Elvacite® 2008 Acrylic Resin Acrylic Resin Elvacite® 2008 is a low molecular weight methylmethacrylate copolymer. It is used in lacquers, gravure inks, and vinyl topcoats requiring low viscosity at high solids. Elvacite® 2008 has methacrylic acid incorporated for pigment dispersions.
Typical Properties & Manufacturers Release Specifications Typical Propertiesa of Elvacite® 2008 Appearance
Solid bead
Specific Gravity, 25° C
1.18
Glass Transition Temp, onset
111°C
Molecular Weight (Mw)
37,000
Particle Size (D50)
140-240 microns
Acid Number
9
Elongation at break (23°C, 50% RH)
0.5%
Packaging
125 kg (275 lb net), non-returnable fiber drums
a) Typical physical properties listed are approximate values and should not be considered manufacturers release specifications. Manufacturers release specifications are subject to change without notice, please contact your Lucite International Representative for the latest product specification details.
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 1
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Elvacite® 2008 Manufacturers Release Specificationsb Inherent Viscosityc
0.172 – 0.194
% Moisture (max)
0.5
b) c)
Manufacturers release specifications are subject to change without notice. Please contact Lucite International, Inc. for the latest information. Inherent viscosity of a solution containing 0.25 g polymer in 50 ml of methylene chloride measured at 20°C using a No. 50 Cannon-Fenske viscometer
Preparing Solutions Elvacite® resins dissolve at room temperature but require constant agitation to prevent solvent-swollen granules of polymer from forming agglomerates and sticking to the walls of the vessel. Important: The polymer beads should be sifted directly into the vortex of the stirred solvent to speed wetting-out and dispersion. Continuous lowshear agitation for periods of 1-12 hours, depending on the grade and concentration of resin, is recommended. After the solution appears clear in the tank, a sample should be spread out on a Leneta card or glass. After the solvent evaporates and a film forms on the card or glass, there should not be any resin seeds. If there are any seeds, the tank should be agitated further to fully dissolve the resin. Tank agitation should not be stopped (except for sampling) until the film test indicates there are no resin seeds. Any cloudiness or residue may indicate that some polymer remains undissolved. The presence of water in the system can also cause cloudiness. Solution time can be reduced by heating; most common solvents can be heated to approximately 49°C (120°F) without the need for reflux equipment. High-shear agitation also cuts dissolving time, but requires care to avoid overheating and excessive solvent loss.
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 2
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Solvent Solubility Table below depicts the solubility of Elvacite® 2008 at 20% solids in various solvents. (S=Soluble, C=Cloudy solution, I=Insoluble) Alcohols Methyl Alcohol Isopropyl alcohol Ethylene glycol
I I I
Ethyl Alcohol Isoamyl alcohol Glycerol
I I I
n-propyl alcohol Cyclohexanol
I I
Ethylene dichloride
S
Perchloroethylene
C
S S
Ethyl acetate n-Amyl acetate
S C
Isopropyl acetate Butyl lactate
S S
S
Methyl amyl acetate I
Amides Formamide I Dimethyl formamide S Chlorohydrocarbons Methylene Chloride S 1,1,1-Trichloroethane I Esters Methyl Formate n-Butyl acetate Propylene glycol monoethyl ether acetate
Ethers Diethyl Ether I “Cellosolve” Solvent C
Diisopropyl ether
I
Tetrahydrofuran (THF)
S
Hydrocarbons Toluene Cyclohexane Turpentine
C I I
Xylene VM & P Naphtha
I I
n-Hexane Mineral Spirits
I I
Ketones Acetone Diisobutyl ketone Diacetone Alcohol
S I C
Methyl Ethyl Ketone S Cyclohexanone I Methyl amyl ketone I
Methyl Isobutyl Ketone Isophorone
C I
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 3
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Solvent Solubility (cont’d) Nitrile Acetonitrile Nitromethane
S S
Nitroparaffins Nitroethane
S
Vegetable Oils Castor oil
I
Linseed oil (alkali-refined)
I
Viscosity Elvacite® 2008 is a low molecular weight methyl methacrylate copolymer. Table II illustrates typical viscosities of Elvacite® 2008 by varying both solvent and resin concentration.
Table II: Elvacite® 2008 Viscosity (cP) Concentration (% Solids) Solvent Methyl Ethyl Ketone Toluene Isopropyl Acetate Cellosolve Solvent
Technical Data Sheet
20%
30%
40%
24 20 20 100
425 100 175 1200
2000 3000 12000
Elvacite® 2008 v20131209
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Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Resin Compatibility Elvacite® 2008 is compatible with the following Elvacite® Resin Grades: 2009, 2010, 2021, 2041 and 2013. It is also compatible with the other types of resins, as illustrated in the following table: Blending Resin Alkyd Aroplaz 1271 Aroplaz 1351 Chempol 13-1410 Paraplex RG-2 Plaskon 3105 Cellulosic Cellulose acetate 39-5-5B
Long linseed drying oil Long castor nondrying oil Safflower drying oil, acrylate mod. Nondrying oil, sebacic Short coconut nondrying oil
30% in MEK MEK/alcohol soln. 100% Resin
Epon 1001
Hypalon 30 Neoprene AC-Soft Rosin Derivatives Ester Gum 8L Pentalyn 255
Elvacite / Blending Resin (by solids weight) 75/25 50/50 25/75 30% in MEK Spencer Kellogg I I H 30% in MEK Spencer Kellogg C H H 50% in Xylene Freeman I I Chemical 30% in MEK Rohm & Haas I I I Co. 60% in Xylene Cargill, Inc. --H H 30% in Acetone or MEK 30% in MEK
Cellulose Acetate Butyrate, ½ - sec. Ethyl Cellulose N-7 Nitrocellulose “RS”, ½-sec Isopropyl Epoxy Epon 828
Elastomers EMD-504
Form of Blended Resin Tested
Description
30% in MEK
Polyisobutylene Chlorosulfonated polyethylene Polychloroprene
Pentaerythritol ester
Technical Data Sheet
Supplier
Hercules Inc.
Eastman Chemical Hercules Inc. Hercules Inc.
Shell Chemical Co. Shell Chemical Co.
30% in Toluene 15% in Toluene 15% in Toluene
Exxon Chemical
30% in MEK 30% in MEK
Hercules Inc. Hercules Inc.
Dupont Polymers Dupont Polymers
Elvacite® 2008 v20131209
I
I
I
C
C
C
I
I
I
C
C
C
C
---
C
C
C
C
I
I
I
I
I
I
I
I
I
H H
I H
I H
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Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Pentalyn 830 Pentaerythritol ester Vinyl Chloride Resins Bakelite VAGH Copolymer Bakelite VMCH Copolymer Bakelite VYHH Copolymer Bakelite VYNS Copolymer Exon 450 Copolymer
30% in MEK
Hercules Inc.
H
H
H
30% in MEK 30% in MEK 30% in MEK 15% in MEK 15% in MEK
C C C C C
C C C C C
C C C C C
Exon 9290
Homopolymer
15% in THF
C
C
C
Geon 103 EP Other Types Arochem 650 Aroset 4110 Dammar
Homopolymer
15% in THF
Union Carbide Union Carbide Union Carbide Union Carbide Firestone Plastics Firestone Plastics B.F. Goodrich
C
C
C
Spencer Kellogg Spencer Kellogg
C C H
C H I
C H H
Dow Corning Corp. Hercules Inc. Hercules Inc. Monsanto Co.
C
C
C
I C C H
I I C I
I I C I
Reichold Chemicals Rohm & Haas Co.
C
C
C
I
I
I
DC-840 Parlon S 10 Piccoumaron Santolite MHP Shellac Super-Bechacite 2000 Uformite MX-61
Maleic-modified hard resin Acrylic resin
30% in MEK 30% in MEK 30% in Toluene Silicone resin 60% in Toluene Chlorinated rubber 30% in MEK Coumarone-indene resin 30% in MEK Sulfonamide-formaldehyde 30% in MEK 30% in Methanol Permanently fusible phenolic 30% in MEK Triazine-formaldehyde resin
30% in MEK
(C=Clear solution, H=Hazy solution, I=Insoluble)
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 6
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Plasticizer Compatibility Elvacite® 2008 is compatible at a 50/50 resin/plasticizer ratio with the following plasticizers: Dibutyl phthalate, Di-(2-ethylhexyl) azelate, Santicizer 8 (N-ethyl toluene sulfonamides), Santicizer 97 (dialkyl adipate), Santicizer 160 (butyl benzyl phthalate), Santicizer 261 (isooctyl benzyl phthalate), Santicizer 278 (benzyl phthalate), Santicizer B-16 (butyl phthalyl butyl glycolate), and Tricresyl phosphate. It is compatible at a 90/10 resin/plasticizer ratio, but incompatible at 50/50 with: Abalyn (methyl abietate), Dibutyl sebacate, Hercoflex 600 (pentaerythritol ester), and Hercoflex 707 (polyol ester). It is incompatible with Resoflex R-296 (alkyd) at a 90/10 resin/plasticizer ratio.
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 7
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
Typical Formulation The following formulation is given as a starting point only. The final formulation will be determined by the coating properties desired.
Barrier Coating for Polystyrene Based on Elvacite® 2008 (#C1-7) Ingredients Elvacite® 2008 Alcohol Soluble Butyrate Toluene Methyl Ethyl Ketone n-Heptane Isopropyl Alcohol, 99% Methyl Amyl Ketone „Ti-Pure‟ R-900 Yellow Iron Oxide, LL.YLO-1788
PVC, % by Wt Solids, % by Wt Solids, % by Vol
% by Wt 9.23 9.23 24.17 9.38 16.12 16.12 8.06 6.59 1.10 100.00 10.70 26.20 16.10
Preparation: Dissolve Elvacite® 2008 in ½ of the prescribed solvent blend; dissolve alcohol-soluble butyrate in remaining solvent blend and combine (Note: mixture may be hazy). Add pigments and disperse.
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 8
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
COMPLIANCE WITH FDA REGULATIONS Lucite International confirms Elvacite® 2008 complies with the compositional requirements of the following United States of America‟s Food and Drug Administration (FDA) regulations. 1. FDA 21 CFR 175.105 for adhesives used as components of articles intended for use in the packaging, transporting, or holding food. 2. FDA 21 CFR 175.300 in resinous and polymeric coatings used as the food contact surface of articles intended for use in producing, packing, processing, preparing, treating, packaging, transporting, or holding food. The coating in its finished form in which it is to contact food is subject to a restriction on its chloroform soluble extractives. Compliance with the limitation on extractives can only be demonstrated by tests carried out in the final article. 3. FDA 21 CFR 175.320 in resinous and polymeric coatings for polyolefin films, provided it is intended for repeated food contact use as specified in FDA 21 CFR 175.300(a). The coating in its finished form in which it is to contact food is subject to a restriction on its chloroform soluble extractives. Compliance with the limitation on extractives can only be demonstrated by tests carried out in the final article. 4. FDA CFR 176.170 as a component of the uncoated or coated food contact surface of paper and paperboard intended for use in producing, manufacturing, packing, processing, preparing, treating, packaging, transporting or holding aqueous and fatty foods. 5. FDA 21 CFR 176.180 as a component of the uncoated or coated food contact surface of paper and paperboard intended for use in producing, manufacturing, packing, processing, preparing, treating, packaging, transporting, or holding dry food. 6. FDA 21 CFR 177.1010 as semi-rigid and rigid acrylic plastics articles intended for use in contact with food. This product is limited to use only in plastic articles intended for repeated use in contact with food. The semi-rigid and rigid acrylic plastics in the finished form in which they are to contact food are subject to limitation on extractives. Compliance with the limitation on extractives can only be demonstrated by tests carried out on the final article. This statement of compliance is correct at the date of issue. As food contact regulations and product formulations are subject to change, it is the user’s responsibility to ensure that they are in possession of a current statement of compliance. Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control.
Date of Issue: February 2009
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 9
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.
The Lucite Center 7275 Goodlett Farms Parkway Cordova, TN 38016 USA T: +1 (901) 381 2000 www.luciteinternational.com/resins Lucite International Specialty Polymers and Resins Ltd Horndale Avenue Newton Aycliffe DL5 6YE United Kingdom T: +44 (0) 1325 300990 F: +44 (0) 1325 314925 www.luciteinternational.com/resins
Technical Data Sheet
Elvacite® 2008 v20131209
Page: 10
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.