl (21% Cl) (see polychlorinated biphenyls)
OSHA CSI
1
60
1000
1
GC-ECD
ST
226-30-16
35
0.5
60
1000
1
GC-ECD
ST
226-30-16
35
3
50
1
GC-FID
ST
226-09
35
1
10
20(50)
8(3.3)
GC-FID
ST
226-81A
36
6
varies
varies
GC-MS
CAN
228 Series
10
200
50 min
GC-FID
ST
226-01
GC-FID
ST
226-01
35
GC-ECD
IMP
225-36-2
59
GC-ECD
ST
226-125
38
Chlorodiphenyl (32% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chlorodiphenyl (42% Cl)
OSHA PV2089
Chlorodiphenyl (42% Cl) (see polychlorinated biphenyls)
NIOSH 5503
Chlorodiphenyl (48% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chlorodiphenyl (54% Cl)
OSHA PV2088
Chlorodiphenyl (54% Cl) (see polychlorinated biphenyls)
NIOSH 5503
Chlorodiphenyl (60% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chlorodiphenyl (62% Cl) (see polychlorinated biphenyls)
OSHA CSI
Chloroethane (ethyl chloride)
NIOSH 2519
2-Chloroethanol (ethylene chlorohydrin)
NIOSH 2513
Chloroform (trichloromethane)
ASTM D 5466
Chloroform (trichloromethane)
OSHA 05
Chloroform (trichloromethane) (hydrocarbons, halogenated)
1062
NIOSH 1003 1269
bis-Chloromethyl ether
OSHA 10
Chloromethyl methyl ether
NON 29
50 (C) 2
15 50
1251
2.4
10-200 500
0.3
10
varies 100 min
20
4
15
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
87
Phone: +1-724-941-9701
35 59
References and abbreviations are found on pages 196-197.
www.skcinc.com
147
Sampling Guide SAMPLING ∞
www.skcinc.com for updates C
Chemical Hazard
Passive Guide
Chloromethyl methyl ether
Agency Reference
Agency Standard Chem F File
TWA (ppm)
CLG/STEL (ppm)
OSHA 10
4-Chloronitrobenzene (nitrobenzenes)
0.1 ppm
NIOSH 2005
Vol. (liter)
Rate (ml/min)
CLG/ STEL
TWA
Time
CLG/ STEL
TWA
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
50
500
100 min
GC-ECD
IMP
225-36-2
59
96
200
8
GC-FID
ST
226-10
35
Chloropentafluoroethane
OSHA CSI
2.5
50
50 min
GC-FID
ST
226-01
35
Chlorophene
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-35
35
o-Chlorophenol
OSHA CSI
40
200
3.3
HPLC-UV
ST
226-10
35
p-Chlorophenol
NIOSH 2014
24
50
8
HPLC-UV
ST
226-10
35
144
100
24
GC-MSD
ST
226-175
38
GC-ECD
ST
226-93
37
GC-FID
ST
226-01
35 35
Chloropicrin
NON 51
0.1
Chloropicrin
OSHA PV2103
0.1
NIOSH 1002
beta-Chloroprene
OSHA 07
1133 25
beta-Chloroprene
OSHA 112
25
o-Chlorostyrene
3 1 (15 min)
beta-Chloroprene
15 min 100
15
10
20(50)
8(3.3)
GC-FID
ST
226-01
6
50
2
GC-ECD
ST
226-111A
37
100 min 15
GC-FID
ST
226-01
35
20
OSHA CSI
200 1.5
3
200
200
Chlorothalonil
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Chlorothalonil
OSHA CSI
180
1000
3
HPLC-UV
F/CST
225-709
79
OSHA CSI
20
200
100 min
GC-FID
ST
226-01
35
o-Chlorotoluene Chlorotoluron
IT
225-22
59
C/HLD
225-1
87
ST
226-30-16
35
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
OSHA CSI
10
200
50 min
GC-FID
ST
226-01
35
Chlorpropham (organonitrogen pesticides)
NIOSH 5601
240
1000
4
HPLC-UV
ST
226-58
or
Chlorpyrifos (Dursban)
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
480
1000
8
GC-FPD
ST
226-30-16
35
240
1000
4
GC-FPD
ST
226-58
36
960
2000
8
IC-UV
F/CST
225-802 Ω
73
C/HLD
225-1
87
1000
4
VAS
F/CST
225-803
73
C/HLD
225-1
87
Chlorotrifluoroethylene
Chlorpyrifos (Dursban) Chlorpyrifos (organophosphorus pesticides) Chromic acid & chromates (as CrO3)
ASTM D 4861
OSHA 62 NIOSH 5600
1394 0.2 mg/m3
OSHA ID 215 (V2) 1439 0.005 mg/m3
15
Chromic acid & chromates (chromium hexavalent)
NIOSH 7600
1 μg/m3 (10 hr)
240
Chromic acid & chromates (chromium hexavalent)
NIOSH 7604
1 μg/m3 (10 hr)
960
2000
8
IC-ECN
F/CST
225-803
73
C/HLD
225-1
87
Chromium & compounds (as Cr)
NIOSH 7024 1457 0.5 mg/m3
10 - 1000
1000 - 3000
varies
AA-F
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-8410
77
Chromium (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
0.5 mg/m3
5-1000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
0.5 mg/m
Chromium (elements by ICP HNO3 digestion)
NIOSH 7303
8-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 0.5 mg/m3
5-1000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium (elements on wipes)
NIOSH 9102
wipe
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
3
Chromium acetate
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium carbonate
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Chromium metal & insoluble compounds
OSHA ID 121 1043 1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77 87
Chromium metal & insoluble compounds
OSHA ID 125G
Chromium phosphate
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
Chromium soluble salts (except hexavalent)
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
960
2000
8
IC-UV
F/CST
225-802 Ω
73
C/HLD
225-1
87
varies
1000-5000
varies
IC
F/CST F/CST
225-802 225-709
or or
F/CST F/CST
225-1713 225-401
or 79
240
1000
4
VAS
F/CST
225-802
73
C/HLD
225-1
87
240
1000
4
IC-ECN
F/CST
225-802
73
C/HLD
225-1
87
Chromium trioxide (CR(VI))
OSHA ID 215 (V2) 1439 0.005 mg/m3
Chromium, hexavalent
ASTM D 6832
Chromium, hexavalent
NIOSH 7600 1032 1 μg/m3
(10 hr) Chromium, hexavalent
NIOSH 7604 1032 1 μg/m3
(10 hr) Chromium, hexavalent
NIOSH 7605
0.001 mg/m3 (10 hr)
1-400
1000-4000
varies
IC-PCD-UV
F/CST
225-802
73
C/HLD
225-1
87
Chromium, hexavalent
NIOSH 7703
0.001 mg/m3 (10 hr)
10-1200
1000-4000
varies
P VAS
F/CST
225-802
73
C/HLD
225-1
87
DPP
F/CST
225-802
73
C/HLD
225-1
87
IC-UV
FLT
225-8-01-1
or
FLT
225-1822
79
IC-UV
F/CST
225-802 Ω
73
C/HLD
225-1
87
225-7 225-1
79 87
CST
225-2LF
86
Chromium, hexavalent
OSHA ID 103
0.005 mg/m3 (C) 960
Chromium, hexavalent
OSHA W4001
0.005 mg/m3 (C)
Chromium, hexavalent (CR(VI)) Chromium, hexavalent (in settled dust) Chrysene
OSHA ID 215 (V2) 1439 0.005 mg/m3
OSHA 58
960 bulk
NIOSH 9101
0.2 mg/m3
30
2000 2000
2000
8
15
8
bulk
CLR or VAS or IC
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
Chrysene (polynuclear aromatic hydrocarbons by GC-MS)
ASTM D 6209
350 m3 (max)
225 L/min
1-24
GC-MS
PUF
226-131
43
FLT
225-1821
79
Chrysene (polynuclear aromatic hydrocarbons by GC)
NIOSH 5515
LFC
480
2000
4
GC-FID
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
Chrysene (polynuclear aromatic hydrocarbons by HPLC)
NIOSH 5506
LFC
480
2000
4
HPLC-UV
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
C/HLD
225-1
87
C/HLD
225-1
87
Chrysosporium species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Chrysosporium species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
Chrysotile (see asbestos fibers)
NIOSH 9000
bulk
Chrysotile fibers (see asbestos fibers)
NIOSH 7400
XRD
Cladosporium species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Cladosporium species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
Clopidol (respirable fraction)
OSHA CSI
5 mg/m3
varies
varies
varies
HPLC-UV
F/CST CYC
225-706 225-105
79 94
C/HLD
225-1
87
15 mg/m3
120
1000
2
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
480
1000
8
GC-FPD
ST
226-30-16
35
varies
varies
varies
GR
FLT CYC
225-8-01 225-105
73 94
C/HLD CST
225-1 225-3LF
87 86
Clopidol (total dust)
OSHA CSI
Co-Ral (coumaphos)
OSHA CSI
Coal dust (< 5% SiO2)
OSHA CSI
2.4 mg/m3/ (%SiO2+2)
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
148
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Agency Reference
Coal dust (> 5% SiO2)
OSHA ID 142
Coal tar naphtha (naphthas) Coal tar pitch volatiles
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
TWA
Rate (ml/min)
CLG/ STEL
TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
(10 mg/m3)/ (%SiO2+2)
varies
varies
varies
GR & XRD
F/CST CYC
NIOSH 1550
100
3
20
2.5
GC-FID
ST
OSHA 58
1076 0.2 mg/m3
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
225-803 225-105
73 94
C
C/HLD CST
225-1 225-3LF
87 86
225-2LF
86
226-01
35
225-7 225-1
79 87
CST
Cobalt
OSHA ID 213
0.1 mg/m3
480
2000
6
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
0.5 mg/m3 (dust, fume)
25-2000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Cobalt (elements by ICP HNO3 digestion)
NIOSH 7303
0.5 mg/m3 (dust, fume)
3-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 0.05 mg/m3
25-2000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt (elements on wipes)
NIOSH 9102
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
Cobalt & compounds (as Co)
NIOSH 7027
(dust, fume) wipe 960
2000
8
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt acetate
OSHA ID 125G
0.05 mg/m
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
Cobalt carbonyl
OSHA ID 121
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Cobalt hydrocarbonyl
OSHA ID 121 1193 0.1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
0.1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
OSHA ID 121 1210 0.1 mg/m3
960
2000
8
AA or AES
F/CST
960
2000
8
GR & HPLC- FLT FD, or GR & C/HLD HPLC-UV
3
(as Co) Cobalt metal, dust & fume
OSHA ID 125G
Cobalt metal, dust & fume (as Co) Coke oven emissions
OSHA 58
0.15 mg/m3
225-3-01
77
C/HLD
225-1
87
225-7 225-1
79 87
CST
225-2LF
86
Command (dimethazone)
OSHA PV2066
60
1000
1
GC-ECD
ST
226-30-16
35
Copper (elements by ICP Aqua Regia ashing)
NIOSH 7301 ¥
1 mg/m3 (dust) 0.1 mg/m3 (fume)
5-1000
1000-4000
varies
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-803
73
Copper (elements by ICP HNO3 digestion)
NIOSH 7303
1 mg/m3 (dust) 0.1 mg/m3 (fume)
15-500,000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Copper (elements by ICP HNO3/HClO4 ashing)
NIOSH 7300 1455 1 mg/m3 (dust)
5-1000
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
Copper (elements on wipes)
NIOSH 9102
ICP-AES
W TMP
225-2414 225-2415
124 TMP 124
225-2403
or
Copper dust Copper dusts & mists
0.1 mg/m3 (fume) wipe
NIOSH 7029
1 mg/m
3
480
1000
8
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA ID 125G
1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
Copper dusts & mists (as Cu)
OSHA ID 121 1205 1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
Copper fume
NIOSH 7029
0.1 mg/m3
480
1000
8
AA-F
F/CST
225-3-01
77
C/HLD
225-1
87
Copper fume
OSHA ID 121 1206 0.1 mg/m3
960
2000
8
AA or AES
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA ID 125G
0.1 mg/m3
480
2000
4
ICP-AES
F/CST C/HLD
225-3-01 225-1
or 87
F/CST
225-3100
77
OSHA ID 206
0.1 mg/m3
480
2000
4
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
960
2000
8
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Copper fume Copper fume (ICP analysis of metal/metalloid particulates from solder operations) Corn starch (see dust, respirable nuisance) Coronene
OSHA CSI
Corundum (Al2O3) (see alpha-alumina [total dust]) Corundum (emery) (particulates, respirable)
NIOSH 0600 1038
375
2500
2.5
GR
FLT CYC
225-8-01 225-01-02
73 95
C/HLD CST
225-1 225-3LF
87 86
Corundum (emery) (particulates, total)
NIOSH 0500 1035
120
2000
1
GR
FLT CST
225-8-01 225-2LF
73 86
C/HLD
225-1
87
141.5
28,300
5 min
varies
BI
225-9611
103
2664
7.4
6
GR
FLT
225-8-01
73
CST
225-3LF
86
225-8-01-1 73 SP 225-381 ♠ and IS 225-386 ♠ 96
Corynebacterium species (bacteria)
OSHA CSI
Cotton dust (raw)
OSHA CSI
1 mg/m3 1 mg/m3
Cotton Dust (raw)
OSHA CSI
Coumarin
OSHA CSI
Crag herbicide (respirable dust)
OSHA CSI
5 mg/m3
Crag herbicide (total dust)
OSHA CSI
15 mg/m
p-Cresidine (see 5-methyl-o-anisidine)
OSHA CSI
960
3
2
8
GR
FLT PPI PPI
225-27 225-388
with or
96
200
8
HPLC-UV
ST
226-30-04
35
varies
varies
varies
CLR
F/CST CYC
225-803 225-105
73 94
C/HLD
225-1
87
90
1500
1
CLR
F/CST
225-3-01
77
C/HLD
225-1
87
di-tert-butyl-p-Cresol
OSHA PV2108
100
1000
100 min
GC-FID
ST
226-57
36
Cresol (all isomers)
NIOSH 2546
10 mg/m3
24
100
4
GC-FID
ST
226-95
37
Cresol (all isomers)
OSHA 32
5 mg/m3
24
100
4
HPLC-UV
ST
226-95
37
Cresols (see Environmental Sampling Guide)
EPA TO-8
Cresylil acid (see cresol, all isomers)
VERT. ELUTRIATOR (NA SKC) and
OSHA CSI
Cristobalite
OSHA ID 142
varies
varies
varies
GR & XRD
F/CST CYC
225-803 225-105
73 94
C/HLD
225-1
87
NIOSH 7500 1370 0.05 mg/m
3
Cristobalite (silica, crystalline [respirable] by XRD )
400-1000
2500
varies
XRD
F/CST C/HLD
225-803 225-1
73 87
CYC
225-01-02
95
0.05 mg/m
3
Cristobalite (silica, crystalline by IR)
NIOSH 7602
400-800
2500
varies
IR
F/CST CYC
225-803 225-01-02
73 95
C/HLD
225-1
87
Cristobalite (silica, crystalline by VAS)
NIOSH 7601 1041 0.05 mg/m
3
400-800
2500
varies
VAS
F/CST CYC
225-803 225-01-02
73 95
C/HLD
225-1
87
Crocidolite fibers (see asbestos fibers)
NIOSH 7400
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
149
Sampling Guide SAMPLING ∞
www.skcinc.com for updates C
Agency Standard TWA (ppm)
CLG/STEL (ppm)
Rate (ml/min)
Chemical Hazard
Agency Reference
Crotonaldehyde
ASTM D 5197
varies
500-1200
5 min-24 hrs
HPLC-UV
ST
226-120
or
ST
226-119
37
Crotonaldehyde
NIOSH 3516
2
48
200
4
DPP
IMP
225-36-2
59
IT
225-22
59
Crotonaldehyde
OSHA 81
2
6
100
1
HPLC-UV
CF/CST 225-9019
61
C/HLD
225-1
87
Crotonaldehyde (aldehydes, screening)
NIOSH 2539
2
5
20
4
GC-FID & GC-MS
ST
226-118
37
226-30-16
35 C/HLD
225-1
87
OSHA PV2015
Cryolite (fluorides)
2.5 mg/m3
NIOSH 7902
Cumene (isopropyl benzene)
OSHA 07
Cumene (isopropyl benzene)
OSHA PV2137
Cumene (isopropyl benzene) (hydrocarbons, aromatic)
NIOSH 1501
1065 50
CLG/ STEL
Time
Passive Guide
Crufomate
Chem F File
Vol. (liter) TWA
TWA
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
60
1000
1
GC-FPD
ST
480
1000
8
ISE
CF/CST 225-9001
61
10
20(50)
8(3.3)
GC-FID
ST
226-01
35 35
50
24
200
2
GC-FID
ST
226-01
50 (skin)
1-30
10-200
8(3.3)
GC-FID
ST
226-01
35
Cumene hydroperoxide
OSHA CSI
120
1000
2
HPLC-UV
IMP
225-36-1
59
IT
225-22
59
Cunninghamella species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
C/HLD
225-1
87
Cunninghamella species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
960
1000-4000
varies
ICP-AES
F/CST
225-3-01
77
C/HLD
225-1
87
C/HLD
225-1
87
Cupric carbonate as Cu (elements by ICP HNO3/ HClO4 ashing)
NIOSH 7300 1455
Curvularia species (fungi, molds, spores)
OSHA CSI
120
1000
2
varies
F/CST
225-3-01
77
Curvularia species (fungi, molds, spores)
OSHA CSI
141.5
28,300
5 min
varies
BI
225-9611
103
Cyanamide
OSHA CSI
10
100
100 min
HPLC-UV
ST
226-30-18
35
Cyanazine
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
Cyanide (as Cn)
OSHA ID 120
120
1000
2
ISE
F/CST IT
225-3-01 225-22
77 59
IMP
225-36-2
59
Cyanides, aerosol & gas
NIOSH 7904
120
500
4
ISE
FLT IMP C/HLD
225-2705 ∆ 225-36-2 225-1
74 59 87
CST IT
225-2LF 225-22
86 59
GC-NPD
ST
226-117
37
GC-NPD
ST
226-117
37 C/HLD
225-1
87
C/HLD
225-1
87
C/HLD
225-1
87
ST
226-30
35
Cyanogen
5 mg/m3 5 mg/m (10 min) 3
12
OSHA PV2104
Cyanogen chloride
200 1
OSHA CSI
Cyanuric acid
NIOSH 5030
5
480
1000
8
HPLC-UV
F/CST
225-802
73
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
2.5-5
10-200
varies
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35 35
Cyclohexane (hydrocarbons, BP 36 to 216 C)
Cyclohexanol
OSHA 07
Cyclohexanol (alcohols combined)
NIOSH 1405
50 (skin)
1-10
10-200
varies
GC-FID
ST
226-01
Cyclohexanol (alcohols III)
NIOSH 1402
50
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Cyclohexanone
OSHA 01
1073 50
10
20(50)
8(3.3)
GC-FID
ST
226-110
37
Cyclohexanone (ketones I)
NIOSH 1300
25
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
1-10
10-200
varies
GC-FID
ST
NA SKC
1124 300
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
300
5-7
10-200
varies
GC-FID
ST
226-01
35
OSHA CSI
480
2000
4
HPLC-UV
F/CST
225-709
79
Cyclohexylamine
OSHA PV2016
20
200
100 min
GC-FID
ST
226-98
37
Cyclonite (RDX)
OSHA CSI
120
1000
2
HPLC-UV
F/CST
225-709
79
Cyclopentane
OSHA CSI
5
200
25 min
GC-FID
ST
226-01
35
Cyhexatin
OSHA ID 197SG
480
2000
4
AA-GF
F/CST C/HLD
225-709 225-1
79 87
OSHA PV2063
60
1000
60 min
GC-ECD
ST
226-30-16
35
2,4-D (2-butoxyethyl ester)
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D (2-butoxyethyl ester)
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D (2,4-dichlorophenoxyacetic acid)
NIOSH 5001
10 mg/m3
180
1000
3
HPLC-UV
F/CST
225-706
79
C/HLD
225-1
87
2,4-D (2,4-dichlorophenoxyacetic acid)
OSHA CSI
10 mg/m3
180
3000
1
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
D & C red #19
OSHA CSI
240
1000
4
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
480
1000
8
GC-ECD
ST
226-58
36
C/HLD
225-1
87
OSHA 07
1134 300
1 200
Cyclohexane
Cyclohexanone (ketones I)
NIOSH 1500 1268 300
1135 50
NIOSH 2555
Cyclohexene
OSHA 07
Cyclohexene (hydrocarbons, BP 36 to 216 C)
NIOSH 1500
N-Cyclohexyl-2-benzothiazolesulfenamide
Cypermethrin
1.5 mg/m3 (skin)
2,4-D acid
NIOSH 5602
2,4-D, BE
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D, EH
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
2,4-D, ME (2,4-dichlorophenoxyacetic acid)
NIOSH 5602
480
1000
8
GC-ECD
ST
226-58
36
Dacthal
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
60
1000
1
GC-FID
ST
226-30-16
35
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
90
1500
1
GC-ECD
F/CST
225-709
79
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
GC-ECD
PUF
226-92
42
ICP
F/CST
225-3-01
77
C/HLD
225-1
87
225-1822 225-2LF
79 86
SP
225-27
87
C/HLD
225-1
87
87
DAP (diallyl phthalate)
10
OSHA CSI
DBP (see dibutyl phthalate)
OSHA 104
p,p-DDE
ASTM D 4861
DDT
OSHA CSI
p,p-DDT
ASTM D 4861
DDVP (dichlorvos)
ASTM D 4861
Decaborane
OSHA CSI
Decabromodiphenyl oxide
1 mg/m3
240-7200 0.05
NIOSH 2559
Decabromodiphenyl oxide
Decyl alcohol
480
1000-5000 30
2000
4-24 2000
4
15
48-960
2000
varies
HPLC-UV
FLT CST
200
1000
3
GC-ECD
F/CST
225-709
79
NIOSH 1500
2
10-50
varies
GC-FID
ST
226-01
35
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
OSHA CSI
n-Decane (hydrocarbons, BP 36 to 216 C) DEHP (see di-2-ethylhexyl phthalate)
OSHA 104
Dehydroabietic acid
OSHA CSI
180
2000
1.5
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
Dehydroisoandrosterone
OSHA CSI
240
1000
4
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
SCN ST
225-26 226-30-05
87 35
C/HLD
225-1
87
NIOSH 5514
0.1 mg/m3
480
1000
8
GC-FPD
FLT CST C/HLD
225-5 225-2LF 225-1
76 86 87
Demeton (Systox)
OSHA CSI
0.1 mg/m3
480
1000
8
GC-FPD
ST
226-30-16
35
Demosan
OSHA CSI
960
2000
8
GC-ECD
F/CST
225-709
79
Demeton
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
150
Analytical Method SKC Collecting Equipment & Page Number
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
DEP (see diethyl phthalate)
Agency Reference
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
Rate (ml/min)
CLG/ STEL
TWA
TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
D
OSHA 104
Desflurane
Di-(2-ethylhexyl) adipate
OSHA 106
1760
OSHA CSI
Di-(2-ethylhexyl) phthalate
5 mg/m3
3
50
1
GC-FID
ST
226-81A
36
180
1000
3
GC-FID
FLT C/HLD
225-17-04 225-1
74 87 35
GC-FID
ST
226-30-16
NIOSH 5020
180
1000
3
GC-FID
F/CST
225-3-01
77
OSHA PV2076
240
1000
4
GC-FID
ST
226-56
36
Di-n-octyl phthalate (DNOP)
OSHA 104
240
1000
4
GC-FID
ST
226-56
36
Di-n-octyl-phthalate (DNOP)
OSHA CSI
90
1000
1.5
GC-ECD
ST
226-56
36
OSHA CSI
Di-(2-ethylhexyl) phthalate (DEHP) Di-n-hexyl phthalate
60
15
1000
1000
1
15
CST
225-3LF
86
C/HLD
225-1
87
Di-sec-octyl phthalate (see di-[2-ethylhexy] phthalate) Di(ethyleneglycol) ethyl ether acrylate
1 mg/m3
OSHA PV2132
Diacetone alcohol
OSHA 07
Diacetone alcohol (alcohols combined)
NIOSH 1405
Diacetone alcohol (alcohols III)
NIOSH 1402
48
200
4
GC-FID
ST
226-110
37
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
50
1-10
10-200
varies
GC-FID
ST
226-01
35
50
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
6
100
1
GC
ST
NA SKC
1123 50
Diacetyl
NIOSH 2557
Diacetyl
OSHA 1012
0.05
9
3
50
200
3
15
GC-FID
ST
226-183
38
Diacetyl
OSHA 1013
0.05
9
3
50
200
3
15
GC-FID
ST
226-183
38
Diallyl disulfide
OSHA PV2086
10
20(50)
8(3.3)
GC-FPD
ST
226-110
37
Diallyl phthalate
OSHA CSI
60
1000
1
GC-FID
ST
226-30-16
35
226-30-18
35
1,2-Diaminoethane
NIOSH 2540
o-Dianisidine
OSHA 71
o-Dianisidine dyes (dyes, benzidine)
1235 LFC
NIOSH 5013
o-Dianisidine-based dyes
OSHA CSI
Diazinon
ASTM D 4861
Diazinon
OSHA 62
10
100
1.7
HPLC-UV
ST
100
1000
100 min
GC-ECD
CF/CST 225-9004
61
C/HLD
225-1
87
480
1000
8
HPLC-UV
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
480
1000
8
HPLC-UV
FLT C/HLD
225-17-04 225-1
74 87
CST
225-3LF
86
240-7200 1396
GC-NPD
PUF
226-92
42
480
1000
1000-5000 4-24 8
GC-FPD
ST
226-30-16
35
Diazinon (organophosphorus pesticides)
NIOSH 5600
0.1 mg/m3
240
1000
4
GC-FPD
ST
226-58
36
Diazomethane
NIOSH 2515
0.2
10
200
50 min
GC-FID
ST
226-23
35
Diazomethane
OSHA CSI
0.2
10
200
50 min
GC-FID
ST
226-23
35
Dibenz(a,h)anthracene
OSHA CSI
960
2000
8
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Dibenz(a,h)anthracene (polynuclear aromatic hydrocarbons by GC-MS)
ASTM D 6209
350 m3 (max)
225 L/min
1-24
GC-MS
PUF
226-131
43
FLT
225-1821
79
Dibenz(a,h)anthracene (polynuclear aromatic hydrocarbons by GC)
NIOSH 5515
480
2000
4
GC-FID
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
Dibenz(a,h)anthracene (polynuclear aromatic hydrocarbons by HPLC)
NIOSH 5506
480
2000
4
HPLC-FD
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
Diborane
NIOSH 6006
120
1000
2
PES
ST CST
226-151 225-32
38 87
FLT
NA SKC
and
35
PK
228 Series
IT
225-22
59
0.1
Dibrom
OSHA CSI
3 mg/m
60
1000
1
GC-FPD
ST
226-30-16
1,2-Dibromo-3-chloropropane (DBCP)
OSHA CSI
1 ppb
10
20(50)
8(3.3)
GC-ECD
ST
226-81A
36
100
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
GC-MS
CAN
228 Series
GC-ECD
ST
226-01
35
Dibromodifluoromethane (difluorodibromomethane)
NIOSH 1012
1,2-Dibromoethane (ethylene dibromide)
ASTM D 5466
1,2-Dibromoethane (ethylene dibromide)
NIOSH 1008
Dibutyl amine
3
6 0.045
0.13
50
varies 200
8
15
120
1000
2
GC-NPD
IMP
225-36-2
59
20(50)
8(3.3)
GC-FID
ST
226-10-04
35
240
2000
2
GC-FPD
FLT C/HLD
225-17-01 225-1
74 87
CST
225-2LF
86
NIOSH 5020
5 mg/m
3
100
1000
100 min
GC-FID
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA 104
5 mg/m3
240
1000
4
GC-FID
ST
226-56
36
0.1 mg/m3
480
1000
8
HPLC & AA-GF
ST C/HLD
226-30 225-1
35 87
F/CST
225-709
79 87
NIOSH 2007
2
Dibutyl phosphate
NIOSH 5017
1
Dibutyl phthalate Dibutyltin bis (isooctyl mercaptoacetate) (organotin compounds as Sn)
varies 3
10
OSHA CSI
2-Dibutyl aminoethanol (aminoethanol compounds I)
Dibutyl phthalate (DBP)
24
NIOSH 5504
2
Dibutyltin dilaurate (as Sn)
OSHA ID 218SG
500
1000
500 min
AA
F/CST
225-3-01
77
C/HLD
225-1
Dibutyltin maleate (as Sn)
OSHA ID 224SG
200
1000
200 min
AA-GF
F/CST
225-3-01
77
C/HLD
225-1
87
OSHA CSI
200
1000
3.3
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Dicamba sodium salt
OSHA CSI
200
1000
3.3
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
1,1-Dichloro-1-fluoroethane
OSHA 113
1
50
20 min
GC-FID
ST
NA SKC
1,1-Dichloro-1-nitroethane
NIOSH 1601
GC-FID
ST
226-81A
36
1,1-Dichloro-1-nitroethane
OSHA 07
10
GC-FID
ST
226-81A
36
1,1-Dichloro-1-nitroethane
OSHA CSI
10
C/HLD
225-1
87
PK
228 Series
PK
228 Series
PK
228 Series
C/HLD
225-1
Dicamba
2
10
20(50) 15
8(3.3) 1000
15
10
20
8
GC-FID
ST
226-81A
36
NON 50
9
50
3
GC-FID
ST
226-09
35
3,3-Dichloro-1,1,1,2,2-pentafluoropropane
OSHA CSI
9
50
3
GC-FID
ST
226-01
35
1,3-Dichloro-1,1,2,2,3-pentafluoropropane
OSHA CSI
9
50
3
GC-FID
ST
226-01
35
Dichloroacetylene
OSHA CSI
GC-FID
ST
226-01
35
3,4-Dichloroaniline
OSHA CSI
73
2,2-Dichloro-1,1,1-trifluoroethane
1
200
5
100
1000
1.5
HPLC
F/CST
225-803
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
m-Dichlorobenzene
m-Dichlorobenzene
OSHA CSI
10
200
50 min
GC-FID
ST
226-01
o-Dichlorobenzene
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
o-Dichlorobenzene
OSHA 07
GC-FID
ST
226-01
p-Dichlorobenzene
ASTM D 5466
p-Dichlorobenzene
OSHA 07
o-Dichlorobenzene (hydrocarbons, halogenated)
NIOSH 1003
p-Dichlorobenzene (hydrocarbons, halogenated)
NIOSH 1003
3,3’-Dichlorobenzidine
OSHA 65
1122
50 (C)
3 6
1121 75
3 50
1.7 (LOQ) 1238
200 varies
0.75
20
3
15 varies
50
2.5
10-200
Phone: +1-724-941-9701
35
GC-MS
CAN
228 Series
15
GC-FID
ST
226-01
35
varies
GC-FID
ST
226-01
35
3
10-200
varies
GC-FID
ST
226-01
35
100
1000
100 min
GC-ECD
CF/CST 225-9004
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
35
61
87
References and abbreviations are found on pages 196-197.
www.skcinc.com
151
Sampling Guide SAMPLING ∞
www.skcinc.com for updates D
Chemical Hazard
Passive Guide
Dichlorodifluoroethane
TWA (ppm)
OSHA 07 ASTM D 5466
1,1-Dichloroethane (ethylidene chloride)
OSHA 07
1,1-Dichloroethane (hydrocarbons, halogenated)
1119 50
100
100
NIOSH 1003 1267 100
Dichloroethyl ether
NIOSH 1004
Dichloroethyl ether
OSHA 07
1,2-Dichloroethylene
OSHA 07
cis-1,2-Dichloroethylene
ASTM D 5466
1,2-Dichloroethylene (hydrocarbons, halogenated)
NIOSH 1003
trans-1,2-Dichloroethylene
NIOSH 2516
Dichlorofluoromethane Dichloromethane
Dichloromethane (see methylene chloride)
NIOSH 2516
Dichloromonofluoromethane (dichlorofluoromethane)
OSHA CSI
2,4-Dichlorophenoxyacetic acid (2,4-D)
5
1,2-Dichloropropane (propylene dichloride)
ASTM D 5466
1,2-Dichloropropane (propylene dichloride)
NIOSH 1013
1,3-Dichloropropene
TWA
Time
CLG/ STEL
TWA
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
3
100
30 min
GC-FID
ST
226-01
35
3
20
2.5
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
6
varies
varies
GC-MS
CAN
228 Series
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
10
10-200
varies
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
15
10
GC-FID
ST
226-01
35 35
1118 200
NIOSH 5001
Rate (ml/min)
CLG/ STEL
10
15
20
1000
8
15
3
20
2.5
GC-FID
ST
226-01
6
varies
varies
GC-MS
CAN
228 Series
200
3
10-200
varies
GC-FID
ST
226-01
DT
810-174D
10
3
20
2.5
GC-FID
ST
226-25
6
varies
varies
GC-MS
CAN
228 Series
ASTM D 5466
Dichloromonofluoromethane (dichlorofluoromethane)
Vol. (liter)
CLG/STEL (ppm)
1000
NIOSH 1018
1,1-Dichloroethane (ethylidene chloride)
cis-1,3-Dichloropropene
Chem F File
OSHA CSI
Dichlorodifluoromethane 1,2-Dichloroethane (ethylene dichloride)
Agency Reference
Agency Standard
226-09
PK
228 Series
PK
228 Series
PK
228 Series
35
35 35
10
3
20
2
GC-FID
ST
226-09
1000
3
20
2.5
GC-FID
ST
226-09 ♠
35
10 mg/m3
180
1000
3
HPLC-UV
F/CST
225-709
79
6
varies
varies
GC-MS
CAN
228 Series
LFC
ST
35
3
20
2.5
GC-ECN
ST
226-81A
36
OSHA CSI
5
200
25 min
GC-FID
ST
226-01
35
C/HLD
225-1
PK
228 Series
87
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
PK
228 Series
trans-1,3-Dichloropropene
ASTM D 5466
6
varies
varies
GC-MS
CAN
228 Series
PK
228 Series
3,4-Dichloropropionanilide
OSHA CSI
W
FLT
225-7
79
2,2-Dichloropropionic acid
OSHA PV2017
10
200
50 min
HPLC-UV
ST
226-10
35
Dichlorotetrafluoroethane
OSHA CSI
3
50
1
GC-FID
ST
226-09
35
ST
226-01
35
1,1-Dichlorotetrafluoroethane
OSHA CSI
2
50
40 min
GC-FID
ST
226-01
35
ST
226-09
35
1,2-Dichlorotetrafluoroethane (dichlorodifluoromethane)
NIOSH 1018
3
20
2.5
GC-FID
ST
226-01
35
ST
226-09
35
35
Dichlorotrifluoroethane
1000
NON 50
Dichlorvos (DDVP)
ASTM D 4861
Dichlorvos (DDVP)
OSHA 62
1395 1 mg/m3
9
50
3
GC-FID
ST
226-09
240-7200
1000- 5000
4-24
GC-ECD
PUF
226-92
42
480
1000
8
GC-FPD
ST
226-30-16
35 42
Dicloran
ASTM D 4861
240-7200
1000- 5000
4-24
GC-ECD
PUF
226-92
Dicofol
ASTM D 4861
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
Dicofol
OSHA CSI
W
SM TB
225-24
124
Dicrotophos
ASTM D 4861
240-7200
1000-5000
4-24
HPLC-UV
PUF
226-92
42
Dicrotophos (Bidrin)
OSHA PV2099
480
1000
8
GC-FPD
ST
226-30-16
35
240
1000
4
GC-FPD
ST
226-58
36
10
100
100 min
GC-FID
ST
226-01
35
varies
varies
GR
FLT CST
225-8-01 225-3LF
73 86
C/HLD
225-1
87
C/HLD
225-1
87
Dicrotophos (organophosphorus pesticides) Dicyclopentadiene Dicyclopentadienyl iron (respirable dust) Dicyclopentadienyl iron (total dust) Dieldrin
OSHA PV2098 OSHA CSI
5 mg/m3
varies
OSHA CSI
15 mg/m3
960
2000
8
AA
F/CST
225-3-01
77
240-7200
1000-5000
4-24
GC-ECD
PUF
226-92
42
180
1500
2
GC-ECD
F/CST
225-709
79
C/HLD
225-1
87
ASTM D 4861
Dieldrin
0.25 mg/m3
OSHA CSI
Diesel emissions (see elemental carbon)
NIOSH 5040
Diesel exhaust particles (see elemental carbon)
NIOSH 5040
Diesel particulate matter
ASTM D 6877
Diesel particulate matter
MSHA 30CFR57
Diesel particulate matter
MSHA 30CFR57
Diethanolamine
TOA-FID TOA-FID
varies
1000-4000
varies
EGA-TOS
DPM
225-317
or
F/CST
225-401
84
350 μg/m3 (total carbon)
varies
2000
varies
TOA-FID
DPM C/HLD
225-317 225-1
84 87
CYC
225-105
85
350 μg/m (total carbon)
varies
varies
varies
TOA-FID
F/CST C/HLD
225-401 225-1
84 87
CYC
225-100
94
IT
225-22
59
IT
225-22
59
C/HLD
225-1
87
3
10
100
100 min
HPLC-UV
ST
226-30-18
35
NIOSH 3509 1006 3
240
1000
4
IC
IMP
225-36-1
59
NIOSH 1610
0.25-3
10-200
varies
GC-FID
ST
226-01
35
OSHA PV2018
Diethanolamine (DEA) (aminoethanol compounds II) Diethyl ether (ethyl ether)
0.25 mg/m3
NIOSH 5600
Diethyl ketone (3-pentanone)
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
NA SKC
Diethyl phthalate (DEP)
OSHA 104
240
1000
4
GC-FID
ST
226-56
36
Diethyl sulfate
OSHA CSI
15
1000
15 min
GC-FID
ST
226-10
35 37
1697 25
10
3
200
200
50 min
15
HPLC
ST
226-96
24
3
50
200
8
15
GC-FID
ST
226-10
35
2
GC-FID
ST
226-10-04
35
20(50)
8(3.3)
GC-FID
ST
226-10-04
35
1000
100 min
GC-NPD
IMP
225-36-1
59
Diethylamine
OSHA 41
Diethylamine (amines, aliphatic)
NIOSH 2010
10
OSHA CSI
10
24
200
NIOSH 2007
10
10 100
2-Diethylaminoethanol 2-Diethylaminoethanol (aminoethanol compounds I) Diethylaminopropylamine (DEP)
25
OSHA CSI
Diethylene dioxide (see dioxane) Diethylene ether (see dioxane) Diethylene glycol (glycols)
60
1000
1
GC-FID
ST
226-57
36
Diethylene glycol methyl ether
NIOSH 5523 1387 OSHA CSI
10
100
100 min
GC-FID
ST
226-01
35
Diethylene glycol monobutyl ether acetate
OSHA CSI
9.6
100
1.6
GC-FID
ST
226-01
35
Diethylene glycol monoethyl ether
OSHA CSI
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
Diethylenetriamine
OSHA 60
10
100
100 min
HPLC-UV
ST
226-30-18
35
1285
Difluorodibromomethane
NIOSH 1012
100
6
50
2
GC-FID
ST
226-01
35
Difluorodibromomethane
OSHA 07
100
10
20
8
GC-FID
ST
226-01
35
Diglycidyl ether of bisphenol A
OSHA CSI
240
1000
4
HPLC-UV
F/CST
225-709
79
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
152
www.skcltd.com
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Diglycolamine Diglyme
Agency Reference
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
TWA
OSHA CSI
20
Rate (ml/min)
CLG/ STEL
TWA
100
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
3
GC-NPD
IMP
225-36-1
59 35
OSHA CSI
20
200
100 min
GC-FID
ST
226-01
Dihexyl phthalate
OSHA PV2076
240
1000
4
GC-FID
ST
226-56
36
Dihydrocapsaicin
NIOSH 5041
480
HPLC-FD
FLT
225-16
79
8(3.3)
GC-FID
ST
226-01
35 35
Diisobutyl ketone
OSHA 07
Diisobutyl ketone (ketones I)
NIOSH 1300
Diisobutyl ketone (ketones I)
OSHA 42
1000
1000
8
15
1116 50
10
20(50)
25
10
20(50)
8(3.3)
GC-FID
ST
226-01
1-10
10-200
varies
GC-FID
ST
NA SKC
NIOSH 2555
Diisocyanates
15
1458
240
1000
1000
4
15
HPLC-UV or CF/CST 225-9002 HPLC-FD C/HLD 225-1
225-22
59
CST
225-32
87
or 87
CF/CST 225-9013
61
IT
225-22
59
120
1000
2
GC-FID
IMP
225-36-1
59
Dimethazone
OSHA PV2066
60
1000
1
GC-ECD
ST
226-30-16
35
Dimethoate
OSHA PV2113
480
1000
8
GC-FPD
ST
226-30-16
35
OSHA CSI
17
50
5.7
HPLC-UV
ST
226-30-04
35
1000
2
20
1.5
GC-FID
ST
226-01
35
1115 1000
2
20
1.5
GC-FID
ST
226-01
35
OSHA PV2019
20
200
100 min
GC-FID
ST
226-01
35
NIOSH 5022
960
2000
8
IC-AA
FLT C/HLD
225-17-01 225-1
74 87
CST
225-2LF
86
12
1000
12 min
GC-FPD
SB
253-10
or
SB
263-10
52
6
100
1
GC-FID
ST
226-01
35
C/HLD IT
225-1 225-22
87 59
ST
226-119
37
Diisopropylamine
5
15
D
IT
OSHA CSI
2,5-Dimethoxyaniline Dimethoxymethane (methylal)
NIOSH 1611
Dimethoxymethane (methylal)
OSHA 07
Dimethyl adipate Dimethyl arsenic acid (arsenic, organo-) Dimethyl disulfide
NON 42
Dimethyl disulfide
OSHA CSI
Dimethyl glutarate
OSHA PV2020
Dimethyl phthalate (DMP)
1413
5 mg/m3
OSHA 104
Dimethyl succinate
OSHA PV2021
Dimethyl sulfate
NIOSH 2524 1284 0.1 (8 hrs.)
Dimethyl sulfate
OSHA PV2147
Dimethyl sulfide
NON 42
Dimethyl sulfide
OSHA CSI
Dimethyl sulfoxide
OSHA CSI
Dimethyl-1,2-dibromo-2,2-dichloroethyl phosphate
OSHA CSI
1 1413
3 mg/m3
200
100 min
GC-FID
ST
226-01
35
240
1000
4
GC-FID
ST
226-56
36
20
200
100 min
GC-FID
ST
226-01
35
12
50
4
GC-ECN
ST
226-114
37 37
10
100
100 min
GC-FPD
ST
226-115
12
1000
12 min
GC-FPD
SB
263-10
52
5
20
4
GC-FPD
ST
226-01
35
10
100
100 min
GC-FID
ST
226-01
35
60
1000
1
GC-FPD
ST
226-30-16
35
10
200
50 min
GC-ECD
ST
226-35-03
36
N,N-Dimethyl-p-toluidine (amines, aromatic)
NIOSH 2002 1055
96
200
8
GC-FID or GC-NSD
ST
226-10
35
Dimethylacetamide
NIOSH 2004 1695 10
48
100
8
GC-FID
ST
226-10
35
OSHA CSI
10
60
1000
1
GC-FID
ST
226-10
35
10
24
50
8
GC-FID
ST
226-10
35
1696 10
10
20
8
HPLC
ST
226-96
37
2,3-Dimethyl-2,3-dinitrobutane
0.15 mg/m3 OEL
20
NON 44
Dimethylacetamide Dimethylamine
NIOSH 2010
Dimethylamine
OSHA 34
2-Dimethylamino ethanol
NIOSH 2561
10-24
20-100
varies
GC-FID
ST
226-94
37
1-Dimethylamino-2-propanol
NIOSH 2561
10-24
20-100
varies
GC-FID
ST
226-94
37
4-Dimethylaminoazobenzene
OSHA CSI
60
1000
1
HPLC-UV
F/CST IMP
225-706 225-36-1
79 59
Dimethylaminobenzene 2,4-Dimethylaminobenzene (amines, aromatic)
OSHA CSI
5
24
50
8
GC-FID
ST
226-10
35
NIOSH 2002
2
24
50
8
GC-FID or GC-NSD
ST
226-10
35
GC-FID
ST
226-01
35
GC-FID
ST
226-98
37
15
GC-FID or GC-NSD
ST
226-10
35
N,N-Dimethylaniline
OSHA 07
5
10
N,N-Dimethylaniline
OSHA PV2064
5
30
N,N-Dimethylaniline (amines, aromatic)
2,5-Dimethylbenzaldehyde
NIOSH 2002 1054 5
trans-1,2-Dimethylcyclohexane
N,N-Dimethylethanolamine N,N-Dimethylethylamine
3
50
8(3.3)
15
2.5 200
8
500-1200
5 min-24 hrs
HPLC-UV
ST
226-120
or
20(50)
8(3.3)
GC-FID
ST
226-01
35
GC-FID
PS
575-001
64
10-24
20-100
varies
GC-FID
ST
226-94
37
OSHA CSI
24
50
8
GC-FID
ST
226-10-04
35
OSHA PV2096
40
100
40 min
GC-NPD
ST
226-18
35
10
24
50
8
GC-FID
ST
226-10
35
1271 10
9.6
GC-NPD
ST
226-01
35
N,N-Dimethylformamide
NIOSH 2004
N,N-Dimethylformamide
OSHA 66
1,1-Dimethylhydrazine
NIOSH 3515
1,1-Dimethylhydrazine
OSHA CSI
Dimethyltin dichloride
NIOSH 5526
Dinitolmide
OSHA CSI
Dinitro-o-cresol
OSHA CSI
4,6-Dinitro-o-sec-butyl phenol
OSHA CSI
Dinitrobenzene (all isomers)
OSHA CSI
2-(2,4-Dinitrophenoxy)ethanol
OSHA CSI
Dinitrotoluene (DNT)
OSHA 44
n-Dioctyl phthalate (DNOP)
OSHA 104
Dioxane (diethylene dioxide)
NIOSH 1602
Dioxane (diethylene dioxide)
OSHA 07
Dioxathion (Delnav)
OSHA CSI
Dioxins (including PHDDs, PCDDs, PBDDs) (see Environmental Sampling Guide)
EPA TO-9A
Diphenyl ether
200
200
10
OSHA CSI NIOSH 2561
N,N-Dimethylethanolamine
24
20(50)
varies
ASTM D 5197
trans-1,4-Dimethylcyclohexane
Diphenyl
10
3
3
20
200
8
15
0.06 (120 min)
60
1000
1
VAS
IMP
225-36-2
59
IT
225-22
59
0.5
96
200
8
CLR
IMP
225-36-2
59
IT
225-22
59
0.1 mg/m3
60
GC-FPD
ST
226-30-16
35
0.2 mg/m3
1 mg/m3 1.5 mg/m3 1 (30 min) 1114 100
60
250
1000
4
60
240
1000
4
HPLC
F/CST
225-706
79
C/HLD
225-1
87
180
1500
2
HPLC-UV
F/CST IT
225-3-01 225-22
77 59
IMP
225-36-1
59
24
50
8
HPLC-UV
ST
226-95
37
60
1000
1
HPLC-UV
ST
226-30-16
35
10
20(50)
8(3.3)
HPLC-UV
ST
226-10
35
60
1000
1
GC-TEA
ST
226-56
36
240
1000
4
GC-FID
ST
226-56
36
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
10
20(50)
8(3.3)
GC-FID
ST
226-01
35
480
1000
8
GC-FPD
ST
226-30-16
35
NIOSH 2530
0.2
30
100
5
GC-FID
ST
226-35-01
35
OSHA PV2022
0.2
20
200
100 min
GC-FID
ST
226-95
37
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
Phone: +1-724-941-9701
References and abbreviations are found on pages 196-197.
www.skcinc.com
153
Sampling Guide SAMPLING ∞
www.skcinc.com for updates D
Chemical Hazard
Passive Guide
Agency Reference
p,p-Diphenyl methane diisocyanate (MDI) (see methylene bisphenyl isocyanate)
OSHA 47
2-Diphenylacetyl-1,3-indandione
OSHA CSI
Diphenylamine
OSHA 78
5,5-Diphenylhydantoin
OSHA CSI
Diphenylmethane-4,4’-diisocyanate (4,4-methylene bisphenyl isocyanate) (isocyanates)
Agency Standard Chem F File
TWA (ppm)
CLG/STEL (ppm)
1229
NIOSH 5521 1001 50 μg/m3
Vol. (liter)
Rate (ml/min)
CLG/ STEL
TWA
TWA
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
480
2000
4
HPLC-UV
F/CST
79
C/HLD
225-1
100
1000
100 min
HPLC-UV
CF/CST 225-9004
61
C/HLD
225-1
87
60
1000
1
HPLC-UV
FLT C/HLD
225-7 ‡ 225-1
79 87
CST
225-3LF
86
225-36-1
59
IT
225-22
59
37
87
200 μg/m3 480 (10 min) C
10
1000
1000
8
10
HPLC-ELCHM IMP & HPLC-UV
225-706
Dipropyl disulfide
OSHA PV2086
10
20(50)
8(3.3)
GC-FPD
ST
226-110
Dipropyl ketone
OSHA CSI
10
20
8
GC-FID
ST
NA SKC
87
Dipropylene glycol methyl ether
OSHA 07
1113 100
10
GC-FID
ST
226-01
35
Dipropylene glycol methyl ether
OSHA 101
100
10
100
100 min
GC-FID
ST
226-01
35
Dipropylene glycol methyl ether (glycol ethers)
NIOSH 2554
3-25
100-200
varies
GC-FID
ST
226-81A
36
Dipropylene glycol monomethyl ether (glycol ethers)
NIOSH 2554
3-25
100-200
varies
GC-FID
ST
226-81A
36
Diquat
OSHA CSI
120
1000
2
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
Direct black 38
OSHA CSI
100
1000
100 min
HPLC
F/CST
225-706
79
C/HLD
225-1
87
480
1000
8
HPLC
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
Direct black 38 (dyes, benzidine)
NIOSH 5013
LFC
3
20(50)
200
8(3.3)
15
Direct blue
OSHA CSI
60
1000
1
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Direct blue 2
OSHA CSI
100
1000
100 min
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Direct blue 6
OSHA CSI
100
1000
100 min
HPLC-UV
F/CST
225-709
79
C/HLD
225-1
87
Direct blue 6 (dyes, benzidine)
NIOSH 5013
LFC
480
1000
8
HPLC
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
Direct blue 8 (dyes, benzidine)
NIOSH 5013
LFC
480
1000
8
HPLC
FLT C/HLD
225-17A 225-1
74 87
CST
225-3LF
86
1000 1000 1000 1000
3 3 100 min 8
HPLC-UV
LFC
180 180 100 480
F/CST F/CST F/CST FLT C/HLD F/CST FLT C/HLD FLT C/HLD F/CST F/CST F/CST ST ST ST F/CST PUF ST ST ST
225-706 225-706 225-709 225-17A 225-1 225-709 225-17A 225-1 225-17A 225-1 225-709 225-709 225-709 226-30-16 226-58 226-30-16 225-706 226-92 226-58 226-73 226-01
79 79 79 74 87 79 74 87 74 87 79 79 79 35 36 35 79 42 or 36 35
C/HLD C/HLD C/HLD CST
225-1 225-1 225-1 225-3LF
87 87 87 86
C/HLD CST
225-1 225-3LF
87 86
CST
225-3LF
86
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
C/HLD
225-1
87
ST
226-30-16
35
ST ST ST ST STC FLT CYC FLT CYC FLT CYC FLT CST FLT CST FLT CST FLT C/HLD ST DPM F/CST C/HLD F/CST C/HLD F/CST F/CST W TMP
226-56 226-01 226-30 226-58 225-9820 225-8-01 225-01-02 225-8-01 225-105 225-8-01 225-01-02 225-8-01 225-2LF 225-8-01 225-2LF 225-8-01 225-2LF 225-17A 225-1 226-30-16 225-317 225-401 225-1 225-3-01 225-1 225-3-01 225-3-01 225-2414 225-2415
36 35 35 36 81 73 95 73 94 73 95 73 86 73 86 73 86 74 87 35 84 79 87 or 87 77 77 124 124
C/HLD CST C/HLD CST C/HLD CST C/HLD
225-1 225-3LF 225-1 225-3LF 225-1 225-3LF 225-1
87 86 87 86 87 86 87
C/HLD
225-1
87
C/HLD
225-1
87
CST
225-3LF
86
CYC CYC
225-105 225-100
85 84
F/CST
225-803
73
C/HLD C/HLD TMP
225-1 225-1 225-2403
87 87 or
Direct blue 98 Direct brown 31 Direct brown 95 Direct brown 95 (dyes, benzidine)
NIOSH 5013
Direct red 2 Direct red 2 (dyes, benzidine)
LFC
120 480
1000 1000
2 8
HPLC-UV
NIOSH 5013
Direct red 28 (dyes, benzidine)
NIOSH 5013
LFC
480
1000
8
HPLC
100 100 120 480 240 480 480 240-7200 240 12 2.5
1000 1000 1000 1000 1000 1000 2000 1000-5000 1000 50 20
100 100 min 2 8 4 8 4 4-24 4 4 2
HPLC-UV
1000 20(50) 1000 1000 15000 2500
1 8(3.3) 2 4 1-10 min varies
GC-TEA
varies
varies
varies
GR
375
2500
2.5
GR
720
1500
8
GR
Direct red 81 Disperse yellow 3 Disulfiram (tetraethylthiuram disulfide) Disulfoton Disulfoton (organophosphorus pesticides) Disyston 2,2’-Dithiobis(benzothiazole) Diuron Diuron (organonitrogen pesticides) Divinyl benzene Divinyl sulfide DMP (see dimethyl phthalate) DNOP (see di-n-octyl phthalate) DNT (dinitrotoluene) Dodecyl alcohol (lauryl alcohol) Dodine Dursban (chlorpyrifos)(organophosphorus pesticides) Dust, inorganic Dust, respirable (in workplace atmospheres) Dust, respirable nuisance Dust, respirable nuisance (particulates) Dust, total nuisance
OSHA CSI OSHA CSI OSHA CSI
OSHA CSI
OSHA CSI OSHA CSI OSHA CSI OSHA PV2105 NIOSH 5600
0.1 mg/m3
OSHA CSI OSHA CSI ASTM D 4861 NIOSH 5601
10 mg/m3
OSHA 89 OSHA CSI
HPLC-UV HPLC-UV HPLC
HPLC
HPLC-UV HPLC-UV GC-FPD GC-FPD GC-FPD HPLC-UV HPLC-UV HPLC-UV GC-FID GC
OSHA 104 OSHA 104
60 10 OSHA CSI 240 NIOSH 5600 0.2 mg/m3 0.6 mg/m3 240 15-150 ASTM D 4532 1418 varies OSHA 44
1.5 mg/m3
OSHA CSI
OSHA CSI
5.0 mg/m3
NIOSH 0600 1038 OSHA CSI
15 mg/m3
GC-FID HPLC-UV GC-FPD
varies GR
Dust, total nuisance (particulates)
NIOSH 0500 1035
120
2000
1
GR
Dust, total, particulates not otherwise regulated
NIOSH 0500 1035
120
2000
1
GR
Dyes, benzidine, o-tolidine, o-dianisidine
NIOSH 5013
480
1000
8
HPLC-UV
480 varies varies
1000 varies varies
8 varies varies
GC-FPD
Dyfonate Elemental carbon (diesel exhaust) Elemental carbon (diesel exhaust)
LFC
OSHA CSI MSHA NIOSH 5040
EGA-TOS TOA-FID
Elements by ICP Aqua Regia ashing (see specific element)
NIOSH 7301 ¥
varies
varies
1000-4000
varies
ICP-AES
Elements by ICP HNO3 digestion (see specific element) Elements by ICP HNO3/HClO4 ashing (see specific element) Elements on wipes (see specific element)
NIOSH 7303
varies
varies varies wipe
1000-4000 1000-4000
varies varies
ICP-AES
NIOSH 7300 1455 varies NIOSH 9102
www.skcltd.com
ICP-AES ICP-AES
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
154
Analytical Method SKC Collecting Equipment & Page Number
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Agency Reference
Elements qualitative Emery (corundum) (particulates, respirable)
OSHA ID 204
Emery (corundum) (particulates, total)
Chem F File
TWA (ppm)
Vol. (liter)
CLG/STEL (ppm)
CLG/ STEL
TWA
Rate (ml/min) TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
2000 2500
8 2.5
XRF
NIOSH 0600 1038
480 375
NIOSH 0500 1035
120
2000
1
GR
F/CST FLT CYC FLT CST FLT CYC FLT CST ST BS CST SCN C/HLD ST ST ST
GR
225-3-01 225-8-01 225-01-02 225-8-01 225-2LF 225-8-01 225-105 225-8-01 225-3LF 226-30-16 225-9595 225-2LF 225-26 225-1 226-81A 226-01 226-170
77 73 95 73 86 73 94 73 86 35 105 86 87 87 36 35 38
225-2705 225-01-02
FLT CYC ST ST F/CST BI F/CST ST ST PUF ST F/CST F/CST F/CST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST ST CAN ST ST PS ST ST ST ST ST ST PS CAN ST ST
Emery (respirable dust)
OSHA CSI
5 mg/m3
varies
varies
varies
GR
Emery (total dust)
OSHA CSI
15 mg/m3
960
2000
8
GR
1000 12500 + 1000
1 5-30 4
GC-ECD
0.1 mg/m3
60 62.5-375 240
12 10 90-720
50 20 1500
4 8 1-8
GC-FID
ASTM D 5955 1419
varies
varies
varies
GR & FLT HPLC-UV & CYC HPLC-FD
ASTM D 6271
1503600 10 20 120 141.5 480 480 10
2500
1-24
HPLC-UV
Endosulfan (Thiodan) Endotoxins (bacteria in air) Endrin
OSHA PV2023 NON 48 NIOSH 5519
Enflurane (ethrane) Enflurane (ethrane) Environmental tobacco smoke (nicotine & 3-ethenylpyridine) Environmental tobacco smoke (respirable particles) Environmental tobacco smoke (solanesol, respirable particles) Epichlorohydrin Epichlorohydrin Epicoccum species (fungi, molds, spores) Epicoccum species (fungi, molds, spores) EPN EPN 1,2-Epoxyethylbenzene 1,2-Epoxypropane (see propylene oxide) 2,4,D-Esters Esters I (see specific compounds) Estradiol Estriol Estrone 1,2-Ethanediol (ethylene glycol) (glycols) 1,2-Ethanediol dinitrate 2-(2-methoxyethoxy)Ethanol Ethanolamine 3-Ethenylpyridine 3-Ethenylpyridine & nicotine Ethion (nialate) Ethion (organophosphorus pesticides) Ethoprop (organophosphorus pesticides) 1-Ethoxy-2-propanol 2-Ethoxyethanol (alcohols IV) 2-Ethoxyethanol (CELLOSOLVE solvent) 2-Ethoxyethanol (CELLOSOLVE solvent) (alcohols IV) 2-Ethoxyethyl acetate (CELLOSOLVE acetate) 2-Ethoxyethyl acetate (esters I) Ethrane (enflurane) Ethyl 2-cyanoacrylate Ethyl acetate Ethyl acetate Ethyl acrylate Ethyl acrylate Ethyl acrylate (esters I) Ethyl alcohol (ethanol) Ethyl alcohol (ethanol) Ethyl alcohol (ethanol) (alcohols I) Ethyl amyl ketone Ethyl benzene Ethyl benzene Ethyl benzene Ethyl benzene Ethyl benzene (hydrocarbons, aromatic) Ethyl bromide (bromoethane) Ethyl bromide (bromoethane) Ethyl butyl ketone (3-heptanone) Ethyl butyl ketone (3-heptanone) (ketones II ) Ethyl butyl ketone (3-heptanone) (ketones II) Ethyl CELLOSOLVE solvent (2-ethoxyethanol) Ethyl chloride Ethyl chloride Ethyl chloride
OSHA 103
1348
OSHA 29 NON 49
NIOSH 1010 OSHA 07
LFC 1112 5
OSHA CSI OSHA CSI
0.5 mg/m3 0.5 mg/m3
NIOSH 5012 OSHA CSI OSHA CSI
3
20(50) 100 1000 28,300 1000 1000 20(50)
200
8(3.3) 3.3 2 5 min 8 8 8(3.3)
varies GC-ECD
GC-FID GC-NSD
15
GC-FID GC-FID varies varies GC-FPD GC-FPD GC-FID
225-1 225-1 225-3LF 225-1
87 87 86 87
C/HLD CST C/HLD
225-1 225-3LF 225-1
87 86 87
VT ◊ FLT ST
225-9598A 225-5 226-104
105 76 37
74 95
C/HLD CST
225-1 225-3LF
87 86
225-2705 225-01-02 226-01 226-01 225-3-01 225-9611 225-709 226-30-16 226-35
74 95 35 35 77 103 79 35 35
CST C/HLD
225-3LF 225-1
86 87
C/HLD
225-1
87
C/HLD
225-1
87
226-92 226-01 225-706 225-706 225-706 226-57 226-35-03 226-01 226-30-18 226-170 226-93 226-30-16 226-58 226-58 226-01 226-01 226-01 226-01 226-01 226-01 226-01 226-98 226-01 226-01 226-81A 226-73 226-01 226-01 226-82 226-01 226-01 228 Series 226-01 226-01 575-002 226-01 226-01 226-01 226-01 NA SKC 226-01 575-001 228 Series 226-25 226-01
42 35 79 79 79 36 36 35 35 38 37 35 36 36 35 35 35 35 35 35 35 37 35 35 36 36 35 35 37 35 35
C/HLD C/HLD C/HLD
225-1 225-1 225-1
87 87 87
PK
228 Series
PK
228 Series
240-7200 1-10 240 60 60 24
ASTM D 4861
varies
NIOSH 1450 OSHA PV2001 OSHA PV2001 OSHA PV2001 NIOSH 5523 1401
0.2 (C)
OSHA 43 OSHA CSI
3
OSHA PV2111 NON 49 ASTM D 5075 1427 OSHA CSI
0.4 mg/m
NIOSH 5600
3
NIOSH 5600 OSHA CSI
NIOSH 1403 1273 0.5 (skin)
1277 200 NIOSH 1403 1273 0.5 (skin) OSHA 79 1277 100 NIOSH 1450 0.5 (skin) OSHA 79
OSHA 29 OSHA 55
NIOSH 1457 OSHA 07
1111
NON 54 OSHA 92 NIOSH 1450 OSHA 07 OSHA 100
1109 1283
NIOSH 1400 OSHA 07
1158
400 400 5 25 4 (LOQ) 1000 1000 1000 25
15
ASTM D 5466
1108 OSHA 1002 1746 OSHA 1002 1746 NIOSH 1501 1053 OSHA 07
100 100 100 100
NIOSH 1011
1107 200 OSHA 07 1106 50 NIOSH 2553 50 NIOSH 1301 50 OSHA 07
125
1000-5000 varies 1000 1000 1000 100 15
6 10 90-720 90-2160 480 240 240 48 1-6 48 1-6 48 1-10 10 12 10 5 10 12 1-10 1 12 1 10 6 10 12 1-24 4 5 10 1-25 24
1.5
15 15
3 0.75
3
1-24 3
4-24 varies 4 1 1 4 1000
100 100 1500 1500 1000 1000 1000 100 10-50 100 10-50 100 10-200 100 100 20 20 20 50 10-200 50 50 50 20(50) varies 20(50) 50 13.83 10-200 20 20 20(50) 10-200 200
100
1000 1000
200 50
200
10-200 200
GC-ECD GC-FID HPLC-UV HPLC-UV HPLC-UV GC-FID
15 1 100 min 1-8 1-24 8 4 4 8 varies 8 varies 8 varies 1.6 2 8 4 8 4 varies 20 min 4 20 min 8(3.3) varies 8(3.3) 4 8 varies 3.3 4 8(3.3) varies 2
HPLC-TEA GC-FID
15
HPLC-UV GC-NSD GC-NPD GC-FPD GC-FPD GC-FPD GC-FID GC-FID
15
GC-FID GC-FID
15
GC-FID GC-FID GC-FID HPLC-UV GC-FID GC-FID
15 15
GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-MS
15
GC-FID GC-FID GC-FID
varies
GC-FID GC-FID
15
GC-FID GC-FID GC-FID GC-FID
GC-FID ASTM D 5466 NIOSH 2519 OSHA 07
1000
6 3 3
varies 50 50
varies 1 1
GC-MS GC-FID GC-FID
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
SKC Inc.
E
C/HLD C/HLD CST C/HLD
Phone: +1-724-941-9701
35 35 64 35 35 35 35 35 64 35 35
References and abbreviations are found on pages 196-197.
www.skcinc.com
155
Sampling Guide SAMPLING ∞
www.skcinc.com for updates E
Chemical Hazard
Ethyl ether (diethyl ether) Ethyl ether (ethyl ether) Ethyl formate Ethyl formate Ethyl lactate Ethyl mercaptan Ethyl mercaptan (mercaptans) Ethyl methacrylate Ethyl methacrylate Ethyl O-(p-nitrophenyl) phenylphosphonothionate (EPN) Ethyl parathion Ethyl propionate Ethyl silicate Ethyl tert-butyl ether (tert-butyl ethyl ether) Ethyl vinyl benzene Ethyl-3-ethoxypropionate Ethylamine Ethylene Ethylene chlorohydrin Ethylene chlorohydrin Ethylene dibromide (1,2-dibromoethane) Ethylene dibromide (1,2-dibromoethane) Ethylene dichloride (1,2-dichloroethane) Ethylene dichloride (1,2-dichloroethane) (hydrocarbons, halogenated) Ethylene glycol (glycols) Ethylene glycol dinitrate Ethylene glycol dinitrate (nitroglycerine) Ethylene glycol isopropyl ether (isopropyl CELLOSOLVE solvent) Ethylene glycol monohexyl ether Ethylene oxide Ethylene oxide Ethylene oxide Ethylene oxide Ethylene oxide (by portable GC) Ethylene oxide (Qazi-Ketcham) Ethylene thiourea Ethylene thiourea Ethylenediamine Ethylenediamine Ethylenimine 2-Ethylhexanol Ethylhexyl acetate 2-Ethylhexyl acrylate di-2-Ethylhexyl phthalate (DEHP) N-Ethylmorpholine ETS (see environmental tobacco smoke) Exserohilum species (fungi, molds, spores) Exserohilum species (fungi, molds, spores) Fenamiphos Fenamiphos (organophosphorus pesticides) Fenarimol Fensulfothion (Dansanit) Fenthion Fenvalerate Ferbam Ferric chloride (see iron salts, soluble as Fe) Ferrovanadium dust
Passive Guide
Agency Standard
Agency Reference
Chem F File
OSHA 07
1105 400
CLG/STEL (ppm)
NIOSH 1452 OSHA 07
100 1104 100
OSHA PV2081
Rate (ml/min)
CLG/ STEL
TWA
3 0.25-3 10 10 10
NIOSH 1610
3
10 (C) 120 NIOSH 2542 1330 0.5 (15 min) 48 12 NIOSH 2537 1-8 OSHA PV2100 10 NIOSH 5012 0.5 mg/m3 480 ASTM D 4861 240-7200 OSHA CSI 10 OSHA CSI 100 9
TWA
20 10-200 20 20(50) 200
OSHA CSI
100 10-50 20(50) 1000 1000-5000 20(50) 50
Time
CLG/ STEL
200
1000 200
TWA (hrs)
2.5 varies 8 8(3.3) 50 min 8 varies 8(3.3) 8 4-24 8(3.3) 3
CLG/STEL (ppm)
15
OSHA PV2025
10
OSHA 36
GC-FID GC-FID GC-FID
120 60
1
10 20 0.13 (15 min) 10 30 10 100 10 2 3
1159 5 NIOSH 1008 0.045 OSHA 02 1072 20 OSHA 03 1063 50 NIOSH 1003 1 NIOSH 5523 1401
50 100 200
NIOSH 2507
ASTM D 5578
0.1 1751 1 NIOSH 3702 1031 0.1 NIOSH 1614 OSHA 1010 NON 14
LFC
NIOSH 5011 OSHA 95
10 1287 10
NIOSH 3514 OSHA CSI OSHA CSI OSHA PV2026 OSHA 104 OSHA CSI
5 mg/m3 20
20(50) 40 20(50) 20(50) 200 10-200
GC-FID GC-FPD GC-NPD GC GC-FID
4 100 min 50 min
200 200 200 200 10-200
1000 15 15
10 6 9.6 5 (10 min) 24 5.0 EL 12 5 (10 min) varies 10 480 480 10 10 48 48 10 12 240 10
OSHA CSI ASTM D 4413
OSHA 60
3 1 3 3
9
OSHA CSI
NIOSH 2540
3
60 0.2 (C) 0.1 mg/m3
OSHA 43
GC-FID GC-FID HPLC-UV
200 100 20 100 50 20-4000 20(50) 2000 2000 100 100 200 200 20(50) 100 1000 20(50)
15
50 min 1 8 4 4 varies 8(3.3) 4 4 1.7 100 min 4 4 8(3.3) 2 4 8(3.3)
GC-ECD GC-ECD GC-ECD GC-FID GC-FID
15 15 1.5
200 100 150 50 varies
GC-FID GC-FID
15 5 15 varies
1 1000 1000
100
3 1.5 1.5 0.75 varies
8(3.3) 8 8(3.3) 8(3.3) 1 varies
HPLC-TEA GC-ECD GC-FID GC-FID
15 15 10 15 varies
GC-FID GC-ECD GC-ECD GC-ECD P GC-PID GC VAS HPLC-UV HPLC-UV HPLC-UV HPLC-UV GC-FID GC-FID GC-FID GC-FID GC-FID
ST ST ST ST ST CF/CST CF/CST ST ST F/CST PUF ST ST PS ST ST ST DT DT ST ST ST ST ST ST
226-01 226-01 226-01 226-01 226-01 225-9007 225-9007 226-30-06 226-01 225-709 226-92 226-01 226-30-04 575-001 226-73 226-01 226-96 800-28051 800-01331 226-81A 226-81A 226-01 226-01 226-01GWS 226-01
35 35 35 35 35 61 61 35 35 79 42 35 35 64 36 35 37 or or 36 36 35 35 35 35
ST ST ST ST
226-57 226-35-03 226-35-03 226-01
36 36 36 35
ST ST ST ST ST SB ST F/CST F/CST ST ST IMP ST ST ST ST ST
226-01 226-16 226-178 226-178 226-178 232 Series 226-36 225-802 225-706 226-30-18 226-30-18 225-36-2 226-01 226-01 226-73 226-56 226-10
35 or 38 38 38 50 36 73 79 35 35 59 35 35 36 36 35
F/CST BI ST ST ST ST ST PUF ST
C/HLD C/HLD
225-1 225-1
87 87
C/HLD
225-1
87
DT DT
810-172 810-172L
or
ST
226-36
36
C/HLD C/HLD
225-1 225-1
87 87
IT
225-22
59
225-3-01 225-9611 226-30-16 226-58 226-30-16 226-30-16 226-30-16 226-92 226-30-16
77 C/HLD 103 35 36 35 35 35 42 35
225-1
87
F/CST C/HLD STC
225-3-01 225-1 225-9820
or 87 81
F/CST
225-3100
77
FLT CYC FLT CST F/CST
225-8-01 225-01-02 225-8-01 225-2LF 225-8204
73 95 73 86 73
C/HLD CST C/HLD
225-1 225-3LF 225-1
87 86 87
C/HLD
225-1
87
IMP PUF F/CST PUF
225-36-2 226-92 225-706 226-131
59 42 79 43
IT
225-22
59
C/HLD FLT
225-1 225-1821
87 79
F/CST C/HLD
225-1713 225-1
74 87
ST
226-30-04
35
NON 49 OSHA CSI OSHA CSI OSHA CSI NIOSH 5600
0.1 mg/m3
OSHA CSI OSHA CSI OSHA CSI ASTM D 4861 OSHA CSI
15 mg/m3
120 141.5 480 240 30 480 480 240-7200 480
1000 28,300 1000 1000 1000 1000 1000 1000-5000 1000
2 5 min 8 4 30 min 8 8 4-24 8
varies varies GC-FPD GC-FPD HPLC-UV GC-FPD GC-FPD HPLC-UV HPLC-UV
OSHA ID 121 OSHA ID 125G 1218 1 mg/m3
NIOSH 0600 1038
Fibrous glass (particulates, total)
NIOSH 0500 1035
480
30
2000
2000
4
15
ICP-AES
15-150
15000
1-10 min
varies
375
2500
2.5
GR
120
2000
1
GR
960
2000
8
GR
1000 1000-5000 2000 225 L/min
2 4-24 8 1-24
ISE
ASTM D 6209
120 240-7200 960 350 m3 (max)
NIOSH 5515
480
2000
4
GC-FID
OSHA CSI
15 mg/m
3
OSHA CSI OSHA CSI ASTM D 4861 OSHA CSI
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000.
156
GC-FPD
DET TB
OSHA 07
GC-FPD GC-FID
OSHA CSI NIOSH 2513
GC-FID
GC-FID 12 10 10
OSHA 89
Analytical Method SKC Collecting Equipment & Page Number GC-FID
Fibers (bioaerosols) Fibers (see specific compounds) Fibrous glass (particulates, respirable)
Fibrous glass dust Flax dust (see dust, total & respirable nuisance) Fluoboric acid Fluometuron Fluoranthene Fluoranthene (polynuclear aromatic hydrocarbons by GC-MS) Fluoranthene (polynuclear aromatic hydrocarbons by GC)
TWA (ppm)
Vol. (liter)
www.skcltd.com
HPLC-UV HPLC-UV GC-MS
References and abbreviations are found on pages 196-197.
SKC Ltd.
Phone: +44 (0)1258 480188
Sampling Guide SAMPLING ∞ Agency Standard Passive Guide
Chemical Hazard
Fluoranthene (polynuclear aromatic hydrocarbons by HPLC) Fluorene Fluorene (polynuclear aromatic hydrocarbons by GC-MS) Fluorene (polynuclear aromatic hydrocarbons by GC)
Agency Reference
Chem F File
TWA (ppm)
CLG/ STEL
TWA
Rate (ml/min) TWA
www.skcinc.com for updates
Time
CLG/ STEL
TWA (hrs)
CLG/STEL (ppm)
Analytical Method SKC Collecting Equipment & Page Number
2000
4
HPLC-FD
2000 225 L/min 2000
8 1-24 4
HPLC-UV
NIOSH 5515
960 350 m3 (max) 480
NIOSH 5506
480
2000
4
HPLC-UV
OSHA CSI ASTM D 6209
ASTM D 5197 1442
Formaldehyde Formaldehyde Formaldehyde (aldehydes, screening)
0.75 1020 0.75 NIOSH 2539 0.016
Formic acid Freon 11 Freon 113 Freon 113 (1,1,2-Trichloro-1,2,2-trifluoroethane) Freon 114 Freon 12 Freon 123 Freon 141b Fumarin Fungi Fungi (in air) Fungi (in air) (BioSampler method) Furans (including PHDFs, PCDFs, PBDFs) (see Environmental Sampling Guide) Furfural Furfural Furfural (aldehydes, screening)
Vol. (liter)
480
NIOSH 5506
Fluorene (polynuclear aromatic hydrocarbons by HPLC) Fluorides Fluorides (aerosol & gas by ISE) Fluorides (as F) Fluorine Fluorotrichloromethane (trichlorofluoromethane) 5-Fluorouracil Folpet Fonofos (dyfonate) Fonofos (organophosphorus pesticides) Formaldehyde Formaldehyde Formaldehyde Formaldehyde
Formaldehyde (see Environmental Sampling Guide) Formaldehyde (see Environmental Sampling Guide) Formaldehyde (see Environmental Sampling Guide) Formaldehyde on dust (textile or wood) Formamide Formetanate (organonitrogen pesticides) Formic acid
CLG/STEL (ppm)
ASTM D 4765 1421 NIOSH 7902 1226 2.5 mg/m3 6 (HF) OSHA ID 110 1227 2.5 mg/m OSHA CSI
3
0.1 1000
NIOSH 1006
NIOSH 3500
0.016
OSHA 1007 OSHA 52
varies 8 1 8
20
ISE
15 15
ISE ISE ISE
240
GC-FID HPLC-UV
0.1 (C) 0.1 (C) 0.1
2 2 0.1
13.8 24 5
28.6 100 20
8 4 4
HPLC-UV
0.1
240 10 240 24
3
NIOSH 2541 1015 0.016
5
1500 1500
3 4-24 8 4 5 min-24 hrs varies varies 4 10 8 15
OSHA PV2027
NIOSH 2016 1761 0.016
2000 1000 1500 1000
1000 1000-5000 1000 1000 500-1200 30-500 30-500 100 100 200 1000
ASTM D 4861
0.1 mg/m
22.5 22.5
GC-FID
180 240-7200 480 240 varies 1-
