Elvacite® 2013 Acrylic Resin - Lucite International

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Elvacite® 2013 Acrylic Resin Acrylic Resin Elvacite® 2013 is a low molecular weight methyl methacrylate/n-butyl methacrylate copolymer. It is a fast-dissolving, low viscosity grade with quick solvent release for use in industrial lacquers, aerosols, inks, and coatings for plastics. Elvacite® 2013 is softer than the methyl methacrylate grades.

Performance Features and Key Benefits  



Fast dissolving grade for use in aerosols, industrial lacquers, inks, and coatings Low viscosity Fast solvent release

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 1

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Typical Properties & Manufacturers Release Specifications Typical Propertiesa of Elvacite® 2013 Appearance

Solid bead

Specific Gravity, 25° C

1.15

Glass Transition Temp, onset

76°C / 168.8°F

Molecular Weight (Mw)

34,000

Particle Size (D50)

160-200 microns

Acid Number

5

Tensile Strength, psi

1,600

Elongation at break (23°C, 50% RH)

0.5%

Methacrylic Acid

0.55-0.75%

Packaging

136 kg (300 lb net), non-returnable fiber drums

a) Typical physical properties listed are approximate values and should not be considered manufacturers release specifications. Manufacturers release specifications are subject to change without notice, please contact your Lucite International Representative for the latest product specification details.

Elvacite® 2013 Manufacturers Release Specificationsb Inherent Viscosityc

0.156 – 0.174

% Moisture (max)

0.35

b) c)

Manufacturers release specifications are subject to change without notice. Please contact Lucite International, Inc. for the latest information. Inherent viscosity of a solution containing 0.25 g polymer in 50 ml of methylene chloride measured at 20°C using a No. 50 Cannon-Fenske viscometer

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 2

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Preparing Solutions Elvacite® resins dissolve at room temperature but require constant agitation to prevent solvent-swollen granules of polymer from forming agglomerates and sticking to the walls of the vessel. Important: The polymer beads should be sifted directly into the vortex of the stirred solvent to speed wetting-out and dispersion. Continuous lowshear agitation for periods of 1-12 hours, depending on the grade and concentration of resin, is recommended. After the solution appears clear in the tank, a sample should be spread out on a Leneta card or glass. After the solvent evaporates and a film forms on the card or glass, there should not be any resin seeds. If there are any seeds, the tank should be agitated further to fully dissolve the resin. Tank agitation should not be stopped (except for sampling) until the film test indicates there are no resin seeds. Any cloudiness or residue may indicate that some polymer remains undissolved. The presence of water in the system can also cause cloudiness. Solution time can be reduced by heating; most common solvents can be heated to approximately 49°C (120°F) without the need for reflux equipment. High-shear agitation also cuts dissolving time, but requires care to avoid overheating and excessive solvent loss.

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 3

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Solvent Solubility Table depicts the solubility of Elvacite® 2013 at 30% solids in various solvents.

Solubility of Elvacite® 2013 Solvent Toluene Acetone Methyl ethyl ketone Dimethyl carbonate Methyl isobutyl ketone n-Butyl acetate t-Butyl acetate Ethyl acetate n-Propyl acetate Methyl acetate 2-propanol Low odor mineral spirits

Solubility S S S S S S I S S S I I

Rating C C C C C C C C C -

(S = Soluble, H = Cloudy/hazy solution, C= Clear solution, I = Insoluble)

Viscosity The table below illustrates typical viscosities of Elvacite® 2013 in varying solvents at 30% solids.

Solvent

Viscosity (cP)

Acetone Toluene Methyl ethyl ketone Methyl isobutyl ketone Dimethyl carbonate Ethyl acetate Methyl acetate n-Propyl acetate

Technical Data Sheet

11.4 21.20 14.20 2.80 18.20 15.5 15.40 33.00

Elvacite® 2013 v20130613

Page: 4

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Resin Compatibility Elvacite® 2013 is compatible with the following Elvacite® Resin Grades: 2008, 2009, 2010, 2014, 2016, 2028, 2021, 2042, and 2043. It is also compatible with the other types of resins, as illustrated in the following table:

Blending Resin

Form of Blended Resin Tested

Description

Supplier

Alkyd

Elvacite / Blending Resin (by solids weight) 75/25 50/50 25/75

E 1271

Long linseed drying oil

30% in MEK

Spencer Kellogg

C

H

H

Aroplaz 1351

Long castor nondrying oil

30% in MEK

Spencer Kellogg

C

C

C

Chempol 13-1410

Safflower drying oil, acrylate modified

50% in Xylene

C

C

C

Paraplex RG-2

Nondrying oil, sebacic

30% in MEK

I

I

I

Plaskon 3105

Short coconut non-drying oil

60% in Xylene

---

H

H

I

I

I

C

C

C

Freeman Chemical Rohm & Haas Co. Cargill, Inc.

Cellulosic Cellulose acetate 39-5-5B Cellulose Acetate Butyrate, ½ - sec.

30% in Acetone or Hercules Inc. MEK Eastman 30% in MEK Chemical

Ethyl Cellulose N-7

30% in MEK

Hercules Inc.

I

I

I

Nitrocellulose “RS”, ½-sec Isopropyl

MEK/alcohol soln. Hercules Inc.

C

C

C

Epon 828

100% Resin

Shell Chemical

C

---

C

Epon 1001

30% in MEK

Shell Chemical

C

C

C

Epoxy

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 5

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Blending Resin

Form of Blended Resin Tested

Description

Supplier

Elastomers

Elvacite / Blending Resin (by solids weight) 75/25 50/50 25/75

EMD-504

Polyisobutylene

30% in Toluene

Exxon Chemical

I

I

---

Hypalon 30

Clorosulfonated polyethylene

15% in Toluene

Dupont Polymers

I

I

---

Neoprene AC-Soft

Polychloroprene

15% in Toluene

Dupont Polymers

I

I

---

30% in MEK

Hercules Inc.

---

H

H

Rosin Derivatives Ester Gum 8L Pentalyn 255

Pentaerythritol ester

30% in MEK

Hercules Inc.

H

H

H

Pentalyn 830

Pentaerythritol ester

30% in MEK

Hercules Inc.

H

H

H

Bakelite VAGH

Copolymer

30% in MEK

Union Carbide

C

C

C

Bakelite VMCH

Copolymer

30% in MEK

Union Carbide

C

C

C

Bakelite VYHH

Copolymer

30% in MEK

Union Carbide

C

C

C

Bakelite VYNS

Copolymer

15% in MEK

Union Carbide

C

C

C

Exon 450

Copolymer

15% in MEK

Firestone Plastics

C

C

---

Exon 9290

Homopolymer

15% in THF

Firestone Plastics

C

C

C

Geon 103 EP

Homopolymer

15% in THF

B.F. Goodrich

C

C

C

Arochem 650

Maleic-modified hard resin

30% in MEK

Spencer Kellogg

C

C

C

Aroset 4110

Acrylic resin

30% in MEK

Spencer Kellogg

C

C

C

I

I

H

Vinyl Chloride Resins

Other Types

Dammar

30% in Toluene

(S = Soluble, H = Cloudy/hazy solution, C= Clear solution, I = Insoluble)

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 6

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Plasticizer Compatibility Elvacite® 2013 is compatible at a 50/50 resin/plasticizer ratio with the following plasticizers: Dibutyl phthalate Di-(2-ethylhexyl) azelate Santicizer 8 (n-ethyl toluene sulfonamides) Santicizer 97 (dialkyl adipate) Santicizer 160 (butyl benzyl phthalate) Santicizer 261 (isooctyl benzyl phthalate) Santicizer 278 (benzyl phthalate) Santicizer B-16 (butyl phthalyl butyl glycolate) Tricresyl phosphate It is compatible at a 90/10 resin/plasticizer ration, but incompatible at a 50/50 with: Abalyn (methyl abietate) Dibutyl sebacate

Hercoflex 600 (pentaerythritol ester) Hercoflex 707 (polyol ester)

It is incompatible with Resoflex R-296 (alkyd) at a 90-10 resin/plasticizer ration.

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 7

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Typical Formulation The following formulation is given as a starting point only. The final formulation will be determined by the coating properties desired. Automotive Refinish Clear Lacquer (#B2-2) Ingredients Elvacite® 2013 CAB 381-2 Butyl Benzyl Phthalate Methyl Isobutyl Ketone Isopropyl Alcohol Toluene Methyl Amyl Ketone

Technical Data Sheet

% by Wt 24.10 8.05 8.05 14.96 5.97 35.26 3.61 100.00

Elvacite® 2013 v20130613

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Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

COMPLIANCE WITH FDA REGULATIONS Lucite International confirms that Elvacite® 2013 complies with the compositional requirements of the following United States of America’s Food and Drug Administration (FDA) regulations. 1. FDA 21 CFR 175.105 for adhesives used as components of articles intended for use in the packaging, transporting, or holding food. 2. FDA 21 CFR 175.300 in resinous and polymeric coatings used as the food contact surface of articles intended for use in producing, packing, processing, preparing, treating, packaging, transporting, or holding food. The coating in its finished form in which it is to contact food is subject to a restriction on its chloroform soluble extractives. Compliance with the limitation on extractives can only be demonstrated by tests carried out in the final article. 3. FDA 21 CFR 175.320 in resinous and polymeric coatings for polyolefin films, provided it is intended for repeated food contact use as specified in FDA 21 CFR 175.300(a). The coating in its finished form in which it is to contact food is subject to a restriction on its chloroform soluble extractives. Compliance with the limitation on extractives can only be demonstrated by tests carried out in the final article. 4. FDA CFR 176.170 as a component of the uncoated or coated food contact surface of paper and paperboard intended for use in producing, manufacturing, packing, processing, preparing, treating, packaging, transporting or holding aqueous and fatty foods. 5. FDA 21 CFR 176.180 as a component of the uncoated or coated food contact surface of paper and paperboard intended for use in producing, manufacturing, packing, processing, preparing, treating, packaging, transporting, or holding dry food. 6. FDA 21 CFR 177.1010 as semi-rigid and rigid acrylic plastics articles intended for use in contact with food. This product is limited to use only in plastic articles intended for repeated use in contact with food. The semi-rigid and rigid acrylic plastics in the finished form in which they are to contact food are subject to limitation on extractives. Compliance with the limitation on extractives can only be demonstrated by tests carried out on the final article. This statement of compliance is correct at the date of issue. As food contact regulations and product formulations are subject to change, it is the user’s responsibility to ensure that they are in possession of a current statement of compliance. Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Date of Issue: February 2009

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 9

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.

Lucite International Inc. The Lucite Center 7275 Goodlett Farms Parkway Cordova, TN 38016 USA T: +1 (901) 381 2000 www.luciteinternational.com/resins Lucite International Specialty Polymers and Resins Ltd Horndale Avenue Newton Aycliffe DL5 6YE United Kingdom T: +44 (0) 1325 300990 F: +44 (0) 1325 314925 www.luciteinternational.com/resins

Technical Data Sheet

Elvacite® 2013 v20130613

Page: 10

Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to guarantee its accuracy or to accept responsibility in respect of factors outside our knowledge or control. Freedom under patent, copyright and registered designs cannot be assumed. Users of this product should consult the relevant Material Safety Data Sheet. Elvacite®, Lucite® and Colacryl® are registered trademarks of Lucite International. Lucite International Speciality Polymers and Resins Ltd is a wholly owned subsidiaries of the Lucite International Group.