South River Mercury TMDL: Study Goals

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South River Mercury TMDL Study

Jack Eggleston

South River Mercury TMDL: Study Goals



Characterize cycling of total mercury and methyl mercury



Develop mathematical models for simulating surface water flows and methyl mercury production and transport



Determine loading reductions needed to achieve fish tissue Hg levels of less than 0.5 ppm

South River Mercury TMDL :

Study Area

Grottoes

>!

Crimora

SOUTH RIVER AT HARRISTON, VA 01627300

Dooms

Waynesboro

>!

SOUTH RIVER NEAR WAYNESBORO VA, 01626000

Mass Balance of Total Mercury

Runoff to river Direct Atmospheric Deposition

Losses to Atmosphere

Tributary Contributions South River Sediment deposition/suspension Point Sources

Downstream Losses

Groundwater Discharge to river

Mass Balance of Methyl Mercury

Net Methylation of Hg in Water Column Tributary Contributions

Volatilization

Bioavailable Mercury (MeHg) in Water Column

Net Sedimentation of MeHg

Porewater MeHg Net Inflow

Downstream Losses

Streamflow Monitoring 2 Existing Continuous Stations Waynesboro, 01626000 1952-present

Harriston, 01627300 1925-present

1 New Periodic Station Dooms

Continuous WQ Monitoring – Proposed Locations Waynesboro Dooms

Harriston

Continuous Stream WQ Monitoring Equipment Sensors In the James River at Cartersville

Out of Water

Mercury Loading Rate – Example Calculation Hurricane Jeanne - September 28, 2004 Streamflow and Mercury Concentrations at Harriston Streamflow (cfs)

14000

8,000

Measured [Hg] (ng/l)

Streamflow (cfs)

7,000 6,000

10000

5,000 8000 4,000 6000 3,000 4000

2,000

2000 0 12:00

Total Mercury Concentration (ng/l)

Estimated [Hg] (ng/l)

12000

1,000

16:00

20:00

0:00

4:00

8:00

0 12:00

Time (Hours from noon 9/28 to noon 9/29)

Mercury Flux Thanks to Ted Turner for outstanding data collection and help.

= (Concentration x Flow) = 46 kg over 19 hours

Flow of this magnitude (6500 daily cfs) has an average recurrence interval of 4 years

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